Opening of Bids - Water Treatment Chemicals 2017-2018 - Chemrite, Inc.

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6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep upwind. Do not touch damaged containers or spilled protective equipment and material unless wearing appropriate protective clothing. Avoid inhalation of vapors and contact with emergency procedures skin and eyes. Wear protective clothing as described in Section 8 of this safety data sheet. Local authorities should be advised if significant spillages cannot be contained. Methods and materials for Keep combustibles (wood, paper, oil, etc.) away from spilled material. Should not be released into containment and cleaning up the environment. This product is miscible in water. Stop leak if possible without any risk. Dike the spilled material, where this is possible. Clean up spills immediately by sweeping or shoveling up the material. Do not return spilled material to the original container; transfer to a clean metal or plastic drum. To clean up potassium permanganate solutions, follow either of the following two options: Option # 1: Dilute to approximately 6% with water, and then reduce with sodium thiosulfate, a bisuiflte or ferrous salt solution. The bisulflte or ferrous salt may require some dilute sulfuric acid (10% w/w) to promote reduction. Neutralize with sodium carbonate to neutral pH, if acid was used. Decant or filter and deposit sludge in approved landfill. Where permitted, the sludge may be drained into sewer with large quantities of water. Option # 2: Absorb with inert media like diatomaceous earth or inert floor dry, collect into a drum and dispose of properly. Do not use saw dust or other incompatible media. Disposal of all materials shall be in full and strict compliance with all federal, state, and local regulations pertaining to permanganates. To clean contaminated floors, flush with abundant quantities of water into sewer, if permitted by federal, state, and local regulations. If not, collect water and treat as described above. Never return spills in original containers for re -use. For waste disposal, see Section 13 of the SIDS. Environmental precautions Do not allow to enter drains, sewers or watercourses. Contact local authorities in case of spillage to drain/aquatic environment. 7. Handling and storage Precautions for safe handling Take any precaution to avoid mixing with combustibles. Do not get this material in your eyes, on your skin, or on your clothing. Do not breathe dust or mist or vapor of the solution. Use personal protective equipment as recommended in Section 8 of the SIDS. If clothing becomes contaminated, remove and wash off immediately. Spontaneous ignition may occur in contact with cloth or paper. When using, do not eat, drink or smoke. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Avoid release to the environment. Conditions for safe storage, Store locked up. Keep container tightly closed and in a well -ventilated place. Store in a cool, dry including any incompatibilities place. Store away from incompatible materials (See Section 10). Store in accordance with NFPA 430 requirements for Class II oxidizers. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Sodium Permanganate Ceiling 5.mg/m3 (CAS 10101-50-5) US. ACGIH Threshold Limit Values Components Type Value Form Sodium Permanganate TWA 0.1 mg/m3 Inhalable fraction. (CAS 10101-50-5) 0.02 mg/m3 Respirable fraction. US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form Sodium Permanganate STEL 3 mg/m3 Fume. (CAS 10101-50-5) TWA 1 mg/m3 Fume. Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines Follow standard monitoring procedures. F2SP-20, Sodium Permanganate SDS US Revision date: 20-March-2015 Issue dale: 20-March-2015 3 / 9