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HomeMy WebLinkAboutOpening of Bids - VPA 2018 Chemical Supply - Spear CorporationCITY OF SOUTH BEND I'NDIANA SELLER'S BID FOR SALE OR LEASE OF MATERIALS BID NAME Venues Parks & Arts 2018 Chernical Supply FOR BIDS DUE December 217 ta) 9:30arn Bidder Date: /Z ~ 7 a,✓ (Firm); 1A)r4 (1oeP0 AA-r7- Address: ok -5-0 of City/State/Zip: ADAet(,QA4C_, ,,W 4t,7A Telephone Number: 65i S]gam.- /,/.z Agent of Bidder (it' Applicable): When the prospective Contractor is unable to certify to any of the stateanents below, it shall attach an explanation to this Affidavit. CONTRACTOR'S NON -COLLUSION AND NON -DEBARMENT AFFIDAVIT, CERTIFICATION REGARDING INVESTMENT WITH IRAN, EMPLOYMENT ELIGIBILITY VERIFICATION, NON-DISCRIMINATION COMMITMENT AND CERTIFICATION OF USE OF UNITED STATES STEEL PRODUCTS OR FOUNDRY PRODUCTS (.Must be completed for all quotes and bids. ]Please type or print) STATE OF SS: COtYNTY ) The undersigned Contractor, being duly sworn upon his/her/its Grath, affirms under the penalties of perjury that: l . Contractor has not, nor has any other member, representative, or agent of the fare, company, corporation or partnership represented by him, entered into any combination, collusion or agreement with any person relative to the price to be bid by anyone at such letting nor to prevent any person from bidding nor to induce .anyone to refrain from bidding, and that this bid is made without reference to any other bid and without any agreement, understanding or combination with any other person in reference to such. bidding. Contractor- further says that no person or persons, firms, or corporation has, have or will receive directly or indirectly, any rebate, fee, gift, commission or thing of value on. account of such sale; and 2. Contractor certifies by submission of this proposal that neither contractor nor any of its principals are presently debarred, suspended, proposed for debarment, declared ineligible, or voluntarily excluded from participation in this transaction by any Federal department or agency; and 3. Contractor has not, nor has any successor to, nor an affiliate of, Contractor, engaged in investment activities in Iran, a. For purposes of this Certification, "Iran" means the government oflran and any agency or instrumentality of Iran, or asotherwise defined at Ind. Code § 5-22-16.5-5, as amended from time -to -time. laea•, 13 — 6101115 BIDIPROPOSAL .n- V.-fax BID NAME Venues Parks & Arts 2018 Chemical Supply FOR BIDS DUB December 21st, 2017 @ 9:30am e Utilize sheets below t©r documenting bid pricing Ver. 13 -- 6101115 4) M yin 9L ea 75 0. of r r 2 .2 2 7i 2 0 16 W m m U� cr W) W) th Cn NI a. ul 41 cr tL 0 pp IL 0 LL 0 0 N 0 o C. 0 CL 0 0 d) .2 u w cx 0 or m 0 0 0 0 co u C3 0 ❑ 0 6wt IL LL E w .2 m 14 0 r �2 'ra C C C 0 L U 'm r_ �2 m a 2 m c 2 m 07 ol 0 61 ll� Nto C7 Id cn M19 NV) 01 th tm 19 i3S Ln RM U7 eq N T Im ta 0 cn r ,m -u C 00, 0 an3: C-4 r m m t3l A 0 .2 zo CL m .0 U) di cn IYG T 4'� U) CD z c U) C 0 U) r 0 N CL 0) LO Lo LO LO to (0 w W to (0 w to 40 dt IL 41 .2 PO O OD �i 14 14 IN'.14 �4 0 �u OL 14 A (L a E w 0 0 E N =,.!Zge 1i 0 wooe. 01 -W d �'; d E - 't z z n d) 2 0 1 , LL ezz 0 e 0,; d7 9 9 o Z9 9 8.66-. &,62 9 9 i 6 Chi ,4 CA C-4 N cq En cq C4 d. d LO N w 13 03 r>l 0 0 .9 L) Im d) t 0 0 u t CL c E CL 0 M a (n fn a w E 00 10, CL a. to 1- 0 Bidder (Firm): Address: .s ZFW,e. C'o2Aoj2. d*aZ 9(o (P '4 04 -g-0 W City/State/Zip: Telephone Number: Td.C:.Caz.- r12.6 Fax Number: s"z 7— r70zY By (Signature) - BOARD OF PUBLIC WORKS Gary A. Gilot, President Suzanna M. Fritzberg, Member A. Mueller, Member .� Aura �oc:Grrr,;.J-_-._._-- (Printed Name) (Title) Therese J. Dorau, Member Elizabeth A. Maradik, Member Attest: Linda M. Martin, Clerk Tier. 13 --- 6101115 b. As provided by Ind. Code § 5-22-16.5-8, as amended from time -to -time, a Contractor is engaged in investment activities in Iran if either: i. Contractor, its successor or its affiliate, provides goods or services of twenty million dollars ($20,000,000) or more in value in the energy sector of Iran; or ii. Contractor, its successor or its affiliate, is a financial institution that extends twenty million dollars ($20,000,000) or more in credit to another person for forty-five (45) days or more, if that person will (i) use the credit to provides goods and services in the energy sector in Iran; and (ii) at the time the financial institution extends credit, is a person identified on list published by the Indiana Department of AdminiWation. 4. Contractor does not knowingly employ or contract with an unauthorized alien, nor retain any employee or contract with a person that the Contractor subsequently learns is an unauthorized alien. Contractor agrees that he/she/it shall enroll in and verify the work eligibility status of all of Contractor's newly hired employees through the E-Verify Program as defined by I.C. 22-5-1.7-3. Contractor's documentation of enrollment and participation in the E-Verify Program is included and attached as part of this bid/quote; and 5. Contractor shall require his/her/its subcontractors performing work under this public contract to certify that the subcontractors do not knowingly employ or contract with an unauthorized alien, nor retain any employee or contract with a person that the subcontractor subsequently learns is an unauthorized alien, and that the subcontractor has enrolled in and is participating in the E-Verify Program. The Contractor agrees to maintain this certification throughout the terra of the contract with the City of South Bend, and understands that the City may terminate the contract for default if the Contractor fails to cure a breach of this provision no later than thirty (30) days after being notified by the City. 6. Persons, partnerships, corporations, associations, or joint venturers awarded a contract by the City of South Bend through its agencies, boards, or commissions shall not discriminate against any employee or applicant for employment in the performance of a City contract with respect to hire, tenure, terms, conditions, or privileges of employment, or any matter directly or indirectly related to employment because of race, sex, religion, color, national origin, ancestry, age, gender expression, gender identity, sexual orientation or disability that does not affect that person's ability to perform the work. In awarding contracts for the purchase of work, labor, services, supplies, equipment, materials, or any combination of the foregoing including, but not limited to, public works contracts awarded under public bidding laws or other contracts in which public bids are not required by law, the City, its agencies, boards, or commissions may consider the Contractor's good faith efforts to obtain participation by those Contractors certified by the State of Indiana as a Minority Business ("MBE") or as a Women's Business Enterprise ("WBE") as a factor in determining the lowest, responsible, responsive bidder. In no event shall persons or entities seeking the award of a City contract be required to award a subcontract to an MBE/WBE; however, it may not unlawfully discriminate against said WBE/MBE. A finding of a discriminatory practice by the City's MBE/WBE Ver. 13 — 6101115 Utilization Board shall prohibit that person or entity from being awarded a City contract for a period of one (1) year from the date of such determination, and such determination may also be grounds for terminating the contact for which the discriminatory practice or noncompliance pertains. 7. The undersigned contractor agrees that the following nondiscrimination commitment shall be made a part of any contract which it may henceforth enter into with the City of South Bend, Indiana or any of its agencies, boards or commissions. Contractor agrees not to discriminate against or intimidate any employee or applicant for employment in the performance of this contract with privileges of employment, or any matter directly or indirectly related to employment, because of race, religion, color, sex, gender expression, gender identity, sexual orientation, handicap, national origin or ancestry. Breach of this provision may be regarded as material breach of contract. I, the undersigned bidder or agent as contractor on a public works project, understand my statutory obligations to the use of steel products or foundry products made in the United States (I.C. 5-16-5-1). I hereby certify that I and all subcontractors employed by me for this project will use steel products or foundry products made in the United States on this project if awarded. I understand I have an affirmative duty to notify the City in my bid that my proposal does not include the use of steel products or foundry products made in the United States. I understand it is my sole obligation and responsibility to provide a justification to the City, subject to review and approval, why the cost of United States made steel or foundry products is unreasonable. Prior to award and upon submission of bid which does not use steel products or foundry products made in the United States, the City, through its director of public works, shall mare a determination if the price of United States made steel or foundry is unreasonable. I understand that violations hereunder may result in forfeiture of contractual payments. Tier. 13 — 6101115 I hereby affirm under the penalties of perjury that the facts and information contained in the foregoing bid for public works are true and correct. Dated this 7 day of �l� , 2C i 7 Contractor/Bidder (Firm) Signature of Con 6act/orBid(der or Its Agent &/id /N5'rO t�3 /�,i✓'f. Printed Name and Title Subscribed and sworn to before me this 71ve day of Je400K , 20_ZZ My Commission Expires l Not afy Public County of Residence JANET SOLLMAN Seal Notary Public - Stale of Indiana Putnam County My Commission Expires Nov 12, 2023 Ver. 13 -- 6101115 (To be completed only by Contractors/Bidders claiming to be a "local Indiana business" pursuant to 1.C. 36-1-12-22) INDIANA LOCAL BUSINESS PREFERENCE CLAIM A "local Indiana business" refers to any of the following: (1) A business whose principal place of business is located in an affected county. (2) A business that pays a majority of its payroll (in dollar volume) to residents of affected counties. (3) A business that employs residents of affected counties as a majority of its employees. (4) A business that makes significant capital investments in the affected counties as defined in rules adopted by the political subdivision. (5) A business that has a substantial positive economic impact on the affected counties as defined by criteria in rules adopted by the political subdivision. An `affected county"refers to St. Joseph County, Indiana, or the following counties located adjacent to St. Joseph County: Elkhart County, Marshall County, Starke County and LaPorte County There are the following price preferences for supplies purchased from a local Indiana business: • 5% for a purchase expected by the purchasing agency to be less than $50, 000 • 3% for a purchase expected by the purchasing agency to beat least $50,000 but less than $100,000. • 1 % fora purchase expected by the purchasing agency to beat least $100,000. Date: Pursuant to I.C. 36-1-12-22, claims a local Indiana business preference for Project (Project # ) located within the City of South Bend, St. Joseph County, Indiana. © The location of the principal place of business is (Address) a St. Joseph County, Indiana El The following county located adjacent to St. Joseph County, Indiana: © The majority of the business's payroll for the 12 months prior to the date of this Bid is to residents of St. Joseph County, Indiana or the adjacent county noted above. ❑ The majority of the business's employees for the 12 months prior to the date of this Bid are residents of St. Joseph County, Indiana, or the adjacent county noted above. If the business is deemed to be the apparent lowest, responsible, responsive bidder, then it shall provide supporting documentation for the 12 month period prior to the date of the Bid of (i) the total payroll amount paid to all employees of the business, and (ii) the total payroll amount paid to employees who are residents of St. Joseph County and the adjacent county noted above. WHEN SUPPLYING SUPPORTING PAYROLL RECORDS, BIDDER SHALL REDACT ALL SOCIAL SECURITY NUMBERS. Dated this day of , 20_. Contractor/Bidder (Firm) Signature of Contractor/Bidder or Its Agent Printed Name and Title Yer. 13 — 6101115 Venues, Parks & Arts 2018 Chemical Supply December 21"k, 2017 @ 9:30am Pursuant to notices given, the undersigned offers bidi(s) to the City of South Bend in accordance with the following attachments) which specify the class or item number or description, quantity, unit, unit price. 1. The City may accept bids from firms on individual items. Z. The City reserves the right to accept or reject any bids on any or all items. 3. The City department of Venues Parks & Arts has the right to order any quantity which the responsible department supervisors, the Director, and/or Purchasing Manager deem necessary during the contract period. 4. All bid prices selected shall remain in effect for purchases within the year 2018. 5. All bids, are to be f.o.b. at any City of South Bend, Venues Parks &Arts facility. No fuel charges will be allowed, 6. To be considered, bids must include a product SDS sheet. T If there are pallet or bulk quantity pricing that is lower, please list that in addition to the individual =11 8. Firm must be authorized wholesaler of chemicals bid, with ability to recognize industry warranties. 9. Chemical supplier must be able to guarantee claims of product performance, 10. Bidder must include application schedule for chemicals provided at no additional cost. 11. Items 1-15 have the specifications listed on the following pages. All others are as noted. Vej-, 13 -- 6101115 NOUNW-UMS =-- I I z KI 1:491121 LOHKE Lei" big - t. BiD FORMS AND EXECUTION A. Bidders are expected to examine the Drawings,, Specifications, Proposal and all Instructions. Failure to do so will be at the Bidder's risk. B. Each Bidder shall furnish all information required by the Notice, Instructions to Bidders and Specifications. Bids must be made on the form provided. The Bidder shall sign the Proposal and Non -Collusion Affidavit, which is a part of the provided form, where indicated, provide a notary signature and provide all other information required. C. The Bidder shall sign the Proposal in the following manner: If the Proposal is made by an individual, his/her name and post office address must be shown. If made by a partnership or joint venture, the name and post office address of each member of the partnership or joint venture must be shown. If made by a corporation, the Proposal must be signed by an officer of the corporation or by a representative duly authorized by the corporation to execute the Proposal in its behalf. 2. SEALED BIDS ONLY A. Bids,, Proposals, Guaranty, and other required documents must be submitted in a sealed envelope marked on the outside with the general classification of material bids, li.e. "Bid for Computer Equipment," "Bid for Front Enid Loader," or "'Bid for Office Supplies." B. When samples are required, such samples shall be delivered or shipped at the bidder's expense to the address specified in the Invitation to Bid. Samples must be shipped separately from bid documents and labeled clearly with the Bidder's name, address and the commodity or equipment classifications and documents, the item (and item number, if any), and Material Safety Data Sheets (if applicable). All samples must be representative of the commodities or equipment which will be supplied by the successful Bidder. All samples will become the property of the City of South Bend and none will be returned, unless otherwise stated in the Specifications. C. In the event of an inconsistency between provisions of the contract documents, the inconsistency shall be resolved by giving precedence in the following order: 3. ORDER OF PRECEDENCE A. Bid Form attached Proposal B. Amendments to Specifications C. Specifications D. Special Provision E. Instructions to Bidders F. Notice to Bidders 4. DELIVERY OF BIDS A. Bids must be delivered to the Office of the Board of Public Works, 13,11 Floor, County -City Building, Room 1316, 227 West Jefferson Boulevard, South Bend, Indiana 46601 (574) 235- 9251, by the time specified (local time) in the Notice to Bidders. If not delivered personally, the sealed envelope containing the Bid must be mailed to the following address:. City of South Bend Clerk of the Board of Public Works 1316 County -City Building 227 West Jefferson Boulevard South Bend, Indiana 46601 B. Thie Post Office Department will be considered agent of the Bidder in delivering the bid. The City will not be responsible for deliveries, Any Bids received after the time specified will be returned unopened. Ven 13 — 6101115 C. Bids will be opened and read publicly at the time and place designated in the Notice to Bidders. Bidders, their authorized agents, and the public are invited to be present. D. Bidders may bid on one (1) or more item, provided however, that the bid submitted for each is delivered in a separate, sealed envelope, with the envelope clearly labeled on the outside as to the specific item for which the bid is being submitted. Bidders may submit separate bid bonds for each item being bid upon OR may submit one (1) bid bond equal to 10% of the combined total of all bids submitted. E. The Board may reject any bid that does not conform to these requirements as non- responsive. ADDENDA -- NO VERBAL INTERPRETATIONS A. No inquiries by Bidders relative to interpretation of Plans, Specifications, Special Provisions, or other Bidding Documents will be answered verbally. If any prospective Bidder is unable or unwilling to comply with one or more requirements of the bidding document, such Bidder should so inform the Board of Public Works in writing. Upon receipt of such information, consideration will be given to the advisability of issuing an Addendum which would thereupon become applicable to all Bidders. Any such inquiry must be submitted at least seven (7) days prior to the bid opening date in order to give the Board sufficient time to consider any necessary Addendum. All answers to such inquiries, in the form of Addenda, will be furnished to all prospective Bidders who have registered with the City. All Bidders are required to acknowledge receipt of any Addenda by inserting the Addendum number and the issuing date on executed Proposals. 6. REJECTION OF PROPOSALS CONTAINING ALTERATION ERASURES INCOMPLETE BIDS AND ETC. A. Proposals shall be rejected if they show any alteration of form, additions not called for, conditional or alternate bids (except when and insofar as are invited), incomplete bids, erasures or irregularities of any kinds. B. All blank spaces for bid prices must be filled in, in ink, with the unit price and total price for each item (This does not apply to divisible bids). In case of incorrect totaling of amounts and where the unit price and the extension thereof do not agree, the unit price for each item shall govern, and the City is authorized to correct all erroneous extension and totals for the purpose of comparing bids. 7. TRADE DISCOUNTS A. Trade discounts shall not be shown separately, but shall be incorporated in the Bidder's unit price, unless otherwise specified. 8. VEHICLE BIDS A. Bidders may bid on one (1) or more vehicles, provided however, that the bid submitted for each vehicle is delivered in a separate, sealed envelope, by vehicle, with the envelope clearly labeled on Bidders may bid on one (1) or more vehicles, provided however, that the bid submitted for each vehicle is delivered in a separate, sealed envelope, by vehicle, with the envelope clearly labeled on the outside as to the specific vehicle for which the bid is being submitted. Bidders may submit separate bid bonds for each vehicle being bid upon OR may submit one (1) bid bond equal to 10% of the combined total of all vehicle bids submitted. 9. The Board may reject any bid that does not conform to these requirements as non- responsive, 10. TAX EXEMPTIONS A. The City of South Bend is exempt from the payment of federal excise and transportation taxes levied under the provision of the Internal Revenue Code. It is also exempt from the Indiana State Gross Retail Tax (sales tax). The City will furnish the successful Bidder with any certificate of exemption required. 11. WITHDRAWAL OF BIDS A. Withdrawal of bids will be allowed only in those cases in which a written request to withdraw a bid is received by the Board of Public Works prior to the date and hour for receiving and opening bids. In such cases, the same will be returned to Bidder unopened. Ver. 13 6101115 12. ESCALATOR OR CONTINGENT CLAUSES A. The use of escalator clauses or other contingent clauses by the Bidder is prohibited, unless requested or permitted by the Invitation to Bid. No Proposal shall contain nor be accompanied by any writing purporting to limit or qualify the City's right to accept such Proposal or purporting to alter such Proposal or any Contract which may be executed pursuant thereto. 13. PRICES MUST BE DELIVERED PRICES A. The bid price shall be a delivered price. All materials shall be shipped F.O.B. destination as specified in the Invitation to Bid. No fuel surcharges accepted. 14. AWARD —WAIVER OF TECHNICALITIES A. The Award of Bid, if any award be made, will be made within sixty (60) calendar days after the opening of Proposals to the lowest responsible and responsive Bidder who's Proposal complies with all the requirements prescribed, exclusive of technicalities waived. Until the final award of the Bid, however, the right is reserved by the City to reject any and all Proposals and to waive technical errors. 15, SPLITTING OF AWARDS/DIVISIBLE BIDS A. Bids will be awarded on the basis of the total dollar amount for all items in the Proposal unless the bid is described by the City as a Divisible Bid. The City may award a Divisible Bid to the lowest responsible and responsive Bidder for each item or class of items as indicated in the bid documents. 16, BIDDER QUALIFICATION A. The City may require any Bidder to submit evidence of qualifications, and may consider any evidence of the financial, technical, and other qualifications and abilities of the Bidder. The City will not award a Contract to a Bidder who, in its opinion, is not fully qualified on the basis of financial resources and responsibility, possession of adequate equipment, personnel, experience, and past record of performance to perform the obligations to be undertaken competently and without delay. 17. PURCHASE ORDERS A. A Purchase Order will be issued to the successful Bidder after formal acceptance of the bid is made by the City. 18. NEW MANUFACTURE A. Unless otherwise specified in the Invitation to Bid, the items offered shall all be new and the latest model of manufacture. 19. SOURCE OF SUPPLY A. If the Bidder is not a manufacturer, the source of supply must be shown and all sub- contractors must be identified. 20. PACKAGING A. All items shall be delivered strongly packed and marked according to accepted commercial practice unless otherwise directed in the Specifications. No charge shall be made for containers and the City shall have no obligation to return containers unless otherwise provided by the Specifications or Special Provisions. Any items not received in good condition will be rejected. 21. INSPECTION OF GOODS A. The City of South Bend reserves the right to inspect and have any goods tested after delivery for compliance with the specifications. Notice of latent defects, which would make the item unfit for the purposes for which they are required, may be given at any time within one year after discovery of the defects. B. All items rejected must be removed immediately by the Contractor at the expense of the Contractor. If the Contractor fails or refuses to remove the rejected items, they may be sold by the City of South Bend. C. In some cases, at the discretion of the City, inspection of the commodities or equipment will be made at the factory, plant, or other establishment where they are produced before shipment. Ver. 13 --- 6101115 D. The above provision shall not be construed in limitations of any rights the City may have under any laws including the Uniform Commercial Code. 22. ASSIGNMENTS A. No person to whom a Contract has been awarded may assign his interest in the Contract without the consent, in writing, of the City. 23. CANCELLATION A. The City of South Bend reserves the right to cancel any Contract for failure or refusal of performance, fraud, deceit, misrepresentation, collusion, conspiracy, or any other misconduct on the part of the Contractor. 24. DEDUCTION OF DAMAGES A. If the City cancels the contract for any cause, it shall deduct from whatever is owed the Contractor on the Contract or any other Contract, any amount sufficient to compensate the City for any damages suffered by it because of the Contractor's wrongdoing. 25. METHOD OF INVOICING FOR PAYMENT A. Contractor shall bill the City of South Bend 1. On regular invoice form giving a complete and detailed description of the goods delivered, including purchase order number. 2. If the Contractor allows a discount, the period of time in which the City must make payment to qualify for the discounts shall be computed from the date the City received the invoice (completely filled out), or the date the goods are delivered and accepted, whichever may be later, and shall not be less than twenty (20) days. 3. If more than one shipment is made under the Contract and on the same purchase order, the City will make partial payments on a basis that is agreeable to both parties. 26. OWNERSHIP OF GOODS A. The goods which are the subject of the Contract shall remain property of the Contractor until delivered to and accepted by the City of South Bend. 27. ESTIMATED QUANTITIES A. If the quantity set forth in the Notice to Bidders and Proposal is approximate and represents the estimated requirements of the City for a specified period of time, the unit price and the extended total price thereof shall be used only as a basis for the evaluation of bids. The actual quantities necessary may be more or less than the estimate, but the City shall neither be obligated nor limited to any specific amount. The City will, if at all possible, restrict increases to twenty percent (20%) of the estimated quantity and will, if at all possible, restrict decreases to twenty percent (20%) of the estimated quantity. 28. TERM "OR EQUAL" A. Where the term "OR EQUAL" is used in these Specifications, the Bidder deviating from specified item shall file with his/her bid a letter fully explaining and justifying his/her proposed article or equal. The City of South Bend shall be the sole judge in determining if the "OR EQUAL" offered meets the Specifications. 29. INDEMNIFICATION CLAUSE A. The Contractor agrees to indemnify, defend, and hold harmless the City of South Bend, its agents, officers, and employees from all costs, losses, claims and suits, including court costs, attorney fees, and other expenses, arising from or out of the negligent performance of this Contract by the Bidder or because or arising out of any defect in the goods, materials or equipment supplied by the Bidder. NOTE: Incoming mail does not reach the Board of Public Works until after 9:30 a.m. If you are sending your bid via Federal Express or another overnight source, please confirm that your package will arrive before the bid opening time and date. Ver. 13 — 6101115 NOTICE TO BIDDERS Notice is hereby given that the City of South Bend, Indiana, will receive sealed bids at the Office of the Board of Public Works 13th Floor, County -City Building, Room 1316, 227 West Jefferson, South, Bend, Indiana, until the hour of 9.30am, Local Time, on December 21 st, 2017 for the following: Venues Parks & Arts 2018 Chemical Supply Specifications are available for download by visiting the City of South Bend's web page at www.southbendin.gov: • Click on "Business" • Click on "City Public Bids" • Click on "Request for Proposals, Vehicles, Equipment and Miscellaneous Bids" • Click on "Bid/Proposal Interest Form"' and: register your company to receive updated information regarding this bid • Select specification to download • Print the specification, or save it to your computer There is no charge for the specifications. The specifications are also available for review only during regular working hours in the Department of Public Works, 13018 County -City Building, South Bend, Indiana 46601 Bids received after 9:30am, Local Time, on December 21't, 2017, wiill be returned unopened. Bids must be on the City of South Bend Bid/Proposal form provided, which includes a Non - Debarment Affidavit, Non-D iscrimil nation Commitment form, and a Non-Colluslon Affidavit Form. The Board may reject any bid that does not conform to these requirements as non -responsive. The Board reserves the right to reject any or all bids or to accept a full or partial award of the bid or bids which, in its judgment, will be to the best interest of the City of South Bend. BOARD OF PUBLIC WORKS Linda M. Martin, Clerk Publish two times: December 1', 2017 December 8th, 2017 Ver. 13 — 6101115 Arch Chemicals, Inc. FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: 1-800-654-6911 (OUTSIDE USA: 1-423-780-2970) FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTRECO: 1-800-424-9300 (OUTSIDE USA: 11-703-527-3887) FOR ALL SIDS QUESTIONS & REQUESTS, CALL 1-800-511 -MSDS (OUTSIDE USA: 1-423-780-23l47) PiRODUCT NAME: Pulsar Plius Calcium Hypochlori'te Briquettes EPA Registration Number: 1258-,1179 REVISION DATE: 106/02/2015 Arch Chemicals, Inc. SUPERCEDES: 05/26/2016 1200 Bluegrass Lakes Parkway Alpharetta, GA 30004 MSDS Number: 000000022378 SYNONYMS: None CHEMICAL FAMILY: Hypochlorlite DESCRIPTION / USE Sanitizer and OxidizerWater treatment chemical FORMULA: Not Applicable/MIixture GHS Classification Oxidizing solids Acute toxicity (Oral) Skin corrosion Serious eye damage Acute toxicity (inhalation) Specific target organ toxicity - single exposure GHS Label element Hazard pictograms Category 2 Category 4 Category I B Category 1 Category 3 Category 3 Y�l Signal word Danger Pulsar Plugs Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 1 of 13 Arch Chemicals, Inc. Hazard statements H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. Precautionary statements Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P220 Keep/Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P260 Do not breathe vapours. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well -ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. Response: P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell, P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/ physician. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use water spray, alcohol -resistant foam, dry chemical or carbon dioxide to extinguish. Storage: P403 + P233 Store in a well -ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/container in accordance with local regulation. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS CAS OR CHEMICAL NAME CAS# % RANGE CALCIUM HYPOCHLORITE 7778-54-3 60 - 80 Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 2 of 13 ARCHNArch Chemicals, ,Inc. SODIUM CHLORIDE 7647-14-5 10 - 20 CALCIUM CHLORATE 10137-74-3 0 - 5 CALCIUM CHLORIDE 10043-52-4 0 - 5 CALCIUM HYDROXIDE 1305-62-0 0 - 4 CALCIUM CARBONATE 471-34-1 0 - 4 1,2,4-BUTANETRICARBOXYLIC ACID, 2- 40372-66-5 02 - 0.8 PHOSPHONO-, SODIUM SALT Water 7732-18-5 4.0 - 8.5 SECTION 4, FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Inhalation: IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Skin Contact: IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Eye Contact: IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Ingestion: IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Notes to Physician: Probable mucosal damage may contraindicate the use of gastric lavage. SECTION 5. FIREFIGHTING MEASURES Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 3 of 13 AW AM Arch MCHN,Chemicals, Inc. Flammability Summary (OSHA): This product is chemically reactive with many substances. Any contamination of the product with other substances by spill or otherwise may result in a chemical reaction and fire., This product is a strong oxidizer which is capable of intensifying a fire once started., Product is not known to be flammable, combustible or pyrophoric. Flammable Properties Flash Point: Autoignition Temperature Extinguishing Media: Fire Fighting Instructions Upper Flammable / Explosive Limit, % in air: Lower Flammable / Explosive Limit, % in air: Not applicable Not applicable Water only. Do not use dry extinguishers containing ammonium compounds. Use water to cool containers exposed to fire. See Section 6 for protective equipment for fire fighting. Not applicable Not applicable SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Response to a large quantity spill (100 pounds or greater) or when Situations: dusting or decomposition gas exposure could occur requires the use of a positive pressure full face supplied air repirator or self contained breathing apparatus (SCSA), chemical resistant gloves, coveralls and boots. In case of fire, this personal protective equipment should be used in addition to normal fire fighter equipment. Spill Mitigation Procedures Air Release: Vapors may be suppressed by the use of water fog. All water utilized to assist in fume suppression, decontamination or fire suppression may be contaminated and must be contained before disposal and/or treatment. Water Release: This product is heavier than water. This material is soluble in water. Monitor all exit water for available chlorine and pH. Advise local authorities of any contaminated water release. Land Release: Contact 1-800-654-6911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical reaction that may spontaneously ignite any combustible material present, resulting in a fire of great intensity. In case of a spill, separate all spilled product from packaging, debris and other material. Using a clean broom or shovel, place all spilled product into plastic bags, and place those bags into a clean, dry disposal container, properly marked and labeled. Disposal containers made of plastic or metal are recommended. Do not seal disposal containers tightly. Immediately remove all product in disposal containers to an isolated area outdoors. Place all damaged packaging material in a disposal container of water to assure decontamination (i.e. removal of all product) before disposal. Place all undamaged packaging in a clean, dry container properly marked and labeled. Call for disposal procedures. Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 4 of 13 Arch Chemicals, Inc. Additional Spill Information : Hazardous concentrations in air may be found in local spill area and immediately downwind. Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. Dispose of spill residues per guidelines under Section 13, Disposal Consideration. This material may be neutralized for disposal; you are requested to contact Arch Chemicals at 1-800-654-6911 before beginning any such procedure. FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC: 1-800-424-9300 REPORTABLE QUANTITY: 10 lbs. (as calcium hypochlorite) per 40 CFR 302.4. SECTION 7. HANDLING AND STORAGE Handling: Avoid inhalation of dust and fumes. Do not take internally. Avoid contact with skin, eyes and clothing. Upon contact with skin or eyes, wash off with water. Remove contaminated clothing and wash before reuse. Storage: Keep product tightly sealed in original containers. Store product in a cool, dry, well -ventilated area. Store away from combustible or flammable products. Keep product packaging clean and free of all contamination, including, e.g. other pool treatment products, acids, organic materials, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. Shelf Life Limitations: Do not store product where the average daily temperature exceeds 950 F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Shelf life (that is, the period of time before the product goes below stated label strength) is determined by storage time and temperatures. Store in a cool, dry and well ventilated area. Prolonged storage at elevated temperatures will significantly shorten the shelf life. Storage in a climate controlled storage area or building is recommended in those areas where extremes of high temperature occur. Incompatible Materials for Storage: Do not allow product to come in contact with other materials, including e.g. other pool treatment products, acids, organic materials, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. A chemical reaction with such substances can cause a fire of great intensity. Do Not Store At temperatures Average daily temperature of 35' C 1950 F. Storage above this Above: temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 5 of 13 Arch Chemicals, Inc. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep airborne exposures below the TLV, PEL or other recommended exposure limit. Protective Equipment for Routine Use of Product Respiratory Protection : Wear a NIOSH approved respirator if levels above the exposure limits are possible. Respirator Type: A NIOSH approved full -face air purifying respirator equipped with combination chlorine/P100 cartridges. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the published limit. Skin Protection : Wear impervious gloves to avoid skin contact. A full impervious suit is recommended if exposure is possible to a large portion of the body. A safety shower should be provided in the immediate work area. Eye Protection: Use chemical goggles. Emergency eyewash should be provided in the immediate work area. Protective Clothing Type: Neoprene, Nitrile, Natural rubber (This includes: gloves, boots, apron, protective suit) Components with workplace control parameters Components (CAS -No..) Value Control parameters Basis (Update) CALCIUM HYPOCHLORITE (7778-54-3) TWA 1 mg/m3 ARCH OEL* CALCIUM HYPOCHLORITE (7778-54-3) Conc 37 -48 mglm3 NIOSH/GUIDE IDLH CALCIUM HYDROXIDE (1305-62-0) TWA 5 mg/m3 ACGIH (02 2014) ARCH OEL: Arch Recommended Occupational Exposure Guideline. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: solid Form Tablet Color: white Odor: Chlorine -like Molecular Weight: 143.00 glmol pH: 10.4 - 10.8 (1% solution in neutral, distilled water) (@ 25 Deg. C) Boiling Point: Not applicable Freezing Point: Not applicable Density: 1.9g/cc Vapor Pressure: (@ 25 Deg. C) Not applicable Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 6 of 13 Arch Chemicals„ Inc. Vapor Density: Viscosity: Fat Solubility: Solubility in Water: Partition coefficient n- octanollwater: Evaporation Rate: Oxidizing: Volatiles, % by vol.: VOC Content HAP Content Not applicable Not applicable No data 18 % (@ 25 Deg. C) Product also contains calcium hydroxide and calcium carbonate which will leave a residue. Not applicable Not applicable Oxidizer Not applicable Not applicable Not applicable SECTION 10. STABILITY AND REACTIVITY Stability and Reactivity Summary: Product is not sensitive to mechanical shock or impact. Product is not sensitive to electrical static discharge. Product will not undergo hazardous polymerization, Product is an NFPA Class 3 oxidizer which can cause a severe increase in fire intensity. Not pyrophoric. Not an organic peroxide. If subjected to excessive temperatures, the product may undergo rapid decomposition, evolution of chlorine gas, and heat sufficient to ignite combustible substances. If product is exposed to small amounts of water, it can react violently to produce heat and toxic gases and spatter. Use copious amounts of water for fires involving this product. Conditions to Avoid: Do not store next to heat source, in direct sunlight, or elevated storage temperature. Do not store where the daily average temperature exceeds 95'F. Prevent ingress of humidity and moisture into container or package. Always close the lid. Chemical Incompatibility: This product is chemically reactive with many substances, including, e.g., other pool treatment products, acids, organics, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, corrosive ,flammable or combustible materials. Do not allow product to contact any foreign matter, including other water treatment products. Contamination or improper use may cause a fire of great intensity, explosion or the release of toxic gases. If product is exposed to small amounts of water, it can react violently to produce heat and toxic gases and spatter. Hazardous Decomposition Products: Chlorine Decomposition Temperature: 170 - 180 °C - , 338 - 356 OF- M-:. N_IIs] -0:ff. Ti.MZP03:�ro U7IU•] led rd U141-kwo- :7t�i[OR..1 Component Animal Toxicology Oral LD50 value: CALCIUM LD50 (65% calcium hypochlorite) 850 mg/kg Rat HYPOCHLORITE Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 7 of 13 Arch Chemicals„ SODIUM CHLORIDE LD50 = 3,000 mglkg Rat CALCIUM CHLORIDE LD50 = 1,000 mglkg Rat CALCIUM HYDROXIDE LD50 = 7,340 mg/kg Rat Component Animal Toxicology Dermal LD50 value: CALCIUM LD50 (65% calcium hypochlorite) > 2,000 mglkg Rabbit HYPOCHLORITE SODIUM CHLORIDE LD50 > 10,000 mglkg Rabbit CALCIUM CHLORIDE LD50 = 2,630 mglkg Rat CALCIUM HYDROXIDE No data Component Animal Toxicology Inhalation LC50 value: CALCIUM Inhalation LC50 1 h (65% calcium hypochlorite), (Nose Only) = 2.04 mgll HYPOCHLORITE Rat Inhalation LC50 4 h (65% calcium hypochlorite), (Nose Only) = 0.51 mg1l Rat SODIUM CHLORIDE Inhalation LC50 1 h > 42 mg/1 Rat CALCIUM CHLORIDE No data CALCIUM HYDROXIDE No data Product Animal Toxicit Oral LD50 value: LD50 Approximately 800 mglkg Rat Dermal LD50 value: LD50 > 2,000 mglkg Rabbit Inhalation LC50 Inhalation LC50 1.00 h (Nose Only) > 2.04 mgll Rat Inhalation LC50 4 h value: (Nose Only) > 0.51 mgll Rat Inhalation LC50 1 h (Nose Only) > 2,04 mg/1 Rat Inhalation LC50 4 h (Nose Only) > 0.51 mg/1 Rat Skin Irritation: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION., WET MATERIAL CAUSES SKIN BURNS. Eye Irritation: Corrosive to eyes. Skin Sensitization: This material is not known or reported to be a skin or respiratory sensitizer. Acute Toxicity: This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to mucous membranes and respiratory tract.The dry material is irritating to the skin. However when wet, it will produce burns to the skin. Subchronic 1 Chronic There are no known or reported effects from repeated exposure except those Toxicity: secondary to burns. Reproductive and Calcium hypochlorite has been tested for teratogenicity in laboratory Developmental Toxicity: animals. Results of this study have shown that calcium hypochlorite is not a teratogen. Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 8 of 13 Arch Chemicals„ Inc. [s1to] III1Xr . I UOTI-6111 Not known or reported to cause reproductive or developmental toxicity. Mutagenicity: Calcium hypochlorite has been tested in the Dominant lethal assay in male mice, and it did not induce a dominant lethal response. Calcium hypochlorite has been reported to produce mutagenic activity in two in vitro assays. It has, however, been shown to lack the capability to produce mutations in animals based on results from the micronucleus assay. In vitro assays frequently are inappropriate to judge the mutagenic potential of bactericidal chemicals due to a high degree of cellular toxicity. The concentration which produces mutations in these in vitro assays is significantly greater than the concentrations used for disinfection. Based on high cellular toxicity in in vitro assays and the lack of mutagenicity in animals, the risk of genetic damage to humans is judged not significant. CALCIUM CHLORIDE This product was determined to be non-mutagenic in the Ames assay. It was also shown to be non- clastogenic in the chromosomal aberration test. Carcinogenicity: This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP or EPA. One hundred mice were exposed dermally 3 times a week for 18 months to a solution of calcium hypochlorite. Histopathological examination failed to show an increased incidence of tumors. IARC (International Agency for Research on Cancer) reviewed studies conducted with several hypochlorite salts. IARC has classified hypochlorite salts as having inadequate evidence for carcinogenicity to humans and animals. IARC therefore considers hypochlorite salts to be not classifiable as to their carcinogenicity to humans (Group 3 Substance). CALCIUM CHLORIDE This chemical is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP, or EPA. SECTION 12. ECOLOGICAL INFORMATION Overview: Highly toxic to fish and other aquatic organisms. Ecological Toxicity Values for: CALCIUM HYPOCHLORITE Bluegill Rainbow trout (Salmo gairdneri), Daphnia magna, Bobwhite quail Mallard ducklings Bobwhite quail - (nominal, static). 96 h LC50 0.088 mgll - (nominal, static). 96 h LC50 0.16 mgll - (nominal, static). 48 h LC50 0.11 mgll - Dietary LC50 > 5,000 ppm - Dietary LC50 > 5,000 ppm - Oral LD50 3,474 mg/kg Ecological Toxicity Values for: CALCIUM CHLORIDE Bluegill - (nominal, static). 96 h LC50 = 10,650 mg/1 Mosquito fish - (nominal, static). 96 h LC50 = 13,400 mgll Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 9 of 13 Arch Chemicals„ Inc. Pimephales promelas (fathead - (nominal, static). 96 h LC50 = 4,630 mgll minnow) Daphnia magna, - (nominal, static). 48 h LC50= 2,770 mg1I Ceriodaphnia dubia - (nominal, static). 48 h LC50= 1,830 mg1I Nitzschia linearis (diatom) - (nominal, static). 5 day LC50 = 3,130 mgll SECTION 13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. Waste Disposal Summary: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: D001.If this product becomes a waste, it will be a hazardous waste which is subject to the Land Disposal restrictions under 40 CFR 268 and must be managed accordingly.As a hazardous solid waste, it must be disposed of in accordance with local, state and federal regulations. Disposal Methods : As a hazardous solid waste it should be disposed of in accordance with local, state and federal regulations. Potential US EPA Waste Codes: D001 SECTION 14. TRANSPORT INFORMATION DOT UN number Description of the goods Class Packing group Labels Emergency Response Guidebook Number 1748 Calcium hypochlorite mixtures dry 5.1 III 5.1 140 TDG UN number 1748 Description of the goods CALCIUM HYPOCHLORITE MIXTURE, DRY Class 5.1 Packing group II Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 10 of 13 AW Arch ARCHON Chemicals„ Inc. Labels : 5A IATA UN number 1748 Description of the goods Calcium hypochlorite mixture, dry Class 5.1 Packing group III Labels 5.1 Packing instruction (cargo 563 aircraft) Packing instruction : 559 (passenger aircraft) Packing instruction Y546 (passenger aircraft) IMDG-CODE UN number 1748 Description of the goods CALCIUM HYPOCHLORITE MIXTURE, DRY Class 5.1 Packing group III Labels 5.1 EmS Number 1 E-H EmS Number 2 S-Q Marine pollutant : yes SECTION 15. REGULATORY INFORMATION This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SIDS), and for workplace labels of non -pesticide chemicals. Signal word DANGER Hazard statements Causes substantial but temporary eye injury. Corrosive. Causes skin burns. Corrosive. Causes irreversible eye damage. This pesticide is toxic to fish. EPCRA - Emergency Planning and Community Right -to -Know Act CERCLA Reportable Quantity Components CAS -No. Component RQ Calculated (lbs) product RQ Ibs Calcium hypochlorite 7778-54-3 10 13 SARA 302 Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 11 of 13 Arch Chemicals, Inc. No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title 111, Section 313. US State Regulations Massachusetts Right To Know Pennsylvania Right To Know New Jersey Right To Know California Prop 65 Calcium hypochlorite 7778-54-3 Calcium chlorate 10137-74-3 Calcium carbonate 471-34-1 Calcium dihydroxide 1305-62-0 Calcium hypochlorite 7778-54-3 Sodium chloride 7647-14-5 Calcium chlorate 10137-74-3 Calcium chloride 10043-52-4 Calcium carbonate 471-34-1 Calcium dihydroxide 1305-62-0 Calcium hypochlorite 7778-54-3 Sodium chloride 7647-14-5 Calcium chlorate 10137-74-3 Calcium chloride 10043-52-4 Calcium carbonate 471-34-1 Calcium dihydroxide 1305-62-0 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA Inventories This is an EPA registered pesticide. AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION SECTIONS REVISED: 1,14 Major References : Available upon request. Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 12 of 13 Arch Chemicals„ Inc. THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT. . Pulsar Plus Calcium Hypochlorite Briquettes REVISION DATE: 06/02/2015 Page 13 of 13 Arch chemicalls, Inc. FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: 1-800-65,4-6911 (OUTSIDE USA: 1-423-780-2970) FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC@: 1-800-424-9300 (OUTSIDE US& 1-703-527-3887) FOR ALL SDS QUESTIONS & REQUESTS, CALL: 1-800-511 -MSDS (OUTSIDE USA: 1-423-780-2347) PRODUCT NAME- Pulsar Power Shock Granular EPA Registration Numiber: 1258-11'73 I. " 0910 Emu Nelpillipil drilil �l I gpijliq�q a_, % REVISION DATE,- 05/26/2015 Arch Chemicals, Inc. SUPERCEDES: 11/06/2009 1200 Bluegrass Lakes Parkway Alpharetta, GA 30004 MSD,S Number: 000000022339 SYNONYMS: None CHEMICAL FAMILY: Hypochlorite DESCRIPTION / USE Sanitizer and Oxidizer FORMULA: Not Applicable/Mixture 63*6 9D0U1F-'4v.By'!MWUB 11-111 � � � � � A U-In GHS Classification Oxidizing solids Acute toxicity (Oral) Acute toxicity (Inhalation) Skin corrosion Serious eye damage Specific target organ toxicity - single exposure GHS Label element Hazard pictograms WM= Category 2 Category 4 Category 2 Category 1 B Category 1 Category 3 (Respiratory system) Danger Pulsar Power Shock Granular REVISION DATE: 015/26/2015 Page 1 of 14 Arch Chemicals, Inc. Hazard statements H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H330 Fatal if inhaled. H335 May cause respiratory irritation. Precautionary statements Prevention: P210 Keep away from heat. P220 Keep/Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well -ventilated area. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P284 Wear respiratory protection. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 1F ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 + P310 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. . P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. P312 Call a POISON CENTER or doctor/ physician if you feel unwell. P363 Wash contaminated clothing before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol -resistant foam to extinguish. Storage: P403 + P233 Store in a well -ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 2 of 14 ARCHNArch .Chemicals,,Inc. SECTION 3. COMPOSITIONIINFORMATION ON INGREDIENTS CAS OR CHEMICAL NAME CAS # % RANGE CALCIUM HYPOCHLORITE 7778-54-3 65 - 90 SODIUM CHLORIDE 7647-14-5 0 - 3 CALCIUM CHLORATE 10137-74-3 0 - 5 CALCIUM CHLORIDE 10043-52-4 0 - 5 CALCIUM HYDROXIDE 1305-62-0 0 - 5 CALCIUM CARBONATE 471.34.1 0 - 4 Water 7732-18-5 9 - 16 SECTION 4. FIRST AID MEASURES General Advice: Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Inhalation: IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Skin Contact: IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Cali a poison control center or doctor for treatment advice. Eye Contact: IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Ingestion: IF SWALLOWED: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Notes to Physician: Probable mucosal damage may contraindicate the use of gastric lavage. Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 3 of 14 Arch Chemicals, Inc. SECTIONS. FIREFIGHTING MEASURES Flammability Summary (OSHA): This product is chemically reactive with many substances. Any contamination of the product with other substances by spill or otherwise may result in a chemical reaction and fire., This product is a strong oxidizer which is capable of intensifying a fire once started., Product is not known to be flammable, combustible or pyrophoric. Flammable Properties Flash Point: Autoignition Temperature: Extinguishing Media: Fire Fighting Instructions: Upper Flammable I Explosive Limit, % in air: Lower Flammable 1 Explosive Limit, % in air: Not applicable Not applicable Water only. Do not use dry extinguishers containing ammonium compounds. Use water to cool containers exposed to fire. See Section 6 for protective equipment for fire fighting. Not applicable Not applicable SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Response to a large quantity spill (100 pounds or greater) or when Situations: dusting or decomposition gas exposure could occur requires the use of a positive pressure full face supplied air repirator or self contained breathing apparatus (SCSA), chemical resistant gloves, coveralls and boots. In case of fire, this personal protective equipment should be used in addition to normal fire fighter equipment. Soil[ Mitiaation Procedures Air Release: Vapors may be suppressed by the use of water fog. All water utilized to assist in fume suppression, decontamination or fire suppression may be contaminated and must be contained before disposal and/or treatment. Vapors may be suppressed by the use of water fog.All water utilized to assist in fume suppression, decontamination or fire suppression may be contaminated and must be contained before disposal and/or treatment. Water Release: This product is heavier than water. This material is soluble in water. Monitor all exit water for available chlorine and pH. Advise local authorities of any contaminated water release.This product is heavier than water.This material is soluble in water. Monitor all exit water for available chlorine and pH. Advise local authorities of any contaminated water release. Pulsar Power Shock Granular REVISION DATE: 05/2612015 Page 4 of 14 Arch Chemicals, Inc. Land Release: Contact 1-800-654-6911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical reaction that may spontaneously ignite any combustible material present, resulting in a fire of great intensity. In case of a spill, separate all spilled product from packaging, debris and other material. Using a clean broom or shovel, place all spilled product into plastic bags, and place those bags into a clean, dry disposal container, properly marked and labeled. Disposal containers made of plastic or metal are recommended. Do not seal disposal containers tightly. Immediately remove all product in disposal containers to an isolated area outdoors. Place all damaged packaging material in a disposal container of water to assure decontamination (i.e. removal of all product) before disposal. Place all undamaged packaging in a clean, dry container properly marked and labeled. Call for disposal procedures. Contact 1-800-654-6911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical reaction that may spontaneously ignite any combustible material present, resulting in a fire of great intensity. In case of a spill, separate all spilled product from packaging, debris and other material. Using a clean broom or shovel, place all spilled product into plastic bags, and place those bags into a clean, dry disposal container, properly marked and labeled. Disposal containers made of plastic or metal are recommended. Do not seal disposal containers tightly. Immediately remove all product in disposal containers to an isolated area outdoors. Place all damaged packaging material in a disposal container of water to assure decontamination (i.e. removal of all product) before disposal. Place all undamaged packaging in a clean, dry container properly marked and labeled. Call for disposal procedures. Additional Spill Information : Hazardous concentrations in air may be found in local spill area and immediately downwind. Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. Dispose of spill residues per guidelines under Section 13, Disposal Consideration. This material may be neutralized for disposal; you are requested to contact Arch Chemicals at 1-800-654-6911 before beginning any such procedure. FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC: 1-800-424-9300 REPORTABLE QUANTITY: 10 lbs. (as calcium hypochlorite) per 40 CFR 302.4. SECTION 7. HANDLING AND STORAGE Handling: Avoid inhalation of dust and fumes, Do not take internally. Avoid contact with skin, eyes and clothing. Upon contact with skin or eyes, wash off with water. Remove contaminated clothing and wash before reuse. Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 5 of 14 Arch Chemicals, Inc. Storage: Shelf Life Limitations: Incompatible Materials for Storage: Do Not Store At temperatures Above: Keep product tightly sealed in original containers. Store product in a cool, dry, well -ventilated area. Store away from combustible or flammable products. Keep product packaging clean and free of all contamination, including, e.g. other pool treatment products, acids, organic materials, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. Do not store product where the average daily temperature exceeds 95' F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products, Shelf life (that is, the period of time before the product goes below stated label strength) is determined by storage time and temperatures. Store in a cool, dry and well ventilated area. Prolonged storage at elevated temperatures will significantly shorten the shelf life. Storage in a climate controlled storage area or building is recommended in those areas where extremes of high temperature occur. Do not store product where the average daily temperature exceeds 95' F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Shelf life (that is, the period of time before the product goes below stated label strength) is determined by storage time and temperatures. Store in a cool, dry and well ventilated area. Prolonged storage at elevated temperatures will significantly shorten the shelf life. Storage in a climate controlled storage area or building is recommended in those areas where extremes of high temperature occur., Average daily temperature of 35' C 195' F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Do not allow product to come in contact with other materials, including e.g. other pool treatment products, acids, organic materials, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. A chemical reaction with such substances can cause a fire of great intensity. Do not allow product to come in contact with other materials, including e.g. other pool treatment products, acids, organic materials, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. A chemical reaction with such substances can cause a fire of great intensity. Average daily temperature of 35' C 195' F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 6 of 14 Arch Chemicals, Inc. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ventilation: Local exhaust ventilation or other engineering controls are normally required when handling or using this product to keep airborne exposures below the TLV, PE;L or other recommended exposure limit. Protective Equipment for Routine Use of Product Respiratory Protection : Wear a NIOSH approved respirator if levels above the exposure limits are possible. Wear a NIOSH approved respirator if levels above the exposure limits are possible., A NIOSH approved full -face air purifying respirator equipped with combination chlorine/P100 cartridges. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the published limit. Respirator Type : A NIOSH approved full -face air purifying respirator equipped with combination chlorine1P100 cartridges. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the published limit. Skin Protection : Wear impervious gloves to avoid skin contact. A full impervious suit is recommended if exposure is possible to a large portion of the body. Eye Protection: Use chemical goggles. Protective Clothing Type: Neoprene, Nitrile, Natural rubber (This includes: gloves, boots, apron, protective suit) General Protective An eye wash and safety shower should be provided in the immediate work Measures: area. Components with workplace control parameters Components (CAS -No.) - Value Control arameters Basis (Update) CALCIUM HYPOCHLORITE= (7778-54-3) TWA 1 mglm3 ARCH OEL* CALCIUM HYPOCHLORITE (7778-54-3) Conc 37 - 48 mglm3 NIOSH/GUIDE IDLH CALCIUM HYDROXIDE (1305-62-0) TWA 5 mg/m3 ACGIH (02 2014) ARCH OEL: Arch Recommended Occupational Exposure Guideline. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Form Color: Odor: Molecular Weight: Relative density solid Free flowing, granular white Chlorine -like 143 glmol Not applicable Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 7 of 14 Arch Chemicals„ Inc. pH: Boiling Point: Freezing Point: Density Vapor Pressure: Vapor Density: Viscosity: Fat Solubility: Solubility in Water: Partition coefficient n- octanollwater: Evaporation Rate: Oxidizing: Volatiles, % by vol.: VOC Content HAP Content 10.5 - 11.5 () (1 % solution in neutral, distilled water), (@ 25 Deg. C) Not applicable Not applicable 0.8 g/cm3 Not applicable Not applicable Not applicable No data Approximately 18%, (@ 25 Deg. C), Product also contains calcium hydroxide and calcium carbonate which will leave a residue. No data Not applicable Oxidizer Not applicable Not applicable Not applicable SECTION 10. STABILITY AND REACTIVITY Stability and Reactivity Summary: Product is not sensitive to mechanical shock or impact. Product is not sensitive to electrical static discharge. Product will not undergo hazardous polymerization. Product is an NFPA Class 3 oxidizer which can cause a severe increase in fire intensity. Not pyrophoric. Not an organic peroxide, It subjected to excessive temperatures, the product may undergo rapid decomposition, evolution of chlorine gas, and heat sufficient to ignite combustible substances. If product is exposed to small amounts of water, it can react violently to produce heat and toxic gases and spatter. Use copious amounts of water for fires involving this product. Product will not undergo hazardous polymerization., NFPA Oxidizer Class: Meets the criteria of an NFPA Class 3 Oxidizer Reactive Properties: Product is not sensitive to mechanical shock or impact. Product is not sensitive to electrical static discharge. Not pyrophoric. Not an organic peroxide. Conditions to Avoid: Do not store next to heat source, in direct sunlight, or elevated storage temperature. Do not store where the daily average temperature exceeds 95 °F. Prevent ingress of humidity and moisture into container or package, Always close the lid. Chemical Incompatibility: This product is chemically reactive with many substances, including, e.g., other pool treatment products, acids, organics, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, corrosive ,flammable or combustible materials. Do not allow product to contact any foreign matter, including other water treatment products. Contamination or improper use may cause a fire of great intensity, explosion or the release of toxic gases. If product is exposed to small amounts of water, it can react violently to produce heat and toxic gases and spatter. Hazardous Decomposition Products: Chlorine Pulsar Power Shock Granular REVISION DATE: 0512612015 Page 8 of 14 Arch Chemicals, Inc. Decomposition Temperature: 170 - 180 °C - , 338 - 356 OF - SECTION 11. TOXICOLOGICAL INFORMATION Component Animal ToxicologV Oral LD50 value: CALCIUM LD60 (65% calcium hypochlorite) 850 mg/kg Rat HYPOCHLORITE SODIUM CHLORIDE LD50 = 3,000 mg/kg Rat CALCIUM CHLORIDE LD50 = 1,000 mglkg Rat CALCIUM HYDROXIDE LD50 = 7,340 mglkg Rat Component Animal Toxicology Dermal LD50 value: CALCIUM LD50 (65% calcium hypochlorite) > 2,000 mg/kg Rabbit HYPOCHLORITE SODIUM CHLORIDE LD50 > 10,000 mg/kg Rabbit CALCIUM CHLORIDE LD50 = 2,630 mglkg Rat CALCIUM HYDROXIDE No data Component Animal ToxicologV Inhalation LC50 value: CALCIUM Inhalation LC50 1 h (65% calcium hypochlorite), (Nose Only) = 2.04 mgll HYPOCHLORITE Rat Inhalation LC50 4 h (65% calcium hypochlorite), (Nose Only) = 0.51 mg/I Rat SODIUM CHLORIDE Inhalation LC50 1 h > 42 mg/1 Rat CALCIUM CHLORIDE No data CALCIUM HYDROXIDE No data Product Animal Toxicit Oral LD50 value: LD50 Believed to be approximately 700 mg/kg Rat Dermal LD50 value: LD50 Believed to be > 2,000 mglkg Rabbit Inhalation LC50 LC50 1.00 h (Nose Only) Believed to be approximately 1.7 mg/1 Rat LC50 4 value: h (Nose Only) Believed to be approximately 0.425 mgll Rat LC50 4 h Believed to be approximately 0.425 mg/I Rat LC50 1 h Believed to be approximately 1.7 mg/I Rat Skin Irritation: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION., WET MATERIAL CAUSES SKIN BURNS. Eye Irritation: Corrosive to eyes. Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 9 of 14 Arch H � Chemicals. Inc. Skin Sensitization: This material is not known or reported to be a skin or respiratory sensitizer. Acute Toxicity: This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to mucous membranes and respiratory tract.The dry material is irritating to the skin. However when wet, it will produce burns to the skin.This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to raucous membranes and respiratory tract.The dry material is irritating to the skin. However when wet, it will produce burns to the skin. Subchronic 1 Chronic There are no known or reported effects from repeated exposure except those Toxicity: secondary to burns. Reproductive and Calcium hypochlorite has been tested for teratogenicity in laboratory Developmental Toxicity: animals. Results of this study have shown that calcium hypochlorite is not a teratogen. CALCIUM CHLORIDE Not known or reported to cause reproductive or developmental toxicity. Mutagenicity: Calcium hypochlorite has been tested in the Dominant lethal assay in male mice, and it did not induce a dominant lethal response. Calcium hypochlorite has been reported to produce mutagenic activity in two in vitro assays. It has, however, been shown to lack the capability to produce mutations in animals based on results from the micronucleus assay. In vitro assays frequently are inappropriate to judge the mutagenic potential of bactericidal chemicals due to a high degree of cellular toxicity. The concentration which produces mutations in these in vitro assays is significantly greater than the concentrations used for disinfection. Based on high cellular toxicity in in vitro assays and the lack of mutagenicity in animals, the risk of genetic damage to humans is judged not significant. CALCIUM CHLORIDE This product was determined to be non-mutagenic in the Ames assay. It was also shown to be non- clastogenic in the chromosomal aberration test. Carcinogenicity: This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP or EPA. One hundred mice were exposed dermally 3 times a week for 18 months to a solution of calcium hypochlorite. Histopathological examination failed to show an increased incidence of tumors. IARC (International Agency for Research on Cancer) reviewed studies conducted with several hypochlorite salts. IARC has classified hypochlorite salts as having inadequate evidence for carcinogenicity to humans and animals. IARC therefore considers hypochlorite salts to be not classifiable as to their carcinogenicity to humans (Group 3 Substance). CALCIUM CHLORIDE This chemical is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP, or EPA. M1*01161 M FAtleelX•Tc]-liff-AN I ZIts] N-61-1 1191 Overview: Highly toxic to fish and other aquatic organisms. Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 10 of 14 Arch Chemicals, Inc. Ecological Toxicity Values for: CALCIUM HYPOCHLORITE Bluegill Rainbow trout (Salmo gairdneri), Daphnia magna, Bobwhite quail Mallard ducklings Bobwhite quail - (nominal, static). 96 h LC50 0.088 mg1I - (nominal, static). 96 h LC50 0.16 mgll - (nominal, static). 48 h LC50 0.11 mgll - Dietary LC50 > 5,000 ppm - Dietary LC50 > 5,000 ppm - Oral LD50 3,474 mg/kg Ecological Toxicity Values for: CALCIUM CHLORIDE Bluegill Mosquito fish Pimephales promelas (fathead minnow) Daphnia magna, Ceriodaphnia dubia Nitzschia linearis (diatom) - (nominal, static). 96 h LC50 = 10,650 mg1I - (nominal, static). 96 h LC50 = 13,400 mg1I - (nominal, static). 96 h LC50 = 4,630 mgll - (nominal, static). 48 h LC50= 2,770 mgll - (nominal, static). 48 h LC50= 1,830 mgll - (nominal, static). 5 day LC50 = 3,130 mgll SECTION 13. DISPOSAL CONSIDERATIONS CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. Waste Disposal Summary: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: D001.1f this product becomes a waste, it will be a hazardous waste which is subject to the Land Disposal restrictions under 40 CFR 268 and must be managed accordingly. Disposal Methods: As a hazardous solid waste it should be disposed of in accordance with local, state and federal regulations. Potential US EPA Waste Codes : D001 LONZA-S10000000001587 SECTION 14. TRANSPORT INFORMATION DOT Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 11 of 14 Arch ARCHN,Chemicals, inc. UN number 2880 Description of the goods Calcium hypochlorite, hydrated mixtures Class 5.1 Packing group II Labels 5.1 Emergency Response 140 Guidebook Number TDG UN number 2880 Description of the goods CALCIUM HYPOCHLORITE, HYDRATED MIXTURE Class 5.1 Packing group II Labels 5.1 IATA UN number 2880 Description of the goods Calcium hypochlorite, hydrated mixture Class 5.1 Packing group II Labels 5.1 Packing instruction (cargo 562 aircraft) Packing instruction 558 (passenger aircraft) Packing instruction Y544 (passenger aircraft) IMDG-CODE UN number 2880 Description of the goods CALCIUM HYPOCHLORITE, HYDRATED MIXTURE Class 5A Packing group II Labels 5.1 EmS Number 1 F H EmS Number 2 S-Q Marine pollutant : yes SECTION 15. REGULATORY INFORMATION This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SIDS), and for workplace labels of non -pesticide chemicals. Signal word DANGER! Hazard statements Causes substantial but temporary eye injury. Corrosive. Causes skin burns. Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 12 of 14 Arch ARCHON Chemicals, Inc. Corrosive. Causes irreversible eye damage. This pesticide is toxic to fish. EPCRA - Emergency Planning and Community Right -to -Know Act CERCLA Reportable Quantity Components CAS -No. Component RQ Calculated (Ibs) product RQ Ibs Calcium hypochlorite 7778-54-3 10 11 SARA 302 No chemicals in this material are subject to the reporting requirements of SARA Title Ili, Section 302. SARA 313 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. US State Regulations Massachusetts Right To Know Pennsylvania Right To Know New Jersey Right To Know California Prop 65 Calcium hypochlorite 7778-54-3 Calcium chlorate 10137-74-3 Calcium dihydroxide 1305-62-0 Calcium carbonate 471-34-1 Calcium hypochlorite 7778-54-3 Calcium chlorate 10137-74-3 Calcium chloride 10043-52-4 Calcium dihydroxide 1305-62-0 Calcium carbonate 471-34-1 Sodium chloride 7647-14-5 Calcium hypochlorite 7778-54-3 Calcium chlorate 10137-74-3 Calcium chloride 10043-52-4 Calcium dihydroxide 1305-62-0 Calcium carbonate 471-34-1 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories; TSCA Pulsar Power Shock Granular REVISION DATE: 05/26/2016 This is an EPA registered pesticide. Page 13 of 14 P TSCA Inventories Arch Chemicals„ Inc. This is an EPA registered pesticide. AfCS (Australia), DSL. (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL. (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION SECTIONS REVISED: 1 Major References : Available upon request. THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT, , Pulsar Power Shock Granular REVISION DATE: 05/26/2015 Page 14 of 14 I` �" �J' 5'q a aa" C emicals urp. "I" . .... .......... . --- SAFETY DATA SHEET 24 Hour Emergency Telephone Number CHEIVITREC 11- 800 - 424 - 9300 All non -emergency questions should be directed to Customer Service (1-386-446-4595) for assistance. 1. Product Identification Synonyms: muriatic acid, swimming pool acid, a solution of hydrogen chloride in water. CAS Number: 7647-01-0 Product Names: SMART Muriatic Acid, Transchem Muriatic Acid Part Numbers: UPC Codes: 118 01792600,1189 2118 017926121187 00001 GEN 017926100011 00001 017926000014 00005 017926000052 00015 017926000,151 00030 017926000304 00055 GEN 017926001554 00055 0179260,00557 T330 n/a Supplier GLN: 00179264004142 2. Hazard Identification Emergency Overview: DANGER! Causes severe skin burns and eye damage. May cause respiratory irritation, Onset of symptoms may be delayed following exposure. Potential Health Effects, GTINs: 00179260011894 00�179261211842 00179261000118 00179260000140 00179260000522 10017926000�158 10017926000301 10017926001551 10017926000554 n/a Inhalation: Corrosive! Inhalation of vapors can cause severe coughing, choking, inflammation of the nose, throat and upper respiratory tract. Severe cases can cause pulmonary edema, circulatory failure and death. Ingestion: Corrosive! Swallowing hydrochloric acid can cause immediate pain and burns to the nose, mouth, throat, esophagus and gastrointestinal tract, May cause nausea, vomiting, diarrhea and in severe cases, death. Page 1 of 5 Skin Contact: Corrosive! Can cause redness, pain and severe burns. May cause deep ulceration and discoloration of the skin. Eye Contact: Corrosive! Vapors are irritating and may cause damage to the eyes. Liquid contact can cause severe burns, permanent eye damage and blindness. Chronic Exposure: Long term exposure to concentrated vapors may cause erosion of the teeth. Long term exposure seldom occurs due to the corrosive properties of hydrochloric acid. Aggravation of Pre-existing Conditions: Persons with pre-existing conditions, such as skin disorders, or eye disease may be more susceptible to the adverse effects of hydrochloric acid. 3. Product Ingredients Components Percent M w t Hydrochloric Acid 31.45 CAS Number: 7647-01-0 GHS Classification: Corrosive 1 B, STOT-SE 3; H314, H335 Water 68.55 CAS Number: 7732-18-5 GHS Classification: Not considered hazardous according to GHS criteria. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Seek immediate medical attention. Ingestion: DO NOT INDUCE VOMITING. Give large quantities of water or milk if available. Never give anything by mouth to an unconscious person. Seek immediate medical attention. Skin Contact: In case of contact with liquid, immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Seek immediate medical attention. Eye Contact: Immediately flush eyes with plenty of flowing water for at least 15 minutes, while lifting upper and lower eyelids. Seek immediate medical attention. 5. Fire Fighting Measures NFPA 704 ratings: Health 3 Flammability 0 Reactivity 1 COR Fire: Not considered to be a fire hazard. May react with metals to form flammable hydrogen gas. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Water or water spray. Neutralize with soda ash or slaked lime. Special Information: In the event of fire, wear full protective clothing and NIOSH approved self- contained breathing apparatus (SCBA), with full face shield, operated in positive pressure mode. Structural firefighting protective clothing is ineffective for fires involving hydrochloric acid. Stay away from ends of tanks. Cool tanks and drums with water spray until well after fire is out. Page 2 of 5 6. Accidental Release Measures Adequately ventilate area of leak or spill. Wear appropriate personal protective equipment (PPE), as specified in Section 8. Isolate hazard area to keep unprotected personnel from entering. Stop the leak if possible. Contain and recover liquid when possible. Neutralize spilled liquid with alkaline materials (soda ash, lime). Then absorb the neutralized liquid with an inert material, such as vermiculite, sand, or earth and place recovered material in an approved, compatible chemical waste container. Do not use combustible materials such as cardboard or saw dust as an absorbent. Do not flush spilled acid to the sewer. EPA regulations require reporting spills and releases to the soil, air and water, in excess of the reportable quantity (5,000 Ibs), to the National Response Center, telephone number 1-800-424-8802. Reporting to the State Emergency Response Commission (SERC) warning point and local authorities (911) is also required. 7. Handling and Storage Store in a cool, dry, ventilated storage area with acid resistant floors and good drainage. Protect from physical damage. Keep out of sunlight and direct heat, water and incompatible materials. Do not wash out container and use it for other purposes. When diluting, the acid should always be added slowly to the water. Never use hot water and never add water to acid. Water added to acid can cause uncontrolled boiling and splashing. Empty acid containers may be hazardous since they retain acid residues of liquid and vapor. Observe all warnings and precautions stated on the acid container label. Wear personal protective equipment when handling, opening containers and using hydrochloric acid. 8. Exposure Control and Personal Protection Airborne Exposure Limits: OSHA Permissible Exposure Limit (PEL) 5 ppm (Ceiling) (7 mg/m) NIOSH Relative Exposure Level (REL) 5 ppm (Ceiling) (7 mg/m) ACGIH Threshold Limit Value (TLV) 2 ppm (Ceiling) (TWA) NIOSH Immediately Dangerous Level (IDLH) 50 ppm Ventilation: A system of local and/or general exhaust is recommended to keep exposure below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the acid at the source, preventing dispersion into the occupied area. Personal Respirators (NIOSH Approved): If exposure limits are exceeded and engineering controls are not feasible, a full face respirator with an acid gas cartridge may be worn up to 50 times the permissible exposure limit (PEL). For emergencies or instances where the exposure levels are not known, use full face, positive pressure, air supplied respirator.. WARNING! Air purifying respirators do not provide protection in oxygen deficient atmospheres. Skin Protection: Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, are needed in areas of unusual exposure to prevent skin contact. Eye Protection: Use safety glasses with side shields, chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick drench facilities (safety shower) in work areas. 9. Physical and Chemical Properties Appearance: Clear, colorless liquid. Solubility: Infinitely soluble in water. Percent Volatile: 100% Vapor Density: 1.27 (Air=1) Odor: Pungent, acrid odor. Specific Gravity: 1.155 — 1.162 Boiling Point: 180 F — 220 F Vapor Pressure: 35 mm Hg @ 86 F Evaporation Rate: < 1 (butyl acetate = 1) pH: < 1 Page 3 of 5 F 10. Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Avoid heat and direct sunlight. Hazardous Decomposition Products: When heated to decomposition, emits toxic hydrogen chloride fumes and will react with water or steam to produce heat and toxic, corrosive fumes. Thermal decomposition in the presence of oxidizing materials produces toxic chlorine fumes and explosive hydrogen gas. Hazardous Polymerization: Will not occur. Incompatibilities: Highly reactive with strong bases, metals, metal oxides, hydroxides, amines, carbonates and alkaline materials. Incompatible with cyanide, sulfides, sulfites and formaldehyde. 11. Toxicological Information Lethal inhaled concentration (LC50) in rats: 3,124 ppm11 hr Not listed on the OSHA, NTP or IARC list of carcinogens. 12. Ecological Information Environmental Fate: Rapidly hydrolyzes when exposed to water. Exhibits extensive evaporation from soil surfaces. Transport through soil may contaminate ground water and will dissolve some of the soil materials (especially those with carbonate bases). Acid will be neutralized to a large degree by contact with carbonates in soil. Environmental Toxicity: Lethal to fish from 25 mgll and up. Toxic to aquatic organisms as a result of pH shift. 13. Disposal Considerations Whatever cannot be recovered or recycled should be handled as Characteristic Hazardous Waste (pH <2.0) and sent to a RCRA approved waste facility. State and local disposal regulations may differ from federal regulations. Dispose of container and contents in accordance with federal, state and local laws. 14. Transport Information Proper Shipping Name: HYDROCHLORIC ACID Full Shipping Description: HYDROCHLORIC ACID, 8, UN1789, PGII 15. Regulatory Information Regulated Ingredient: hydrogen chloride (CAS # 7647-01-0) U.N. GHS Classification & Labeling Information: Classification: Corrosive 1 B Specific Target Organ Toxicity (STOT)� - SingleExposure 3 >< N Signal Word. DANGER H Statements: H314: Causes severe skin burns and eye damage. H335: May cause respiratory irritation. P Statements: P307+315: If exposed, get immediate medical attention. P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P280: Wear protective glove slprotective clothing/eye protection/face protection. Page 4 of 5 P264: Wash thoroughly after handling P273: Avoid release into the environment U. S. Federal Reaulatory Information EPA Clean Air Act: Listed as Hazardous Air Pollutant EPA Clean Water Act: Listed TSCA: The ingredients of this product are listed on TSCA inventory (40 CFR 710). RCRA: This product as supplied is a D002 (corrosive) waste. pH < 2 CERCLA RQ: 5000 lbs. (hydrochloric acid) SARA Title III § 302: None SARA Title III § 3111312:Acute Health Hazard Canadian Regulatory Information: WHMIS Category: Class E Corrosive Material Ingredient Disclosure List: Listed Domestic Substances List (DSL): Listed 16.Other Information Label Hazard Warning: SARA Title I II § 313: Listed POISON DANGER CORROSIVE, MAY BE FATAL IF SWALLOWED OR INHALED. LIQUID AND MIST CAN CAUSE SEVERE BURNS TO ALL BODY TISSUE. Label Precautions: Do not get in eyes, on skin, or on clothing. Avoid breathing vapor or mist. Keep container closed when not in use. Use with adequate ventilation. Wash thoroughly after handling. KEEP OUT OF REACH OF CHILDREN. Label First Aid: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. if inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water, for at least 15 minutes, Remove contaminated clothing and shoes. Wash clothing before reuse. SEEK MEDICAL ATTENTION. Disclaimer Notice: This information is furnished without warranty, expressed or implied, except that it is accurate to the best knowledge of Sunbelt Chemicals Corp. at the time it was prepared. Sunbelt Chemicals Corp. assumes no liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, Sunbelt Chemicals Corp. cannot guarantee that these are the only hazards that exist. Sunbelt Chemicals Corp. assumes no legal responsibility for loss, damage or expense arising out of, or in any way connected with, the handling, storage, use or disposal of this product. sds118.pdf Revised: 217/13 revision supersedes 1/2912010 Prepared by: Sunbelt Chemicals Corp. Page 5 of S