HomeMy WebLinkAboutOpening of Bids - Water Treatment Chemicals 2017-2018 - Alexander Chemical Corp, A Carus CompanyBID NAME
FOR BIDS DUE
Date:
Address:
City/State/Zip:
CITY OF SOUTH BEND, INDIANA
SELLER'S BID FOR SALE OR LEASE OF MATERIALS
Bidder
March 10, 2017 (Firm):
315 Fifth Street
Alexander Chemical Corporation, A Carus Company
Peru, IL 61354 Telephone Number: ( 800 ) 435-6856
Agent of Bidder (if Applicable):
N/A
When the prospective Contractor is unable to certify to any of the statements belmv, it shall attach an explanation to this Affidavit.
CONTRACTOR'S NON -COLLUSION AND NON -DEBARMENT AFFIDAVIT, CERTIFICATION
REGARDING INVESTMENT WITH MAN, EMPLOYMENT ELIGIBILITY VERIFICATION, NON-
DISCRIMINATION COMMITMENT AND CERTIFICATION OF USE OF UNITED STATES STEEL
PRODUCTS OR FOUNDRY PRODUCTS
(Must be completed for all quotes and bids. Please type or print)
STATE OF ILLINOIS )
) SS:
LASALLE COUNTY )
The undersigned Contractor, being duly sworn upon his/her/its oath, affirms under the penalties of perjury that:
1. Contractor has not, nor has any other member, representative, or agent of the firm, company,
corporation or partnership represented by him, entered into any combination, collusion or agreement with
any person relative to the price to be bid by anyone at such letting nor to prevent any person from bidding
nor to induce anyone to refrain from bidding, and that this bid is made without reference to any other bid
and without any agreement, understanding or combination with any other person in reference to such
bidding. Contractor further says that no person or persons, firms, or corporation has, have or will receive
directly or indirectly, any rebate, fee, gift, commission or thing of value on account of such sale; and
2. Contractor certifies by submission of this proposal that neither contractor nor any of its principals
are presently debarred, suspended, proposed for debarment, declared ineligible, or voluntarily excluded
from participation in this transaction by any Federal department or agency; and
3. Contractor has not, nor has any successor to, nor an affiliate of, Contractor, engaged in investment activities
in Iran.
a. For purposes of this Certification, "Iran" means the government of Iran and any agency or
instrumentality of Iran, or as otherwise defined at Ind. Code § 5-22-16.5-5, as amended from time -to -
time.
b. As provided by Ind. Code § 5-22-16.5-8, as amended from time -to -time, a Contractor is engaged in
investment activities in Iran if either:
2
i. Contractor, its successor or its affiliate, provides goods or services of twenty million dollars
($20,000,000) or more in value in the energy sector of Iran; or
ii. Contractor, its successor or its affiliate, is a financial institution that extends twenty million
dollars ($20,000,000) or more in credit to another person for forty-five (45) days or more, if
that person will (i) use the credit to provides goods and services in the energy sector in hran;
and (ii) at the time the financial institution extends credit, is a person identified on list
published by the Indiana Department of Administration.
4. Contractor does not knowingly employ or contract with an unauthorized alien, nor retain any
employee or contract with a person that the Contractor subsequently learns is an unauthorized alien.
Contractor agrees that he/she/it shall enroll in and verify the work eligibility status of all of Contractor's
newly hired employees through the E-Verify Program as defined by I.C. 22-5-1.7-3. Contractor's
documentation of enrollment and participation in the E-Verify Program is included and attached as part
of this bid/quote; and
5. Contractor shall require his/her/its subcontractors performing work under this public contract to
certify that the subcontractors do not knowingly employ or contract with an unauthorized alien, nor retain
any employee or contract with a person that the subcontractor subsequently learns is an unauthorized
alien, and that the subcontractor has enrolled in and is participating in the E-Verify Program, The
Contractor agrees to maintain this certification throughout the term of the contract with the City of South
Bend, and understands that the City may terminate the contract for default if the Contractor fails to cure
a breach of this provision no later than thirty (30) days after being notified by the City.
6. Persons, partnerships, corporations, associations, or joint venturers awarded a contract by the City
of South Bend through its agencies, boards, or commissions shall not discriminate against any employee
or applicant for employment in the performance of a City contract with respect to hire, tenure, terms,
conditions, or privileges of employment, or any matter directly or indirectly related to employment
because of race, sex, religion, color, national origin, ancestry, age, gender expression, gender identity,
sexual orientation or disability that does not affect that person's ability to perform the work.
In awarding contracts for the purchase of work, labor, services, supplies, equipment, materials, or any
combination of the foregoing including, but not limited to, public works contracts awarded under public
bidding laws or other contracts in which public bids are not required by law, the City, its agencies, boards,
or commissions may consider the Contractor's good faith efforts to obtain participation by those
Contractors certified by the State of Indiana as a Minority Business ("MBE") or as a Women's Business
Enterprise ("WBE") as a factor in determining the lowest, responsible, responsive bidder.
In no event shall persons or entities seeking the award of a City contract be required to award a subcontract
to an MBE/WBE; however, it may not unlawfully discriminate against said WBE/MBE. A finding of a
discriminatory practice by the City's MBE/WBE Utilization Board shall prohibit that person or entity
from being awarded a City contract for a period of one (1) year from the date of such determination, and
such determination may also be grounds for terminating the contact for which the discriminatory practice
or noncompliance pertains.
7. The undersigned contractor agrees that the following nondiscrimination commitment shall be
made a part of any contract which it may henceforth enter into with the City of South Bend, Indiana or
any of its agencies, boards or commissions.
Contractor agrees not to discriminate against or intimidate any employee or applicant for employment in
the performance of this contract with privileges of employment, or any matter directly or indirectly related
to employment, because of Lace, religion, color, sex, gender expression, gender identity, sexual
orientation, handicap, national origin or ancestry. Breach of this provision may be regarded as material
breach of contract.
I, the undersigned bidder or agent as contractor on a public works project, understand my statutory
obligations to the use of steel products or foundry products made in the United States (I.C. 5-16-8-1). I
hereby certify that I and all subcontractors employed by me for this project will use steel products or
foundry products on this project if awarded. I understand that violations hereunder may result in forfeiture
of contractual payments.
I hereby affirm under the penalties of perjury that the facts and information contained in the foregoing bid for public works
are true and correct.
Dated this 10th day of March 20 17
Subscribed and sworn to before me this 10th
My Commission Expires-h-l4z
Comity of Residence
Alexander Chemical Corporation, A Carus Compai
Contractor/Bidder (Firm)
�&.4aM
Signature of Contractor/Bidder or Its Agent
Susan Buchanan, VP, CFO
Printed Name and Title
day of March 20 17
" %a � - - ��M
..
=PUBLICSTATE
L
RR
OF ILLINOISS:04/11/18
Cl
(To be completed only by Contractors/Bidders claiming to be a "local Indiana business" pursuant to I.C. 36-1-12-22)
INDIANA LOCAL BUSINESS PREFERENCE CLAIM
A "local Indiana business" refers to any of the following:
(1) A business whose principal place of business is located in an affected county.
(2) A business that pays a majority of its payroll (in dollar volume) to residents of affected counties.
(3) A business that employs residents of affected counties as a majority of its employees.
(4) A business that makes significant capital investments in the affected counties as defined in rules
adopted by the political subdivision.
(5) A business that has a substantial positive economic impact on the affected counties as defined by
criteria in rules adopted by the political subdivision.
An "affected county" refers to St. Joseph County, Indiana, or the following counties located adjacent to St.
Joseph County: Elkhart County, Marshall County, Starke County and LaPorte County
There are the following price preferences for supplies purchased from a local Indiana business:
• 5% for a purchase expected by the purchasing agency to be less than $50, 000
• 3% for a purchase expected by the purchasing agency to beat least $50,000 but less than
$100,000.
• 1 % for a purchase expected 4yffiepurchasing agency to beat least $100, 000.
Date: March 10, 2017
Pursuant to I.C. 36-1-12-22, Alexander Chemical Corporation, A Carus Company claims a local Indiana business preference
for Project `Hater Treatment chemicals 2016-2017 (Project # ) located within the City of South Bend, St.
Joseph County, Indiana.
The location of the principal place of business is 7593 Kingsbury Ind Park, Kingsbury, IN 46345
(Address)
❑ St. Joseph County, Indiana
® The following county located adjacent to St. Joseph County, Indiana: LaPorte County
❑ The majority of the business's payroll for the 12 months prior to the date of this Bid is to residents of St. Joseph
County, Indiana or the adjacent county noted above.
❑ The majority of the business's employees for the 12 months prior to the date of this Bid are residents of St. Joseph
County, Indiana, or the adjacent county noted above.
If the business is deemed to be the apparent lowest, responsible, responsive bidder, then it shall provide supporting
documentation for the 12 month period prior to the date of the Bid of (i) the total payroll amount paid to all employees of the
business, and (ii) the total payroll amount paid to employees who are residents of St. Joseph County and the adjacent
county noted above.
WHEN SUPPLYING SUPPORTING PAYROLL RECORDS,
BIDDER SHALL REDACT ALL SOCIAL SECURITY NUMBERS.
Dated this loth day of March 2017.
Alexander Chemical Corporation, A Carus Company
Contractor/Bidder ((`►Fiirm))
SlgnatuContractor/Bidder �or Its Agent
Susan Buchanan, VP, CFO
Printed Name and Title
5
SPECIFICATIONS
CITY OF SOUTH BEND
BID NAME Water Treatment Chemicals 2017-2018
FOR BIDS DUE March 14, 2017; 9:30 a.m., Local Time
BLENDED PHOSPHATE SEQUESTRANT CORROSION INHIBITOR.............................................................................. 10
CHLORINESPECIFICATIONS.................................................................................................................................................... 2
DRYPOLYMER FLOCCULENT................................................................................................................................................ 17
FERRICCHLORIDE..............................................................................................................................7
FLUORISILICICACID..................................................................................................................................................................
8
LIQUID CALCIUM NITRATE 66%...........................................................................................................................................
18
POTASSIUM PERMANGANATE................................................................................................................................................9
SALTSPECIFICATION...............................................................................................................................................................
14
SODIUM HYPOCHLORITE 12.5%............................................................................................................................................
19
SODIUM PERMANGANATE..................................................................................................................20
SULFURDIOXIDE........................................................................................................................................................................
16
FOR ALL CHEMICALS
For security purposes vendors shall confirm via fax a copy of the delivery driver's license,
truck and trailer information alone with the anticipated time of arrival not later than 24
hours prior to arrival. Failure to do so will be cause for rejection of material, no billable
time will be accepted.
Water Works facility deliveries are to be made on normal work -days between 7: 00 a.m. and 11: 00 a.m. with
unloading to be completed before 1: 00 p.m, Waste Water facility deliveries are to be made between the
hours of 6: 00 AM and 4: 00 PMMonday through Friday.
No stop -off or fuel surcharges allowed; however, demurrage charges will be allowed after 2 hours
per stop. All deliveries are F.O.B. Delivery Point.
Awards of this bid will be divisible by product. Awards will be based on the lowest responsive
and responsible bidder per unit prices on the attached schedule.
All prices quoted are to be effective May 1, 2017 through April 30, 2018 (One Year). Prices are
to be firm throughout that period without increases.
Quantities are estimated and not guaranteed.
1
I. CHLORINE SPECIFICATIONS
INCLUDE BOTH 1504 AND TON CYLINDERS
A. GENERAL
1. Only containers which currently are authorized by regulation for chlorine,
which have been inspected and reconditioned as described herein, and which
have been tested within the period required by regulations should be filled. It
is illegal to ship chlorine containers that have been filled by or without the
consent of the owner.
2. Due to the volatile nature of this chemical, the chlorine provider must be able
to have one (1) accredited Safety and Handling of Chlorine class per year.
3. Chlorine quotes should be deposit -free. No cylinder deposit should be
included in the quote.
Boiling Point
-29.29°F (-34.05°C)
Critical Density
35.77 lb./cu. ft.
Critical Pressure
1118.4 psia (76.1 Atmos.
Critical Temperature
291.20 144.°C
Critical Volume
0.02796 cu. ft./lb.
Latent Heat of Vaporization
123.7 Btu./lb. @Boiling point
Liquid Gas Relationship:
1 volume liquid chlorine = wt. at
457.6 volumes of chlorine, 825 @
standard conditions
Melting Point
-149.76°F (-100.980C
Specific Gravity - Dry Gas
2.482
Specific Gravity — Liquid
1.468 0 (° - 40C)
B. CHLORINE 150 POUND CYLINDERS
1. Construction
a) All cylinders must be compatible with Chlorine Institute Emergency Kit "A". All
kit devices must be useable on any cylinder in chlorine service. The maximum
neck ring diameter that will accommodate an "A" hood is 4-314 inches.
2. Cylinder Types
a) Chlorine cylinders must comply with DOT specs, 3A480, 3AA480, 25, 3, 3BN480
or 3E1800. The regulations permit only one opening in chlorine cylinders -at
the top for the valve connection.
3. Cylinder Styles
a) Cylinders maybe of three styles: footring, bumped bottom, or double bottom.
4. Cylinder Threads
2
a) The threads in new cylinders are NGT threads 314-14NGT(CI).
5. Chlorine Ton Containers
a) All ton containers must be compatible with Chlorine Institute Emergency Kit "B ".
6. Ton Container Types
a) Chlorine ton container types must comply with DOT spec. 106A50OX, DOT or
ICC 106A500, 27, BE27.
b) Ton Container Valve and Fuse Plug Opening Threads
c) The threads in new ton containers are 314-14NGT (CI).
7. Valve Protection
a) The cylinder and ton container valves are protected during shipment and storage
by a removable steel valve protective housing or cap. Pressure relief devices
shall not be covered by the housing.
8. Cylinder and Ton Container Capacity
a) In cases where the capacity of a chlorine container is not known, it can be
determined by weighing it empty and again when completely filled with water,
and by multiplying the weight of water at 60°F by 1.25. This is the maximum
allowable weight of chlorine allowed in the cylinder or ton container.
1f 11 C 1r�TJI 212 M
1. Cylinder Stamping
a) When manufactured, cylinders are stamped with DOT specification number,
serial number, and owners and/or builders identifying symbols as well as
inspector's official mark and initial test date [DOT Section 173.34(c)] of 49CFR.
2. Ton Container Stamping
a) When manufactured, ton containers are stamped with DOT specification number,
material, serial number, inspector's official mark, name, mark or initials of
company for whose use the lank is made, (or builder's symbol and serial
number), date of test, and water capacity [DOT Section 179.300-18]. Tare
weights may be stamped by builder. Changes in stamping must be made in
compliance with DOT Section 173.31(d) or 49CFR.
3. Retest Stamping
a) Retested cylinders [DOT 49 CFR, Section 173.34 (e) (6)J and ton containers
[DOT 49 CFR, Section 173.31(d) (7)J must be stamped to show date of retest.
For cylinders, the stamp must include the test facility's certification number in a
prescribed pattern. Ton containers do not require the test facility's number on
the container.
4. Tare -Weight Stamping
a) It is recommended that all new chlorine cylinders and ton containers be stamped
with the original tare weight by the container manufacturer.
D. VALVES
1. Cylinders
a) Chlorine cylinders are to have a single chlorine style Ceodeux D174 valve which
is equipped with a fusible metal plug -type relief device. This is a must comply
.safety requirement.
2. Ton Container Valves
a) Chlorine ton containers are to have two identical chlorine style Ceodeux D174
valves near the center of one head. This is a must comply safely requirement.
When vertically aligned, the valve in the upper position is used for gas
withdrawal, and the lower one for liquid withdrawal. The standard ton container
valve is identical to the cylinder valve except that it has no fusible metal type
relief device, and the valve seat diameter may be larger than on most cylinder
valves. There are tow sizes of ton container valves: 314 inch NGT and 1 inch
NGT.
3. Valve Outlet Threads
a) Outlet threads on cylinder and ton containers are special straight threads
(1, 030" - 14NGO-RH-FXT) which conform to connection number CGA 820 and
B20C which utilize a yoke -type connection. These threads are to accommodate
the outlet cap only and are not to be used for chlorine hose connections.
E. PRESSURE RELIEF DEVICES
1. Cylinders
a) The relief device on chlorine cylinders is a fusible metal plug in the cylinder
valve located below the valve seat. The fusible metal is cast into an 'Alloy "B" or
Alloy 'A" holder which is screwed into a tapped hole in the valve body. The
fusible plugs are designed to melt between 158 degrees F and 165 degrees F.
2. Ton Containers
a) Ton container valves contain no fusible plugs. The container itself is equipped
with six threaded fusible plugs, three in each head, spaced approximately 1200
apart.
3. Ton Container and Cylinder Inspection, Cleaning, and Reconditioning
a) In addition to the required period retest, it is recommended that each ton
container and cylinder be internally and externally inspected prior to each
filling. This includes all appurtenances, such as valves andfusible plugs.
Criteria for such inspection is outlined in "Cylinder and Ton container
Procedure for Chlorine Packaging, "Chlorine Institute Pamphlet 17, Sections 3,
4, and 5.
F. PERIODIC RETESTING AND RE -INSPECTION
1. Cylinder and Ton Containers to be Tested
a) Cylinders (except DOT 3E 1800) and ton containers must be retested at least
once in five years (DOT Section 173.34e and Section 173.31 d).
b) Cylinders cannot be filled until they are retested after the five year anniversary
of the month in which it was tested. Ton containers can be filled until the end of
the calendar year during which their five year test is due.
c) Retests are also required after any reheat treatment. In addition, retest any
container which shows evidence of weakness at any time, or show a S percent or
more loss in weight.
2. Test Procedure
a) Cylinders and ton containers are hydrostatically retested by the hydrostatic
expansion method (DOT Section 173.34 (a) and Section 173.31 (d)J. If at the
time of requalification a container shows a leak or a permanent expansion which
exceeds 10% of the total expansion, it must be condemned.
3. Container Records
a) Records must be kept showing results of the test. Each container must have the
test date plainly and permanently stamped into the metal of one head or the
chime of each task passing the hydrostatic retest.
G. CONDITIONS OF DELIVERY
1. A South Bend Water Works representative shall specify the location for
chlorine cylinder and ton container deliveries.
2. Delivery Locations:
Location
Type of Container
Address
North Station
2,000 lb. Ton Container
830 North Michigan Street
Carriage Hills
150 lb. Cylinder
52290 Shenandoah Drive
Erskine
150 lb. Cylinder
4116 South Fellows Street
South
1,250 lb. Ton Container
3600 South Main Street
Cleveland South
150 lb. Cylinder
4900 Cleveland Road
Cleveland North
150 lb. Cylinder
4949 Cleveland Road
Waste Water
2,000 lb. Ton Container
3113 Riverside Drive
3. Vendor personnel shall conduct all activities related to the loading and
unloading of cylinders.
4. Ton containers will need to be delivered with a cherry picker.
5. Minimum deliveries are two (2) ton containers and twelve cylinders.
6. Supplier must be able to guarantee delivery within five (5) calendar days after
order placement
7. Vendor personnel shall not unload any filled cylinders or ton containers prior
to live inspection by South Bend Water Works Personnel.
8. Vendor personnel shall assist South fiend personnel in the visual inspection of
each cylinder or ton container for:
a) External damage or defect
b) Proper installation of valve protection housing or caps
c) Visual inspection of valves and fusible plugs
d) Determination of markings of retest and recertification
9. Motor vehicles used to ship ton containers shall be properly equipped with lift
equipment suitable for handling containers to any point where the container is
to be loaded upon or unloaded from the vehicle.
a) Cylinders containing chlorine shall be securely lashed in an upright position,
loaded into racks securely attached to the motor vehicle, or packed in boxes or
crates of such dimensions as to prevent their overturning.
II. FERRIC CHLORIDE
G�82MMU
1. Normal concentration percent by Weight; 33-35%
2. Specific Gravity: 0.33
B. DELIVERY
1. Full truck deliveries (4500 gallons) to the Ferric feed facility Plant located
at; 3113 Riverside Drive, South Bend, IN 46628
III. FLUORISILICIC ACID
A. GENERAL
1. The Fluorisilicic Acid supplied under these specifications shall be clean and
free of visible suspended matter and shall not contain more than 0.020 percent
of the "heavy metals", mercury, lead, bismuth and copper expressed as lead
(Pb); and shall contain no soluble mineral or organic substances in quantities
capable of a deleterious or injurious effect upon the health of those consuming
water that has been treated properly with fluorsilicic acid.
2. Product to meet the latest AWWA standard for Fluorisilicic Acid (13703).
3. Price is to be based on a 23% solution.
4. Bidders shall quote price per pound.
B. DELIVERY
1. The vendor shall deliver bulk fluoride to the following well locations in the
quantities as specified by a representative of the South Bend Water Works.
2. 23% Fluorisilicic Acid delivered in tank truckloads.
3. Deliveries are estimated at thirteen (13) tank trucks with two to four stop -offs
per 20,000 lb. load.
4. No stop -off or fuel surcharges allowed however, demurrage charges will be
allowed after 2 hours per stop.
5. Suppliers must furnish own unloading hose at least 40 feet in length with
proper couplings to hook onto two male N.P.T., and must blow off hose to
bulk tank at each stop.
6. City will not accept delivery of more than 10% over the order quantity.
7. Delivery Locations:
Location
Bulk Tank
Address
North Station
1600 gallons
830 North Michigan Sheet
Carriage Hills
0 gallons
52290 Shenandoah Drive
Edison
1350 gallons
2708 Rockne Drive
Erskine
450 gallons
4116 South Fellows Street
South
500 gallons
3600 South Main Street
Cleveland South
1100 gallons
4900 Cleveland Road
Cleveland North
550 gallons
4949 Cleveland Road
Pinhook
1000 gallons
3801 Riverside Drive
Olive
1750 gallons
915 South Olive Street
IV. POTASSIUM PERMANGANATE
A. MATERIAL
Free Flowing Grade Potassium Permanganate shall meet the requirements of
AW WA Specification 603-98 and shall be manufactured domestically and
certified suitable for use in public water supply by appropriate state and
federal agencies.
1. The potassium permanganate shall be delivered in 55 pound pails made of 24-
gauge steel or plastic and shall be equipped with a handle.
a) The pails shall remain the property of the South Bend Water Works.
b) The pails shall be unloaded and neatly stacked at the pumping stations.
2. Deliveries will be ordered on an as needed basis with each delivery consisting
of approximately 8 to 16 (55 Lb.) pails.
3. Deliveries must be made within 5 days of placement of the order.
4. Vendor shall deliver pails to the following site:
a) Water Works North Station — 830 North Michigan Street
V. BLENDED PHOSPHATE SEOUESTRANT CORROSION INHIBITOR
A. STANDARDS
1. Product shall be a minimum of 85% sodium pyrophosphate.
2. The remaining ingredient(s) shall also be sodium phosphate material(s).
Product must already be listed in the latest National Sanitation Foundation
(NSF) Standard 60 directory.
3. The percent phosphate as PO4 must be disclosed and by Indiana law, be
marked on the outside of the container.
B. TECHNICAL ASSISTANCE
1. The successful vendor giving a quote must also provide on -site technical
assistance to the Authority for an eight hour day per month for the first six
months of product usage.
2. After the first 6 months of on -site technical assistance, the Authority will
request further on -site technical assistance on an as needed basis.
3. The vendor shall provide a per visit cost in their quote for the additional site
visits.
4. Each visit will be one workday (Monday through Friday only), from 7:00 a.m.
to 3:30 p.m. EST.
5. Vendor must submit the name(s) and resume(s) of the technical representative
that will perform the on -site assistance with your quote submittal.
6. The technical representative shall be an employee or certified representative
of the vendor and have a minimum of three years of experience in the
application of blended phosphate sequestering products in municipal water
supply and be available Monday through Friday from 7:00 a.m. to 3:30 p.m.
EST to answer questions which may arise in applying their product.
C. REQUIREMENTS
1. A list of two municipal references within a one hundred mile radius of South
Bend using the product for a minimum of one year.
2. Each reference must include the name of the municipality, the
superintendent's name, and phone number.
3. A one pint sample must be submitted with bid for analysis.
4. During the contract period, additional sampling and analysis will be made.
5. Contract can be nullified if testing indicates unauthorized changes have been
made to product.
6. Samples of product being used by references may also be sampled.
7. Evaluation
IN
a) Sample product analysis
b) Reference interview and possible sample analysis
c) Verification of ingredients.
8. Testing
a) The City reserves the right to submit samples of the polyphosphate product to an
independent laboratory of the Chy's choice for chemical, biological, and
physical analysis and testing.
b) Any product which, in the City's opinion, contains hazardous or deleterious
substance or fails to comply with these specifications will be disqualified.
c) The cost of this analysis and testing will be incurred by the vendor with the
understanding that a maximum often samples per year will be submitted.
d) Guaranteed minimum available phosphate percentage as PO4 is to be Eighty
Percent (80%).
9. Other evaluation:
a) List of data that confirms products effect on (a) copper, (b) sequestration
b) List of data that confirms company' experience in other cities and technical
support.
10. Certified Analysis
a) The supplier shall provide a certified chemical analysis of a polyphosphate
product sample taken from the production facility from which he proposes to
supply the City of South Bend.
b) He shall further certify analysis to be representative of the product he proposes
to provide the City.
11. Performance Requirements
a) When applied at a rate yielding not more than four (4) parts of polyphosphate as
PO4 to each part of iron and manganese, the product shall be capable of holding
iron and manganese in solution for no fewer than five (5) days at seventy (70)
degrees Fahrenheit in the presence of one-hat(milligram per liter (0.5 mg/1) free
chlorine residual and for no less than twenty-four (24) hours at 140 degree F.
b) The City reserves the right to run performance tests once a month.
c) Any product which, in the City's opinion, does not meet the specified
performance requirements or fails to comply with the specifications will be
disqualified.
D. COVERAGE
1. These specifications cover blends of phosphate compounds used to stabilize or
sequester soluble iron and manganese in potable water.
E. PHYSICAL FORM
1. Product shall be a granular form. Powdered material will not be accepted.
11
F. PHYSICAL STANDARDS
1. Phosphate blend shall comply with the following physical requirements:
a) Color: White
b) Solubility: Completely miscible in water
c) Percent Phosphate as PO4 Minimum of 80%
d) Physical Form: Granular
G. CHEMICAL STANDARDS
1. Phosphate blend shall contain only NSP approved phosphorous ingredients.
2. No amines or other chelating agents shall be used.
3. Blended phosphate product formulation shall be only sodium salts of
phosphate compounds.
4. No potassium salts shall be used.
5. Impurities in polyphosphate products shall not exceed the following
concentrations:
Arsenic as AS
0.001 mg/1
Copper as CU
0.2 mg/1
Heavy Metals (total as Pb)
0.001 mg/1
Iron FE
0.1 mg/1
Manganese as MN
< .05 mg/1
Organics as C
None
Silica as SIO2
1.0
Zinc as ZN 1
0.01 mg/1
6. In addition to the above standards, polyphosphate products shall contain no
substance, for which the Indiana Pollution Control Board has established a
limit in potable water, in a concentration exceeding the limit established for
potable water.
H. PACKAGING & DELIVERY
1. Product shall be shipped in 50 pound bags and stored locally.
2. Deliveries are to be made within two to three days of notice.
3. Vender will be required to deliver product weekly or as needed to each well
field in order to maintain specified stock levels.
4. Weekly delivery receipts will be issued.
12
5. Delivery sites are as follows:
Location
Address
Carriage Hills
52290 Shenandoah Drive
Erskine
4116 South Fellows Street
South
3600 South Main Street
Cleveland South
4900 Cleveland Road
Cleveland North
4949 Cleveland Road
13
VI. SOLAR SALT SPECIFICATION
A. GENERAL
1. The salt will be used to prepare a saturated brine solution which will be used
as a chloride source for the on -site hypochlorite generator.
2. Bids will be all inclusive.
3. Solar salt/Purex manufactured by Morton Salt (or equal) shall be supplied in
bulk deliveries and blown into the brine saturator tank using the supplier's
truck -mounted blower.
4. The existing brine saturator tank has the capacity to receive 25-ton bulk
deliveries.
5. Equipment such as hoses with the 4" quick disconnect shall be provided with
salt delivery by the provider.
6. Off-loading truck air pressure shall not exceed 10 p.s.i. for every salt delivery.
B. PRODUCT
1. Salt for sodium hypochlorite generation
2. To ensure proper operation of the on -site hypochlorite generator, solar salt
shall meet or exceed the following quality parameters:
Description
Percent
Maximum/
Minimum
Water Insoluble
0.01%
maximum
Calcium Nitrate
0.14%
maximum
Magnesium Sulfate
0.02%
maximum
Magnesium Chloride
0.1%
maximum
Sodium Chloride
99.82%
minimum
NaCl Wet
93.3%
1 minimum
NaCl Dry
96.3%
minimum
Moisture (as H2O)
3%
maximum
Lead
0.0007%
maximum
Copper
0.0003%
maximum
Iron (as Fe)
0.002%
maximum
Fluoride
0.01%
maximum
3. Sodium Chloride content shall be determined per the AWWA B200-03
standard or per ASTM Standard Methods.
4. Salt shall be certified to ANSI/NSF Standard 60 when the sodium
hypochlorite solution produced by the electrolytic generator will be used for
disinfection of drinking water.
5. Salt shall contain no anti -caking or free -flowing additives or conditioners.
14
6. Salt shall be medium, coarse or extra coarse grade with a minimum bulls
density of 60 lb/ft3 to avoid use of gravel bed in brine saturator tank.
C. PHYSICAL PROPERTIES
1. Purex or Equal
a) The pour (loose) bulk density shall be 1.15-1.25 g/nal (72-78 lbs/ft').
b) Production shall be unscreened, receiving a coarse scalping of 10-14niesh. The
mean crystal size shall be 290-430 urn.
c) The mean suiface area of the crystals shall be 65-98 eni. sq/g.
d) Sodium Chloride content shall be determined per the AWWA B200-03 standard
or per ASTMStandard Methods.
e) Morton's Purex or equal shall be certified to ANSINNSFStandard 60 when the
sodium hypochlorite solution produced by the electrolytic generator will be used
for disinfection of drinking water.
Morton's Purex or equal shall contain no anti -caking or free flowing additives
or conditioners.
D. DELIVERY LOCATIONS:
1. Edison Filtration Plant, 2708 Rockne Drive, South Bend, IN
2. Olive GAC Building, 915 S. Olive Street, South Bend, IN
mi
VII. SULFUR DIOXIDE
A. PROPERTIES
Boiling Point
-10°C
Color
Colorless
Specific Gravity
(80°F)
1.363
Critical Temp.
314.82°F
Critical Pressure
1141.5 PSIA
B. USAGE
1. Estimated annual usage is 100 tons, more or less, to be delivered in 2,000 lb
containers of liquid SO2 in truckload lots of 10 containers.
C. DELIVERY
1. Supplier must be able to guarantee delivery of 10 tons (20,000 lbs) within five
(5) calendar days fi•om release of requirement.
2. Material to be delivered F.O.B.
3. No freight surcharges allowed.
4. Billing must be submitted on a CWT unit basis.
5. Delivery Location: Waste Water Treatment Plant located at 3113 Riverside
Drive, South Bend, Indiana 46628.
16
VIII. DRY POLYMER FLOCCULENT
A. GENERAL
1. The purpose of this specification is to outline minimum acceptable properties
of a polymer at the Bureau of Waste Water in the treatment process.
2. Quantity of the polymer stated in this specification is intended as an estimated
usage during a 12 month period rather than an absolute quantity.
3. Polymer is considered a performance product and must meet certain standards
due to compliance related issues on the NPDES Permit.
4. Any supplier that has not been previously approved must perform bench
testing on any polymer bid to prove the product will meet the standards
necessary to ensure permit compliance.
5. When samples are required, such samples shall be delivered or shipped at the
vendor's expense to the following name and address: Nancy Clay, 3113
Riverside Dr. South Bend, IN 46628.
6. Samples must be clearly labeled with your company's name, address, and
(item number).
7. All samples must be representative of the item bid.
8. All samples will become the property of the City of South Bend, and will not
be returned.
B. PROPERTIES
1. Products will be a high molecular weight cationic polyelectrolyte, supplied as
a micro -bead or in granular form.
2. The product must be completely non -dusting, fi-ee flowing and completely
soluble in water with a very rapid dissolving rate.
3. Typical Properties
Bulls Density
50 lbs. per cubic ft.
Particle Size
95% less than 1 min
pH of 1 % Solution
3.5 — 4.5
C. PACKAGING/DELIVERY
1. Packaging to be in 50 — 55 lb polyethylene bags.
2. Must be able to guarantee delivery of 9,000 lbs within 14 calendar days after
order placement.
3. Prices must be submitted in cost per pound with freight included.
4. Material to be delivered F.O.B. the Waste Water Treatment plant located at
3113 Riverside Drive, South Bend, IN. 46628.
17
IX. LIQUID CALCIUM NITRATE 66%
A. GENERAL
1. The estimated annual usage of Liquid Calcium Nitrate (66%) is 45,000
gallons, more or less.
2. Supplier must be able to guarantee delivery of 4,000 to 5,200 gallons within
five (5) calendar days after order placement.
B. TYPICAL PROPERTIES
Concentrations:
Ca(NO3)2
46.34%
Ca 03 2. 41420
66.5%
Ca
11.2%
Mn (ppm)
Less than 1
Specific Gravity:
1.454 g/ml at 20'C
pH:
6.00 at 20°C
C. DELIVERY
1. Full truckload quantities are to be approximately 3,500 gallons
2. Delivery will be to two separate remote locations. Geyer Ditch GPS location
41.69565,-86.40614. Sage Road GPS location 41.71024,-86.41629.
3. Remote locations are accessed via a combination lock. Delivery requests will
include the combination lock if City personnel will not be on -site during
deliveries. If City personnel will be on -site the combination will be omitted
from the manifest.
4. Prices must be submitted in cost per gallon with freight included.
X. SODIUM HYPOCHLORITE 12.5%
A. GENERAL
1. The estimated annual usage of Sodium Hypochlorite is 30,000 gallons, more or less.
2. The City owns multiple 2,550+ gallon tanks for the storage of Sodium Hypochlorite 12.5%.
3. These tanks come equipped with all necessary Fittings and outlets, as well as secondary
containment for increased safety.
4. Supplier must have necessary hoses and connectors to connect to a 2 inch quick disconnect
fitting.
5. Product delivered to a Water Filtration Facility must meet the required ANSUNSF Standard
60.
B. TYPICAL PROPERTIES
Concentrations
Sodium Hypochlorite
12.5%
Specific Gravity
1.1964
pH
12.5 to 13.5
Molecular Weight
74.44
Boiling Point
>212°F
Freezing Point
-1 VF
C. DELIVERY
1. Supplier must be able to guarantee delivery of 1,800 to 4,500 gallons within seven (7)
calendar days after order placement.
2. Full truck load quantities of approximately 1,800 to 4,500 gallons are to be delivered, F.O.B.
to:
a) Waste Water Treatment Plant, 3113 Riverside Drive, South Bend, 1N. 46628.
b.) Pinhook Filtration Plant, 2801 Riverside Drive, South Bend, IN 46628.
c.) Edison Filtration Plant, 2708 Rockne Drive, South Bend, IN 46615.
3.) Prices must be submitted in cost per gallon with freight included.
19
XI. SODIUM PERMANGANATE
A. GENERAL:
1. The bid will be for two separate line items for the same product (20% Liquid Sodium
Permanganate)
2. One line item will be for deliveries of 275-gallon totes.
3. The other will be for deliveries between 500 and 550 gallon increments.
B. TYPICAL PROPERTIES
1. Product shall be bulk 20% (by weight) +/- 0.5% liquid sodium permanganate (NaMn04).
2. 20% Liquid Sodium Permanganate shall be produced domestically with in the United
States.
3. Product shall meet or exceed ANSI/AW WA standard B603-03 or subsequent revisions.
4. Product shall be listed by the NSF as being in full compliance with NSF Standard No. 60
for Drinking Water Treatment Chemicals — Health Effects.
C. DELIVERY
1. All deliveries shall be made within 48 hours of the request to the following address: 2801
Riverside Drive, South Bend IN 46628.
2. The product is to be delivered in clean containers/tanks and is free of contamination.
Contamination of stock shall render the contractor liable for disposal of contaminated material,
cleanup of storage facilities and Rill replacement of stock at the Supplier's expense.
3. All deliveries shall be made on weekdays (excluding holidays) between the hours 7:00 AM
and 11:00 AM
4. The off-loading of the 275-gallon totes containing sodium permanganate from the delivery
vehicle to the City's storage location will be performed by pressurizing the container to our point
of delivery or by transfer pump.
5. Deliveries must be coordinated with the City. The Identity of the driver must be made known
by fax or email 24 hr. prior to delivery. The delivery vehicle operator must call the City contact
no less than one hour prior to delivery.
6. The Contractor and shipper shall be responsible for all health, safety, and costs associated with
the transportation of the product to the Pinhook WTP. 2801 Riverside Drive 46628.
7. The City reserves the right to reject any delivery which does not conform to these
specifications or which has been contaminated.
pill
BID NAME
FOR BIDS DUE
BID/PROPOSAL
CITY OF SOUTH BEND
Water Treatment Chemicals 2017-2018
March 14, 2017 ; 9:30 a.m., Local Time
Item
Estimated
No
Item
Quantity/Y
Unit
Unit Price
Extended
ear
1
Chlorine— 1 Ton Cylinders
150
Ton
$ 294.00
$44,100.00
2
Chlorine— 150 Lb. Cylinder
150
Cyl.
$ 34.00
$ 6,100.00
3
Ferric Chloride
90,000
Gal.
$ NO BID
4
Fluorisilicie Acid — 23%
260
Ton
$ 349.00
$90,740.00
5
Potassium Permanganate — 55 Lb.
7,500
Lbs.
Pails
$ 3.40
$25,500.00
6
Blended Phosphate Sequestrant
22,500
Lbs.
$ NO BID
7
Solar Salt
125
Ton
$ NO BID
g
Sulfur Dioxide —1 Ton Cylinders
100
Ton
$ 486.00
$48,600.00
9
Dry Polymer Flocculent — 50 / 55
40,000
Lbs.
Lb. Polyethylene Bag
$ NO BID
10
Liquid Calcium Nitrate
25,000
Gal.
$ 1.98
$49,500.00
11
Sodium Hypochlorite —12.5%
30,000
Gal.
$ .72
$21,600.00
Sodium Permanganate
12
275 Gallon Totes
2,200
Gal.
$ NO BID
Sodium Permanganate
13
2,200
Gal.
500-500 Gallon Bulb
$ NO BID
Bidder (Firm):
Alexander Chemical Corporation, A Carus Company
Address: 315 Fifth Street
Telephone
City/State/Zip: Peru, IL61354 Number:
By: Susan Buchanan
Printed Name
VP. CFO
800-435-6856
�)6��
(Signature)
21
BOARD OF PUBLIC WORKS
Gary A. Gilot, President Elizabeth A. Maradik, Member
Therese J. Doran, Member
Suzanna M. Fritzberg, Member
James A. Mueller, Member Attest: Linda M. Martin, Clerk
22
Alexander
Chemical
A Carus Company
CgRUS®
Alexander Chemical Corporation, A Carus Company, is a 100%women owned business and will offer
free safety training for Certified Education Credits.
4v/ , `-
Susan Buchanan, VP, CFO
315 Fifth Street, P.O. Box 599, Peru, IL 61354
Tel 800.435.6856, Fax 815.224.6697
CITY OF SOUTH BEND
INSTRUCTIONS TO BIDDERS
1. BID FORMS AND EXECUTION
A. Bidders are expected to examine the Drawings, Specifications, Proposal and all Instructions.
Failure to do so will be at the Bidder's risk.
B. Each Bidder shall furnish all information required by the Notice, Instructions to Bidders and
Specifications. Bids must be made on the form provided. The Bidder shall sign the Proposal
and Non -Collusion Affidavit, which is a part of the provided form, where indicated, provide a
notary signature and provide all other information required.
C. The Bidder shall sign the Proposal in the following manner: If the Proposal is made by an
individual, his/her name and post office address must be shown. If made by a partnership or
joint venture, the name and post office address of each member of the partnership or joint
venture must be shown. If made by a corporation, the Proposal must be signed by an officer
of the corporation or by a representative duly authorized by the corporation to execute the
Proposal in its behalf.
2. SEALED BIDS ONLY
A. Bids, Proposals, Guaranty, and other required documents must be submitted in a sealed
envelope marked on the outside with the general classification of material bids, i.e. "Bid for
Computer Equipment," "Bid for Front End Loader," or "Bid for Office Supplies."
B. When samples are required, such samples shall be delivered or shipped at the bidder's
expense to the address specified in the Invitation to Bid. Samples must be shipped
separately from bid documents and labeled clearly with the Bidder's name, address and the
commodity or equipment classifications and documents, the item (and item number, if any),
and Material Safety Data Sheets (if applicable). All samples must be representative of the
commodities or equipment which will be supplied by the successful Bidder. All samples will
become the property of the City of South Bend and none will be returned, unless otherwise
stated in the Specifications.
C. In the event of an inconsistency between provisions of the contract documents, the
inconsistency shall be resolved by giving precedence in the following order:
3. ORDER OF PRECEDENCE
A. Bid Form attached Proposal
B. Amendments to Specifications
C. Specifications
D. Special Provision
E. Instructions to Bidders
F. Notice to Bidders
4. DELIVERY OF BIDS
A. Bids must be delivered to the Office of the Board of Public Works, 131h Floor, County -City
Building, Room 1316, 227 West Jefferson Boulevard, South Bend, Indiana 46601 (574) 235-
9251, by the time specified (local time) in the Notice to Bidders. If not delivered personally,
the sealed envelope containing the Bid must be mailed to the following address:
City of South Bend
Clerk of the Board of Public Works
1316 County -City Building
227 West Jefferson Boulevard
South Bend, Indiana 46601
B. The Post Office Department will be considered agent of the Bidder in delivering the bid. The
City will not be responsible for deliveries. Any Bids received after the time specified will
be returned unopened.
23
C. Bids will be opened and read publicly at the time and place designated in the Notice to
Bidders. Bidders, their authorized agents, and the public are invited to be present.
D. Bidders may bid on one (1) or more item, provided however, that the bid submitted for each is
delivered in a separate, sealed envelope, with the envelope clearly labeled on the outside
as to the specific item for which the bid is being submitted. Bidders may submit separate bid
bonds for each item being bid upon OR may submit one (1) bid bond equal to 10% of the
combined total of all bids submitted.
E. The Board may reject any bid based on being non -responsiveness should such bid not
conform to these requirements as listed herein or if a bid cannot be delivered in a
manner consistent with the needs of the City.
S. ADDENDA— NO VERBAL INTERPRETATIONS
A. No inquiries by Bidders relative to interpretation of Plans, Specifications, Special Provisions,
or other Bidding Documents will be answered verbally. If any prospective Bidder is unable or
unwilling to comply with one or more requirements of the bidding document, such Bidder
should so inform the Board of Public Works in writing. Upon receipt of such information,
consideration will be given to the advisability of issuing an Addendum which would thereupon
become applicable to all Bidders. Any such inquiry must be submitted at least seven (7) days
prior to the bid opening date in order to give the Board sufficient time to consider any
necessary Addendum. All answers to such inquiries, in the form of Addenda, will be furnished
to all prospective Bidders who have registered with the City. All Bidders are required to
acknowledge receipt of any Addenda by inserting the Addendum number and the issuing date
on executed Proposals.
6, REJECTION OF PROPOSALS CONTAINING ALTERATION ERASURES INCOMPLETE
BIDS AND ETC.
A. Proposals shall be rejected if they show any alteration of form, additions not called for,
conditional or alternate bids (except when and insofar as are invited), incomplete bids,
erasures or irregularities of any kinds.
B. All blank spaces for bid prices must be filled in, in ink, with the unit price and total price for
each item (This does not apply to divisible bids). In case of incorrect totaling of amounts and
where the unit price and the extension thereof do not agree, the unit price for each item shall
govern, and the City is authorized to correct all erroneous extension and totals for the purpose
of comparing bids.
7. TRADE DISCOUNTS
A. Trade discounts shall not be shown separately, but shall be incorporated in the Bidder's unit
price, unless otherwise specified.
8. VEHICLE BIDS
A. Bidders may bid on one (1) or more vehicles, provided however, that the bid submitted for
each vehicle is delivered in a separate, sealed envelope, by vehicle, with the envelope clearly
labeled on Bidders may bid on one (1) or more vehicles, provided however, that the bid
submitted for each vehicle is delivered in a separate, sealed envelope, by vehicle, with the
envelope clearly labeled on the outside as to the specific vehicle for which the bid is being
submitted. Bidders may submit separate bid bonds for each vehicle being bid upon OR may
submit one (1) bid bond equal to 10% of the combined total of all vehicle bids submitted.
B. If an Option is included within these specifications, please be advised that, optional items
placed in the specifications are to determine the best configuration of the item within a
budgeted amount and may be included in the award criteria. If the Board elects to award
one or more option(s), the base bid price and the option bid price(s) will be totaled and
compared for all bidders offering the final configuration. Award will be made based on the
lowest responsible/responsive bid prices submitted for the base bid with the selected
option(s), if applicable. Failure to submit a bid on an option may result in the entire bid being
non -responsive, depending on the final configuration of the product.
I.'
9. The Board may reject any bid that does not conform to these requirements as non-
responsive.
10. TAX EXEMPTIONS
A. The City of South Bend is exempt from the payment of federal excise and transportation taxes
levied under the provision of the Internal Revenue Code. It is also exempt from the Indiana
State Gross Retail Tax (sales tax). The City will furnish the successful Bidder with any
certificate of exemption required.
11. WITHDRAWAL OF BIDS
A. Withdrawal of bids will be allowed only in those cases in which a written request to withdraw a
bid is received by the Board of Public Works prior to the date and hour for receiving and
opening bids. In such cases, the same will be returned to Bidder unopened.
12. ESCALATOR OR CONTINGENT CLAUSES
A. The use of escalator clauses or other contingent clauses by the Bidder is prohibited, unless
requested or permitted by the Invitation to Bid. No Proposal shall contain nor be
accompanied by any writing purporting to limit or qualify the City's right to accept such
Proposal or purporting to alter such Proposal or any Contract which may be executed
pursuant thereto.
13. PRICES MUST BE DELIVERED PRICES
A. The bid price shall be a delivered price. All materials shall be shipped F.O.B. destination as
specified in the Invitation to Bid. No fuel surcharges accepted.
14. AWARD —WAIVER OF TECHNICALITIES
A. The Award of Bid, if any award be made, will be made within sixty (60) calendar days after the
opening of Proposals to the lowest responsible and responsive Bidder who's Proposal
complies with all the requirements prescribed, exclusive of technicalities waived. Until the
final award of the Bid, however, the right is reserved by the City to reject any and all
Proposals and to waive technical errors.
15. SPLITTING OF AWARDS/DIVISIBLE BIDS
A. Bids will be awarded on the basis of the total dollar amount for all items in the Proposal unless
the bid is described by the City as a Divisible Bid. The City may award a Divisible Bid to the
lowest responsible and responsive Bidder for each item or class of items as indicated in the
bid documents.
16. BIDDER QUALIFICATION
A. The City may require any Bidder to submit evidence of qualifications, and may consider any
evidence of the financial, technical, and other qualifications and abilities of the Bidder. The
City will not award a Contract to a Bidder who, in its opinion, is not fully qualified on the basis
of financial resources and responsibility, possession of adequate equipment, personnel,
experience, and past record of performance to perform the obligations to be undertaken
competently and without delay.
17. PURCHASE ORDERS
A. A Purchase Order will be issued to the successful Bidder after formal acceptance of the bid is
made by the City.
18. NEW MANUFACTURE
A. Unless otherwise specified in the Invitation to Bid, the items offered shall all be new and the
latest model of manufacture.
19. SOURCE OF SUPPLY
A. If the Bidder is not a manufacturer, the source of supply must be shown and all sub-
contractors must be identified.
20. PACKAGING
A. All items shall be delivered strongly packed and marked according to accepted commercial
practice unless otherwise directed in the Specifications. No charge shall be made for
containers and the City shall have no obligation to return containers unless otherwise
25
provided by the Specifications or Special Provisions. Any items not received in good
condition will be rejected.
21. INSPECTION OF GOODS
A. The City of South Bend reserves the right to inspect and have any goods tested after delivery
for compliance with the specifications. Notice of latent defects, which would make the item
unfit for the purposes for which they are required, may be given at any time within one year
after discovery of the defects.
B. All items rejected must be removed immediately by the Contractor at the expense of the
Contractor. If the Contractor fails or refuses to remove the rejected items, they may be sold
by the City of South Bend,
C. In some cases, at the discretion of the City, inspection of the commodities or equipment will
be made at the factory, plant, or other establishment where they are produced before
shipment.
D. The above provision shall not be construed in limitations of any rights the City may have
under any laws including the Uniform Commercial Code.
22. ASSIGNMENTS
A. No person to whom a Contract has been awarded may assign his interest in the Contract
without the consent, in writing, of the City.
23. CANCELLATION
A. The City of South Bend reserves the right to cancel any Contract for failure or refusal of
performance, fraud, deceit, misrepresentation, collusion, conspiracy, or any other misconduct
on the part of the Contractor.
24. DEDUCTION OF DAMAGES
A. If the City cancels the contract for any cause, it shall deduct from whatever is owed the
Contractor on the Contract or any other Contract, any amount sufficient to compensate the
City for any damages suffered by it because of the Contractor's wrongdoing.
25. METHOD OF INVOICING FOR PAYMENT
A. Contractor shall bill the City of South Bend
1. On regular invoice form giving a complete and detailed description of the goods delivered,
including purchase order number.
2. If the Contractor allows a discount, the period of time in which the City must make
payment to qualify for the discounts shall be computed from the date the City received the
invoice (completely filled out), or the date the goods are delivered and accepted,
whichever may be later, and shall not be less than twenty (20) days.
3. If more than one shipment is made under the Contract and on the same purchase order,
the City will make partial payments on a basis that is agreeable to both parties.
26. OWNERSHIP OF GOODS
A. The goods which are the subject of the Contract shall remain property of the Contractor until
delivered to and accepted by the City of South Bend.
27. ESTIMATED QUANTITIES
A. If the quantity set forth in the Notice to Bidders and Proposal is approximate and represents
the estimated requirements of the City for a specified period of time, the unit price and the
extended total price thereof shall be used only as a basis for the evaluation of bids. The
actual quantities necessary may be more or less than the estimate, but the City shall neither
be obligated nor limited to any specific amount. The City will, if at all possible, restrict
increases to twenty percent (20%) of the estimated quantity and will, if at all possible, restrict
decreases to twenty percent (20%) of the estimated quantity.
28. TERM "OR EQUAL"
A. Where the term "OR EQUAL" is used in these Specifications, the Bidder deviating from
specified item shall file with his/her bid a letter fully explaining and justifying his/her proposed
26
article or equal. The City of South Bend shall be the sole judge in determining if the "OR
EQUAL" offered meets the Specifications.
29. INDEMNIFICATION CLAUSE
A. The Contractor agrees to indemnify, defend, and hold harmless the City of South Bend, its
agents, officers, and employees from all costs, losses, claims and suits, including court costs,
attorney fees, and other expenses, arising from or out of the negligent performance of this
Contract by the Bidder or because or arising out of any defect in the goods, materials or
equipment supplied by the Bidder.
NOTE: Incoming mail does not reach the Board of Public Works until after 9:30 a.m. If
you are sending your bid via Federal Express or another overnight source,
please confirm that your package will arrive before the bid opening time and
date.
27
-" IA Document A310TM — 2010
CONTRACTOR:
(Name, legal status and address)
ALEXANDER CHEMICAL CORPORATION, A
CARUS COMPANY
315 Fifth Street
Peru, IL 61354
SURETY:
(Name, legal status and principal place
of business)
INTERNATIONAL FIDELITY INSURANCE
COMPANY
One Newark Center
Newark, NJ 07102
OWNER:
(Name, legal status and address)
CITY OF SOUTH BEND CLERK OF THE BOARD OF PUBLIC WORKS
1316 County -City Building, 227 West Jefferson Blvd, South Bend, IN 46601
BOND AMOUNT: Ten percent of amount bid.
(101 of Amount Bid)
This document has important legal
consequences. Consultation with
an attorney is encouraged with
respect to its completion or
modification.
Any singular reference to
Contractor, Surely, Owner or
other party shall be considered
plural where applicable.
PROJECT:
(Name, location or address, and Project number, if any)
Supply Chlorine, Fluorisilicic Acid, Potassium Permanganate, Sulfur Dioxide, Liquid Project Number, if any:
Calcium Nitrate, and Sodium Hypochlorite
The Contractor and Surety are bound to the Owner in the amount set forth above, for the payment of which the
Contractor and Surety bind themselves, their heirs, executors, administrators, successors and assigns, jointly and
severally, as provided herein The conditions of this Bond are such that if the Owner accepts the bid of the Contractor
within the time specified in the bid documents, or within such time period as may be agreed to by the Owner and
Contractor, and the Contractor either (1) enters into a contract with the Owner in accordance with the terns of such
bid, and gives such bond or bonds as may be specified in the bidding or Contract Documents, with a surety admitted
in the jurisdiction of the Project and otherwise acceptable to the Owner, for the faithful performance of such Contract
and for the prompt payment of labor and material furnished in the prosecution thereof, or (2) pays to the Owner the
difference, not to exceed the amount of this Bond, between the amount specified in said bid and such larger amount
for which the Owner may in good faith contract with another party to perform the work covered by said bid, then this
obligation shall be null and void, otherwise to remain in full force and effect. The Surety hereby waives any notice of
an agreement between the Owner and Contractor to extend the time in which the Owner may accept the bid. Waiver of
notice by the Surety shall not apply to any extension exceeding sixty (60) days in the aggregate beyond the time for
acceptance of bids specified in the bid documents, and the Owner and Contractor shall obtain Ute Surety's consent for
an extension beyond sixty (60) days. \\\\\\ tttttll IIIIIU//t//t/////
If this Bond is issued in connection with a subcontractor's bid to a Contractor, the term Contractor in t� haU„
be deemed to be Subcontractor and the tern Owner shall be deemed to be Contractor.
When this Bond has been furnished to comply with a statutory or other legal requirement in the loagion d ire , ca E E
any provision in this Bond conflicting with said statutory or legal requirement shall be deemed delro�
provisions conforming to such statutory or other legal requirement shall be deemed incorporated heT�itnVYi2
furnished, the intent is that this Bond shall be construed as a statutory bond and not as a common law�r�-.,
Signed and sealed this 8th day of March, 2017
ALEXANDER CHEMICAL CORPORATION,
(Prin i' (Seal)
(Witness)
(Title) Susan Buchanan, VP, CPO
r1 _ INTERNATIONAL FIDELITY INSURANCE COMPANY
c�_.�J\lQ>\L (Surey) 1 (Seal)
�77itness) SamanthaChierici d/:swr/�A JQ
(Title) Aerie Walton, Attorney in Fact
AIA Document A3101O —2010. Copyright 01963. 1970 and 2010 by The American Institute of Architects. All rights reserved.
Tel (s7s)s2a-72oo POWER OF ATTORNEY
INTERNATIONAL FIDELITY INSURANCE COMPANY
ALLEGHENY CASUALTY COMPANY
ONE NEWARK CENTER, 20TH FLOOR NEWARK, NEW JERSEY 07102-5207
KNOW ALL MEN BY THESE PRESENTS: That INTERNATIONAL FIDELITY INSURANCE COMPANY, a corporation organized and existing under
the laws of the Slate of New Jersey, and ALLEGHENY CASUALTY COMPANY a corporation organized and existing under the laws of the Slate of
New Jersey, having their principal office in the City of Newark, New Jersey, do hereby constitute and appoint
DEREK J. ELSTON, AERIE WALTON, LINDAM. NAPOLILLO, MARCIA K. CESAFSKY,
CHRISTOPHER.P. TROHA, MARY F. DOYLE
Chicago; IL.
of
IG
a meeting duly held on
and deliver for and on its behalf as surety, any and all bonds and undertakings, contracts of indemnity
h are or may be allowed, required orpermitted by law, statute, rule, regulation; contract or otherwise
of these presents, shall be as binding upon the said INTERNATIONAL FIDELITY :INSURANCE
as fully andamply, to all intents and purposes, as. if the .same had been duly executed and
principal offices, y ly y
and is granted undeto anand by authorly of the following resINTERNATIONAL
lution adopt) ON y the
Board of Di ecto sE
VY at a meeting dulyy held on the 20th day of July, 2010 and. by the Board of Directors of ALLEGHENY
5tn day of August, 2000:
,yoke:
behalf
in the
agents
of any
of any
when
of the
IN WITNESS WHEREOF, INTERNATIONAL FIDELITY INSURANCE COMPANY and ALLEGHENY CASUALTY COMPANY have each executed and
attested these presents on this 31st day of December, 2016.
/W,STATE OF .. County of Essex NEW
JERSEY toPSUgtryco
s1G U� q
y fsaarvt 41936K
ROBERT W. MINSTER
Chief Executive Officer (International fidelity VJERgOy
Insurance Company) and President (Allegheny
Casualty Company)
On this 31st day of December 2016, before me came the individual who executed the preceding instrument, to. me personally known, and, being by me duly
sworn, said he is the therein described and authorized officer of INTERNATIONAL FIDELITY INSURANCE COMPANY and ALLEGHENY CASUALTY
COMPANY; that theseats affixed to said instrument are the Corporate Sealsof said Companies; that the said Corporate Seals and his signature were
duly affixed by order of the Boards of Directors of said Companies. < IN TESTIMONY WHEREOF, I have hereunto set my hand affixed my Official Seal,
at the City of Newark, New Jersey the day and year first above written. ,•
ogrsYroRPUBLIC
��.'
- V NOTAPY
' Uri
•• s ' 47
A NOTARY PUBLIC OF NEW JERSEY
FOF NEW �02 • My Commission Expires April 16, 2019.
„"'....... f`"• CERTIFICATION
I, the undersigned officer of INTERNATIONAL FIDELITY INSURANCE COMPANY and ALLEGHENY CASUALTY COMPANY do hereby certify that I have
compared the foregoing copy of the Power of Attorney and affidavit, and the copy of the Sections of the By -Laws of said Companies as set forth in said
Power of Attorney, with the originals on file in the home office of :said companies, and that the same are correct transcripts thereof, and of the whole
of the said originals, and that the said Power of Attorney has not been revoked and is now in full force and affect.
IN TESTIMONY WHEREOF,.. I havehereunto setmy hand this'. dcy of
MARIA BRANCO, Assistant Secretary
ACKNOWLEDGEMENT BY SURETY
STATE OF ILLINOIS
COUNTY OF COOK
On this 8t" day of March, 2017, before me, Derek Elston, a Notary Public,
within and for said County and State, personally appeared Aerie Walton to
me personally known to be the Attorney -in -Fact of and for International
Fidelity Insurance Company and acknowledged that s/he executed the said
instrument as the free act and deed of said Company.
IN WITNESS WHEREOF, I have hereunto set my hand and affixed my
official seal, at my office in the aforesaid County, the day and year in this
certificate first above written.
Notary Public in the State of Illinois
County of Cook
OFFICIAL SEAL
DEREK ELSTON
NOTARY PUBLIC, STATE OF ILLIN015
MY COMMISSION EXPIRES 09/OB/2018
PRODUCT SPECIFICATION SHEET
Chlorine
Effective 02/20/2015
Chemical Properties:
CAS#:
Chemical formula:
Chlorine, weight %:
Moisture, ppm:
Non-volatile residue ppm:
Bromine, ppm:
Physical Properties:
Boiling point:
Freezing point:
Specific gravity (Gas), g/mL:
Specific gravity (Liquid), g/mL:
Vapor pressure, psig:
Appearance:
Odor:
7782-50-5
Cl2
99.50 Minimum
50.00 Maximum
50.00 Maximum
180 Maximum
- 29.39 OF
- 150.00 OF
2.49@32OF
1.47 @ 32/39.2 "F
72 @ 60 OF
Amber -colored liquid, vaporizes
to greenish -yellow gas
Sharp, suffocating, pungent
Meets ANSI/AWWA specification B301
NSF International maximum use: 30.00 mg/L
Packaged by:
Alexander Chemical Corporation
Kingsbury Industrial Park
Kingsbury, Indiana 46345
800/348-8827
LSAFETY DATA SHEET
1. Identification
Product identifier Chlorine - Chlorine Liquefied Gas Under Pressure
Other means of identification Not available.
Recommended use Chlorine is primarily used as a water treatment chemical as a disinfectant. Also used as a
bleaching agent and in the manufacture of many consumer products.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company name
Carus Corporation
Address
315 5th Street
Peru, Illinois 61354, USA
Telephone
(815) 223-1500
Toll Free
(800) 435-6856
Fax
(815)224-6816
E-mail
salesmkt@caruscorporation.com
Website
www.caruscorporation.com
Company name
Alexander Chemical Corporation, a Carus Group Inc. Company
Address
7593 S. First Road,
Kingsbury Industrial Park, Kingsbury, Indiana 46345, USA
Website
www.alexanderchemical.com
Company name
Sierra Chemical Co, a Carus Group Inc. Company
Address
2302 Larkin Circle
Sparks, Nevada 89431, USA
Website
www.sierrachemsales.com
Contact person
Dr. Chithambarathanu Pillai
Telephone
(800) 348-8827 - All other non -emergency inquiries about the product should be
directed to the company
Emergency telephone
For Hazardous Materials [or Dangerous Goods] Incidents ONLY
number
(spill, leak, fire, exposure or accident), call CHEMTREC at
CHEMTREC®, USA: 001 (800) 424-9300
CHEMTRECO, Mexico (Toll -Free - must be dialed from within country):
001-800-13-203-9987
CHEMTRECO, Other countries: 001 (703) 527-388
2. Hazard(s) identification
Physical hazards
Oxidizing gases Category 1
Gases under pressure Liquefied gas
Health hazards
Acute toxicity, inhalation Category 2
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
Specific target organ toxicity, single exposure Category 3 respiratory tract irritation
Environmental hazards Hazardous to the aquatic environment, acute Category 1
hazard
OSHA defined hazards Not classified.
Label elements
< >< X >*
—+
Signal word Danger
Chlorine - Chlorine Liquefied Gas Under Pressure SIDS US
921762 Version #: 01 Revision date: - Issue date: 05-August-2014 1 / 8
Hazard statement
May cause or intensify fire; oxidizer. Contains gas under pressure; may explode if heated. Fatal if
inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Very
toxic to aquatic life.
Precautionary statement
Prevention
Keep/Store away from clothing and other combustible materials. Keep reduction valves/valves
and fittings free from oil and grease. Do not breathe gas. Use only outdoors or in a well -ventilated
area. In case of inadequate ventilation wear respiratory protection. Wash hands thoroughly after
handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release
to the environment.
Response
In case of fire: Stop leak if safe to do so. If inhaled: Remove person to fresh air and keep
comfortable for breathing. Immediately call a poison center/doctor. If on skin: Wash with plenty of
water. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and
wash it before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention. Get medical advice/attention if you feel unwell.
Storage Store locked up. Protect from sunlight. Store in a well -ventilated place. Keep container tightly
closed.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
3. Composition/information on ingredients
Substances
Chemical name Common name and CAS number %
synonyms
Chlorine 7782-50-5 > 99
Composition comments All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First -aid measures
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or
artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance.
Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device. Call a physician or poison control center immediately.
Skin contact
Frostbite: Do not remove clothes, but flush with copious amounts of lukewarm water. Get medical
attention immediately.
Eye contact
Frostbite: Immediately and briefly flush with lukewarm, gently flowing water. Cover both eyes with
a sterile dressing. Immediately obtain medical attention. GAS: Not applicable. No effects expected.
Ingestion
Not likely, due to the form of the product.
Most important
May cause central nervous system effects. Dizziness. Headache. Nausea, vomiting. Severe eye
symptoms/effects, acute and
irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision.
delayed
Permanent eye damage including blindness could result. May cause respiratory irritation.
Coughing. Burning pain and severe corrosive skin damage. May cause redness and pain.
Indication of immediate
Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special
Symptoms may be delayed.
treatment needed
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance.
5. Fire -fighting measures
Suitable extinguishing media
Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
None known.
media
Specific hazards arising from
Contents under pressure. Greatly increases the burning rate of combustible materials. Containers
the chemical
may explode when heated. During fire, gases hazardous to health may be formed. Hydrogen
chloride gas.
Special protective equipment
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Chlorine - Chlorine Liquefied Gas Under Pressure SDS US
921762 Version #: 01 Revision date: - Issue date: 05-August-2014 2/8
Fire -fighting
Allow gas to burn if flow cannot be shut off immediately. Apply water from safe distance to cool
equipmentlinstructions
container and protect surrounding area. In case of fire: Stop leak if safe to do so. Do not move
cargo or vehicle if cargo has been exposed to heat. ALWAYS stay away from tanks engulfed in
flame. Move containers from fire area if you can do so without risk. Do not direct water at source of
leak or safety devices as icing may occur. Use water spray to cool unopened containers. Do not
get water inside containers. Withdraw immediately in case of rising sound from venting safety
device or any discoloration of tanks due to fire. For massive fire in cargo area, use unmanned
hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Specific methods
Cool containers exposed to flames with water until well after the fire is out.
General fire hazards
May intensify fire; oxidizer.
6. Accidental release measures
Personal precautions,
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and
low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
emergency procedures
Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas.
Emergency personnel need self-contained breathing equipment. Do not touch damaged
containers or spilled material unless wearing appropriate protective clothing. Ventilate closed
spaces before entering them. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for
If this gas leaks without igniting, extreme caution must be used; flammable or explosive mixtures
containment and cleaning up
with air may be formed. Extinguish all flames in the vicinity. This product is miscible in water. Stop
leak if you can do so without risk. Use water spray to reduce vapors or divert vapor cloud drift.
Isolate area until gas has dispersed. Dike far ahead of spill for later disposal. Prevent entry into
waterways, sewer, basements or confined areas. Following product recovery, flush area with
water. For waste disposal, see section 13 of the SDS.
Environmental precautions
Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground. Runoff from fire control or dilution water may cause
pollution.
7. Handling and storage
Precautions for safe handling Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect
material from direct sunlight. Keep away from combustible material. Contents under pressure.
Keep reduction valves free from grease and oil. Valve protection caps must remain in place unless
container is secured with valve outlet piping to use point. Close valve after each use and when
container is empty. Do not drop, drag, slide or roll cylinders on their sides. Use a suitable hand
truck to move gas containers. Use a pressure reducing regulator when connecting container to
piping or systems. Never insert an object (e.g. wrench, screwdriver, pry bar) into cap openings.
Use an adjustable strap wrench to remove over -tight or rusted caps. Open valve slowly. Do not
use gas directly from containers. Do not heat container by any means to increase the discharge
rate of product from the container.
Avoid breathing gas. Use only outdoors or in a well -ventilated area. Avoid contact with eyes, skin,
and clothing. Wash hands thoroughly after handling. Avoid release to the environment. Observe
good industrial hygiene practices. Wear appropriate personal protective equipment. Use personal
protection as recommended in Section 8 of the SDS.
Conditions for safe storage, Store locked up. Store in a cool, dry place out of direct sunlight. Store in original tightly closed
including any incompatibilities container. Store in a well -ventilated place. Store in cool place. Refrigeration recommended. Do not
store near combustible materials. Keep away from food, drink and animal feedingstuffs. Store
away from incompatible materials (see Section 10 of the SDS). Store in accordance with NFPA
430 requirements for Class II oxidizers.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
Chlorine (CAS 7782-50-5) Ceiling 3 mg/m3
1 ppm
US. ACGIH Threshold Limit Values
Components Type Value
Chlorine (CAS 7782-50-5) STEL 1 ppm
TWA 0.5 ppm
Chlorine - Chlorine Liquefied Gas Under Pressure SDS US
921762 Version #: 01 Revision date: - Issue date: 05-August-2014 3/8
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Chlorine (CAS 7782-50-5)
Ceiling 1.45 mg/m3
0.5 ppm
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.
Other
Wear appropriate chemical resistant clothing.
Respiratory protection
In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such
considerations
as washing after handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical
properties
Appearance
Physical state
Gas.
Form
Compressed liquefied gas.
Color
Greenish yellow.
Odor
Pungent.
Odor threshold
Not available.
pH
Not available.
Melting pointifreezing point
-150 °F (-101.11 °C)
Initial boiling point and boiling
-29 °F (-33.89 °C)
range
Flash point
Not available.
Evaporation rate
Not available.
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive
limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
72 psig (60 °F)
Vapor density
Not available.
Relative density 1.47 ±0.03 (Liquid) (32 °F (0 °C))
2.49 ±0.03 (Gas) (32 - 39 °F (0 - 3.89 °C))
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto -ignition temperature
Decomposition temperature
Viscosity
Completely soluble in water.
Not available.
Not available.
Not available.
Not available.
Chlorine - Chlorine Liquefied Gas Under Pressure SDS US
921762 Version #: 01 Revision date: - Issue date: 05-August-2014 4/8
10. Stability and reactivity
Reactivity
Greatly increases the burning rate of combustible materials.
Chemical stability
Material is stable under normal conditions.
Possibility of hazardous
Reacts violently with water or moist air to form hydrogen chloride.
reactions
Conditions to avoid
Keep away from combustible material. Contact with incompatible materials.
Incompatible materials
Combustible material. Reducing agents. Ammonia. Alcohols, Water.
Hazardous decomposition
Chlorine reacts with water and generate hydrogen chloride.
products
11. Toxicological information
Information on likely routes of exposure
Ingestion Expected to be a low ingestion hazard.
Inhalation Toxic if inhaled.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Symptoms related to the Dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging,
physical, chemical and tearing, redness, swelling, and blurred vision. Coughing. Skin irritation. May cause redness and
toxicological characteristics pain.
Information on toxicological effects
Acute toxicity
Components
Chlorine (CAS 7782-50-5)
Acute
Inhalation
LC50
Skin corrosionlirritation
Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization
Skin sensitization
Germ cell mutagenicity
Fatal if inhaled.
Species
Test Results
Mouse 137 ppm, 1 Hours
Rat 293 ppm, 1 Hours
Causes skin irritation.
Causes serious eye irritation.
Not available.
This product is not expected to cause skin sensitization.
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity - May cause respiratory irritation.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not available.
12. Ecological information
Ecotoxicity Very toxic to aquatic life with long lasting effects.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
Chlorine - Chlorine Liquefied Gas Under Pressure SDS US
921762 Version #: 01 Revision date: - Issue date: 05-August-2014 5/8
13. Disposal considerations
Disposal instructions
Consult authorities before disposal. Do not allow this material to drain into sewers/water supplies.
Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
Dispose of in accordance with local regulations.
products
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
UN number
UN1017
UN proper shipping name
Chlorine
Transport hazard class(es)
Class
2.3
Subsidiary risk
5.1, 8
Label(s)
2.3, 5.1, 8
Packing group
Not applicable.
Environmental hazards
Marine pollutant
Yes
Special precautions for user Read safety instructions, SIDS and emergency procedures before handling.
Special provisions
2, B9, B14, N86, T50, TP19
Packaging exceptions
None
Packaging non bulk
304
Packaging bulk
314,315
IATA
UN number
UN1017
UN proper shipping name
Chlorine
Transport hazard class(es)
Class
2.3
Subsidiary risk
5.1, 8
Label(s)
2.3, 5.1, 8
Packing group
Not applicable.
Environmental hazards
Yes
ERG Code
2CP
Special precautions for user
Passenger and Cargo Aircraft Quantity limitation: Forbidden.
IMDG
UN number
UN1017
UN proper shipping name
CHLORINE
Transport hazard class(es)
Class
2.3
Subsidiary risk
5.1. 8
Label(s)
2.3, 5.1, 8
Packing group
Not applicable.
Environmental hazards
Marine pollutant
Yes
EmS
F-C, S-U
Special precautions for user
Read safety instructions, SIDS and emergency procedures before handling.
Transport in bulk according to
Not applicable.
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations
This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
Chlorine - Chlorine Liquefied Gas Under Pressure SIDS US
921762 Version #: 01 Revision date: - Issue date: 05-August-2014 6/8
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated,
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Chlorine (CAS 7782-50-5)
1111163115i]
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Chemical name CAS number Reportable Threshold Threshold Threshold
quantity planning quantity planning quantity, planning quantity,
lower value upper value
Chlorine 7782-50-5 10 100lbs
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Chemical name
Chlorine
Other federal regulations
CAS number % by wt.
7782-50-5 > 99
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Chlorine (CAS 7782-50-5)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Chlorine (CAS 7782-50-5)
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations This chemical is a pesticide product registered by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ
from the classification criteria and hazard information required for safety data sheets, and for
workplace labels of non -pesticide chemicals. Following is the hazard information as required on
the pesticide label:
DANGER/POISON
Keep out of reach of children.
Liquefied Gas Under Pressure.
Non-flammable.
Fatal if inhaled.
Liquid causes severe burns.
Hazardous to Humans and domestic animals.
Corrosive. Causes irreversible eye damage and skin burns.
Fatal if swallowed inhaled or absorbed through skin.
Harmful if swallowed.
Do not swallow or inhale.
This product is toxic or highly toxic to fish and aquatic invertebrates to fish and wildlife.
Chlorine is a Non-flammable gas, liquefied, under pressure.
US. Massachusetts RTK - Substance List
Chlorine (CAS 7782-50-5)
US. New Jersey Worker and Community Right -to -Know Act
Chlorine (CAS 7782-50-5)
US. Pennsylvania Worker and Community Right -to -Know Law
Chlorine (CAS 7782-50-5)
US. Rhode Island RTK
Chlorine (CAS 7782-50-5)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
Chlorine - Chlorine Liquefied Gas Under Pressure SIDS US
921762 Version #: 01 Revision date: - Issue date: 05-August-2014 7/8
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
NFPA ratings
05-August-2014
4�O
Disclaimer The information contained herein is accurate to the best of our knowledge. However, data, safety
standards and government regulations are subject to change and, therefore, holders and users
should satisfy themselves that they are aware of all current data and regulations relevant to their
particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE
ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN.
CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS
FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions
relating to storage, handling, and use of the product are beyond the control of Carus Corporation,
and shall be the sole responsibility of the holder or user of the product.
(Carus and design) is a registered service mark of Carus Corporation
Chlorine - Chlorine Liquefied Gas Under Pressure SDS US
921762 Version #: 01 Revision date: - Issue date: 05-August-2014 8/8
Listing Category Search Page I NSF International Page 1 of 1
X
The Public Health and Safety Organization
NSF Product and Service Listings
These NSF Official Listings are current as of Friday, March 03, 2017 at 12n5 a.m. Eastern Time. Please contact NSF
International to confirm the status of any Listing, report errors, or make suggestions.
Alert: NSF is concerned about fraudulent downloading and manipulation of website tent. Always confirm this information by
clicking on the below link for the most accurate information: http://info.nsf.org/Certified/"`PwsChemicals/Listings.asp?
Com an Name=alexander&TradeName=chlorine&
NSF/ANSI 6o
Drinking Water Treatment Chemicals - Health Effects
Alexander Chemical Corporation
7593 South First Road
Kingsbury Industrial Park
Kingsbury, IN 46345
United States
800-445-9458
630-955-6050
Facility: Kingsbury, IN
Chtorine[CL]
TSrade Designation Product Function Max Use
Chlorine Disinfection & Oxidation 30 mg/L
[CL] The residual levels of chlorine (hypochlorite ion and hypochlorous acid), chlorine
dioxide, chlorate ion, chloramine and disinfection by-products shall be monitored in the
finished drinking water to ensure compliance to all applicable regulations.
Number of matching Manufacturers is t
Number of matching Products is i
Processing time was o seconds
http://info.nsf.org/Certified/PwsChemicals/Listings.asp?CompanyName=alexander&Trade... 3/3/2017
PRODUCT SPECIFICATION SHEET
o. Alexander Chemical HYDROFLUOSILICIC ACID
-�
corporation Effective 11/7/2003
Updated: 6/21/2013
Chemical Properties:
Chemical formula: HZSiFs
Molecular weight: 144.06
Hydrofluosilicic acid, %: 23.00 - 25.00
Hydrofluoric acid (HF), %: 1 Maximum
Heavy metals as lead, ppm: 200.00 maximum
Color: 25 APHA maximum
Physical Properties:
Boiling point, OF:
225.00
Freezing point, OF:
- 4.00
Specific gravity @ 60 OF:
1.223 @ 25.00 %
Vapor pressure, mm Hg @ 167 OF:
218
pH:
1.2
Appearance:
White to Straw Yellow
Odor:
Sour, pungent
Solubility in water:
Complete
NSF International maximum use:
6.00 milligrams per liter
Meets ANSI / AWWA specification B703-06
Packaged by:
Alexander Chemical Corporation
Kingsbury Industrial Park
Kingsbury, Indiana 46345
800-348-8827
SAFETY DATA SHEET
1. Identification
Product identifier
Hydrofluosilicic acid
Other means of identification
Synonyms
Fluorosilicic acid, Hydrofluorosilicic acid
Recommended use
Hydrofluosilicic acid is an acid used in water treatment application.
Recommended restrictions
None known.
Manufacturer/Importer/Supplier/Distributor information
Company name
Carus Corporation
Address
315 5th Street
Peru, IL
Telephone
(815) 223-1500
Toll Free
(800) 435-6856
Fax
(815)224-6816
E-mail
salesmkt@caruscorporation.com
Website
www.caruscorporation.com
Company name
Alexander Chemical Corporation, a Carus Group Inc. Company
Address
7593 S. First Road,
Kingsbury Industrial Park, USA
Website
www.alexanderchemical.com
Company name
Sierra Chemical Co, a Carus Group Inc. Company
Address
2302 Larkin Circle
Sparks, NV 89431
Website www.sierrachemsales.com
Contact person Dr. Chithambarathanu Pillai
Telephone (800) 348-8827 - All other non -emergency inquiries about the product should be
directed to the company
Emergency telephone For Hazardous Materials (or Dangerous Goods] Incidents ONLY
number
(spill, leak, fire, exposure or accident), call CHEMTREC at
CHEMTRECO, USA: 001 (800) 424-9300
CHEMTRECO, Mexico (Toll -Free - must be dialed from within country):
001-800-13-203-9987
CHEMTREC®, Other countries: 001 (703) 527-388
2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Acute toxicity, oral Category 4
Skin corrosion/irritation Category 1 B
Serious eye damage/eye irritation Category 1
OSHA defined hazards Not classified.
Label elements
•
Signal word Danger
Hazard statement Harmful if swallowed. Causes severe skin burns and eye damage.
Precautionary statement
Prevention Do not breathe mist. Do not eat, drink or smoke when using this product. Wear protective
gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling.
Hydrofluosilicic acid SIDS US
920631v Version #: 01 Revision date: - Issue date: 28-January-2015 1/8
Response
If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If
inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. Immediately call a poison center/doctor.
Storage
Store locked up.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s)not otherwise
None known.
classified (HNOC)
3. Composition/information on ingredients
Substances
Chemical name
Common name and CAS number %
synonyms
Hydrofluorosilicicacid
16961-83-4 24
Composition comments
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First -aid measures
Inhalation
Move injured person into fresh air and keep person calm under observation. Get medical attention
if symptoms occur.
Skin contact
Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Get medical attention immediately. Chemical burns must be treated by a physician.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Hold eyelids apart. Continue rinsing. Get medical attention immediately.
Ingestion
Rinse mouth thoroughly with water and give large amounts of milk or water to people not
unconscious. Do not induce vomiting. If vomiting occurs, the head should be kept low so that
stomach vomit doesn't enter the lungs. Obtain medical attention and take along these instructions.
Most important
Corrosive. Prolonged contact causes serious eye and tissue damage. May cause burns in mucous
symptoms/effects, acute and
membranes, throat, esophagus and stomach. May cause lung edema. Symptoms may be delayed.
delayed
Indication of immediate
In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation,
medical attention and special
Symptoms may be delayed.
treatment needed
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Wash contaminated clothing before reuse.
5. Fire -fighting measures
Suitable extinguishing media
Use fire -extinguishing media appropriate for surrounding materials.
Unsuitable extinguishing
Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from Fire may produce irritating, corrosive and/or toxic gases.
the chemical
Special protective equipment Firefighters should wear full protective clothing including self contained breathing apparatus.
and precautions for firefighters Structural firefighters protective clothing will only provide limited protection.
Fire -fighting Use standard firefighting procedures and consider the hazards of other involved materials. Use
equipmentlinstructions water spray to cool unopened containers. Cool containers with flooding quantities of water until
well after fire is out. Prevent runoff from fire control or dilution from entering streams, sewers, or
drinking water supply.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Local authorities should be advised if significant spillages
protective equipment and cannot be contained. Stay upwind. Keep out of low areas. Ensure adequate ventilation. Avoid
emergency procedures contact with eyes, skin, and clothing. Avoid breathing mist or vapor. Use personal protection
recommended in Section 8 of the SIDS.
Hydrofluosilicic acid SIDS US
920631v Version* 01 Revision date: - Issue date: 28-January-2015 2/8
Methods and materials for Should not be released into the environment.
containment and cleaning up
Large Spills: Dike far ahead of liquid spill for later disposal. Use a non-combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.
Small Spills: Absorb spill with vermiculite or other inert material. Clean contaminated surface
thoroughly. After removal flush contaminated area thoroughly with water.
Never return spills in original containers for re -use.
Environmental precautions Prevent further leakage or spillage if safe to do so. Do not contaminate water.
7. Handling and storage
Precautions for safe handling Handle and open container with care. Use only with adequate ventilation. Avoid contact with skin,
eyes and clothing. Avoid breathing mist or vapor. Wash thoroughly after handling. Observe good
industrial hygiene practices.
Conditions for safe storage, Keep in a well -ventilated place. Keep containers tightly closed in a dry, cool and well -ventilated
including any incompatibilities place. Keep this material away from food, drink and animal feed. Use care in handling/storage.
Transfer and storage systems should be compatible and corrosion resistant.
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
Hydrofluorosilicic acid (CAS PEL 2.5 mg/m3
16961-83-4)
US. OSHA Table Z-2 (29 CFR 1910.1000)
Components Type Value Form
Hydrofluorosilicic acid (CAS TWA 2.5 mg/m3 Dust.
16961-83-4)
US. ACGIH Threshold Limit Values
Components Type Value
Hydrofluorosilicic acid (CAS TWA 2.5 mg/m3
16961-83-4)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value
Hydrofluorosilicic acid (CAS TWA 2.5 mg/m3
16961-83-4)
Biological limit values
ACGIH Biological Exposure Indices
Components Value Determinant Specimen Sampling Time
Hydrofluorosilicic acid (CAS 3 mg/I Fluoride Urine
16961-83-4)
2 mg/I Fluoride Urine
* - For sampling details, please see the source document.
Appropriate engineering Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of
controls inhalation of vapors. Eye wash facilities and emergency shower must be available when handling
this product.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear approved safety glasses or goggles.
Skin protection
Hand protection
Wear protective gloves. Be aware that the liquid may penetrate the gloves. Frequent change is
advisable. Suitable gloves can be recommended by the glove supplier.
Other
Wear appropriate chemical resistant clothing. Protective shoes or boots. Structural firefighters
protective clothing provides limited protection in fire situations ONLY; it is not effective in spill
situations. Wear chemical protective equipment that is specifically recommended by the Personal
Protective Equipment manufacturer.
Hydrofluosilicic acid SDS US
920631v Version #: 01 Revision date: - Issue date: 28-January-2015 3/8
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn. In case of inadequate ventilation or risk
of inhalation of mist, use suitable respiratory equipment with particle filter. In the United States of
America, if respirators are used, a program should be instituted to assure compliance with OSHA
29 CFR 1910.134 and ANSI Z88.2.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene When using, do not eat, drink or smoke. Wash hands before breaks and immediately after
considerations handling the product. Remove and isolate contaminated clothing and shoes. Handle in accordance
with good industrial hygiene and safety practice. Launder contaminated clothing before reuse.
9. Physical and chemical properties
Appearance
White to straw yellow solution.
Physical state
Liquid.
Form
Liquid.
Color
White to straw yellow.
Odor
Pungent, sour penetrating odor.
Odor threshold
Not available.
pH
1.2
Melting point/freezing point
-4 -F (-20 °C)
Initial boiling point and boiling
225 °F (107.22 °C)
range
Flash point
Not available.
Evaporation rate
Not available.
Flammability (solid, gas)
Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower
Not available.
N
Flammability limit - upper
Not available.
(%)
Vapor pressure
218 mm Hg (100 °F / 38 °C)
Vapor density
Not available.
Relative density
1.22 t 0.03
Relative density temperature
77 °F (25 °C)
Solubility(ies)
Solubility (water)
Completely soluble in water.
Partition coefficient
No data available.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
Not available.
Viscosity
Not available.
Other information
VOC (Weight %)
Not available
10. Stability and reactivity
Reactivity
The product is non -reactive under normal conditions of use, storage and transport.
Chemical stability
Stable at normal conditions.
Possibility of hazardous
Contact with metals may evolve flammable hydrogen gas.
reactions
Conditions to avoid
Keep away from water, steam or other incompatible materials.
Incompatible materials
Glass. Stoneware. Metals. Bases.
Hazardous decomposition
Hydrogen fluoride. Silicon tetrafluoride. Hydrogen gas.
products
Hydrofluosilicic acid SIDS US
920631 v Version #: 01 Revision date: - Issue date: 28-January-2015 4/8
11. Toxicological information
Information on likely routes of exposure
Ingestion
Harmful if swallowed. Causes digestive tract burns.
Inhalation
Causes respiratory tract burns. May cause lung edema.
Skin contact
Causes severe skin burns.
Eye contact
Causes severe eye burns.
Symptoms related to the
Corrosive. Prolonged contact causes serious eye and tissue damage. May cause burns in
physical, chemical and
mucous membranes, throat, esophagus and stomach. May cause lung edema. Symptoms may be
toxicological characteristics
delayed.
Information on toxicological effects
Acute toxicity
Harmful if swallowed.
Components
Species Test Results
Hydrofluorosilicicacid (CAS 16961-83-4)
Acute
Oral
LD50
Rat 430 mg/kg
Skin corrosion/irritation
Causes severe skin burns.
Serious eye damage/eye
Causes severe eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization
No data available.
Skin sensitization
No data available.
Germ cell mutagenicity
No data available.
Carcinogenicity
No data available.
OSHA Specifically Regulated
Substances (29 CPR 1910.1001-1050)
Not listed.
Reproductive toxicity No data available.
Specific target organ toxicity - No data available.
single exposure
Specific target organ toxicity - No data available.
repeated exposure
Aspiration hazard No data available.
Chronic effects Prolonged overexposure to fluorides may increase fluoride content of bones and teeth, and may
result in fluorosis, with mottling of teeth (in children) and brittleness of bones. Absorbed fluoride
can cause metabolic imbalances with irregular heartbeat, nausea, dizziness, vomiting and
seizures. Risk of hypocalcemia with nervous problems (tetany) and cardiac arrhythmia.
12. Ecological information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data available.
Bioaccumulative potential No data available.
Mobility in soil The product is water soluble and may spread in water systems.
Other adverse effects The product may affect the acidity (pH -factor) in water with risk of harmful effects to aquatic
organisms.
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Dispose of contents/container in accordance with
local/regional/national/international regulations. Dispose in accordance with all applicable
regulations.
Hazardous waste code D002: Waste Corrosive material [pH —2 or=>12.5, or corrosive to steel)
Waste codes should be assigned by the user based on the application for which the product was
used.
Hydrofluosilicic acid SDS US
920631v Version #: 01 Revision date: - Issue date: 28-January-2015 5/8
Waste from residues / unused Dispose of in accordance with local regulations.
products
Contaminated packaging Dispose of in accordance with local regulations. Since emptied containers may retain product
residue, follow label warnings even after container is emptied.
14. Transport information
DOT
UN number
UN1778
UN proper shipping name
Fluorosilicic acid
Transport hazard class(es)
Class
8
Subsidiary risk
-
Label(s)
8
Packing group
II
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions
A6, A7, B2, B15, I132, N3, N34, T8, TP2, TP12
Packaging exceptions
None
Packaging non bulk
202
Packaging bulk
242
DOT BULK
BULK
UN number
UN1778
UN proper shipping name
Fluorosilicic acid
Transport hazard class(es)
Class
8
Label(s)
8
Packing group
II
Special precautions for user
Read safely instructions, SIDS and emergency procedures before handling.
Special provisions
A6, A7, 62, B15, I132, N3, N34, T8, TP2, TP12
Packaging exceptions
None
Packaging non bulk
202
Packaging bulk
242
IATA
UN number
UN1778
UN proper shipping name
Fluorosilicic acid
Transport hazard class(es)
Class
8
Subsidiary risk
-
Label(s) Packing
8
group Environmental
II
hazards ERG Code
No.
8L
Special precautions for user Read safety instructions, SIDS and emergency procedures before handling.
IMDG
UN number
UN1778
UN proper shipping name
FLUOROSILICIC ACID
Transport hazard class(es)
Class
8
Subsidiary risk
-
Label(s) Packing
8
group Environmental
II
hazards
Marine pollutant
No.
Ems
F-A, S-B
Special precautions for user
Read safety instructions, SIDS and emergency procedures before handling.
Transport in bulk according to
This product is a liquid and when transported in bulk is covered under MARPOL 73/78 Annex II.
Annex 11 of MARPOL 73178 and
This product is listed in the IBC Code.
the IBC Code
Ship type: 3
Pollution category: Y
Hydrofluosilicic acid
SDS US
920631v Version #: 01 Revision date:
- Issue date: 28-January-2015 6/8
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - Yes
SARA 302 Extremely hazardous substance
Not listed.
SARA 3111312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
US. Massachusetts RTK - Substance List
Hydrofluorosilicic acid (CAS 16961-83-4)
US. New Jersey Worker and Community Right -to -Know Act
Hydrofluorosilicic acid (CAS 16961-83-4)
US. Pennsylvania Worker and Community Right -to -Know Law
Hydrofluorosilicic acid (CAS 16961-83-4)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
25-July-2014
01
Hydrofluosilicic acid SIDS US
920631v Version #: 01 Revision date: - Issue date: 28-January-2015 7/8
NFPA ratings
0
1
v'
References Registry of Toxic Effects of Chemical Substances (RTECS)
GESTIS Substance Database
US. ARC Monographs on Occupational Exposures to Chemical Agents
Disclaimer The information contained herein is accurate to the best of our knowledge. However, data, safety
standards and government regulations are subject to change and, therefore, holders and users
should satisfy themselves that they are aware of all current data and regulations relevant to their
particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE
ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN.
CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTABILITY OR FITNESS
FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions
relating to storage, handling, and use of the product are beyond the control of Carus Corporation,
and shall be the sole responsibility of the holder or user of the product.
(Carus and design) is a registered service mark of Carus Corporation.
Hydrofluosilicic acid SIDS US
920631v Version #: 01 Revision date: - Issue date: 28-January-2015 8/8
Listing Category Search Page I NSF International
Page 1 of 2
The Public Health and Safety Organization
NSF Product and Service Listings
These NSF Official Listings are current as of Friday, March 03, 2017 at 12:15 a.m. Eastern
Time. Please contact NSF International to confirm the status of any Listing, report errors, or
make suggestions.
Alert: NSF is concerned about fraudulent downloading and manipulation of website text.
Always confirm this information by clicking on the below link for the most accurate
information: http://info.nsf.org/Certified/PwsChemicals/Listings.asp?
CompanyName=alexander&TradeName=hydrofluosilicic+acid&
Drinking Water
Alexander Chemical
Corporation
7593 South First Road
Kingsbury Industrial Park
Kingsbury, IN 46345
United States
800-445-9458
630-955-6050
Facility: Kingsbury, IN
Hydrofluosilicic Acid
Trade Designation
NSF/ANSI
Treatment
Effects
6o
Chemicals
Product Function
- Health
Max Use
http://info.nsf org/Certified/PwsChemicals/Listings.asp?CompanyName=alexander&Trade... 3/3/2017
Listing Category Search Page I NSF International
Page 2 of 2
Hydrofluosilicie Acid - Water Treatment Fluoridation 6 mg/L
Grade
Number of matching Manufacturers is 1
Number of matching Products is 1
Processing time was o seconds
http://info.nsf.org/Certified/PwsChemicals/Listings.asp?CompanyName=alexander&Trade... 3/3/2017
Municipal Drinking Water
CAS Registry No.
7722-64-7
Free -Flowing Grade is recommended where potassium
permanganate is subjected to high humidity conditions and where
the material is to be dry fed through a chemical feeder or stored
in a bin or hopper.
FREE -FLOWING GRADE
Assay
Guaranteed 97% KMn04
Particle Size
20% maximum retained on #425 micron
(formerly #40 U.S. Standard Sieve )
7% maximum through #75 micron
(formerly #200 U.S. Standard Sieve)
Standards and Specifications
CAIROX® potassium permanganate is certified by the National
Sanitation Foundation (NSF) to NSF/ANSI Standard 60: Drinking
Water Treatment Chemicals - Health Effects.
Free -Flowing Grade meets:
AW WA Standard B603
Military Specifications MIL-P-I 1970-C dated 14 October 1983
Water Chemical Codex RMIC values
CHEMICAL/PHYSICAL DATA
Formula
KMn04
Formula Weight
158.0 g/mol
Form
Granular Crystalline
Specific Gravity
Solid
2.703 g/cm3
3% Solution
1.020 g/mL by weight, 20eC / 4"C
Bulk Density
Approximately 100 Ib/ft3
Decomposition may
start at I50 eC / 302 eF
SOLUBILITY IN DISTILLED WATER
Temperature
Solubility
eC "F
g/L oz/gal
0 32
27.8 3.7
20 68
65.0 8.6
40 104
125.2 16.7
60 140
230.0 30.7
70 158
286.4 38.3
75 167
323.5 43.2
CAIROX® POTASSIUM PERMANGANATE
FREE -FLOWING GRADE DATA SHEET
SHIPPING CONTAINERS
25 lag pail (1) (55.125 Its) net, with handle, made of HDPE,
weighs 3.IIbs. It is tapered to allow nested storage of empty
drums, stands approximately 15% inches high and has a maximum
diameterof 12 inches.
150 kg drunral (330.750 lb) net, made of 22-gauge steel,
weighs 22.4 lbs. It stands approximately 29%z inches high and is
approximately 19a/4 inches in diameter.
1500 kg CYCLE BINTN(z) reusable container (3307 lb) net
Bulk, up to 48,000 Ibs
Special Packages will be considered on request.
(1) Meets UN performance oriented packaging requirements.
(2) The CYCLE BIN meets DOT 56 or UN I IA Specifications.
DESCRIPTION
Crystals or granules are dark purple with a metallic sheen,
sometimes with a dark bronze -like appearance. Potassium
permanganate has a sweetish, astringent taste and is odorless.
Protect containers against physical damage. When handling
potassium permanganate, respirators should be worn to avoid
irritation of or damage to mucous membranes. Eye protection
should also be worn when handling potassium permanganate as a
solid or in solution.
Potassium permanganate is stable and will keep indefinitely if
stored in a cool, dry area in closed containers. Concrete floors
are preferred to wooden decks. To clean up spills and leaks,
follow the steps recommended in the SDS. Be sure to use goggles,
rubber gloves, and respirator when cleaning up a spill or leak.
Avoid contact with acids, peroxides, and all combustible organic or
readily oxidizable materials including inorganic oxidizable materials
and metal powders. With hydrochloric acid, chlorine gas is
liberated. Potassium permanganate is not combustible, but will
support combustion. It may decompose if exposed to intense
heat. Fires may be controlled and extinguished by using large
quantities of ytater. Refer to the SDS for more information.
CORPORATE HEADQUARTERS] 315 Fifth Street, Peru It 613541 Tel+ 1,815,223.1590 11-600-435-69561 Fax+ 1.815.224A697I Web: www.mruscorparat! on, cam I E-Mail: sale smkt®caruscorporalion.cdm
CARUS EUROPE I Parque Empresarial de ASIPO I CISetumpno Races 3, Plants 1, Oficina 13-14133428 Cayes. Llanera Spain I Tot +3438578.55.131 Fax+34.985JA55.10 Copyright 2012
rev. 07/16
Form id CX 1020
The information contained herein is accurate m the best of our knowledge. However, dart, safety standards and government regulations
are subject to change: and the conditions of handling, use or misuse of me product are beyond our control. Carus Corporation makes
no nme, either expressed or implied, including any warranties of merchantablllry and fitness for a particular purpose. Gres also !
continues all liability for reliance on the completeness or confirming accuracy of any Information included herein. Users should satisfy
themselves that they are aware of all current dark relevant to their particular users). P.
Carus and Design is a registered service mark of Carus Corporation.CNROXO is a registered trademark of Carus Commis.. Re,ponrible RESPONSIBLE CARD
CarcB 1,aregivered aervlra mark of me American Cheminry Cereal, 4 uua.r...�mnn.r. nuuvununnr C"k
Municipal Drinking Water
CAS Registry No.
7722-64-7
CORROSIVE PROPERTIES
Potassium permanganate is compatible with many metals and
synthetic materials. Natural rubbers and fibers are often
incompatible. Solution pH and temperature are also important
factors. The material must be compatible with either the acid or
alkali also being used.
In neutral and alkaline solutions, potassium permanganate is not
corrosive to iron, mild steel, or stainless steel; however, chloride
corrosion of metals may be accelerated when an oxidant such as
permanganate is present in solution. Plastics such as
polypropylene, polyvinyl chloride Type I (PVC 1), epoxy resins,
fiberglass reinforced plastic (FRP), Penton, Lucite, Viton A, and
Hypalon are suitable. Teflon FEP and TFE, and Tefzel ETFE are
best. Refer to Material Compatibility Chart
Aluminum, zinc, copper, lead, and alloys containing these metals
may be (slightly) affected by potassium permanganate solutions.
Actual studies should be made under the conditions in which
permanganate will be used
SHIPPING
CAIROX potassium permanganate is classified and listed as an
oxidizer by PHMSA (Pipeline and Hazardous Materials Safety
Administration, Department of Transportation, in 49 CFR
Subchapter C, HMR (Hazardous Materials Regulation), Part
172.101 HMT (Hazardous Materials Table). It is shipped under
Interstate Commerce Comission's (ICC) Tariff 19.
Proper Shipping Name: Potassium Permanganate
(RQ-100/45.4)
Hazard Class: Oxidizer
Identification Number: UN 1490
Label Requirements: Oxidizer
Packaging Requirements: 49 CFR Parts 100 to 199,
Sections: 173.152, 173.153, 173.194
Shipping Limitations:
Minimum quantities:
Rail car: See Tariff for destination
Truck: No minimum
CAIROX® POTASSIUM PERMANGANATE
FREE -FLOWING GRADE DATA SHEET
REPACKING
When potassium permanganate is repacked, the packing, markings,
labels, and shipping conditions must meet applicable Federal
regulations. See Code of Federal Regulations-49, Transportation
(parts 100-199) and Federal Hazardous Materials Substances Act,
IS U.S.C. 1261.
APPLICATIONS
Listed below are some of the many applications of potassium
permanganate. Permanganate is a powerful oxidizing agent. The
optimum condition under which it is to be used can be easily
established through technical service evaluations or laboratory
testing.
• Oxidation and Synthesis
• Water Treatment
• Municipal Wastewater Treatment
• Industrial Wastewater Treatment
• Metal Surface Treatment
• Equipment Cleaning
• Purification of Gases
• Mining and Metallurgical
• Slag Quenching
• Food Processing
.I .I••I• IEMMEE I t I I I
CORPORATE HEADQUARTERS 1315 Fifth Street, Peru IL 613S41 Tel+ 1.815.223.150011-800-435-6856[Fax + 1.815,224.66971111 ~.caruuorpontieo.com I E-Mail: salesmkt®camscorporatiuncom
CARUS EUROPE I ParOue Empresarial de ASIPO I C/Secunflum Races3, Plants 1. Olicina 13-14133428 Cayes. Llanera Spain llet +34.985.78.55.131 Fax+36.985.70.55.10 Copyright 2012
rev. 07/16
Form # CX 1020
The information contained herein Is accurate to the best of our knowledge. However, data, safety standards and government regulations
are subject to changes and the conditions of handling. use or misuse of the product are beyond our control. Carus Corporation makes
no amv,either expressed or implied. Including any warranties of merchantability and fitness for a particular purporu se. Cams also
disclaims all liability for reliance on the completeness or confirming accuracy of any information included herein. Users should satisfy
themselves that they are aware of all current data relevant to their particular mots).
Carus and Dentin is a registered service mark of Carus corporation, Csdr0X®is areginead vaderomof Carus Corpamtion. Responsible RESPONSIBLE CARE CAR
ones is a registered service mark of the A elan Chemistry Coundl.
SAFETY DATA SHEET
1. Identification
Product identifier
Potassium Permanganate
Other means of identification
Not available.
Recommended use
Potassium Permanganate is an oxidant recommended for applications that require a strong
oxidant.
Recommended restrictions
Use in accordance with supplier's recommendations.
Manufacturer / Importer / Supplier
/ Distributor information
Company name CARUS CORPORATION
Address 315 Fifth Street,
Peru, IL 61354, USA
Telephone 815 223-1500 - All other non -emergency inquiries about the product should be
directed to the company
E-mail salesmkt@caruscorporation.com
Website www.caruscorporation.com
Contact person Dr. Chithambarathanu Pillai
Emergency Telephone For Hazardous Materials [or Dangerous Goods] Incidents ONLY
(spill, leak, fire, exposure or accident), call CHEMTREC at
CHEMTREC®, USA: 001 (800) 424-9300
CHEMTREC®, Mexico (Toll -Free - must be dialed from within country):
01-800-681-9531
CHEMTREC@, Other countries: 001 (703) 527-3887
2. Hazard(s) identification
Physical hazards Oxidizing solids Category 2
Health hazards Acute toxicity, oral Category 4
Skin corrosion/irritation Category 1B
Specific target organ toxicity, single exposure Category 1 (Respiratory System)
Specific target organ toxicity, repeated Category 1 (Respiratory System, Central
exposure Nervous System)
Environmental hazards Hazardous to the aquatic environment, acute Category 1
hazard
Hazardous to the aquatic environment, Category 1
long-term hazard
OSHA defined hazards Not classified.
Label elements
d'000�
Signal word Danger
Hazard statement May intensify fire; oxidizer. Harmful if swallowed. Causes severe skin burns and eye damage.
Causes damage to organs (Respiratory System). Causes damage to organs (Respiratory System,
Central Nervous System) through prolonged or repeated exposure. Very toxic to aquatic life. Very
toxic to aquatic life with long lasting effects.
Precautionary statement
Prevention Keep away from heat. Keep/Store away from clothing//combustible materials. Wash thoroughly
after handling. Do not breathe dust. Wear protective gloves/protective clothing/eye protection/face
protection. Do not eat, drink or smoke when using this product. Take any precaution to avoid
mixing with combustibles. Avoid release to the environment.
Response In case of fire: Use water for extinction. If swallowed: Rinse mouth. Do NOT induce vomiting. If on
skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash
contaminated clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable
for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Collect spillage. Immediately call a poison
center/doctor.
Storage Rtnre Innkarl iin
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
3. Composition/information on ingredients
Substances
Chemical name Common name and CAS number %
synonyms
Potassium permanganate
7722-64-7 >97.5
Composition comments
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First -aid measures
Inhalation
Remove victim to fresh air and keep at rest in a position comfortable for breathing. For breathing
difficulties, oxygen may be necessary. Get medical attention immediately.
Skin contact
Remove contaminated clothing and shoes. Immediately flush skin with plenty of water. Get
medical attention immediately. Wash contaminated clothing before reuse.
Contact with skin may leave a brown stain of insoluble manganese dioxide. This can be easily
removed by washing with a mixture of equal volume of household vinegar and 3% hydrogen
peroxide, followed by washing with soap and water.
Eye contact
Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open
eyelids wide apart. Continue rinsing. Get medical attention immediately.
Ingestion
Immediately rinse mouth and drink plenty of water. Never give anything by mouth to a victim who is
unconscious or is having convulsions. Do not induce vomiting. If vomiting occurs, keep head low
so that stomach content doesn't get into the lungs. Get medical attention immediately.
Most important Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent
symptoms/effects, acute and eye damage including blindness could result.
delayed
Indication of immediate Provide general supportive measures and treat symptomatically. Decomposition products are
medical attention and special alkaline. Brown stain is insoluble manganese dioxide.
treatment needed
General information In the case of accident or if you feel unwell, seek medical advice immediately (show the label
where possible). Ensure that medical personnel are aware of the material(s) involved, and take
precautions to protect themselves.
5. Fire -fighting measures
Suitable extinguishing media Flood with water from a distance, water spray or fog.
Unsuitable extinguishing The following extinguishing media are ineffective: Dry chemical. Foam. Carbon dioxide (CO2).
media Halogenated materials.
Specific hazards arising from May intensify fire; oxidizer. May ignite combustibles (wood, paper, oil, clothing, etc.). Contact with
the chemical incompatible materials or heat (135 "C / 275 OF) could result in violent exothermic chemical
reaction. Oxidizing agent, may cause spontaneous ignition of combustible materials. By heating
and fire, corrosive vapors/gases may be formed.
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
the workplace.
Fire -fighting Move container from fire area if it can be done without risk. Cool containers exposed to flames with
equipment/instructions water until well after the fire is out. Prevent runoff from fire control or dilution from entering
streams, sewers, or drinking water supply. Dike fire control water for later disposal. Water runoff
can cause environmental damage.
General fire hazards The product is not flammable. May intensify fire; oxidizer. May ignite combustibles (wood, paper,
oil, clothing, etc.). Contact with incompatible materials or heat (135 °C / 275 °F) could result in
violent exothermic chemical reaction.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Minimize dust generation and accumulation. Avoid inhalation
protective equipment and of dust and contact with skin and eyes. Keep upwind. Do not touch damaged containers or spilled
emergency procedures material unless wearing appropriate protective clothing. Wear protective clothing as described in
Section 8 of this safety data sheet. Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for
Keep combustibles (wood, paper, oil, etc.) away from spilled material. Should not be released into
containment and cleaning up
the environment. This product is miscible in water. Stop leak if possible without any risk. Dike the
spilled material, where this is possible. Clean up spills immediately by sweeping or shoveling up
the material. Do not return spilled material to the original container; transfer to a clean metal or
plastic drum. To clean up potassium permanganate solutions, follow either of the following two
options:
Option # 1: Dilute to approximately 6% with water, and then reduce with sodium thiosulfate, a
bisulfite or ferrous salt solution. The bisulfite or ferrous salt may require some dilute sulfuric acid
(10% w/w) to promote reduction. Neutralize with sodium carbonate to neutral pH, if acid was used.
Decant or filter and deposit sludge in approved landfill. Where permitted, the sludge may be
drained into sewer with large quantities of water.
Option # 2: Absorb with inert media like diatomaceous earth or inert floor dry, collect into a drum
and dispose of properly. Do not use saw dust or other incompatible media. Disposal of all
materials shall be in full and strict compliance with all federal, state, and local regulations
pertaining to permanganates.
To clean contaminated floors, flush with abundant quantities of water into sewer, if permitted by
federal, state, and local regulations. If not, collect water and treat as described above.
Never return spills in original containers for re -use.
Environmental precautions
Do not allow to enter drains, sewers or watercourses. Contact local authorities in case of spillage
to drain/aquatic environment.
7. Handling and storage
Precautions for safe handling
Take any precaution to avoid mixing with combustibles. Keep away from clothing and other
combustible materials. Do not get this material in your eyes, on your skin, or on your clothing. Do
not breathe dust or mist or vapor of the solution. If clothing becomes contaminated, remove and
wash off immediately. When using, do not eat, drink or smoke. Good personal hygiene is
necessary. Wash hands and contaminated areas with water and soap before leaving the work site.
Avoid release to the environment.
Conditions for safe storage,
Store locked up. Keep container tightly closed and in a well -ventilated place. Store in a cool, dry
including any incompatibilities
place. Store away from incompatible materials (See Section 10). Follow applicable
local/national/international recommendations on storage of oxidizers. Store in accordance with
NFPA 430 requirements for Class II oxidizers.
8. Exposure controls/personal
protection
Occupational exposure limits
No exposure limits noted for ingredient(s).
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type Value
Potassium permanganate
Ceiling 5 mg/m3
(CAS 7722-64-7)
US. ACGIH Threshold Limit
Values
Components
Type Value Form
Potassium permanganate
TWA 0.1 mg/m3 Inhalable fraction.
(CAS 7722-64-7)
0.02 mg/m3 Respirable fraction.
US. NIOSH: Pocket Guide to
Chemical Hazards
Components
Type Value Form
Potassium permanganate
STEL 3 mg/m3 Fume.
(CAS 7722-64-7)
TWA 1 mg/m3 Fume.
Biological limit values
No biological exposure limits noted for the ingredient(s).
Exposure guidelines
Follow standard monitoring procedures.
Appropriate engineering
Provide adequate general and local exhaust ventilation. An eye wash and safety shower must be
controls
available in the immediate work area.
Individual protection measures,
such as personal protective equipment
Eyelface protection
Wear safety glasses with side shields (or goggles). Wear face shield if there is risk of splashes.
Skin protection
Hand protection
Use protective gloves made of: Rubber or plastic. Suitable gloves can be recommended by the
glove supplier.
Other
Wear chemical -resistant, impervious gloves.
Respiratory protection In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment
with particle filter. In the United States of America, if respirators are used, a program should be
instituted to assure compliance with OSHA 29 CFR 1910.134.
Measurement Element: Manganese (Mn)
10 mg/m3
Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95
filtering facepieces) except quarter -mask respirators. The following filters may also be used: N99,
R99, P99, N100, R100 or P100.
Any supplied -air respirator.
25 mg/m3
Any supplied -air respirator operated in a continuous -flow mode.
Any powered, air -purifying respirator with a high -efficiency particulate filter.
50 mg/m3
Any air -purifying, full -face piece respirator equipped with an N100, R100, or P100 filter.
Any supplied -air respirator with a tight -fitting face piece that is operated in a continuous -flow mode.
Any powered, air -purifying respirator with a tight -fitting face piece and a high -efficiency particulate
filter.
Any self-contained breathing apparatus with a full face piece.
Any supplied -air respirator with a full face piece.
500 mg/m3
Any supplied -air respirator operated in a pressure -demand or other positive -pressure mode.
Emergency or planned entry into unknown concentrations or IDLH conditions -
Any self-contained breathing apparatus that has a full face piece and is operated in a
pressure -demand or other positive -pressure mode.
Escape
Any air -purifying, full -face piece respirator equipped with an N100, R100, or P100 filter.
Any appropriate escape -type, self-contained breathing apparatus.
Thermal hazards
Wear appropriate thermal protective clothing, when necessary.
General hygiene
When using, do not eat, drink or smoke. Keep from contact with clothing and other combustible
considerations
materials. Remove and wash contaminated clothing promptly. Wash hands before breaks and
immediately after handling the product. Handle in accordance with good industrial hygiene and
safely practice.
9. Physical and chemical properties
Appearance
Not available.
Physical state
Solid.
Form
Powder.
Color
Dark purple.
Odor
Odorless.
Odor threshold
Not applicable.
pH
Not applicable.
Melting point/freezing point
Starts to decompose with evolution of oxygen (02) at temperatures above 150 °C. Once initiated,
the decomposition is exothermic and self sustaining.
Initial boiling point and boiling
Not applicable.
range
Flash point
Not applicable.
Evaporation rate
Not applicable.
Flammability (solid, gas)
Non flammable.
Upper/lower flammability or explosive limits
Flammability limit - lower
Not applicable.
N
Flammability limit - upper
Not applicable.
N
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
Not applicable.
Vapor density
Not applicable.
Relative density
2.7 (20 °C) ( Water = 1)
Solubility(ies)
Solubility (water)
64 g/I water (20 °C)
Partition coefficient
Not applicable.
(n-octanol/water)
Auto -ignition temperature
Not available.
Decomposition temperature
464 °F (240 °C)
Viscosity
Not applicable.
Other information
Explosive properties
Not explosive. Can explode in contact with sulfuric acid, peroxides and metal powders.
Granulometry
Mass median : 175.8 pm Particle size: D90 < 298 pm, D10 < 106.1 pm
Molecular formula
H-Mn-04.K
Molecular weight
158.03 g/mol
Oxidizing properties
Strong oxidizing agent.
10. Stability and reactivity
Reactivity
The product is stable and non -reactive under normal conditions of use, storage and transport.
Chemical stability
Stable at normal conditions.
Possibility of hazardous
Contact with combustible material may cause fire. Can explode in contact with sulfuric acid,
reactions
peroxides and metal powders. Starts to decompose with evolution of oxygen (02) at temperatures
above 150'C. Once initiated, the decomposition is exothermic and self sustaining.
Conditions to avoid
Contact with incompatible materials or heat (135 °C / 275 °F) could result in violent exothermic
chemical reaction.
Incompatible materials
Acids. Peroxides. Reducing agents. Combustible material. Metal powders. Contact with
hydrochloric acid liberates chlorine gas.
Hazardous decomposition
By heating and fire, corrosive vapors/gases may be formed.
products
11. Toxicological information
Information on likely routes of exposure
Ingestion
Harmful if swallowed.
Inhalation
May cause irritation to the respiratory system.
Skin contact
Causes severe skin burns.
Eye contact
Causes serious eye damage.
Symptoms related to the
Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent
physical, chemical and
eye damage including blindness could result.
toxicological characteristics
Information on toxicological effects
Acute toxicity
Harmful if swallowed.
Components
Species Test Results
Potassium permanganate (CAS 7722-64-7)
Acute
Dermal
LD50
Rat 2000 mg/kg
Oral
LD50
Rat 2000 mg/kg
Skin corrosion/irritation
Causes severe skin burns.
Serious eye damage/eye
Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization
Test data conclusive but not sufficient for classification.
Skin sensitization
Test data conclusive but not sufficient for classification.
Germ cell mutagenicity
Test data conclusive but not sufficient for classification.
Carcinogenicity
Test data conclusive but not sufficient for classification.
Reproductive toxicity
Test data conclusive but not sufficient for classification.
Specific target organ toxicity -
Causes damage to organs (respiratory system).
single exposure
Specific target organ toxicity
repeated exposure
Aspiration hazard
Chronic effects
Further information
12. Ecological information
Ecotoxicity
Components
Causes damage to organs (respiratory system, central nervous system) through prolonged or
repeated exposure.
Based on available data, the classification criteria are not met.
May cause damage to respiratory system. Prolonged exposure, usually over many years, to
manganese oxide fume/dust can lead to chronic manganese poisoning, chiefly affecting the
central nervous system.
No other specific acute or chronic health impact noted.
Very toxic to aquatic life with long lasting effects.
Species
Potassium permanganate (CAS 7722-64-7)
Aquatic
Fish LC50 Bluegill (Lepomis macrochirus)
Carp (Cyprinus carpio)
Goldfish (Carassius auratus)
Test Results
2.7 mg/I, 96 hours, static
2.3 mg/I, 96 hours, flow through
2.3 mg/I, 96 hours
1.8 - 5.6 mg/I
3.16 - 3.77 mg/I, 96 hours
2.97 - 3.11 mg/I, 96 hours
3.3 - 3.93 mg/I, 96 hours, static
Milkfish, salmon -herring (Chanos > 1.4 mg/I, 96 hours
chanos)
Rainbow trout (Oncorhynchus mykiss) 1.8 mg/I, 96 hours
1.08 - 1.38 mg/I, 96 hours
0.77 - 1.27 mg/I, 96 hours
Rainbow trout,donaldson trout 0.275 - 0.339 mg/I, 96 hours
(Oncorhynchus mykiss)
Persistence and degradability
Expected to be readily converted by oxidizable materials to insoluble manganese oxide.
Bioaccumulative potential
Potential to bioaccumulate is low.
Mobility in soil
Not available.
Mobility in general
The product is water soluble and may spread in water systems.
Other adverse effects
None known.
13. Disposal considerations
Disposal instructions
Dispose of contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
D001: Ignitable waste
The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
Do not allow this material to drain into sewers/water supplies. Dispose in accordance with all
products
applicable regulations.
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Rinse container at least three times to an absence of pink color before disposing. Empty
containers should be taken to an approved waste handling site for recycling or disposal.
14. Transport information
DOT
UN number
UN1490
UN proper shipping name
Potassium permanganate
Transport hazard class(es)
Class
5.1
Subsidiary risk
-
Packing group
II
Environmental hazards
Marine pollutant
Yes
Special precautions for user Not available.
Special provisions
168, IP2, IP4, T3, TP33
Packaging exceptions
152
Packaging bulk
240
IATA
UN number
UN1490
UN proper shipping name
Potassium permanganate
Transport hazard class(es)
Class
5.1
Subsidiary risk
-
Label(s)
5.1
Packing group
11
Environmental hazards
Yes
ERG Code
5L
Special precautions for user Read safety instructions, SIDS and emergency procedures before handling.
IMDG
UN number
UN1490
UN proper shipping name
POTASSIUM PERMANGANATE
Transport hazard class(es)
Class
5.1
Subsidiary risk
-
Label(s)
5.1
Packing group
II
Environmental hazards
Marine pollutant Yes
EmS F-H, S-Q
Special precautions for user Read safety instructions, SIDS and emergency procedures before handling.
Transport in bulk according to Not available.
Annex II of MARPOL 73178 and
the IBC Code
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200,
All components are on the U.S. EPA TSCA Inventory List.
CERCLA/SARA Hazardous Substances - Not applicable.
Drug Enforcement Administration (DEA) (21 CFR 1310.02 (b) 8: List II chemical.
Department of Homeland Security (DHS) Chemical Facility Anti -Terrorism Standards (6 CFR 27,
Appendix A): Listed.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Potassium permanganate (CAS 7722-64-7) LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Chemical name
Potassium permanganate
Other federal regulations
CAS number % by wt.
7722-64-7 >97.5
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Potassium permanganate (CAS 7722-64-7)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and
Chemical Code Number
Potassium permanganate (CAS 7722-64-7) 6579
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))
Potassium permanganate (CAS 7722-64-7) 15 % wt
DEA Exempt Chemical Mixtures Code Number
Potassium permanganate (CAS 7722-64-7) 6579
US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth
defects or other reproductive harm.
California OSH Hazardous Substance List: Listed.
US. Massachusetts RTK - Substance List
Potassium permanganate (CAS 7722-64-7)
US. New Jersey Worker and Community Right -to -Know Act
Potassium permanganate (CAS 7722-64-7)
US. Pennsylvania Worker and Community Right -to -Know Law
Potassium permanganate (CAS 7722-64-7)
US. Rhode Island RTK
Potassium permanganate (CAS 7722-64-7)
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region
Inventory name
Australia
Australian Inventory of Chemical Substances (AICS)
Canada
Domestic Substances List (DSL)
Canada
Non -Domestic Substances List (NDSL)
China
Inventory of Existing Chemical Substances in China (IECSC)
Europe
European Inventory of Existing Commercial Chemical
Substances (EINECS)
Europe
European List of Notified Chemical Substances (ELINCS)
Japan
Inventory of Existing and New Chemical Substances (ENCS)
Korea
Existing Chemicals List (ECL)
New Zealand
New Zealand Inventory
Philippines
Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
On inventory (yes/no)*
Yes
Yes
No
Yes
Yes
No
Yes
Yes
Yes
Yes
Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
NFPA Ratings
17-February-2014
01
List of abbreviations
LD50: Lethal Dose, 50%.
References Chemical safety report.
ECHA registered substances database
Disclaimer This safety data sheet was prepared in accordance with the Safety Data Sheet for Chemical
Products (JIS Z 7250:2005). The information contained herein is accurate to the best of our
knowledge. However, data, safety standards and government regulations are subject to change
and, therefore, holders and users should satisfy themselves that they are aware of all current data
and regulations relevant to their particular use of product. CARUS CORPORATION DISCLAIMS
ALL LIABILITY FOR RELIANCE ON THE COMPLETENESS OR ACCURACY OR THE
INFORMATION INCLUDED HEREIN. CARUS CORPORATION MAKES NO WARRANTY, EITHER
EXPRESS OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF
MERCHANTIABILITY OR FITNESS FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT
DESCRIBED HEREIN. All conditions relating to storage, handling, and use of the product are
beyond the control of Carus Corporation, and shall be the sole responsibility of the holder or user
of the product.
(Carus and design) is a registered service mark of Carus Corporation.
Listing Category Search Page I NSF International Page 1 of 2
The Public Health and Safety Organization
NSF Product and Service Listings
These NSF Official Listings are current as of Friday, March 03, 2017 at 12:15 a.m. Eastern Time. Please contact
NSF International to confirm the status of any Listing, report errors, or make suggestions.
Alert: NSF is concerned about fraudulent downloading and manipulation of website text. Always confirm this
information by clicking on the below link for the most accurate information:
http://info.nsf.oEg/Certified/PwsChemicals /Listings. asp?CompanvName=carus&TradeName=cairox&
NSF/ANSI 6o
Drinking Water Treatment Chemicals - Health Effects
Carus Corporation
315 Fifth Street
P.O. Box 599
Peru, IL 61354-0599
United States
800-435-6856
815-223-1500
Facility: # 1 La Salle, IL
Potassium Permanganate[PO]
7Y-ade Designation
CAIROX® Potassium Permanganate Code C
CAIROX® Potassium Permanganate Code F
CAIROX® Potassium Permanganate Free -Flowing Grade
CAIROX® Potassium Permanganate GP 1020
CAIROXQ Potassium Permanganate GT 1020
CAIROX® Potassium Permanganate Technical Grade
Product Function
Max Use
Oxidant
5omg/L
Oxidant
5omg/L
Oxidant
5omg/L
Oxidant
5omg/L
Oxidant
5omg/L
Oxidant
5omg/L
[PO] The finished drinking water shall be monitored to ensure that levels of manganese
do not exceed 0.05 mg/L.
http://info.nsf.org/Certified/PwsChemicals/Listings.asp?CompanyName=carus&TradeName... 3/3/2017
Listing Category Search Page I NSF International
Page 2 of 2
[PO] The finished drinking water shall be monitored to ensure that levels of manganese
do not exceed 0.05 mg/L.
Number of matching Manufacturers is t
Number of matching Products is 6
Processing time was o seconds
http://info.nsf.org/Certified/PwsChemicals/Listings.asp?CompanyName=carus&TradeName... 3/3/2017
PRODUCT SPECIFICATION SHEET
Sulfur Dioxide
AG111akr Effective 09/10/2015
pre«s
> ..
Chemical Properties:
CAS#:
7446-09-5
Chemical formula:
SO2
Sulfur Dioxide, weight %:
99.9 Minimum
Moisture, ppm:
100.00 Maximum
Sulfuric acid, ppm:
25.00 Maximum
Non-volatile residue ppm:
100.00 Maximum
Physical Properties:
Boiling point:
14 "F
Freezing point:
- 104 °F
Specific gravity (Gas), g/mL
2.25 @ 32 °F
Specific gravity (Liquid), g/mL:
1.43 @ 32/39 °F
Vapor pressure, psig:
28 @ 60 -F
Appearance:
Colorless
Odor:
Suffocating, pungent odor
Packaged by:
Alexander Chemical Corporation
Kingsbury Industrial Park
Kingsbury, Indiana 46345
800/348-8827
GSAFETY DATA SHEET
1. Identification
Product identifier
Sulfur dioxide
Other means of identification
Not available.
Recommended use
Sulfur dioxide is a strong reducing agent and used in chemical manufacturing.
Recommended restrictions
None known.
Manufacturer/Importer/Supplier/Distributor information
Company name Carus Corporation
Address 315 51h Street
Peru, Illinois 61354, USA
Telephone (815)223-1500
Toll Free (800) 435-6856
Fax (815)224-6816
E-mail salesmkt@caruscorporation.com
Website www.caruscorporation.com
Company name Alexander Chemical Corporation, a Carus Group Inc. Company
Address 7593 S. First Road,
Kingsbury Industrial Park, Kingsbury, Indiana 46345, USA
Website www.alexanderchemical.com
Company name Sierra Chemical Co, a Carus Group Inc. Company
Address 2302 Larkin Circle
Sparks, Nevada 89431, USA
Website www.sierrachemsales.com
Contact person Dr. Chithambarathanu Pillai
Telephone (800) 348-8827 - All other non -emergency inquiries about the product should be
directed to the company
Emergency telephone For Hazardous Materials [or Dangerous Goods] Incidents ONLY
number
(spill, leak, fire, exposure or accident), call CHEMTREC at
CHEMTREC®, USA: 001 (800) 424-9300
CHEMTREC®, Mexico (Toll -Free - must be dialed from within country):
001-800-13-203-9987
CHEMTRECO, Other countries: 001 (703) 527-388
2. Hazard(s) identification
Physical hazards Gases under pressure Liquefied gas
Health hazards Acute toxicity, inhalation Category 3
Skin corrosion/irritation Category 18
Serious eye damage/eye irritation Category 1
OSHA defined hazards Not classified.
Label elements
MOW 3
Signal word Danger
Hazard statement Contains gas under pressure; may explode if heated. Causes severe skin burns and eye damage.
Toxic if inhaled.
Precautionary statement
Prevention Do not breathe gas. Wear protective gloves/protective clothing/eye protection/face protection.
Wash thoroughly after handling. Use only outdoors or in a well -ventilated area.
Sulfur dioxide SDS US
920566 Version #: 02 Revision date: 30-July-2014 Issue date: 11-July-2014 1 / 7
Response
If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If inhaled:
Remove person to fresh air and keep comfortable for breathing. Immediately call a poison
center/doctor. Wash contaminated clothing before reuse.
Storage
Protect from sunlight. Store in a well -ventilated place. Keep container tightly closed. Store locked
up.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise
None known.
classified (HNOC)
3. Composition/information on ingredients
Substances
Chemical name
Common name and CAS number %
synonyms
Sulfur dioxide
7446-09-5 99.9
Composition comments
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First -aid measures
Inhalation
Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration.
Call a physician or poison control center immediately.
Skin contact
Frostbite: Do not remove clothes, but flush with copious amounts of lukewarm water. Call an
ambulance and continue to flush during transportation to hospital.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion
Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully
conscious, give a cupful of water. Never give anything by mouth to an unconscious person. If
vomiting occurs, keep head lower than the hips to help prevent aspiration. This material is a gas
under normal atmospheric conditions and ingestion is unlikely.
Most important
Symptoms include itching, burning, redness, and tearing of eyes. Contact with liquefied gas may
symptoms/effects, acute and
cause frostbite. Be aware that symptoms of lung edema (shortness of breath) may develop up to
delayed
24 hours after exposure.
Indication of immediate
Provide general supportive measures and treat symptomatically.
medical attention and special
treatment needed
6. Fire -fighting measures
Suitable extinguishing media Carbon dioxide or dry powder.
Unsuitable extinguishing Do not use a solid water stream as it may scatter and spread fire.
media
Specific hazards arising from By heating and fire, harmful vapors/gases may be formed,
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters Selection of respiratory protection for firefighting: follow the general fire precautions indicated in
the workplace.
Fire -fighting Evacuate area. Allow gas to burn if flow cannot be shut off immediately. Apply water from safe
equipment/instructions distance to cool container and protect surrounding area.
6. Accidental release measures
Personal precautions,
Evacuate the area promptly. No action shall be taken involving any personal risk or without
protective equipment and
suitable training. Keep unnecessary personnel away.
emergency procedures
Ensure adequate ventilation. In case of inadequate ventilation, use respiratory protection. For
personal protection, see Section 8 of the SDS.
Methods and materials for
Ventilate well, stop flow of gas or liquid if possible. Immediately contact emergency personnel. For
containment and cleaning up
waste disposal, see Section 13 of the SDS.
Environmental precautions
Should not be released into the environment. Prevent further leakage or spillage if safe to do so.
Prevent from entering into soil, ditches, sanitary sewers, waterways and/or groundwater.
Sulfur dioxide SDS US
920566 Version #: 02 Revision date: 30-July-2014 Issue date: 11-July-2014 2/7
7. Handling and storage
Precautions for safe handling Use only with adequate ventilation. Do not breathe gas. Do not get in eyes, on skin, on clothing.
Wear appropriate personal protective equipment (See Section 8). Eating, drinking, and smoking
should be prohibited in areas where this material is handled, stored, and processed. Observe good
industrial hygiene practices.
Conditions for safe storage, Store in a cool, dry, well -ventilated place. Secure cylinders in an upright position at all times, close
including any incompatibilities all valves when not in use. Keep container tightly closed and sealed until ready for use. Protect
cylinders from damage. Store away from incompatible materials (See Section 10).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Material
Type
Value
Sulfur dioxide (CAS
PEL
13 mg/m3
7446-09-5)
5 ppm
US. ACGIH Threshold Limit Values
Material
Type
Value
Sulfur dioxide (CAS
STEL
0.25 ppm
7446-09-5)
US. NIOSH: Pocket Guide to Chemical
Hazards
Material
Type
Value
Sulfur dioxide (CAS
STEL
13 mg/m3
7446-09-5)
5 ppm
TWA 5 mg/m3
2 ppm
Biological limit values
No biological exposure limits noted for the ingredient(s).
Appropriate engineering
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
controls
levels below recommended exposure limits. The engineering controls also need to keep gas,
vapor, or dust concentrations below any lower explosive limits.
Individual protection measures, such as personal protective equipment
Eye/face protection
Wear approved safety glasses or goggles.
Skin protection
Hand protection
Wear appropriate chemical resistant gloves.
Other
Wear protective clothing appropriate for the risk of exposure.
Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure
limits (where applicable) or to an acceptable level (in countries where exposure limits have not
been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Do not eat, drink or smoke when using the product. Wash thoroughly after handling. Provide
considerations eyewash station and safety shower. Handle in accordance with good industrial hygiene and safety
practices.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Colorless liquefied gas.
Gas.
Liquefied gas.
Colorless.
Strong pungent.
Not available.
-104 °F (-75.56 °C)
14 °F (-10 °C)
Not available.
Sulfur dioxide SDS US
920566 Version #: 02 Revision date: 30-July-2014 Issue date: 11-July-2014 3/7
Evaporation rate
Not available.
Flammability (solid, gas)
Non flammable.
Upper/lower flammability or explosive limits
Flammability limit - lower
Not available.
N
Flammability limit - upper
Not available.
N
Vapor pressure
4.43 mm Hg at 0 °F / -18 °C
Vapor density
2.26 Ibs per cubic feet at 32 °F / 0 °C
Relative density
1.36 f 0.03
Relative density temperature
77 -F (25 -C)
Solubility(ies)
Solubility (water)
Auto -ignition temperature
Decomposition temperature
Viscosity
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
Moderate soluble in water.
Not available.
Not available.
Not applicable.
The product is non -reactive under normal conditions of use, storage and transport.
Stable under normal temperature conditions and recommended use.
Polymerization will not occur.
In a fire or if heated, a pressure increase will occur and the container may burst or explode.
Alkali metals. Water. Ammonia. Zinc. Aluminum. Copper, Brass. Oxidizing agents.
Sulfur oxides (SOx.).
11. Toxicological information
Information on likely routes of exposure
Ingestion This material is a gas under normal atmospheric conditions and ingestion is unlikely.
Inhalation Toxic if inhaled.
Skin contact
Causes severe skin burns.
Eye contact
Causes serious eye damage.
Symptoms related to the
Symptoms include itching, burning, redness, and tearing of eyes. Contact with liquefied gas may
physical, chemical and
cause frostbite. Be aware that symptoms of lung edema (shortness of breath) may develop up to
toxicological characteristics
24 hours after exposure.
Information on toxicological effects
Acute toxicity
Toxic if inhaled. Suffocation (asphyxiant) hazard - if allowed to accumulate to concentrations that
reduce oxygen below safe breathing levels. Exposure to rapidly expanding gas or vaporizing liquid
may cause frostbite ("cold burn").
Skin corrosion/irritation
Causes severe skin burns.
Serious eye damage/eye
Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization No data available.
Skin sensitization No data available.
Germ cell mutagenicity No data available.
Carcinogenicity This product is not considered to be a carcinogen by NTP, IARC, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Sulfur dioxide (CAS 7446-09-5) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity No data available.
Sulfur dioxide SDS US
920566 Version #: 02 Revision date: 30-July-2014 Issue date: 11-July-2014 4/7
Specific target organ toxicity -
single exposure
Specific target organ toxicity -
repeated exposure
Aspiration hazard
12. Ecological information
Ecotoxicity
Persistence and degradability
Bioaccumulative potential
Mobility in soil
Other adverse effects
No data available.
No data available.
Not classified.
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
No data available.
No data available.
The product is water soluble and may spread in water systems.
None known.
13. Disposal considerations
Disposal instructions Dispose in accordance with all applicable regulations. Empty containers may contain product
residues. Do not puncture or incinerate even when empty. This material and/or its container must
be disposed of as hazardous waste. Return the empty cylinder to the supplier.
Hazardous waste code Waste codes should be assigned by the user based on the application for which the product was
used.
Waste from residues / unused
products
Contaminated packaging
14. Transport information
DOT
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Packing group
Special precautions for user
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
IATA
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
ERG Code
Special precautions for user
IMDG
UN number
UN proper shipping name
Transport hazard class(es)
Class
Subsidiary risk
Label(s)
Packing group
Environmental hazards
Marine pollutant
Dispose of in accordance with local regulations.
Since emptied cylinders may retain product residue, follow label warnings even after cylinder is
emptied.
UN1079
Sulfur dioxide
2.3
Not applicable.
Read safety instructions, SIDS and emergency procedures before handling.
3, B14, T50, TP19
None
304
314,315
UN1079
Sulphur dioxide
2.3
8
2.3, 8
Not applicable.
No
2CP
Read safety instructions, SIDS and emergency procedures before handling.
UN1079
SULPHUR DIOXIDE
2.3
8
2.3, 8
Not applicable.
112
Sulfur dioxide SDS US
920566 Version #: 02 Revision date: 30-July-2014 Issue date: 11-July-2014 5/7
EmS F-C, S-U
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Transport in bulk according to Not applicable. This product is a compressed or liquefied gas and when transported in bulk is
Annex II of MARPOL 73178 and covered under IGC code.
the IBC Code
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Chemical name CAS number Reportable Threshold Threshold Threshold
quantity planning quantity planning quantity, planning quantity,
lower value upper value
Sulfur dioxide 7446-09-5 100 500 Ibs
SARA 311/312 Hazardous Yes
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Sulfur dioxide (CAS 7446-09-5)
Clean Water Act (CWA) Hazardous substance
Section 112(r) (40 CFR
68.130)
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations WARNING: This product contains a chemical known to the State of California to cause cancer and
birth defects or other reproductive harm.
This chemical is a pesticide product registered by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ
from the classification criteria and hazard information required for safety data sheets, and for
workplace labels of non -pesticide chemicals. Following is the hazard information as required on
the pesticide label:
DANGER
Keep out of reach of children.
Pressurized Liquid Gas
Hazardous vapor and liquid.
Liquid causes burns of skin and eyes.
Hazardous to Humans and domestic animals.
Harmful if swallowed. Do not swallow or inhale.
This product is toxic to fish and wildlife.
Sulfur dioxide is a Non-flammbale, whitish colored gas of pungent odor.
Corrosive in presence of water.
Sulfur dioxide SDS US
920566 Version M 02 Revision date: 30-July-2014 Issue date: 11-July-2014 6/7
US. Massachusetts RTK - Substance List
Sulfur dioxide (CAS 7446-09-5)
US. New Jersey Worker and Community Right -to -Know Act
Sulfur dioxide (CAS 7446-09-5)
US. Pennsylvania Worker and Community Right -to -Know Law
Sulfur dioxide (CAS 7446-09-5)
US. Rhode Island RTK
Sulfur dioxide (CAS 7446-09-5)
US. California Proposition 65
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Sulfur dioxide (CAS 7446-09-5)
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 11-July-2014
Revision date 30-July-2014
Version # 02
NFPA ratings
0
References Registry of Toxic Effects of Chemical Substances (RTECS)
GESTIS Substance Database
Disclaimer The information contained herein is accurate to the best of our knowledge. However, data, safety
standards and government regulations are subject to change and, therefore, holders and users
should satisfy themselves that they are aware of all current data and regulations relevant to their
particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE
ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN.
CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTABILITY OR FITNESS
FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions
relating to storage, handling, and use of the product are beyond the control of Carus Corporation,
and shall be the sole responsibility of the holder or user of the product.
(Carus and design) is a registered service mark of Carus Corporation.
Sulfur dioxide SDS US
920666 Version #: 02 Revision date: 30-July-2014 Issue date: 11-July-2014 7/7
GSAFETY DATA SHEET
1. Identification
Product identifier Calcium nitrate solution
Other means of identification Not available.
Recommended use Calcium nitrate solution is used as a water treatment chemical and in a variety of industrial
applications.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company name
Carus Corporation
Address
315 5th Street
Peru, Illinois 61354, USA
Telephone
(815) 223-1500
Toll Free
(800) 435-6856
Fax
(815) 224-6816
E-mail
salesmkt@caruscorporation.com
Website
www.caruscorporation.com
Company name
Alexander Chemical Corporation, a Carus Group Inc. Company
Address
7593 S. First Road,
Kingsbury Industrial Park, Kingsbury, Indiana 46345, USA
Website
www,alexanderchemical.com
Company name
Sierra Chemical Co, a Carus Group Inc. Company
Address
2302 Larkin Circle
Sparks, Nevada 89431, USA
Website
www.sierrachemsales.com
Contact person
Dr. Chithambarathanu Pillai
Telephone
(800) 348-8827 - All other non -emergency inquiries about the product should be
directed to the company
Emergency telephone
For Hazardous Materials [or Dangerous Goods] Incidents ONLY
number
(spill, leak, fire, exposure or accident), call CHEMTREC at
CHEMTREC®, USA: 001 (800) 424-9300
CHEMTREC®, Mexico (Toll -Free - must be dialed from within country):
001-800-13-203-9987
CHEMTREC®, Other countries: 001 (703) 527-388
2. Hazard(s) identification
Physical hazards
Not classified.
Health hazards
Acute toxicity, oral Category 4
Serious eye damage/eye irritation Category 1
OSHA defined hazards
Not classified.
Label elements
•
Signal word Danger
Hazard statement Harmful if swallowed. Causes serious eye damage.
Precautionary statement
Prevention Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear
protective gloves/eye protection/face protection.
Response If swallowed: Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center/doctor. Rinse mouth.
Calcium nitrate solution SIDS US
921755 Version #: 01 Revision date: - Issue date: 05-August-2014 1 / 6
Storage Store away from incompatible materials.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise None known.
classified (HNOC)
3. Composition/information on ingredients
Mixtures
Chemical name CAS number %
Calcium nitrate
13477-34-4 66-70
Composition comments
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First -aid measures
Inhalation
Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact
Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Ingestion
If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Get medical
advice/attention if you feel unwell.
Most important
Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
symptoms/effects, acute and
vision. Permanent eye damage including blindness could result.
delayed
Indication of immediate
Provide general supportive measures and treat symptomatically. Keep victim under observation.
medical attention and special
Symptoms may be delayed.
treatment needed
General information
Take off all contaminated clothing immediately. Contact with combustible material may cause fire.
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated
clothing before reuse.
5. Fire -fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire -fighting In case of fire and/or explosion do not breathe fumes. In case of fire: Stop leak if safe to do so.
equipmentlinstructions Move containers from fire area if you can do so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep away
protective equipment and from clothing and other combustible materials. Wear appropriate protective equipment and
emergency procedures clothing during clean-up. Do not touch damaged containers or spilled material unless wearing
appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if
significant spillages cannot be contained. For personal protection, see section 8 of the SIDS.
Calcium nitrate solution SDS US
921755 Version #: 01 Revision date: - Issue date: 05-August-2014 2/6
Methods and materials for
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep
containment and cleaning up
combustibles (wood, paper, oil, etc.) away from spilled material. Ventilate the contaminated area.
This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Use a non-combustible material like vermiculite, sand or earth to soak up the product
and place into a container for later disposal. Prevent entry into waterways, sewer, basements or
confined areas. Following product recovery, flush area with water.
Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers
for later disposal. Clean surface thoroughly to remove residual contamination.
Never return spills to original containers for re -use. For waste disposal, see section 13 of the SDS.
Wear appropriate protective equipment and clothing during clean-up.
Environmental precautions
Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling
Provide adequate ventilation. Keep away from heat. Keep away from clothing and other
combustible materials. Take any precaution to avoid mixing with combustibles. Do not get this
material in contact with eyes. Do not taste or swallow. When using, do not eat, drink or smoke.
Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe
good industrial hygiene practices.
Conditions for safe storage,
Keep away from heat. Store in a cool, dry place out of direct sunlight. Store in original tightly
including any incompatibilities
closed container. Store in a well -ventilated place. Do not store near combustible materials. Store
away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield.
Skin protection
Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.
Other Wear suitable protective clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Keep from contact with clothing and other combustible materials. Remove and wash contaminated
considerations clothing promptly. Keep away from food and drink. Always observe good personal hygiene
measures, such as washing after handling the material and before eating, drinking, and/or
smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state
Form
Color
Odor
Odor threshold
PH
Melting point/freezing point
Initial boiling point and boiling
range
Flash point
Evaporation rate
Liquid.
Clear liquid.
Colorless.
No distinct odor.
Not available.
3-8
-31 °F (-35 °C)
212 °F (100 °C) 760 mm Hg
Not available.
Not available.
Calcium nitrate solution SDS US
921755 Version #: 01 Revision date: - Issue date: 05-August-2014 316
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
N
Flammability limit- upper Not available.
N
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto -ignition temperature
Decomposition temperature
Viscosity
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
Not available.
Not available.
1.47 ±0.03 for 20% solution at 15 Celcius.
Completely soluble in water.
Not available.
Not available.
Not available.
Not available.
The product is stable and non -reactive under normal conditions of use, storage and transport.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Heat. Contact with incompatible materials.
Reducing agents.
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Ingestion Harmful if swallowed.
Inhalation No adverse effects due to inhalation are expected.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Causes serious eye damage.
Symptoms related to the Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred
physical, chemical and vision. Permanent eye damage including blindness could result.
toxicological characteristics
Information on toxicological effects
Acute toxicity Harmful if swallowed.
Skin corrosionlirritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by ARC, ACGIH, NTP, or OSHA.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Calcium nitrate solution SDS US
921755 Version #: 01 Revision date: - Issue date: 05-August-2014 4/6
Specific target organ toxicity - Not classified.
single exposure
Specific target organ toxicity - Not classified.
repeated exposure
Aspiration hazard Not classified.
12. Ecological information
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability
No data is available on the degradability of this product.
Bioaccumulative potential
No data available.
Mobility in soil
No data available.
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused Dispose of in accordance with local regulations.
products
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to This substance/mixture is not intended to be transported in bulk.
Annex II of MARPOL 73/78 and
the IBC Code
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard -Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 3111312 Hazardous
Yes
chemical
Calcium nitrate solution SDS US
921755 Version #: 01 Revision date: - Issue date: 05-August-2014 5/6
SARA 313 (TRI reporting)
Chemical name
Calcium nitrate
Other federal regulations
CAS number % by wt.
13477-34-4 66-70
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right -to -Know Act
Calcium nitrate (CAS 13477-34-4)
US. Pennsylvania Worker and Community Right -to -Know Law
Not listed.
US. Rhode Island RTK
Calcium nitrate (CAS 13477-34-4)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)`
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
'A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
NFPA ratings
05-August-2014
F
la,
Disclaimer The information contained herein is accurate to the best of our knowledge. However, data, safety
standards and government regulations are subject to change and, therefore, holders and users
should satisfy themselves that they are aware of all current data and regulations relevant to their
particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE
ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN.
CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS
FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions
relating to storage, handling, and use of the product are beyond the control of Carus Corporation,
and shall be the sole responsibility of the holder or user of the product.
(Carus and design) is a registered service mark of Carus Corporation
Calcium nitrate solution SDS US
921755 Version #: 01 Revision date: - Issue date: 05-August-2014 6/6
Trade %
Weight % Sodium Hypochlorite
Available Chlorine, Weight %
Excess Alkalinity, g/I *
Excess Alkalinity, Trade %
Excess Alkalinity, Weight %
Sodium Hydroxide*
Specific Gravity
PRODUCT SPECIFICATION SHEET
Sodium Hypochlorite, 12.5%
EPA Reg. No. 7151-20001
EPA Est, 7151-fN-001
Effective 06/07/2016
Lower Control
Limit
14.1
12.5
11.92
2
0.2
0.17
NH
Upper Control
Limit
17.5
15.0
14.28
5
0.5
0.41
1.23
* Excess Alkalinity on finished product is customized to specific customer requirements
Properties:
Chemical formula: NaOCI
Molecular weight: 74.44 g/mol
Appearance: Bright yellow to yellow -green liquid
Odor: Chlorine odor
pH: 12.5 - 13.5
Boiling Point: > 212°F @ 12.50 Weight % Available Chlorine
Freezing Point: - 11 OF @ 12.50 Weight % Available Chlorine
Solubility in Water: Complete
Manufactured bv:
Alexander Chemical Corporation
Kingsbury Industrial Park
Kingsbury, Indiana 46345
800/348-8827
Distributed by:
Alexander Chemical Corporation
6300 Trillium Trail
Mason, Michigan 48854
517/676-8884
NSf.
�4 NSF International maximum use for 12.50 Weight/o Available
Chlorine: 84 milligrams per liter
GSAFETY DATA SHEET
1. Identification
Product identifier Sodium hypochlorite solution - sodium hypochlorite 12.5%
Other means of identification Not available.
Recommended use Primarily used as a water treatment chemical as a disinfectant. Also used as a bleaching agent.
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Company name
Carus Corporation
Address
315 5th Street
Peru, Illinois 61354, USA
Telephone
(815) 223-1500
Toll Free
(800) 435-6856
Fax
(815)224-6816
E-mail
salesmkt@caruscorporation.com
Website
www.raruscorporation.com
Company name
Alexander Chemical Corporation, a Carus Group Inc. Company
Address
7593 S. First Road,
Kingsbury Industrial Park, Kingsbury, Indiana 46345, USA
Website
www.alexanderchemical.com
Company name
Sierra Chemical Co, a Carus Group Inc. Company
Address
2302 Larkin Circle
Sparks, Nevada 89431, USA
Website
www.sierrachemsales.com
Contact person
Dr. Chithambarathanu Pillai
Telephone
(800) 348-8827 - All other non -emergency inquiries about the product should be
directed to the company
Emergency telephone
For Hazardous Materials [or Dangerous Goods] Incidents ONLY
number
(spill, leak, fire, exposure or accident), call CHEMTREC at
CHEMTRECO, USA: 001 (800) 424-9300
CHEMTRECO, Mexico (Toll -Free - must be dialed from within country):
001-800-13-203-9987
CHEMTRECO, Other countries: 001 (703) 527-388
2. Hazard(s) identification
Physical hazards Corrosive to metals Category 1
Health hazards Skin corrosion/irritation Category 1
Serious eye damage/eye irritation Category 1
Environmental hazards Hazardous to the aquatic environment, acute Category 1
hazard
OSHA defined hazards Not classified.
Label elements
Signal word Danger
Hazard statement May be corrosive to metals. Causes severe skin burns and eye damage. Toxic to aquatic life.
Precautionary statement
Prevention Keep only in original container. Do not breathe mist or vapor. Wash thoroughly after handling.
Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face
protection.
Sodium hypochlorite solution - sodium hypochlorite 12.5% SDS US
921760cp Version #: 02 Revision date: 19-January-2016 Issue date: 30-July-2014 1/8
Response
If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower. If inhaled: Remove person to fresh air and
keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison
center/doctor. Wash contaminated clothing before reuse. Absorb spillage to prevent material
damage.
Storage
Store locked up. Store in corrosive resistant container with a resistant inner liner.
Disposal
Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s)not otherwise
None known.
classified (HNOC)
3. Composition/information on ingredients
Mixtures
Chemical name
CAS number %
Sodium chloride
7647-14-5 5-20
Sodium hypochlorite
7681-52-9 5-20
Sodium hydroxide
1310-73-2 1-5
Composition comments
All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4. First -aid measures
Inhalation
Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact
Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a physician or
poison control center immediately. Chemical burns must be treated by a physician. Wash
contaminated clothing before reuse.
Eye contact
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Call a physician or poison control center immediately.
Ingestion
Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If
vomiting occurs, keep head low so that stomach content doesn't get into the lungs.
Most important
Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
symptoms/effects, acute and
include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
delayed
blindness could result.
Indication of immediate
Provide general supportive measures and treat symptomatically. Chemical burns: Flush with water
medical attention and special
immediately. While flushing, remove clothes which do not adhere to affected area. Call an
treatment needed
ambulance. Continue flushing during transport to hospital. Keep victim under observation.
Symptoms may be delayed.
General information
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire -fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2)
Unsuitable extinguishing
Do not use waterjet as an extinguisher, as this will spread the fire.
media
Specific hazards arising from
During fire, gases hazardous to health may be formed.
the chemical
Special protective equipment
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
and precautions for firefighters
Fire -fighting
Move containers from fire area if you can do so without risk.
equi pmentlinstructions
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
6. Accidental release measures
Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
protective equipment and low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe
emergency procedures mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant
spillages cannot be contained. For personal protection, see section 8 of the SIDS.
Sodium hypochlorite solution - sodium hypochlorite 12.5% SIDS US
921760cp Version #: 02 Revision date: 19-January-2016 Issue date: 30-July-2014 2/8
Methods and materials for This product is miscible in water,
containment and cleaning up
Large Spills: Stop the flow of material, if this is without risk. Use water spray to reduce vapors or
divert vapor cloud drift. Dike the spilled material, where this is possible. Absorb spillage to prevent
material damage. Use a non-combustible material like vermiculite, sand or earth to soak up the
product and place into a container for later disposal. Prevent entry into waterways, sewer,
basements or confined areas. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re -use. For waste disposal, see section 13 of the SIDS.
Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all
environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into
drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Do not breathe mist or vapor. Do not get in eyes, on skin, or on clothing. Provide adequate
ventilation. Wear appropriate personal protective equipment. Avoid release to the environment.
Observe good industrial hygiene practices.
Conditions for safe storage, Store locked up. Store in corrosive resistant container with a resistant inner liner. Keep only in the
including any incompatibilities original container. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value
Sodium hydroxide (CAS PEL 2 mg/m3
1310-73-2)
US. ACGIH Threshold Limit Values
Components Type Value
Sodium hydroxide (CAS Ceiling 2 mg/m3
1310-73-2)
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type
Sodium hydroxide (CAS
1310-73-2)
Ceiling
US. Workplace Environmental Exposure Level (WEEL) Guides
Components
Sodium hypochlorite (CAS
7681-52-9)
Type
Value
2 mg/m3
Value
STEL 2 mg/m3
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses with side shields (or goggles) and a face shield.
Skin protection
Hand protection Wear appropriate chemical resistant gloves. Be aware that the liquid may penetrate the gloves.
Frequent change is advisable. Nitrile or neoprene gloves are recommended.
Other Wear appropriate chemical resistant clothing.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene Always observe good personal hygiene measures, such as washing after handling the material
considerations and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
Sodium hypochlorite solution - sodium hypochlorite 12.5% SDS US
921760cp Version #: 02 Revision date: 19-January-2016 Issue date: 30-July-2014 318
9. Physical and chemical properties
Appearance
Physical state
Liquid.
Form
Greenish yellow liquid.
Color
Light greenish yellow.
Odor
Chlorine.
Odor threshold
Not available.
pH
1 1.5±0.3
Melting point1freezing point
-150 T (-101.11 °C)
Initial boiling point and boiling
> 212 T (> 100 °C)
range
Flash point
Not available.
Evaporation rate
Not available.
Flammability (solid, gas)
Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
Not available.
(%)
Flammability limit - upper
Not available.
(%)
Explosive limit - lower (%)
Not available.
Explosive limit - upper (%)
Not available.
Vapor pressure
Vapor density
Relative density
Solubility(ies)
Solubility (water)
Partition coefficient
(n-octanol/water)
Auto -ignition temperature
Decomposition temperature
Viscosity
10. Stability and reactivity
Reactivity
Chemical stability
Possibility of hazardous
reactions
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
Not available.
Not available.
1.09 -1.21
Completely soluble in water.
Not available.
Not available.
Not available.
Not available.
May be corrosive to metals.
Material is stable under normal conditions.
No dangerous reaction known under conditions of normal use.
Contact with incompatible materials.
Acids. Metals. Strong oxidizing agents.
No hazardous decomposition products are known. Contact with acids liberates toxic gas.
11. Toxicological information
Information on likely routes of exposure
Ingestion Causes digestive tract burns.
Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful.
Skin contact Causes severe skin burns.
Eye contact Causes serious eye damage.
Symptoms related to the Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may
physical, chemical and include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including
toxicological characteristics blindness could result.
Information on toxicological effects
Sodium hypochlorite solution - sodium hypochlorite 12.5% SIDS US
921760cp Version #: 02 Revision date: 19-January-2016 Issue date: 30-July-2014 418
Acute toxicity
Components
Species
Test Results
Sodium chloride (CAS 7647-14-5)
Acute
Oral
LD50
Rat
3000 mg/kg
Sodium hydroxide (CAS 1310-73-2)
Acute
Dermal
LC50
Rabbit
1350 mg/kg, (Calculated)
Oral
LDLo
Rabbit
500 mg/kg, (Calculated)
Sodium hypochlorite (CAS 7681-52-9)
Acute
Oral
LD50 Rat 8.91 g/kg
Skin corrosion/irritation Causes severe skin burns and eye damage.
Serious eye damage/eye Causes serious eye damage.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not classified.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
Sodium hypochlorite (CAS 7681-52-9) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
Not classified.
single exposure
Specific target organ toxicity -
Not classified.
repeated exposure
Aspiration hazard
Not classified.
Chronic effects
Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity
Components
Sodium chloride (CAS 7647-14-5)
Aquatic
Crustacea LC50
Fish
LC50
Sodium hydroxide (CAS 1310-73-2)
Aquatic
Crustacea EC50
Fish
LC50
Species
Daphnia magna
Rainbow trout,donaldson trout
(Oncorhynchus mykiss)
Test Results
874 mg/I, 48 hours
4747 - 7824 mg/I, 96 hours
Water flea (Ceriodaphnia dubia) 34.59 - 47.13 mg/I, 48 hours
Western mosquitofish (Gambusia affinis) 125 mg/I, 96 hours
Sodium hypochlorite solution - sodium hypochlorite 12.5% SDS US
921760 Version #: 01 Revision date: - Issue date: 30-July-2014 5/8
Components
Species Test Results
Sodium hypochlorite (CAS 7681-52-9)
Aquatic
Fish
LC50 Rainbow trout,donaldson trout 0.03 - 0.07 mg/I, 96 hours
(Oncorhynchus mykiss)
Persistence and degradability
No data is available on the degradability of this product.
Bioaccumulative potential
No data available.
Mobility in soil
No data available.
Other adverse effects
No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow
this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches
with chemical or used container. Dispose of contents/container in accordance with
local/regional/national/international regulations.
Local disposal regulations
Dispose in accordance with all applicable regulations.
Hazardous waste code
D002: Waste Corrosive material [pH <=2 or=>12.5, or corrosive to steel]
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
Dispose of in accordance with local regulations.
products
Contaminated packaging
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
UN number
UN1791
UN proper shipping name
Hypochlorite solutions
Transport hazard class(es)
Class
8
Subsidiary risk
-
Label(s)
8
Packing group
II
Environmental hazards
Marine pollutant
Yes
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
Special provisions
A7, B2, B15, IB2, IP5, N34, T7, TP2, TP24
Packaging exceptions
154
Packaging non bulk
202
Packaging bulk
242
IATA
UN number
UN1791
UN proper shipping name
Hypochlorite solution
Transport hazard class(es)
Class
8
Subsidiary risk
-
Packing group
II
Environmental hazards
Yes
ERG Code
8L
Special precautions for user Read safety instructions, SDS and emergency procedures before handling.
IMDG
UN number UN1791
UN proper shipping name HYPOCHLORITE SOLUTION
Sodium hypochlorite solution - sodium hypochlorite 12.5% SDS US
921760cp Version #: 02 Revision date: 19-January-2016 Issue date: 30-July-2014 6/8
Transport hazard class(es)
Class
8
Subsidiary risk
Label(s)
8
Packing group
II
Environmental hazards
Marine pollutant
Yes
EmS
F-A, S-B
Special precautions for user Read safety instructions, SIDS and emergency procedures before handling.
Transport in bulk according to This product is a liquid and when transported in bulk is covered under MARPOL 73/78 Annex II,
Annex II of MARPOL 73178 and This product is listed in the IBC Code.
the IBC Code Ship type: 2
Pollution category: Y
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical' as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
CERCLA Hazardous Substance List (40 CFR 302.4)
Sodium hydroxide (CAS 1310-73-2)
Sodium hypochlorite (CAS 7681-52-9)
LISTED
LISTED
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - No
Pressure Hazard- No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 3111312 Hazardous
Yes
chemical
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations This chemical is a pesticide product registered by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ
from the classification criteria and hazard information required for safety data sheets, and for
workplace labels of non -pesticide chemicals. Following is the hazard information as required on
the pesticide label:
DANGER
Keep out of reach of children. Hazardous to Humans and domestic animals.
Corrosive, causes severe skin and eye irritation or chemical burns to broken skin.
Causes eye damage.
This pesticide is toxic to fish and aquatic organisms.
Strong oxidizing agent.
US. Massachusetts RTK - Substance List
Sodium hydroxide (CAS 1310-73-2)
Sodium hypochlorite solution - sodium hypochlorite 12.5% SDS US
921760 Version #: 01 Revision date: - Issue date: 30-July-2014 7/8
Sodium hypochlorite (CAS 7681-52-9)
US. New Jersey Worker and Community Right -to -Know Act
Sodium hydroxide (CAS 1310-73-2)
Sodium hypochlorite (CAS 7681-52-9)
US. Pennsylvania Worker and Community Right -to -Know Law
Sodium hydroxide (CAS 1310-73-2)
Sodium hypochlorite (CAS 7681-52-9)
US. Rhode Island RTK
Sodium hydroxide (CAS 1310-73-2)
Sodium hypochlorite (CAS 7681-52-9)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance
Not listed.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s).
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date
Revision date
Version #
NFPA ratings
30-July-2014
19-January-2016
02
0
0
Disclaimer The information contained herein is accurate to the best of our knowledge. However, data, safety
standards and government regulations are subject to change and, therefore, holders and users
should satisfy themselves that they are aware of all current data and regulations relevant to their
particular use of product. CARUS CORPORATION DISCLAIMS ALL LIABILITY FOR RELIANCE
ON THE COMPLETENESS OR ACCURACY OR THE INFORMATION INCLUDED HEREIN.
CARUS CORPORATION MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY WARRANTIES OF MERCHANTIABILITY OR FITNESS
FOR PARTICULAR USE OR PURPOSE OF THE PRODUCT DESCRIBED HEREIN. All conditions
relating to storage, handling, and use of the product are beyond the control of Carus Corporation,
and shall be the sole responsibility of the holder or user of the product.
Sodium hypochlorite solution - sodium hypochlorite 12.5% SDS US
921760cp Version #: 02 Revision date: 19-January-2016 Issue date: 30-July-2014 818
Listing Category Search Page I NSF International
Page 1 of I
The Public Health and Safety Organization
NSF Product and Service Listings
These NSF Official Listings are current as of Friday, March 03, 2017 at 12:15 a.m. Eastern Time. Please contact NSF
International to confirm the status of any Listing, report errors, or make suggestions.
Alert: NSF is concerned about fraudulent downloading and manipulation of website text. Always confirm this information by
clicking on the below link for the most accurate information: http://info.nsf.org/CeitifiedZPwsChemicals/Listings.ash
Com aaDyName=alexander&TradeName=sodium+hvoochlorite&
NSF/ANSI 6o
Drinking Water Treatment Chemicals - Health Effects
Alexander Chemical Corporation
7593 South First Road
Kingsbury Industrial Park
Kingsbury, IN 46345
United States
800-445-9458
630-955-6o5o
Facility: Kingsbury, IN
Sodium Hypochlorite[CL]
7Y•ade Designation Product Function Max Use
12.5% Sodium Hypochlorite Disinfection & Oxidation 84mg/L
Sodium Hypochlorite 12.5% Disinfection & Oxidation 84 mg/L
Sodium Hypochlorite 15% Disinfection & Oxidation 67mg/L
[CLl The residual levels of chlorine (hypochlorite ion and hypochlorous acid), chlorine
dioxide, chlorate ion, chloramine and disinfection by-products shall be monitored in the
finished drinking water to ensure compliance to all applicable regulations.
Number of matching Manufacturers is i
Number of matching Products is 3
Processing time was i seconds
http://info.nsf org/Certified/PwsChemicals/Listings.asp?CompanyName=alexander&Trade... 3/3/2017