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HomeMy WebLinkAboutFormer Gas Station Phase II ESA - Walkerton, IN Prepared for: City of South Bend Brownfields Coalition 227 West Jefferson Boulevard, 13th Floor South Bend, Indiana 46601 Phase II Environmental Site Assessment Report Former Gasoline Service Station Property 204 Roosevelt Road Walkerton, Indiana 46574 Symbiont Project No. W150460 September 1, 2016 Prepared for: City of South Bend Brownfields Coalition 227 West Jefferson Boulevard, 13th Floor South Bend, Indiana 46601 Phase II Environmental Site Assessment Report Former Gasoline Service Station Property 204 Roosevelt Road Walkerton, Indiana 46574 Symbiont Project No. W150460 September 1, 2016 Ryan Eckdale-Dudley, GISP Project Manager Symbiont Nivas R. Vijay, CHMM Project Manager Heartland Environmental Associates, Inc. P:\Former Gas Station Phase II ESA - Walkerton, IN Symbiont TABLE OF CONTENTS Section Page EXECUTIVE SUMMARY ...................................................................................... i 1.0 INTRODUCTION .................................................................................................. 1 2.0 BACKGROUND INFORMATION ......................................................................... 2 2.1 Site Description/Background .................................................................... 2 2.2 Physical Setting ........................................................................................ 2 2.3 Recognized Environmental Conditions .................................................... 2 2.4 Objective and Scope of Work ................................................................... 3 3.0 METHODS OF INVESTIGATION ........................................................................ 5 3.1 Soil Assessment ....................................................................................... 5 3.2 Groundwater Assessment ........................................................................ 5 3.3 Ground Penetrating Radar Survey ........................................................... 6 4.0 PHASE II ENVIRONMENTAL SITE ASSESSMENT RESULTS .......................... 7 4.1 Soil Conditions ......................................................................................... 7 4.1.1 Field Observations ........................................................................ 7 4.1.2 Laboratory Analytical Results ....................................................... 7 4.2 Groundwater Conditions ........................................................................... 8 4.2.1 Site Hydrogeology ........................................................................ 8 4.2.2 Laboratory Analytical Results ....................................................... 8 4.3 Ground Penetrating Radar Results .......................................................... 8 5.0 CONCLUSIONS AND RECOMMENDATIONS .................................................... 9 5.1 Conclusions .............................................................................................. 9 5.2 Recommendations ................................................................................. 10 6.0 LIMITATIONS .................................................................................................... 11 7.0 REFERENCES ................................................................................................... 12 TABLES 1 Lead in Soil, Former Gasoline Service Station, Walkerton, Indiana 2 Lead in Groundwater, Former Gasoline Service Station, Walkerton, Indiana 3 Groundwater Elevation Data, Former Gasoline Service Station, Walkerton, Indiana P:\Former Gas Station Phase II ESA - Walkerton, IN Symbiont TABLE OF CONTENTS (CONTINUED) FIGURES 1 Site Location Map 2 Soil Boring Location Map 3 Potentiometric Surface Map APPENDICES A Soil Boring Logs B Laboratory Reports P:\Former Gas Station Phase II ESA - Walkerton, IN Symbiont ACRONYMS AND ABBREVIATIONS amsl Above Mean Sea Level bgs Below Ground Surface Coalition City of South Bend Brownfields Coalition ESA Environmental Site Assessment EPA United States Environmental Protection Agency GPR Ground Penetrating Radar HEA Heartland Environmental Associates, Inc IDEM Indiana Department of Environmental Management mg/kg Milligrams per Kilogram MS Matrix Spike MSD Matrix Spike Duplicate PAH Polycyclic Aromatic Hydrocarbon PID Photoionization Detector ppm Parts Per Million Pace Pace Analytical, Indianapolis, IN PVC Polyvinyl Chloride QAPP Quality Assurance Project Plan QA/QC Quality Assurance/Quality Control RCG Remediation Closure Guide REC Recognized Environmental Condition RMGSL Residential Migration to Groundwater SAG Site Assessment Grant SAP Sampling and Analysis Plan Site Former Gasoline Service Station, 204 Roosevelt Road, Walkerton, IN Symbiont Symbiont Science, Engineering and Construction µg/kg Micrograms per Kilogram µg/l Micrograms per Liter UST Underground Storage Tank VOC Volatile Organic Compound P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont i EXECUTIVE SUMMARY This Phase II Environmental Site Assessment (ESA) Report summarizes the results of an environmental investigation of a former Gasoline Service Station located at 204 Roosevelt Road, Walkerton, Indiana (referred to as the “Site” or the “property”) (Figure 1) This work was completed in accordance with a site-specific Sampling and Analysis Plan prepared by Symbiont and Heartland Environmental Associates, Inc. (Heartland) (Symbiont, 2016) and approved by the United States Environmental Protection Agency (EPA). The Phase II ESA was completed under the City of South Bend Brownfields Coalition’s EPA Community- Wide Brownfield Site Assessment Grant. The purpose of the Phase II ESA was to evaluate recognized environmental conditions and other environmental concerns identified in the Phase I ESA (Heartland, 2016). CONCLUSIONS The following conclusions regarding Site conditions are based on the results of the Phase II ESA. Soil  Lead was detected in Site soil samples at concentrations ranging from 2.6 to 9.7 milligrams per kilogram (mg/kg). Detected concentrations of lead did not exceed the Indiana Department of Environmental Management (IDEM), Remediation Closure Guide (RCG) Residential Migration to Groundwater Screening Levels (RMGSLs). The presence of low concentrations of lead are presumed to be naturally occurring (http://sustainableindiana2016.org/lead-in-indianas-soil/) and not likely associated with a petroleum release.  Polycyclic aromatic hydrocarbons (PAHs) including 1-methylnaphthalene, 2- methylnaphthalene and naphthalene were detected in soil samples collected from two Site soil borings installed within the direct vicinity of a former Site Underground Storage Tank (UST). Detected concentrations of these compounds did not exceed IDEM RCG RMGSLs. These detections of PAHs are likely associated with the former UST.  Volatile organic compounds (VOCs) were not detected in any of the soil samples collected at the Site. Based on these results, there appear to be no significant impacts to Site soil in the vicinity of the sample locations. Groundwater  Lead was detected in groundwater samples at concentrations ranging from 13.0 to 3,590 micrograms per liter (µg/l). The concentration of lead in all but one of the groundwater samples collected at the Site exceeded its respective IDEM RCG Residential Screening P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont ii Level (RSL) of 15 µg/l. It is likely, due to the low concentrations of lead encountered and the limited lead impacts encountered in soil, that lead impacts in groundwater are a result of elevated turbidity in groundwater samples collected from temporary groundwater piezometers and are not a result of impacts due to historic site usage.  Naphthalene was the only PAH detected in groundwater samples collected at the Site. Naphthalene was detected at a concentration of 1.7 µg/l in one groundwater sample collected at the Site within the direct vicinity of the former Site UST. The detected concentration of naphthalene is equivalent to its respective IDEM RCG RSL. This detection of naphthalene is likely associated with the former UST.  Methylene Chloride was the only VOC detected in groundwater samples collected at the Site. Concentrations of methylene chloride in two groundwater samples collected at the Site were 5.4 and 6.9 µg/l. These detected concentrations of VOCs exceeded the IDEM RCG RSL of 5 µg/l. However, the laboratory qualified the detection as common laboratory contaminants and these detections are therefore considered to be the result of laboratory contamination. Based on these results, there appear to be no significant impacts to Site groundwater in the vicinity of the sample locations. RECOMMENDATIONS Based on the results of field observations, and soil and groundwater analytical data, there appears to be only minor impacts to soil and groundwater associated with the RECs (former UST) identified in the Phase I ESA. The Site is located in a mixed-use residential and commercial area directly northwest of downtown Walkerton, Indiana. The site is provided with municipal water by the Town of Walkerton. The area of the Site where groundwater impacts were encountered in the northern portion of the Site, located adjacent to Roosevelt Road right-of-way. Limited exposure pathways to these low level groundwater impacts are present due to the location of the impacts, the utilization of municipal water in the direct area of the Site, and the lack of soil impacts present at the site. Additional soil and/or groundwater investigations related to the RECs do not appear to be warranted at the Site at this time based on the results of this Phase II ESA. Interested parties may wish to retain legal counsel in this matter as Symbiont and Heartland are not qualified to provide legal advice. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 1 Section 1.0 INTRODUCTION This Phase II Environmental Site Assessment (ESA) Report summarizes the results of an environmental investigation of a property located at 204 Roosevelt Road, Walkerton, Indiana. (herein referred to as the “Site” or “property”). The ESA was completed in accordance with a site-specific Sampling and Analysis Plan (SAP) prepared by Symbiont (Symbiont, 2016) and approved by the United States Environmental Protection Agency (EPA). The Phase II ESA was completed as part of a EPA Community-Wide Brownfield Site Assessment Grant awarded to the City of South Bend Brownfields Coalition (Coalition) in September 2014 under Cooperative Agreement BF-00E01371. The Site location map is provided as Figure 1. The purpose of the Phase II ESA was to evaluate recognized environmental conditions (RECs) and other environmental concerns identified in the Phase I ESA (Heartland, 2016). Specifically, the purpose of the assessment was to determine if there is evidence of underground storage tanks (USTs) at the Site and to confirm the presence of petroleum products and/or hazardous substances at the Site in conditions that constitute disposal or release, or provide sufficient information to render a professional opinion that there is no reasonable basis to suspect the presence of hazardous substances or petroleum products at the Site. Supporting documentation is presented in the following appendices:  Appendix A – Soil Boring Logs  Appendix B – Laboratory Reports P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 2 Section 2.0 BACKGROUND INFORMATION 2.1 SITE DESCRIPTION/BACKGROUND The site is located on approximately 1.1-acres situated on two parcels (Parcel #s 010-1032- 0603 & 010-1032-0607). The Site was originally developed for residential use by at least 1922. The Site operated as a gasoline service station from at least the early 1960s through the mid to the late 1980s. The site was vacant from this time through the early 2000s, when the site building was razed. The property currently consists of vacant grounds with gravel parking and landscaped areas, and is currently owned by Mr. Lawrence E. Hiler. A Site location map is provided as Figure 1. 2.2 PHYSICAL SETTING The Site elevation is approximately 717 feet above mean sea level and is generally flat. 2.3 RECOGNIZED ENVIRONMENTAL CONDITIONS A Phase I ESA conducted in April 2016 (Heartland, 2016), identified the following Recognized Environmental Conditions (REC) at the Site. Historical Presence of an Underground Storage Tank The Site historically operated as a gasoline service station from at least the early 1960s through the mid to the late 1980s. During its operation as a gasoline service station, the site likely operated USTs. Historic reports reviewed indicate the Site potentially operated three (3) gasoline USTs and one (1) waste oil UST; however, documentation pertaining to the registration and the removal and/or closure of any site USTs was not uncovered as part of the Phase I ESA. Historic subsurface investigations conducted at the Site have indicated the presence of elevated total petroleum hydrocarbon (TPH) impacts to soil as well as potential free product petroleum. To date only limited environmental subsurface investigation has been conducted at the Site. Historical Property Use as an Automobile Service Garage As stated above, the site operated as gasoline service station from the early 1960s through the mid to the late 1980s. The site was vacant from this time through the early 2000s when the site building was razed. Base on the results of the Phase I ESA, it was determined that a Phase II ESA should be conducted to evaluate for the presence of petroleum impacts to soil and/or groundwater based on historic usage of the site. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 3 2.4 OBJECTIVE AND SCOPE OF WORK The objective of this Phase II ESA is to evaluate RECs identified in the Phase I ESA (Heartland, 2016). Specifically, the purpose of the assessment is to determine if USTs are present at the Site and to confirm the presence of petroleum products at the Site in conditions that constitute disposal or release, or provide sufficient information to render a professional opinion that there is no reasonable basis to suspect the presence of petroleum products at the Site. If present and applicable, the extent and magnitude of impact(s) will be evaluated to assess appropriate additional investigations and potential remedial actions. Field investigation activities and laboratory analyses were conducted in accordance with the site specific SAP (Symbiont 2016) and the Quality Assurance Project Plan (QAPP) (Heartland, 2016). The scope of work for confirming the presence of an UST on-Site included:  Performing a ground penetrating radar (GPR) survey in the vicinity of the former USTs to identify existing and/or tank excavation pits. The scope of work for investigation of potential Site soil impacts included:  Sample collection and descriptive logging of soil at 14 boring locations across the Site.  Field screening of soil samples in each boring using a photoionization detector (PID) for the presence of volatile organic compounds (VOCs).  Soil and samples collected across the Site were submitted to an analytical laboratory for analysis of lead, polycyclic aromatic hydrocarbons (PAHs), and VOCs.  Field duplicate, trip blank, matrix-spike (MS) and matrix-spike duplicate (MSD) samples were collected and also analyzed in accordance with the SAP and QAPP.  Surveying boring locations. The scope of work for investigation of potential Site groundwater impacts included:  Completion of all 14 soil borings as temporary 1-inch diameter polyvinyl chloride (PVC) groundwater monitoring wells.  Measurement of water levels and confirmation of the presence/absences of light non- aqueous phase liquids (LNAPL), and development and sampling of temporary wells.  Collection of groundwater samples for laboratory analysis of dissolved lead, PAHs, and VOCs. Field duplicate, trip blank, MS and MSD samples were collected and submitted to the laboratory for analysis in accordance with the SAP and QAPP.  Surveying temporary monitoring wells. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 4 Section 3.0 METHODS OF INVESTIGATION This section summarizes the methods of investigation used to perform the field and laboratory portions of the Phase II ESA. 3.1 SOIL ASSESSMENT Soil Boring Installation Fourteen soil borings were installed using Geoprobe® Dual-Tube direct-push drilling techniques. The soil types and observations were described and recorded by an onsite geologist. Soil boring logs are provided in Appendix A. The locations of boreholes are shown in Figure 2. All probe drilling rods and soil sampling equipment were decontaminated prior to arrival onsite and between soil boring locations. Sampling equipment was decontaminated with an Alconox equivalent wash followed by clean tap water or distilled water rinses. Field Screening Soil samples from approximately every one to two-foot interval of subsurface were field screened for the presence of VOCs using a PID. The results were recorded in parts per million (ppm) and are reported on the soil boring logs (Appendix A). Sampling and Laboratory Analysis One soil sample was collected from each soil boring for laboratory analysis. Soil samples for laboratory analyses were collected from immediately above the water table, which was estimated at approximately 11 feet below ground surface (bgs). Soil samples for laboratory analysis were placed directly into laboratory-supplied containers, preserved as appropriate, and immediately placed in a cooler on ice for shipping to Pace Analytical – Indianapolis, Indiana (Pace) under a chain of custody for analysis. Soil samples were analyzed for lead using EPA Method 6010B, PAHs using EPA Method 8270 SIM and VOCs using EPA Method 8260. Field duplicate samples were submitted for lead, PAH and VOCs analysis. Trip blanks were submitted to the laboratory for VOC analysis. Laboratory reports are provided in Appendix B. Evaluation Criteria Potential environmental impacts to soil were evaluated by comparing the concentrations of the detected constituents with their respective IDEM Remediation Closure Guide (RCG) Residential Migration to Groundwater Screening Levels (RMGSLs) and Residential Direct Contact Screening Levels, as issued March 2012 and amended March 2016. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 5 3.2 GROUNDWATER ASSESSMENT Temporary Monitoring Well Installation Temporary monitoring wells constructed of 1-inch diameter schedule 40 polyvinyl chloride blank well casing and 0.010-inch slotted well screens were installed in twelve of the fourteen soil boring locations. Quartz filter sand was placed in the annular space between the borehole wall and the outside of each screen. The annular space above the filter pack was filled to the ground surface with granular bentonite to serve as a seal to prevent infiltration of surface water runoff into the borings. The locations of the temporary wells provided in Figure 2. Water Level Measurements After the wells were developed and given time to recharge, static groundwater level measurements were collected. The water level recorded at each monitoring well was used to determine the surface elevation of the water table at each well. Measurements were recorded using a Solinist™ water level indicator which was decontaminated between each well. The approximate depth to the water table is presented in Table 3. An oil/water interface probe was used to determine the presence or absence of LNAPL in each of the temporary monitoring wells. LNAPL was not detected in any of the temporary monitoring wells. Groundwater was not encountered at boring locations SB-10, SB-11, and SB-12 and recorded as “dry”. Sampling and Laboratory Analysis Temporary groundwater monitoring wells were allowed to stabilize following well installation for at least 24-hours prior to sampling. Groundwater samples were collected from each temporary well utilizing dedicated disposable bailers after allowing for the 24-hour stabilization period. Groundwater samples were not collected from wells SB-10, SB-11, and SB-12 because groundwater was not encountered at these locations. Groundwater samples collected for dissolved lead were collected with a disposable bailer and placed into a non-preserved container and filtered by the laboratory prior to analysis. Groundwater samples collected for PAH analysis were collected with a disposable bailer and samples were placed directly into laboratory supplied non-preserved amber glass jars. Groundwater samples collected for VOC analysis were collected with a disposable bailer and samples were placed directly into laboratory-supplied sample jars containing a hydrochloric acid preservative. Samples were then labeled and placed in a cooler on ice for shipping to Pace under a chain of custody for analysis. Groundwater sample analyses included total lead, PAHs and VOCs. Field sampling precision and data quality was evaluated through the use of sample duplicates and trip blanks. Field duplicate samples were submitted for lead PAHs and VOCs analysis. Trip blanks were submitted to the laboratory for VOC analysis. Laboratory reports are provided in Appendix B. Evaluation Criteria Potential environmental impacts to groundwater were evaluated by comparing the concentrations of the detected constituents with their respective IDEM RCG Residential Screening Levels (RSLs), as issued March 2012 and amended March 2016. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 6 3.3 GROUND PENETRATING RADAR SURVEY GPR is a non-destructive geophysical method that uses the reflection of microwave radiation to image the subsurface. Pulsed high frequency radio waves in the microwave band of the radio spectrum (radar) are directed into the ground and the reflected signals are detected, processed, and displayed to give a visual image of the subsurface structure. The GPR detects differences in physical properties such as conductivity and density; metallic objects are most clearly visible, but it can also detect PVC, concrete, and often old excavations if the backfill is different from native soil. As each scan progresses, the GPR presents a sub-surface image in real time, allowing USTs, utilities, foundations, and other significant anomalies to be marked out directly in the field. A GPR survey was conducted in the areas where suspected underground storage tanks could be present based on findings of the Phase I ESA. Additionally, a GPR survey was conducted at all boring locations to clear the drilling areas of underground utilities prior to conducting subsurface work. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 7 Section 4.0 PHASE II ENVIRONMENTAL SITE ASSESSMENT RESULTS The soil and groundwater sample locations are depicted on Figure 2. Laboratory reports for soil and groundwater are provided in Appendix B and summarized in Tables 1 and 2. Water level measurements are summarized in Table 3. 4.1 SOIL CONDITIONS The following paragraphs describe the results of the Phase II ESA soil investigation. 4.1.1 Field Observations The land surface in the vicinity of soil borings SB-1, SB-2 and SB-14 are generally covered with 3 to 6-inches of gravel road paving. The land surface in the vicinity of soil borings SB-7, SB-8 and SB-9 are generally covered with approximately 3-inches of asphalt. The remaining boring locations are covered with top soil and grass and/or native soil. Soil borings SB-2 through SB-14 were drilled to a total depth of approximately 16 feet bgs. Soil boring SB-1 was drilled to a total depth of approximately 12 feet bgs. The Site is generally underlain by discontinuous, fine to medium sands, hard silt, and occasional gravel seams. The water table is generally encountered in a coarse grained sand that occurs at approximately 10 to 12 feet bgs (Appendix A). VOCs were not detected at concentrations exceeding 1.0 ppm in soil samples screened using a PID (Appendix A). 4.1.2 Laboratory Analytical Results Laboratory analytical results for soil samples are summarized in Table 1. Sample results are discussed in the following paragraphs. Lead in Soil Lead was detected in all soil samples collected from each of the soil borings drilled and sampled on Site. Concentrations of lead ranged from 2.6 milligrams per kilogram (mg/kg) in a soil sample collected from 8 to 10 feet bgs from soil boring SB-1 to 9.7 mg/kg in a soil sample collected from 14 to 16 feet bgs from soil boring SB-4 (Table 1). PAHs in Soil PAHs including 1-methylnaphthalene, 2-methylnaphthalene, and naphthalene were detected in two soil samples collected at the Site. 1-Methylnaphthalene was detected at a concentration of 0.0061 mg/kg in a soil sample collected from boring SB-8 from 10 to 12 feet bgs. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 8 Concentrations of 1-methylnaphthalene, 2-methylnaphthalene and naphthalene were 0.021 mg/kg, 0.051 mg/kg and 0.020 mg/kg, respectively; in a soil sample collected from soil boring SB-14 from 10 to 12 feet bgs (Table 1). VOCs in Soil VOCs were not detected exceeding laboratory detection limits in Site soil samples (Appendix B). 4.2 GROUNDWATER CONDITIONS The following paragraphs describe the results of the groundwater investigation. 4.2.1 Site Hydrogeology Depth to groundwater was measured in Site temporary monitoring wells on July 20 and 21, 2016. Groundwater elevation at the Site ranged from 83.60 feet above mean sea level (amsl) at SB-4 to 87.74 feet amsl at SB-1. The apparent flow direction of groundwater across the Site is primarily to the east-southeast (Table 3; Figure 3). 4.2.2 Laboratory Analytical Results Laboratory analytical results for groundwater samples are summarized in Table 2. Sample results are discussed in detail in the following paragraphs. Lead in Groundwater Lead was detected in all groundwater samples collected from temporary groundwater monitoring wells installed and sampled at the Site. Concentrations of lead in groundwater ranged from 13.0 micrograms per liter µg/l in a groundwater sample collected from SB-2 to 3,590 µg/l in a groundwater sample collected from SB-9 (Table 2). PAHs in Groundwater Naphthalene was detected at a concentration of 1.7 µg/l in a groundwater sample collected in temporary groundwater monitoring well SB-14 (Table 2). VOCs in Groundwater Methylene chloride was detected in two groundwater samples collected at the Site. Concentrations of methylene chloride were 5.5 µg/l and 6.9 µg/l in groundwater samples collected from temporary groundwater monitoring wells SB-1 and SB-8, respectively. The analytical laboratory qualified these detections as common laboratory contaminants (Table 2; Appendix B). 4.3 GROUND PENETRATING RADAR RESULTS The GPR survey did not identify any sub surface structures and/or anomalies that were interpreted as a potential UST. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 9 Section 5.0 CONCLUSIONS AND RECOMMENDATIONS The following paragraphs summarize the conclusions and recommendations of this Phase II ESA. 5.1 CONCLUSIONS The following conclusions regarding Site conditions are based on the results of the Phase II ESA. Soil  Lead was detected in site soil samples at concentrations ranging from 2.6 to 9.7 mg/kg. Detected concentrations of lead did not exceed the IDEM RCG RMGSLs. The presence of low concentrations of lead are presumed to be naturally occurring (http://sustainableindiana2016.org/lead-in-indianas-soil/) and not likely associated with a petroleum release.  PAHs including 1-methylnaphthalene, 2-methylnaphthalene and naphthalene were detected in soil samples collected from two Site soil borings installed within the direct vicinity of a former Site UST. Detected concentrations of these compounds did not exceed IDEM RCG RMGSLs. These detections of PAHs are likely associated with the former UST.  VOCs were not detected in any of the soil samples collected at the Site. Based on these results, there appear to be no significant impacts to Site soil in the vicinity of the sample locations. Groundwater  Lead was detected in groundwater samples at concentrations ranging from 13.0 to 3,590 ug/l. The concentration of lead in all but one of the groundwater samples collected at the Site exceeded its respective IDEM RCG RSL of 15 ug/l. It is likely, due to the low concentrations of lead encountered and the limited lead impacts encountered in soil, that lead impacts in groundwater are a result of elevated turbidity in groundwater samples collected from temporary groundwater piezometers and are not a result of impacts due to historic site usage.  Naphthalene was the only PAH detected in groundwater samples collected at the Site. Naphthalene was detected at a concentration of 1.7 ug/l in one groundwater sample collected at the Site within the direct vicinity of the former Site UST. The detected concentration of naphthalene is equivalent to its respective IDEM RCG RSL. This detection of naphthalene is likely associated with the former UST.  Methylene Chloride was the only VOC detected in groundwater samples collected at the Site. Concentrations of methylene chloride in two groundwater samples collected at the Site were 5.4 to 6.9 ug/l. These detected concentrations of VOCs exceeded the IDEM P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 10 RCG RSL of 5 ug/l. However, the laboratory qualified the detection as common laboratory contaminants and these detections are therefore considered to be the result of laboratory contamination. Based on these results, there appear to be no significant impacts to Site groundwater in the vicinity of the sample locations. RECOMMENDATIONS Based on the results of field observations, and soil and groundwater analytical data, there appears to be only minor impacts to soil and groundwater associated with the RECs (former UST) identified in the Phase I ESA. The Site is located in a mixed-use residential and commercial area directly northwest of downtown Walkerton, Indiana. The site is provided with municipal water by the Town of Walkerton. The area of the Site where groundwater impacts were encountered in the northern portion of the Site, located adjacent to Roosevelt Road right-of-way. Limited exposure pathways to these low level groundwater impacts are present due to the location of the impacts, the utilization of municipal water in the direct area of the Site, and the lack of soil impacts present at the site. Additional soil and/or groundwater investigations related to the RECs do not appear to be warranted at the Site at this time based on the results of this Phase II ESA. Interested parties may wish to retain legal counsel in this matter as Symbiont and Heartland are not qualified to provide legal advice. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 11 Section 6.0 LIMITATIONS The Phase II ESA was performed in accordance with generally accepted practices for the environmental consulting profession, undertaking similar studies at the same time and in the same geographical area as the work conducted by Symbiont and Heartland. Symbiont and Heartland observed the degree of care and skill that are generally exercised by the profession under similar circumstances and conditions. No other warranty is expressed or implied. Symbiont and Heartland’s observations, findings, and opinions should not be considered as scientific certainties, but only as opinion based upon our professional judgment concerning the significance of the data gathered during the course of this investigation. Specifically, Symbiont and Heartland cannot represent that the Property contains hazardous or toxic materials or other latent conditions beyond that observed by Symbiont and Heartland during the course of the investigation. Additionally, due to limitations of the investigation process and the necessary use of data furnished by others, Symbiont, Heartland, and its subcontractors cannot assume liability if actual conditions differ from the information presented in this report. P:\Former Gas Station Phase II ESA - Walkerton, IN.doc Symbiont 12 Section 7.0 REFERENCES Heartland, 2015, Quality Assurance Project Plan, City of South Bend Brownfields Coalition, Community-Wide Brownfields Assessment Project, prepared for The City of South Bend and Coalition Partners, The City of Mishiwaka, and Saint Joseph County, Indiana, February 2015. Heartland, 2016, Phase I Environmental Site Assessment, Former Gasoline Service Station Property, 204 Roosevelt Road, Walkerton, Indiana, February 5, 2016. Symbiont, 2016, Sampling and Analysis Plan for Phase II Environmental Site Assessment, Former Gasoline Service Station Property, 204 Roosevelt Road, Walkerton, Indiana 46274, March 17, 2016. TABLES TABLE 1DETECTED CONSTITUENTS IN SOILFORMER GASOLINE SERVICE STATION204 ROOSEVELT ROADWALKERTON, INDIANAGROUNDWATERRESIDENTIAL (mg/kg)COMMERCIAL/ INDUSTRIAL (mg/kg)EXCAVATION (mg/kg)SOIL MTG RESIDENTIAL (mg/kg)SB-18 - 10 07/19/16 2.6SB-212 - 14 07/19/16 5.6SB-312 - 14 07/19/16 3.2SB-414 - 16 07/19/16 9.7SB-514 - 16 07/19/16 3.7SB-610 - 12 07/19/16 4.0SB-710 - 12 07/19/16 6.3SB-810 - 12 07/19/16 7.8SB-910 - 12 07/19/16 9.6SB-1012 - 14 07/20/16 6.6SB-1112 - 14 07/20/16 5.9SB-1210 - 12 07/20/16 4.5SB-1310 - 12 07/20/16 4.9SB-1410 - 12 07/20/16 7.6SB-810 - 12 07/19/161-Methylnaphthalene0.0061 250 390 390 1.21-Methylnaphthalene0.021 250 390 390 1.22-Methylnaphthalene0.051 340 3000 6800 3.7Naphthalene0.020 53 170 3100 .11IDEM RCG = Indiana Department of Environmental Management, Remediation Closure Guidebgs = below ground surfacemg/kg = milligrams per kilogramMTG = migration to groundwater1000 270SAMPLE DATELeadCONSTITUENTRESULT (mg/kg)IDEM RCG SCREENING LEVELS, MARCH 2016SB-14 10 - 12 07/20/16SOIL EXPOSURE, DIRECT CONTACTPolycyclic Aromatic HydrocarbonsBORING IDENTIFERSAMPLE DEPTH(feet bgs)400 800Table 1 - Soil Data12:22 PM1 of 1 TABLE 2DETECTED CONSTITUENTS IN GROUNDWATERFORMER GASOLINE SERVICE STATION204 ROOSEVELT ROADWALKERTON, INDIANAIDEM RCG SCREENING LEVELS, MARCH 2016GROUNDWATERRESIDENTIAL TAP (ug/L)SB-1 7/20/2016272SB-2 7/20/2016 13.0SB-4 7/21/2016490SB-6 7/21/201667.4SB-7 7/21/2016358SB-8 7/21/20161,140SB-9 7/21/20163,590SB-13 7/21/201645.2SB-14 7/20/201641.0SB-1 7/20/20165.5*SB-8 7/21/20166.9*SB-14 7/20/2016 Naphthalene1.7 1.7BOLD = Indicates detected concentration exceeds screening level.IDEM RCG = Indiana Department of Environmental Management, Remediation Closure Guideug/l = micrograms per liter* = Qualified by the laboratory as a common lab contaminant. See Appendix B for laboratory reports.Methylene ChlorideVolatile Organic Compounds155BORING/TEMPORARY WELL IDENTIFIERSAMPLE DATE CONSTITUENTRESULT(ug/l)LeadPolycyclic Aromatic HydrocarbonsTable 2 - Groundwater Analytical8/31/20161 of 1 TABLE 3GROUNDWATER ELEVATION DATAFORMER GASOLINE SERVICE STATION204 ROOSEVELT ROADWALKERTON, INDIANATEMPORARY WELL IDENTIFIERMEASURING POINT ELEVATION(feet amsl)TOTAL DEPTH OF WELL (feet below MPE)DEPTH TO WATER(feet below MPE)WATER LEVEL ELEVATION(feet amsl)SB-1 98.75 12.47 11.01 87.74SB-2 100.27 15.02 13.82 86.45SB-4 100.22 18.35 16.62 83.60SB-6 99.94 15.59 13.84 86.10SB-7 99.98 14.90 14.12 85.86SB-8 99.18 14.72 12.01 87.17SB-9 98.90 14.68 11.24 87.66SB-10 100.94 15.85 Dry - -SB-11 101.12 16.54 Dry - -SB-12 99.53 14.90 Dry - -SB-13 99.87 14.90 14.59 85.28SB-14 100.20 15.99 13.67 86.53amsl = above mean sea levelMPE = measuring point elevationNOTE: Temporary wells not set in soil borings SB-3 and SB-5.Table 3 - Groundwater Elevation Data8/31/20161 of 1 FIGURES APPENDIX A SOIL BORING LOGS Gravel paving material Medium sand, dark yellow-brown, 10YR 5/4 Medium sand, dark yellow-brown, 10YR 4/4, wet Total depth 12--ft, piezometer set at 12-ft 5 10 15 2.2 3.2 3.9 0.0 0.0 0.0 0.0 0.0 0.0 SB-1 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/19/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 12 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.46DrillerChris Chambers 2067 Drill Rig Asphalt and gravel Medium sand, dark yellow-brown, 10YR 4/4, clayey, cohesive, low moisture Medium sand, yellow-brown, 10YR 5/4, medium moisture, loose, wet at 14-ft Total depth 16--ft 5 10 15 3.0 3.7 3.2 3.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-2 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/19/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 99.46 FeetDrillerChris Chambers 2067 Drill Rig Medium sand, dark yellow-brown, 10YR 4/4, sl moist, pushed rock Medium sand, yellow-brown, 10YR 5/4, slightly moist, medium moist at 16-ft Total depth 16--ft, No water encountered, no piezometer set 5 10 15 1.5 3.2 3.5 3.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-3 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/19/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 99.87DrillerChris Chambers 2067 Drill Rig Medium sand, dark yellow-brown, 10YR 4/4, sl moist, pushed rock Medium sand, silty, clayey, yellow-brown, 10YR 5/4, slightly moist, cohesive Medium sand, dark yellow brown, 10YR 5/4, loose Total depth 16-ft 5 10 15 3.2 3.4 3.5 4.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-4 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/19/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 100.35DrillerChris Chambers 2067 Drill Rig Fine to medium sand, dark yellow-brown, 10YR 4/4, slightly moist Medium sand, silty, clayey, yellow-brown, 10YR 5/4, slightly moist Poor recovery Clay, silty, hard, gray, 10YR 5/1, low moisture Total depth 16-ft. Could not set piezometer to depth 5 10 15 3.0 3.1 3.2 0.7 2.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-5 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/19/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 99.20DrillerChris Chambers 2067 Drill Rig Medium sand, dark yellow-brown, 10YR 4/4, slightly moist, loose, hard at 4-ft Medium sand, silty, clayey, yellow-brown, 10YR 5/4, slightly moist, loose, rock fragments at 13.4-ft Silt, very hard, gray, 10YR 5/1, low moisture Total depth 16-ft. 5 10 15 2.9 2.6 3.1 3.7 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-6 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/19/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 99.70DrillerChris Chambers 2067 Drill Rig Asphalt Medium sand, dark yellow-brown, 10YR 4/4, slightly moist, loose Medium sand, dark yellow-brown, 10YR 4/4, slightly moist, cohesive Medium sand, yellow-brown, 10YR 5/4, slightly moist, loose Medium to coarse sand & fine to medium gravel, very silty, wet Silt, hard, gray, 10YR 5/1 Total depth 16-ft 5 10 15 3.0 3.2 4.0 4.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-7 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/19/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 99.78DrillerChris Chambers 2067 Drill Rig Asphalt Gravel, topsoil Medium sand, silty, dark yellow-brown, 10YR 4/4, slightly moist, loose Medium sand hard, some pebbles, dark yellow-brown, 10YR 4/4 Medium sand, dark yellow-brown, 10YR 5/4, slightly moist Sand & gravel, muddy, wet Silt, hard, brown, 10YR 5/3 Silt, hard, gray, 10YR 5/1 Total depth 16-ft 5 10 15 3.2 2.9 4.0 4.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-8 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/19/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 99.16DrillerChris Chambers 2067 Drill Rig Asphalt topsoil & fine sand, light yellow brown, 10YR 5/6 Soil, dark brown, organic Fine to medium sand hard, some pebbles, dark yellow-brown, 10YR 4/4 Medium sand, gray brown, 10YR 5/2 Medium sand, dark yellow brown, 10YR 4/4, wet Sand & gravel, dark yellow brown, 10YR 4/4, wet Silt, brown, 10YR 5/3 Silt, clayey, gray, 10YR 4/1 Total depth 16-ft 5 10 15 2.8 3.3 3.4 4.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-9 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/19/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.51DrillerChris Chambers 2067 Drill Rig topsoil & fine sand, light yellow brown, 10YR 5/6. low moisture Medium sand, dark yellow brown, 10YR 4/4, low moisture Medium sand, dark yellow brown, 10YR 4/4, slightly moist Medium sand to medium gravel, dark yellow brown, 10YR 4/4, wet Total depth 16-ft 5 10 15 3.0 2.0 2.9 2.9 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-10 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/20/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 100.82DrillerChris Chambers 2067 Drill Rig topsoil & grass Fine sand, light yellow brown, 10YR 5/6. low moisture Medium to coarse sand, silty, hard, dark yellow brown, 10YR 4/4, slightly moist Medium sand, dark yellow brown, 10YR 4/4, slightly moist Medium sand & gravel, dark yellow brown, 10YR 4/4, moist Total depth 16-ft 5 10 15 2.8 3.1 3.2 3.3 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-11 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/20/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 100.02DrillerChris Chambers 2067 Drill Rig topsoil & grass Fine sand, gray, 10YR 6/1. dry Fine to medium sand, silty, hard, light yellow brown, 10YR 6/4, low moisture Fine to medium sand, silty, hard, yellow brown, 10YR 5/4, low moisture Medium sand, some fine gravel, dark yellow brown, 10YR 4/4, wet Silt, some coarse sand grains, hard, brown, 10YR 5/3, some mottling Total depth 16-feet 5 10 15 2.7 2.9 2.9 3.2 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-12 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/20/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 99.39DrillerChris Chambers 2067 Drill Rig topsoil & grass Silt to fine sand, light yellow brown, 10YR 6/4. dry Fine to medium sand, silty, yellow brown, 10YR 5/4, low moisture Medium sand, yellow brown, 10YR 5/4, slightly moist Fine to medium gravel, dark yellow brown, 10YR 4/4, wet Fine sand, dark yellow brown, 10YR 4/4 wet Silt, hard, brown, 10YR 5/3, low moisture Silt, gray, 10YR 5/1, low moisture Total depth 16-feet 5 10 15 3.1 3.2 3.2 4.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-13 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/20/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.62DrillerChris Chambers 2067 Drill Rig Gravel paving Silt , light yellow brown, 10YR 6/4. dry Silt & fine sand, dark brown, 10YR 4/3, low moisture Fine to medium sand, yellow brown, 10YR 5/4, slightly moist Fine to medium sand, dark yellow brown, 10YR 4/4, slightly moist, some fine gravel at 12-ft Medium sand, some fine to medium gravel, dark yellow brown, 10YR 4/4, wet Silt, brown, 10YR 5/3, low moisture, soft at 13.7, hard at 15-ft Silt, gray, 10YR 5/1, low moisture Total depth 16-feet 5 10 15 3.2 3.1 3.5 4.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-14 Former Gasoline Station Drilling Contractor 5200-16-05 Geologist John R. Barnhart, L.P.G. Date Drilled 7/20/2016 Boring Diameter 2 Inches Feet Geoprobe Static Water Level Walkerton, IN204 Roosevelt Road Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\204 Roosevelt, Walkerton\Phase II ESA\Walkerton.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 99.39DrillerChris Chambers 2067 Drill Rig APPENDIX B LABORATORY REPORTS #=CL# August 02, 2016 LIMS USE: FR - GREG WAGGLE LIMS OBJECT ID: 50150004 50150004 Project: Pace Project No.: RE: Mr. Greg Waggle Symbiont 6737 W. Washington St. Suite 3440 Milwaukee, WI 53214 204 Roosevelt Road (Walkerton) Dear Mr. Waggle: Enclosed are the analytical results for sample(s) received by the laboratory on July 20, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Mick Mayse mick.mayse@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 1 of 56 #=CP# CERTIFICATIONS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Indiana Certification IDs 7726 Moller Road, Indianapolis, IN 46268 Illinois Certification #: 200074 Indiana Certification #: C-49-06 Kansas/NELAP Certification #:E-10177 Kentucky UST Certification #: 0042 Kentucky WW Certification #:98019 Ohio VAP Certification #: CL-0065 Oklahoma Certification #: 2014-148 Texas Certification #: T104704355-15-9 West Virginia Certification #: 330 Wisconsin Certification #: 999788130 USDA Soil Permit #: P330-10-00128 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 2 of 56 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Lab ID Sample ID Matrix Date Collected Date Received 50150004001 WT-SB-1(008010)Solid 07/19/16 09:20 07/20/16 08:50 50150004002 WT-SB-2(012014)Solid 07/19/16 09:56 07/20/16 08:50 50150004003 WT-SB-3(012014)Solid 07/19/16 10:50 07/20/16 08:50 50150004004 WT-SB-4(014016)Solid 07/19/16 15:22 07/20/16 08:50 50150004005 WT-SB-5(014016)Solid 07/19/16 12:40 07/20/16 08:50 50150004006 WT-SB-6(010012)Solid 07/19/16 13:15 07/20/16 08:50 50150004007 WT-SB-7(010012)Solid 07/19/16 14:08 07/20/16 08:50 50150004008 WT-SB-8(010012)Solid 07/19/16 14:44 07/20/16 08:50 50150004009 WT-SB-9(010012)Solid 07/19/16 15:20 07/20/16 08:50 50150004010 WT-FD-1 Solid 07/19/16 11:00 07/20/16 08:50 50150004011 TRIP BLANK Water 07/19/16 08:00 07/20/16 08:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 3 of 56 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 50150004001 WT-SB-1(008010)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004002 WT-SB-2(012014)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004003 WT-SB-3(012014)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004004 WT-SB-4(014016)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004005 WT-SB-5(014016)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004006 WT-SB-6(010012)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004007 WT-SB-7(010012)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004008 WT-SB-8(010012)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004009 WT-SB-9(010012)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004010 WT-FD-1 EPA 6010 1 PASI-IJPK REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 4 of 56 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IWDB 50150004011 TRIP BLANK EPA 8260 75 PASI-ITMW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 5 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-1(008010)Lab ID:50150004001 Collected:07/19/16 09:20 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 2.6 mg/kg 07/26/16 02:45 7439-92-107/23/16 11:201.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 05:29 83-32-907/20/16 21:310.0053 1 Acenaphthylene ND mg/kg 07/22/16 05:29 208-96-807/20/16 21:310.0053 1 Anthracene ND mg/kg 07/22/16 05:29 120-12-707/20/16 21:310.0053 1 Benzo(a)anthracene ND mg/kg 07/22/16 05:29 56-55-307/20/16 21:310.0053 1 Benzo(a)pyrene ND mg/kg 07/22/16 05:29 50-32-807/20/16 21:310.0053 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 05:29 205-99-207/20/16 21:310.0053 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 05:29 191-24-207/20/16 21:310.0053 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 05:29 207-08-907/20/16 21:310.0053 1 Chrysene ND mg/kg 07/22/16 05:29 218-01-907/20/16 21:310.0053 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 05:29 53-70-307/20/16 21:310.0053 1 Fluoranthene ND mg/kg 07/22/16 05:29 206-44-007/20/16 21:310.0053 1 Fluorene ND mg/kg 07/22/16 05:29 86-73-707/20/16 21:310.0053 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 05:29 193-39-507/20/16 21:310.0053 1 1-Methylnaphthalene ND mg/kg 07/22/16 05:29 90-12-0 N207/20/16 21:310.0053 1 2-Methylnaphthalene ND mg/kg 07/22/16 05:29 91-57-607/20/16 21:310.0053 1 Naphthalene ND mg/kg 07/22/16 05:29 91-20-307/20/16 21:310.0053 1 Phenanthrene ND mg/kg 07/22/16 05:29 85-01-807/20/16 21:310.0053 1 Pyrene ND mg/kg 07/22/16 05:29 129-00-007/20/16 21:310.0053 1 Surrogates 2-Fluorobiphenyl (S)51 %.07/22/16 05:29 321-60-807/20/16 21:3125-121 1 p-Terphenyl-d14 (S)55 %.07/22/16 05:29 1718-51-007/20/16 21:3127-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 04:17 67-64-10.10 1 Acrolein ND mg/kg 07/29/16 04:17 107-02-80.10 1 Acrylonitrile ND mg/kg 07/29/16 04:17 107-13-10.10 1 Benzene ND mg/kg 07/29/16 04:17 71-43-20.0052 1 Bromobenzene ND mg/kg 07/29/16 04:17 108-86-10.0052 1 Bromochloromethane ND mg/kg 07/29/16 04:17 74-97-50.0052 1 Bromodichloromethane ND mg/kg 07/29/16 04:17 75-27-40.0052 1 Bromoform ND mg/kg 07/29/16 04:17 75-25-20.0052 1 Bromomethane ND mg/kg 07/29/16 04:17 74-83-90.0052 1 2-Butanone (MEK)ND mg/kg 07/29/16 04:17 78-93-30.026 1 n-Butylbenzene ND mg/kg 07/29/16 04:17 104-51-80.0052 1 sec-Butylbenzene ND mg/kg 07/29/16 04:17 135-98-80.0052 1 tert-Butylbenzene ND mg/kg 07/29/16 04:17 98-06-60.0052 1 Carbon disulfide ND mg/kg 07/29/16 04:17 75-15-00.010 1 Carbon tetrachloride ND mg/kg 07/29/16 04:17 56-23-50.0052 1 Chlorobenzene ND mg/kg 07/29/16 04:17 108-90-70.0052 1 Chloroethane ND mg/kg 07/29/16 04:17 75-00-30.0052 1 Chloroform ND mg/kg 07/29/16 04:17 67-66-30.0052 1 Chloromethane ND mg/kg 07/29/16 04:17 74-87-30.0052 1 2-Chlorotoluene ND mg/kg 07/29/16 04:17 95-49-80.0052 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 6 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-1(008010)Lab ID:50150004001 Collected:07/19/16 09:20 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 04:17 106-43-40.0052 1 Dibromochloromethane ND mg/kg 07/29/16 04:17 124-48-10.0052 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 04:17 106-93-40.0052 1 Dibromomethane ND mg/kg 07/29/16 04:17 74-95-30.0052 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 04:17 95-50-10.0052 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 04:17 541-73-10.0052 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 04:17 106-46-70.0052 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 04:17 110-57-60.10 1 Dichlorodifluoromethane ND mg/kg 07/29/16 04:17 75-71-80.0052 1 1,1-Dichloroethane ND mg/kg 07/29/16 04:17 75-34-30.0052 1 1,2-Dichloroethane ND mg/kg 07/29/16 04:17 107-06-20.0052 1 1,1-Dichloroethene ND mg/kg 07/29/16 04:17 75-35-40.0052 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 04:17 156-59-20.0052 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 04:17 156-60-50.0052 1 1,2-Dichloropropane ND mg/kg 07/29/16 04:17 78-87-50.0052 1 1,3-Dichloropropane ND mg/kg 07/29/16 04:17 142-28-90.0052 1 2,2-Dichloropropane ND mg/kg 07/29/16 04:17 594-20-70.0052 1 1,1-Dichloropropene ND mg/kg 07/29/16 04:17 563-58-60.0052 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 04:17 10061-01-50.0052 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 04:17 10061-02-60.0052 1 Ethylbenzene ND mg/kg 07/29/16 04:17 100-41-40.0052 1 Ethyl methacrylate ND mg/kg 07/29/16 04:17 97-63-20.10 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 04:17 87-68-30.0052 1 n-Hexane ND mg/kg 07/29/16 04:17 110-54-30.0052 1 2-Hexanone ND mg/kg 07/29/16 04:17 591-78-60.10 1 Iodomethane ND mg/kg 07/29/16 04:17 74-88-40.10 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 04:17 98-82-80.0052 1 p-Isopropyltoluene ND mg/kg 07/29/16 04:17 99-87-60.0052 1 Methylene Chloride ND mg/kg 07/29/16 04:17 75-09-20.021 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 04:17 108-10-10.026 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 04:17 1634-04-40.0052 1 Naphthalene ND mg/kg 07/29/16 04:17 91-20-30.0052 1 n-Propylbenzene ND mg/kg 07/29/16 04:17 103-65-10.0052 1 Styrene ND mg/kg 07/29/16 04:17 100-42-50.0052 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 04:17 630-20-60.0052 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 04:17 79-34-50.0052 1 Tetrachloroethene ND mg/kg 07/29/16 04:17 127-18-40.0052 1 Toluene ND mg/kg 07/29/16 04:17 108-88-30.0052 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 04:17 87-61-60.0052 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 04:17 120-82-10.0052 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 04:17 71-55-60.0052 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 04:17 79-00-50.0052 1 Trichloroethene ND mg/kg 07/29/16 04:17 79-01-60.0052 1 Trichlorofluoromethane ND mg/kg 07/29/16 04:17 75-69-40.0052 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 04:17 96-18-40.0052 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 04:17 95-63-60.0052 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 7 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-1(008010)Lab ID:50150004001 Collected:07/19/16 09:20 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 04:17 108-67-80.0052 1 Vinyl acetate ND mg/kg 07/29/16 04:17 108-05-40.10 1 Vinyl chloride ND mg/kg 07/29/16 04:17 75-01-40.0052 1 Xylene (Total)ND mg/kg 07/29/16 04:17 1330-20-70.010 1 Surrogates Dibromofluoromethane (S)110 %.07/29/16 04:17 1868-53-770-128 1 Toluene-d8 (S)100 %.07/29/16 04:17 2037-26-572-139 1 4-Bromofluorobenzene (S)99 %.07/29/16 04:17 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 6.8 %07/28/16 11:370.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 8 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-2(012014)Lab ID:50150004002 Collected:07/19/16 09:56 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 5.6 mg/kg 07/26/16 02:47 7439-92-107/23/16 11:200.98 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/26/16 14:42 83-32-907/21/16 10:300.026 5 Acenaphthylene ND mg/kg 07/26/16 14:42 208-96-807/21/16 10:300.026 5 Anthracene ND mg/kg 07/26/16 14:42 120-12-707/21/16 10:300.026 5 Benzo(a)anthracene ND mg/kg 07/26/16 14:42 56-55-307/21/16 10:300.026 5 Benzo(a)pyrene ND mg/kg 07/26/16 14:42 50-32-807/21/16 10:300.026 5 Benzo(b)fluoranthene ND mg/kg 07/26/16 14:42 205-99-207/21/16 10:300.026 5 Benzo(g,h,i)perylene ND mg/kg 07/26/16 14:42 191-24-207/21/16 10:300.026 5 Benzo(k)fluoranthene ND mg/kg 07/26/16 14:42 207-08-907/21/16 10:300.026 5 Chrysene ND mg/kg 07/26/16 14:42 218-01-907/21/16 10:300.026 5 Dibenz(a,h)anthracene ND mg/kg 07/26/16 14:42 53-70-307/21/16 10:300.026 5 Fluoranthene ND mg/kg 07/26/16 14:42 206-44-007/21/16 10:300.026 5 Fluorene ND mg/kg 07/26/16 14:42 86-73-707/21/16 10:300.026 5 Indeno(1,2,3-cd)pyrene ND mg/kg 07/26/16 14:42 193-39-507/21/16 10:300.026 5 1-Methylnaphthalene ND mg/kg 07/26/16 14:42 90-12-0 N207/21/16 10:300.026 5 2-Methylnaphthalene ND mg/kg 07/26/16 14:42 91-57-607/21/16 10:300.026 5 Naphthalene ND mg/kg 07/26/16 14:42 91-20-3 ED07/21/16 10:300.026 5 Phenanthrene ND mg/kg 07/26/16 14:42 85-01-807/21/16 10:300.026 5 Pyrene ND mg/kg 07/26/16 14:42 129-00-007/21/16 10:300.026 5 Surrogates 2-Fluorobiphenyl (S)83 %.07/26/16 14:42 321-60-807/21/16 10:3025-121 5 p-Terphenyl-d14 (S)94 %.07/26/16 14:42 1718-51-007/21/16 10:3027-124 5 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 04:55 67-64-10.10 1 Acrolein ND mg/kg 07/29/16 04:55 107-02-80.10 1 Acrylonitrile ND mg/kg 07/29/16 04:55 107-13-10.10 1 Benzene ND mg/kg 07/29/16 04:55 71-43-20.0050 1 Bromobenzene ND mg/kg 07/29/16 04:55 108-86-10.0050 1 Bromochloromethane ND mg/kg 07/29/16 04:55 74-97-50.0050 1 Bromodichloromethane ND mg/kg 07/29/16 04:55 75-27-40.0050 1 Bromoform ND mg/kg 07/29/16 04:55 75-25-20.0050 1 Bromomethane ND mg/kg 07/29/16 04:55 74-83-90.0050 1 2-Butanone (MEK)ND mg/kg 07/29/16 04:55 78-93-30.025 1 n-Butylbenzene ND mg/kg 07/29/16 04:55 104-51-80.0050 1 sec-Butylbenzene ND mg/kg 07/29/16 04:55 135-98-80.0050 1 tert-Butylbenzene ND mg/kg 07/29/16 04:55 98-06-60.0050 1 Carbon disulfide ND mg/kg 07/29/16 04:55 75-15-00.010 1 Carbon tetrachloride ND mg/kg 07/29/16 04:55 56-23-50.0050 1 Chlorobenzene ND mg/kg 07/29/16 04:55 108-90-70.0050 1 Chloroethane ND mg/kg 07/29/16 04:55 75-00-30.0050 1 Chloroform ND mg/kg 07/29/16 04:55 67-66-30.0050 1 Chloromethane ND mg/kg 07/29/16 04:55 74-87-30.0050 1 2-Chlorotoluene ND mg/kg 07/29/16 04:55 95-49-80.0050 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 9 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-2(012014)Lab ID:50150004002 Collected:07/19/16 09:56 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 04:55 106-43-40.0050 1 Dibromochloromethane ND mg/kg 07/29/16 04:55 124-48-10.0050 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 04:55 106-93-40.0050 1 Dibromomethane ND mg/kg 07/29/16 04:55 74-95-30.0050 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 04:55 95-50-10.0050 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 04:55 541-73-10.0050 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 04:55 106-46-70.0050 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 04:55 110-57-60.10 1 Dichlorodifluoromethane ND mg/kg 07/29/16 04:55 75-71-80.0050 1 1,1-Dichloroethane ND mg/kg 07/29/16 04:55 75-34-30.0050 1 1,2-Dichloroethane ND mg/kg 07/29/16 04:55 107-06-20.0050 1 1,1-Dichloroethene ND mg/kg 07/29/16 04:55 75-35-40.0050 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 04:55 156-59-20.0050 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 04:55 156-60-50.0050 1 1,2-Dichloropropane ND mg/kg 07/29/16 04:55 78-87-50.0050 1 1,3-Dichloropropane ND mg/kg 07/29/16 04:55 142-28-90.0050 1 2,2-Dichloropropane ND mg/kg 07/29/16 04:55 594-20-70.0050 1 1,1-Dichloropropene ND mg/kg 07/29/16 04:55 563-58-60.0050 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 04:55 10061-01-50.0050 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 04:55 10061-02-60.0050 1 Ethylbenzene ND mg/kg 07/29/16 04:55 100-41-40.0050 1 Ethyl methacrylate ND mg/kg 07/29/16 04:55 97-63-20.10 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 04:55 87-68-30.0050 1 n-Hexane ND mg/kg 07/29/16 04:55 110-54-30.0050 1 2-Hexanone ND mg/kg 07/29/16 04:55 591-78-60.10 1 Iodomethane ND mg/kg 07/29/16 04:55 74-88-40.10 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 04:55 98-82-80.0050 1 p-Isopropyltoluene ND mg/kg 07/29/16 04:55 99-87-60.0050 1 Methylene Chloride ND mg/kg 07/29/16 04:55 75-09-20.020 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 04:55 108-10-10.025 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 04:55 1634-04-40.0050 1 Naphthalene ND mg/kg 07/29/16 04:55 91-20-30.0050 1 n-Propylbenzene ND mg/kg 07/29/16 04:55 103-65-10.0050 1 Styrene ND mg/kg 07/29/16 04:55 100-42-50.0050 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 04:55 630-20-60.0050 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 04:55 79-34-50.0050 1 Tetrachloroethene ND mg/kg 07/29/16 04:55 127-18-40.0050 1 Toluene ND mg/kg 07/29/16 04:55 108-88-30.0050 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 04:55 87-61-60.0050 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 04:55 120-82-10.0050 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 04:55 71-55-60.0050 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 04:55 79-00-50.0050 1 Trichloroethene ND mg/kg 07/29/16 04:55 79-01-60.0050 1 Trichlorofluoromethane ND mg/kg 07/29/16 04:55 75-69-40.0050 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 04:55 96-18-40.0050 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 04:55 95-63-60.0050 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 10 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-2(012014)Lab ID:50150004002 Collected:07/19/16 09:56 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 04:55 108-67-80.0050 1 Vinyl acetate ND mg/kg 07/29/16 04:55 108-05-40.10 1 Vinyl chloride ND mg/kg 07/29/16 04:55 75-01-40.0050 1 Xylene (Total)ND mg/kg 07/29/16 04:55 1330-20-70.010 1 Surrogates Dibromofluoromethane (S)107 %.07/29/16 04:55 1868-53-770-128 1 Toluene-d8 (S)105 %.07/29/16 04:55 2037-26-572-139 1 4-Bromofluorobenzene (S)95 %.07/29/16 04:55 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 5.9 %07/28/16 11:370.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 11 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-3(012014)Lab ID:50150004003 Collected:07/19/16 10:50 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 3.2 mg/kg 07/26/16 02:49 7439-92-107/23/16 11:201.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/26/16 14:58 83-32-907/21/16 10:300.0053 1 Acenaphthylene ND mg/kg 07/26/16 14:58 208-96-807/21/16 10:300.0053 1 Anthracene ND mg/kg 07/26/16 14:58 120-12-707/21/16 10:300.0053 1 Benzo(a)anthracene ND mg/kg 07/26/16 14:58 56-55-307/21/16 10:300.0053 1 Benzo(a)pyrene ND mg/kg 07/26/16 14:58 50-32-807/21/16 10:300.0053 1 Benzo(b)fluoranthene ND mg/kg 07/26/16 14:58 205-99-207/21/16 10:300.0053 1 Benzo(g,h,i)perylene ND mg/kg 07/26/16 14:58 191-24-207/21/16 10:300.0053 1 Benzo(k)fluoranthene ND mg/kg 07/26/16 14:58 207-08-907/21/16 10:300.0053 1 Chrysene ND mg/kg 07/26/16 14:58 218-01-907/21/16 10:300.0053 1 Dibenz(a,h)anthracene ND mg/kg 07/26/16 14:58 53-70-307/21/16 10:300.0053 1 Fluoranthene ND mg/kg 07/26/16 14:58 206-44-007/21/16 10:300.0053 1 Fluorene ND mg/kg 07/26/16 14:58 86-73-707/21/16 10:300.0053 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/26/16 14:58 193-39-507/21/16 10:300.0053 1 1-Methylnaphthalene ND mg/kg 07/26/16 14:58 90-12-0 N207/21/16 10:300.0053 1 2-Methylnaphthalene ND mg/kg 07/26/16 14:58 91-57-607/21/16 10:300.0053 1 Naphthalene ND mg/kg 07/26/16 14:58 91-20-307/21/16 10:300.0053 1 Phenanthrene ND mg/kg 07/26/16 14:58 85-01-807/21/16 10:300.0053 1 Pyrene ND mg/kg 07/26/16 14:58 129-00-007/21/16 10:300.0053 1 Surrogates 2-Fluorobiphenyl (S)54 %.07/26/16 14:58 321-60-807/21/16 10:3025-121 1 p-Terphenyl-d14 (S)60 %.07/26/16 14:58 1718-51-007/21/16 10:3027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 05:33 67-64-10.097 1 Acrolein ND mg/kg 07/29/16 05:33 107-02-80.097 1 Acrylonitrile ND mg/kg 07/29/16 05:33 107-13-10.097 1 Benzene ND mg/kg 07/29/16 05:33 71-43-20.0049 1 Bromobenzene ND mg/kg 07/29/16 05:33 108-86-10.0049 1 Bromochloromethane ND mg/kg 07/29/16 05:33 74-97-50.0049 1 Bromodichloromethane ND mg/kg 07/29/16 05:33 75-27-40.0049 1 Bromoform ND mg/kg 07/29/16 05:33 75-25-20.0049 1 Bromomethane ND mg/kg 07/29/16 05:33 74-83-90.0049 1 2-Butanone (MEK)ND mg/kg 07/29/16 05:33 78-93-30.024 1 n-Butylbenzene ND mg/kg 07/29/16 05:33 104-51-80.0049 1 sec-Butylbenzene ND mg/kg 07/29/16 05:33 135-98-80.0049 1 tert-Butylbenzene ND mg/kg 07/29/16 05:33 98-06-60.0049 1 Carbon disulfide ND mg/kg 07/29/16 05:33 75-15-00.0097 1 Carbon tetrachloride ND mg/kg 07/29/16 05:33 56-23-50.0049 1 Chlorobenzene ND mg/kg 07/29/16 05:33 108-90-70.0049 1 Chloroethane ND mg/kg 07/29/16 05:33 75-00-30.0049 1 Chloroform ND mg/kg 07/29/16 05:33 67-66-30.0049 1 Chloromethane ND mg/kg 07/29/16 05:33 74-87-30.0049 1 2-Chlorotoluene ND mg/kg 07/29/16 05:33 95-49-80.0049 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 12 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-3(012014)Lab ID:50150004003 Collected:07/19/16 10:50 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 05:33 106-43-40.0049 1 Dibromochloromethane ND mg/kg 07/29/16 05:33 124-48-10.0049 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 05:33 106-93-40.0049 1 Dibromomethane ND mg/kg 07/29/16 05:33 74-95-30.0049 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 05:33 95-50-10.0049 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 05:33 541-73-10.0049 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 05:33 106-46-70.0049 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 05:33 110-57-60.097 1 Dichlorodifluoromethane ND mg/kg 07/29/16 05:33 75-71-80.0049 1 1,1-Dichloroethane ND mg/kg 07/29/16 05:33 75-34-30.0049 1 1,2-Dichloroethane ND mg/kg 07/29/16 05:33 107-06-20.0049 1 1,1-Dichloroethene ND mg/kg 07/29/16 05:33 75-35-40.0049 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 05:33 156-59-20.0049 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 05:33 156-60-50.0049 1 1,2-Dichloropropane ND mg/kg 07/29/16 05:33 78-87-50.0049 1 1,3-Dichloropropane ND mg/kg 07/29/16 05:33 142-28-90.0049 1 2,2-Dichloropropane ND mg/kg 07/29/16 05:33 594-20-70.0049 1 1,1-Dichloropropene ND mg/kg 07/29/16 05:33 563-58-60.0049 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 05:33 10061-01-50.0049 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 05:33 10061-02-60.0049 1 Ethylbenzene ND mg/kg 07/29/16 05:33 100-41-40.0049 1 Ethyl methacrylate ND mg/kg 07/29/16 05:33 97-63-20.097 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 05:33 87-68-30.0049 1 n-Hexane ND mg/kg 07/29/16 05:33 110-54-30.0049 1 2-Hexanone ND mg/kg 07/29/16 05:33 591-78-60.097 1 Iodomethane ND mg/kg 07/29/16 05:33 74-88-40.097 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 05:33 98-82-80.0049 1 p-Isopropyltoluene ND mg/kg 07/29/16 05:33 99-87-60.0049 1 Methylene Chloride ND mg/kg 07/29/16 05:33 75-09-20.019 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 05:33 108-10-10.024 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 05:33 1634-04-40.0049 1 Naphthalene ND mg/kg 07/29/16 05:33 91-20-30.0049 1 n-Propylbenzene ND mg/kg 07/29/16 05:33 103-65-10.0049 1 Styrene ND mg/kg 07/29/16 05:33 100-42-50.0049 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 05:33 630-20-60.0049 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 05:33 79-34-50.0049 1 Tetrachloroethene ND mg/kg 07/29/16 05:33 127-18-40.0049 1 Toluene ND mg/kg 07/29/16 05:33 108-88-30.0049 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 05:33 87-61-60.0049 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 05:33 120-82-10.0049 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 05:33 71-55-60.0049 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 05:33 79-00-50.0049 1 Trichloroethene ND mg/kg 07/29/16 05:33 79-01-60.0049 1 Trichlorofluoromethane ND mg/kg 07/29/16 05:33 75-69-40.0049 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 05:33 96-18-40.0049 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 05:33 95-63-60.0049 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 13 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-3(012014)Lab ID:50150004003 Collected:07/19/16 10:50 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 05:33 108-67-80.0049 1 Vinyl acetate ND mg/kg 07/29/16 05:33 108-05-40.097 1 Vinyl chloride ND mg/kg 07/29/16 05:33 75-01-40.0049 1 Xylene (Total)ND mg/kg 07/29/16 05:33 1330-20-70.0097 1 Surrogates Dibromofluoromethane (S)108 %.07/29/16 05:33 1868-53-770-128 1 Toluene-d8 (S)101 %.07/29/16 05:33 2037-26-572-139 1 4-Bromofluorobenzene (S)93 %.07/29/16 05:33 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 7.0 %07/28/16 11:380.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 14 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-4(014016)Lab ID:50150004004 Collected:07/19/16 15:22 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 9.7 mg/kg 07/26/16 02:51 7439-92-107/23/16 11:201.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 19:50 83-32-907/21/16 10:300.0054 1 Acenaphthylene ND mg/kg 07/22/16 19:50 208-96-807/21/16 10:300.0054 1 Anthracene ND mg/kg 07/22/16 19:50 120-12-707/21/16 10:300.0054 1 Benzo(a)anthracene ND mg/kg 07/22/16 19:50 56-55-307/21/16 10:300.0054 1 Benzo(a)pyrene ND mg/kg 07/22/16 19:50 50-32-807/21/16 10:300.0054 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 19:50 205-99-207/21/16 10:300.0054 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 19:50 191-24-207/21/16 10:300.0054 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 19:50 207-08-907/21/16 10:300.0054 1 Chrysene ND mg/kg 07/22/16 19:50 218-01-907/21/16 10:300.0054 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 19:50 53-70-307/21/16 10:300.0054 1 Fluoranthene ND mg/kg 07/22/16 19:50 206-44-007/21/16 10:300.0054 1 Fluorene ND mg/kg 07/22/16 19:50 86-73-707/21/16 10:300.0054 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 19:50 193-39-507/21/16 10:300.0054 1 1-Methylnaphthalene ND mg/kg 07/22/16 19:50 90-12-0 N207/21/16 10:300.0054 1 2-Methylnaphthalene ND mg/kg 07/22/16 19:50 91-57-607/21/16 10:300.0054 1 Naphthalene ND mg/kg 07/22/16 19:50 91-20-307/21/16 10:300.0054 1 Phenanthrene ND mg/kg 07/22/16 19:50 85-01-807/21/16 10:300.0054 1 Pyrene ND mg/kg 07/22/16 19:50 129-00-007/21/16 10:300.0054 1 Surrogates 2-Fluorobiphenyl (S)71 %.07/22/16 19:50 321-60-807/21/16 10:3025-121 1 p-Terphenyl-d14 (S)77 %.07/22/16 19:50 1718-51-007/21/16 10:3027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 06:11 67-64-10.11 1 Acrolein ND mg/kg 07/29/16 06:11 107-02-80.11 1 Acrylonitrile ND mg/kg 07/29/16 06:11 107-13-10.11 1 Benzene ND mg/kg 07/29/16 06:11 71-43-20.0054 1 Bromobenzene ND mg/kg 07/29/16 06:11 108-86-10.0054 1 Bromochloromethane ND mg/kg 07/29/16 06:11 74-97-50.0054 1 Bromodichloromethane ND mg/kg 07/29/16 06:11 75-27-40.0054 1 Bromoform ND mg/kg 07/29/16 06:11 75-25-20.0054 1 Bromomethane ND mg/kg 07/29/16 06:11 74-83-90.0054 1 2-Butanone (MEK)ND mg/kg 07/29/16 06:11 78-93-30.027 1 n-Butylbenzene ND mg/kg 07/29/16 06:11 104-51-80.0054 1 sec-Butylbenzene ND mg/kg 07/29/16 06:11 135-98-80.0054 1 tert-Butylbenzene ND mg/kg 07/29/16 06:11 98-06-60.0054 1 Carbon disulfide ND mg/kg 07/29/16 06:11 75-15-00.011 1 Carbon tetrachloride ND mg/kg 07/29/16 06:11 56-23-50.0054 1 Chlorobenzene ND mg/kg 07/29/16 06:11 108-90-70.0054 1 Chloroethane ND mg/kg 07/29/16 06:11 75-00-30.0054 1 Chloroform ND mg/kg 07/29/16 06:11 67-66-30.0054 1 Chloromethane ND mg/kg 07/29/16 06:11 74-87-30.0054 1 2-Chlorotoluene ND mg/kg 07/29/16 06:11 95-49-80.0054 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 15 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-4(014016)Lab ID:50150004004 Collected:07/19/16 15:22 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 06:11 106-43-40.0054 1 Dibromochloromethane ND mg/kg 07/29/16 06:11 124-48-10.0054 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 06:11 106-93-40.0054 1 Dibromomethane ND mg/kg 07/29/16 06:11 74-95-30.0054 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 06:11 95-50-10.0054 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 06:11 541-73-10.0054 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 06:11 106-46-70.0054 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 06:11 110-57-60.11 1 Dichlorodifluoromethane ND mg/kg 07/29/16 06:11 75-71-80.0054 1 1,1-Dichloroethane ND mg/kg 07/29/16 06:11 75-34-30.0054 1 1,2-Dichloroethane ND mg/kg 07/29/16 06:11 107-06-20.0054 1 1,1-Dichloroethene ND mg/kg 07/29/16 06:11 75-35-40.0054 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 06:11 156-59-20.0054 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 06:11 156-60-50.0054 1 1,2-Dichloropropane ND mg/kg 07/29/16 06:11 78-87-50.0054 1 1,3-Dichloropropane ND mg/kg 07/29/16 06:11 142-28-90.0054 1 2,2-Dichloropropane ND mg/kg 07/29/16 06:11 594-20-70.0054 1 1,1-Dichloropropene ND mg/kg 07/29/16 06:11 563-58-60.0054 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 06:11 10061-01-50.0054 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 06:11 10061-02-60.0054 1 Ethylbenzene ND mg/kg 07/29/16 06:11 100-41-40.0054 1 Ethyl methacrylate ND mg/kg 07/29/16 06:11 97-63-20.11 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 06:11 87-68-30.0054 1 n-Hexane ND mg/kg 07/29/16 06:11 110-54-30.0054 1 2-Hexanone ND mg/kg 07/29/16 06:11 591-78-60.11 1 Iodomethane ND mg/kg 07/29/16 06:11 74-88-40.11 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 06:11 98-82-80.0054 1 p-Isopropyltoluene ND mg/kg 07/29/16 06:11 99-87-60.0054 1 Methylene Chloride ND mg/kg 07/29/16 06:11 75-09-20.021 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 06:11 108-10-10.027 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 06:11 1634-04-40.0054 1 Naphthalene ND mg/kg 07/29/16 06:11 91-20-30.0054 1 n-Propylbenzene ND mg/kg 07/29/16 06:11 103-65-10.0054 1 Styrene ND mg/kg 07/29/16 06:11 100-42-50.0054 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 06:11 630-20-60.0054 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 06:11 79-34-50.0054 1 Tetrachloroethene ND mg/kg 07/29/16 06:11 127-18-40.0054 1 Toluene ND mg/kg 07/29/16 06:11 108-88-30.0054 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 06:11 87-61-60.0054 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 06:11 120-82-10.0054 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 06:11 71-55-60.0054 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 06:11 79-00-50.0054 1 Trichloroethene ND mg/kg 07/29/16 06:11 79-01-60.0054 1 Trichlorofluoromethane ND mg/kg 07/29/16 06:11 75-69-40.0054 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 06:11 96-18-40.0054 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 06:11 95-63-60.0054 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 16 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-4(014016)Lab ID:50150004004 Collected:07/19/16 15:22 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 06:11 108-67-80.0054 1 Vinyl acetate ND mg/kg 07/29/16 06:11 108-05-40.11 1 Vinyl chloride ND mg/kg 07/29/16 06:11 75-01-40.0054 1 Xylene (Total)ND mg/kg 07/29/16 06:11 1330-20-70.011 1 Surrogates Dibromofluoromethane (S)108 %.07/29/16 06:11 1868-53-770-128 1 Toluene-d8 (S)101 %.07/29/16 06:11 2037-26-572-139 1 4-Bromofluorobenzene (S)87 %.07/29/16 06:11 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 6.6 %07/28/16 11:380.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 17 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-5(014016)Lab ID:50150004005 Collected:07/19/16 12:40 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 3.7 mg/kg 07/26/16 03:01 7439-92-107/23/16 11:201.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 20:39 83-32-907/21/16 10:300.0054 1 Acenaphthylene ND mg/kg 07/22/16 20:39 208-96-807/21/16 10:300.0054 1 Anthracene ND mg/kg 07/22/16 20:39 120-12-707/21/16 10:300.0054 1 Benzo(a)anthracene ND mg/kg 07/22/16 20:39 56-55-307/21/16 10:300.0054 1 Benzo(a)pyrene ND mg/kg 07/22/16 20:39 50-32-807/21/16 10:300.0054 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 20:39 205-99-207/21/16 10:300.0054 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 20:39 191-24-207/21/16 10:300.0054 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 20:39 207-08-907/21/16 10:300.0054 1 Chrysene ND mg/kg 07/22/16 20:39 218-01-907/21/16 10:300.0054 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 20:39 53-70-307/21/16 10:300.0054 1 Fluoranthene ND mg/kg 07/22/16 20:39 206-44-007/21/16 10:300.0054 1 Fluorene ND mg/kg 07/22/16 20:39 86-73-707/21/16 10:300.0054 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 20:39 193-39-507/21/16 10:300.0054 1 1-Methylnaphthalene ND mg/kg 07/22/16 20:39 90-12-0 N207/21/16 10:300.0054 1 2-Methylnaphthalene ND mg/kg 07/22/16 20:39 91-57-607/21/16 10:300.0054 1 Naphthalene ND mg/kg 07/22/16 20:39 91-20-307/21/16 10:300.0054 1 Phenanthrene ND mg/kg 07/22/16 20:39 85-01-807/21/16 10:300.0054 1 Pyrene ND mg/kg 07/22/16 20:39 129-00-007/21/16 10:300.0054 1 Surrogates 2-Fluorobiphenyl (S)66 %.07/22/16 20:39 321-60-807/21/16 10:3025-121 1 p-Terphenyl-d14 (S)71 %.07/22/16 20:39 1718-51-007/21/16 10:3027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 08:04 67-64-10.080 1 Acrolein ND mg/kg 07/29/16 08:04 107-02-80.080 1 Acrylonitrile ND mg/kg 07/29/16 08:04 107-13-10.080 1 Benzene ND mg/kg 07/29/16 08:04 71-43-20.0040 1 Bromobenzene ND mg/kg 07/29/16 08:04 108-86-10.0040 1 Bromochloromethane ND mg/kg 07/29/16 08:04 74-97-50.0040 1 Bromodichloromethane ND mg/kg 07/29/16 08:04 75-27-40.0040 1 Bromoform ND mg/kg 07/29/16 08:04 75-25-20.0040 1 Bromomethane ND mg/kg 07/29/16 08:04 74-83-90.0040 1 2-Butanone (MEK)ND mg/kg 07/29/16 08:04 78-93-30.020 1 n-Butylbenzene ND mg/kg 07/29/16 08:04 104-51-80.0040 1 sec-Butylbenzene ND mg/kg 07/29/16 08:04 135-98-80.0040 1 tert-Butylbenzene ND mg/kg 07/29/16 08:04 98-06-60.0040 1 Carbon disulfide ND mg/kg 07/29/16 08:04 75-15-00.0080 1 Carbon tetrachloride ND mg/kg 07/29/16 08:04 56-23-50.0040 1 Chlorobenzene ND mg/kg 07/29/16 08:04 108-90-70.0040 1 Chloroethane ND mg/kg 07/29/16 08:04 75-00-30.0040 1 Chloroform ND mg/kg 07/29/16 08:04 67-66-30.0040 1 Chloromethane ND mg/kg 07/29/16 08:04 74-87-30.0040 1 2-Chlorotoluene ND mg/kg 07/29/16 08:04 95-49-80.0040 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 18 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-5(014016)Lab ID:50150004005 Collected:07/19/16 12:40 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 08:04 106-43-40.0040 1 Dibromochloromethane ND mg/kg 07/29/16 08:04 124-48-10.0040 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 08:04 106-93-40.0040 1 Dibromomethane ND mg/kg 07/29/16 08:04 74-95-30.0040 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 08:04 95-50-10.0040 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 08:04 541-73-10.0040 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 08:04 106-46-70.0040 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 08:04 110-57-60.080 1 Dichlorodifluoromethane ND mg/kg 07/29/16 08:04 75-71-80.0040 1 1,1-Dichloroethane ND mg/kg 07/29/16 08:04 75-34-30.0040 1 1,2-Dichloroethane ND mg/kg 07/29/16 08:04 107-06-20.0040 1 1,1-Dichloroethene ND mg/kg 07/29/16 08:04 75-35-40.0040 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 08:04 156-59-20.0040 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 08:04 156-60-50.0040 1 1,2-Dichloropropane ND mg/kg 07/29/16 08:04 78-87-50.0040 1 1,3-Dichloropropane ND mg/kg 07/29/16 08:04 142-28-90.0040 1 2,2-Dichloropropane ND mg/kg 07/29/16 08:04 594-20-70.0040 1 1,1-Dichloropropene ND mg/kg 07/29/16 08:04 563-58-60.0040 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 08:04 10061-01-50.0040 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 08:04 10061-02-60.0040 1 Ethylbenzene ND mg/kg 07/29/16 08:04 100-41-40.0040 1 Ethyl methacrylate ND mg/kg 07/29/16 08:04 97-63-20.080 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 08:04 87-68-30.0040 1 n-Hexane ND mg/kg 07/29/16 08:04 110-54-30.0040 1 2-Hexanone ND mg/kg 07/29/16 08:04 591-78-60.080 1 Iodomethane ND mg/kg 07/29/16 08:04 74-88-40.080 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 08:04 98-82-80.0040 1 p-Isopropyltoluene ND mg/kg 07/29/16 08:04 99-87-60.0040 1 Methylene Chloride ND mg/kg 07/29/16 08:04 75-09-20.016 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 08:04 108-10-10.020 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 08:04 1634-04-40.0040 1 Naphthalene ND mg/kg 07/29/16 08:04 91-20-30.0040 1 n-Propylbenzene ND mg/kg 07/29/16 08:04 103-65-10.0040 1 Styrene ND mg/kg 07/29/16 08:04 100-42-50.0040 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 08:04 630-20-60.0040 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 08:04 79-34-50.0040 1 Tetrachloroethene ND mg/kg 07/29/16 08:04 127-18-40.0040 1 Toluene ND mg/kg 07/29/16 08:04 108-88-30.0040 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 08:04 87-61-60.0040 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 08:04 120-82-10.0040 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 08:04 71-55-60.0040 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 08:04 79-00-50.0040 1 Trichloroethene ND mg/kg 07/29/16 08:04 79-01-60.0040 1 Trichlorofluoromethane ND mg/kg 07/29/16 08:04 75-69-40.0040 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 08:04 96-18-40.0040 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 08:04 95-63-60.0040 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 19 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-5(014016)Lab ID:50150004005 Collected:07/19/16 12:40 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 08:04 108-67-80.0040 1 Vinyl acetate ND mg/kg 07/29/16 08:04 108-05-40.080 1 Vinyl chloride ND mg/kg 07/29/16 08:04 75-01-40.0040 1 Xylene (Total)ND mg/kg 07/29/16 08:04 1330-20-70.0080 1 Surrogates Dibromofluoromethane (S)115 %.07/29/16 08:04 1868-53-770-128 1 Toluene-d8 (S)127 %.07/29/16 08:04 2037-26-572-139 1 4-Bromofluorobenzene (S)73 %.07/29/16 08:04 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 8.7 %07/28/16 11:380.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 20 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-6(010012)Lab ID:50150004006 Collected:07/19/16 13:15 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 4.0 mg/kg 07/26/16 03:04 7439-92-107/23/16 11:201.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 20:56 83-32-907/21/16 10:300.0052 1 Acenaphthylene ND mg/kg 07/22/16 20:56 208-96-807/21/16 10:300.0052 1 Anthracene ND mg/kg 07/22/16 20:56 120-12-707/21/16 10:300.0052 1 Benzo(a)anthracene ND mg/kg 07/22/16 20:56 56-55-307/21/16 10:300.0052 1 Benzo(a)pyrene ND mg/kg 07/22/16 20:56 50-32-807/21/16 10:300.0052 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 20:56 205-99-207/21/16 10:300.0052 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 20:56 191-24-207/21/16 10:300.0052 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 20:56 207-08-907/21/16 10:300.0052 1 Chrysene ND mg/kg 07/22/16 20:56 218-01-907/21/16 10:300.0052 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 20:56 53-70-307/21/16 10:300.0052 1 Fluoranthene ND mg/kg 07/22/16 20:56 206-44-007/21/16 10:300.0052 1 Fluorene ND mg/kg 07/22/16 20:56 86-73-707/21/16 10:300.0052 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 20:56 193-39-507/21/16 10:300.0052 1 1-Methylnaphthalene ND mg/kg 07/22/16 20:56 90-12-0 N207/21/16 10:300.0052 1 2-Methylnaphthalene ND mg/kg 07/22/16 20:56 91-57-607/21/16 10:300.0052 1 Naphthalene ND mg/kg 07/22/16 20:56 91-20-307/21/16 10:300.0052 1 Phenanthrene ND mg/kg 07/22/16 20:56 85-01-807/21/16 10:300.0052 1 Pyrene ND mg/kg 07/22/16 20:56 129-00-007/21/16 10:300.0052 1 Surrogates 2-Fluorobiphenyl (S)69 %.07/22/16 20:56 321-60-807/21/16 10:3025-121 1 p-Terphenyl-d14 (S)75 %.07/22/16 20:56 1718-51-007/21/16 10:3027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 08:41 67-64-10.10 1 Acrolein ND mg/kg 07/29/16 08:41 107-02-80.10 1 Acrylonitrile ND mg/kg 07/29/16 08:41 107-13-10.10 1 Benzene ND mg/kg 07/29/16 08:41 71-43-20.0052 1 Bromobenzene ND mg/kg 07/29/16 08:41 108-86-10.0052 1 Bromochloromethane ND mg/kg 07/29/16 08:41 74-97-50.0052 1 Bromodichloromethane ND mg/kg 07/29/16 08:41 75-27-40.0052 1 Bromoform ND mg/kg 07/29/16 08:41 75-25-20.0052 1 Bromomethane ND mg/kg 07/29/16 08:41 74-83-90.0052 1 2-Butanone (MEK)ND mg/kg 07/29/16 08:41 78-93-30.026 1 n-Butylbenzene ND mg/kg 07/29/16 08:41 104-51-80.0052 1 sec-Butylbenzene ND mg/kg 07/29/16 08:41 135-98-80.0052 1 tert-Butylbenzene ND mg/kg 07/29/16 08:41 98-06-60.0052 1 Carbon disulfide ND mg/kg 07/29/16 08:41 75-15-00.010 1 Carbon tetrachloride ND mg/kg 07/29/16 08:41 56-23-50.0052 1 Chlorobenzene ND mg/kg 07/29/16 08:41 108-90-70.0052 1 Chloroethane ND mg/kg 07/29/16 08:41 75-00-30.0052 1 Chloroform ND mg/kg 07/29/16 08:41 67-66-30.0052 1 Chloromethane ND mg/kg 07/29/16 08:41 74-87-30.0052 1 2-Chlorotoluene ND mg/kg 07/29/16 08:41 95-49-80.0052 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 21 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-6(010012)Lab ID:50150004006 Collected:07/19/16 13:15 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 08:41 106-43-40.0052 1 Dibromochloromethane ND mg/kg 07/29/16 08:41 124-48-10.0052 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 08:41 106-93-40.0052 1 Dibromomethane ND mg/kg 07/29/16 08:41 74-95-30.0052 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 08:41 95-50-10.0052 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 08:41 541-73-10.0052 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 08:41 106-46-70.0052 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 08:41 110-57-60.10 1 Dichlorodifluoromethane ND mg/kg 07/29/16 08:41 75-71-80.0052 1 1,1-Dichloroethane ND mg/kg 07/29/16 08:41 75-34-30.0052 1 1,2-Dichloroethane ND mg/kg 07/29/16 08:41 107-06-20.0052 1 1,1-Dichloroethene ND mg/kg 07/29/16 08:41 75-35-40.0052 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 08:41 156-59-20.0052 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 08:41 156-60-50.0052 1 1,2-Dichloropropane ND mg/kg 07/29/16 08:41 78-87-50.0052 1 1,3-Dichloropropane ND mg/kg 07/29/16 08:41 142-28-90.0052 1 2,2-Dichloropropane ND mg/kg 07/29/16 08:41 594-20-70.0052 1 1,1-Dichloropropene ND mg/kg 07/29/16 08:41 563-58-60.0052 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 08:41 10061-01-50.0052 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 08:41 10061-02-60.0052 1 Ethylbenzene ND mg/kg 07/29/16 08:41 100-41-40.0052 1 Ethyl methacrylate ND mg/kg 07/29/16 08:41 97-63-20.10 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 08:41 87-68-30.0052 1 n-Hexane ND mg/kg 07/29/16 08:41 110-54-30.0052 1 2-Hexanone ND mg/kg 07/29/16 08:41 591-78-60.10 1 Iodomethane ND mg/kg 07/29/16 08:41 74-88-40.10 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 08:41 98-82-80.0052 1 p-Isopropyltoluene ND mg/kg 07/29/16 08:41 99-87-60.0052 1 Methylene Chloride ND mg/kg 07/29/16 08:41 75-09-20.021 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 08:41 108-10-10.026 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 08:41 1634-04-40.0052 1 Naphthalene ND mg/kg 07/29/16 08:41 91-20-30.0052 1 n-Propylbenzene ND mg/kg 07/29/16 08:41 103-65-10.0052 1 Styrene ND mg/kg 07/29/16 08:41 100-42-50.0052 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 08:41 630-20-60.0052 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 08:41 79-34-50.0052 1 Tetrachloroethene ND mg/kg 07/29/16 08:41 127-18-40.0052 1 Toluene ND mg/kg 07/29/16 08:41 108-88-30.0052 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 08:41 87-61-60.0052 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 08:41 120-82-10.0052 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 08:41 71-55-60.0052 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 08:41 79-00-50.0052 1 Trichloroethene ND mg/kg 07/29/16 08:41 79-01-60.0052 1 Trichlorofluoromethane ND mg/kg 07/29/16 08:41 75-69-40.0052 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 08:41 96-18-40.0052 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 08:41 95-63-60.0052 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 22 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-6(010012)Lab ID:50150004006 Collected:07/19/16 13:15 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 08:41 108-67-80.0052 1 Vinyl acetate ND mg/kg 07/29/16 08:41 108-05-40.10 1 Vinyl chloride ND mg/kg 07/29/16 08:41 75-01-40.0052 1 Xylene (Total)ND mg/kg 07/29/16 08:41 1330-20-70.010 1 Surrogates Dibromofluoromethane (S)107 %.07/29/16 08:41 1868-53-770-128 1 Toluene-d8 (S)98 %.07/29/16 08:41 2037-26-572-139 1 4-Bromofluorobenzene (S)95 %.07/29/16 08:41 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 5.1 %07/28/16 11:380.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 23 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-7(010012)Lab ID:50150004007 Collected:07/19/16 14:08 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 6.3 mg/kg 07/26/16 03:10 7439-92-107/23/16 11:200.97 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 21:12 83-32-907/21/16 10:300.0054 1 Acenaphthylene ND mg/kg 07/22/16 21:12 208-96-807/21/16 10:300.0054 1 Anthracene ND mg/kg 07/22/16 21:12 120-12-707/21/16 10:300.0054 1 Benzo(a)anthracene ND mg/kg 07/22/16 21:12 56-55-307/21/16 10:300.0054 1 Benzo(a)pyrene ND mg/kg 07/22/16 21:12 50-32-807/21/16 10:300.0054 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 21:12 205-99-207/21/16 10:300.0054 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 21:12 191-24-207/21/16 10:300.0054 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 21:12 207-08-907/21/16 10:300.0054 1 Chrysene ND mg/kg 07/22/16 21:12 218-01-907/21/16 10:300.0054 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 21:12 53-70-307/21/16 10:300.0054 1 Fluoranthene ND mg/kg 07/22/16 21:12 206-44-007/21/16 10:300.0054 1 Fluorene ND mg/kg 07/22/16 21:12 86-73-707/21/16 10:300.0054 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 21:12 193-39-507/21/16 10:300.0054 1 1-Methylnaphthalene ND mg/kg 07/22/16 21:12 90-12-0 N207/21/16 10:300.0054 1 2-Methylnaphthalene ND mg/kg 07/22/16 21:12 91-57-607/21/16 10:300.0054 1 Naphthalene ND mg/kg 07/22/16 21:12 91-20-307/21/16 10:300.0054 1 Phenanthrene ND mg/kg 07/22/16 21:12 85-01-807/21/16 10:300.0054 1 Pyrene ND mg/kg 07/22/16 21:12 129-00-007/21/16 10:300.0054 1 Surrogates 2-Fluorobiphenyl (S)69 %.07/22/16 21:12 321-60-807/21/16 10:3025-121 1 p-Terphenyl-d14 (S)77 %.07/22/16 21:12 1718-51-007/21/16 10:3027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 09:19 67-64-10.11 1 Acrolein ND mg/kg 07/29/16 09:19 107-02-80.11 1 Acrylonitrile ND mg/kg 07/29/16 09:19 107-13-10.11 1 Benzene ND mg/kg 07/29/16 09:19 71-43-20.0055 1 Bromobenzene ND mg/kg 07/29/16 09:19 108-86-10.0055 1 Bromochloromethane ND mg/kg 07/29/16 09:19 74-97-50.0055 1 Bromodichloromethane ND mg/kg 07/29/16 09:19 75-27-40.0055 1 Bromoform ND mg/kg 07/29/16 09:19 75-25-20.0055 1 Bromomethane ND mg/kg 07/29/16 09:19 74-83-90.0055 1 2-Butanone (MEK)ND mg/kg 07/29/16 09:19 78-93-30.027 1 n-Butylbenzene ND mg/kg 07/29/16 09:19 104-51-80.0055 1 sec-Butylbenzene ND mg/kg 07/29/16 09:19 135-98-80.0055 1 tert-Butylbenzene ND mg/kg 07/29/16 09:19 98-06-60.0055 1 Carbon disulfide ND mg/kg 07/29/16 09:19 75-15-00.011 1 Carbon tetrachloride ND mg/kg 07/29/16 09:19 56-23-50.0055 1 Chlorobenzene ND mg/kg 07/29/16 09:19 108-90-70.0055 1 Chloroethane ND mg/kg 07/29/16 09:19 75-00-30.0055 1 Chloroform ND mg/kg 07/29/16 09:19 67-66-30.0055 1 Chloromethane ND mg/kg 07/29/16 09:19 74-87-30.0055 1 2-Chlorotoluene ND mg/kg 07/29/16 09:19 95-49-80.0055 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 24 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-7(010012)Lab ID:50150004007 Collected:07/19/16 14:08 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 09:19 106-43-40.0055 1 Dibromochloromethane ND mg/kg 07/29/16 09:19 124-48-10.0055 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 09:19 106-93-40.0055 1 Dibromomethane ND mg/kg 07/29/16 09:19 74-95-30.0055 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 09:19 95-50-10.0055 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 09:19 541-73-10.0055 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 09:19 106-46-70.0055 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 09:19 110-57-60.11 1 Dichlorodifluoromethane ND mg/kg 07/29/16 09:19 75-71-80.0055 1 1,1-Dichloroethane ND mg/kg 07/29/16 09:19 75-34-30.0055 1 1,2-Dichloroethane ND mg/kg 07/29/16 09:19 107-06-20.0055 1 1,1-Dichloroethene ND mg/kg 07/29/16 09:19 75-35-40.0055 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 09:19 156-59-20.0055 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 09:19 156-60-50.0055 1 1,2-Dichloropropane ND mg/kg 07/29/16 09:19 78-87-50.0055 1 1,3-Dichloropropane ND mg/kg 07/29/16 09:19 142-28-90.0055 1 2,2-Dichloropropane ND mg/kg 07/29/16 09:19 594-20-70.0055 1 1,1-Dichloropropene ND mg/kg 07/29/16 09:19 563-58-60.0055 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 09:19 10061-01-50.0055 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 09:19 10061-02-60.0055 1 Ethylbenzene ND mg/kg 07/29/16 09:19 100-41-40.0055 1 Ethyl methacrylate ND mg/kg 07/29/16 09:19 97-63-20.11 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 09:19 87-68-30.0055 1 n-Hexane ND mg/kg 07/29/16 09:19 110-54-30.0055 1 2-Hexanone ND mg/kg 07/29/16 09:19 591-78-60.11 1 Iodomethane ND mg/kg 07/29/16 09:19 74-88-40.11 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 09:19 98-82-80.0055 1 p-Isopropyltoluene ND mg/kg 07/29/16 09:19 99-87-60.0055 1 Methylene Chloride ND mg/kg 07/29/16 09:19 75-09-20.022 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 09:19 108-10-10.027 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 09:19 1634-04-40.0055 1 Naphthalene ND mg/kg 07/29/16 09:19 91-20-30.0055 1 n-Propylbenzene ND mg/kg 07/29/16 09:19 103-65-10.0055 1 Styrene ND mg/kg 07/29/16 09:19 100-42-50.0055 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 09:19 630-20-60.0055 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 09:19 79-34-50.0055 1 Tetrachloroethene ND mg/kg 07/29/16 09:19 127-18-40.0055 1 Toluene ND mg/kg 07/29/16 09:19 108-88-30.0055 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 09:19 87-61-60.0055 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 09:19 120-82-10.0055 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 09:19 71-55-60.0055 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 09:19 79-00-50.0055 1 Trichloroethene ND mg/kg 07/29/16 09:19 79-01-60.0055 1 Trichlorofluoromethane ND mg/kg 07/29/16 09:19 75-69-40.0055 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 09:19 96-18-40.0055 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 09:19 95-63-60.0055 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 25 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-7(010012)Lab ID:50150004007 Collected:07/19/16 14:08 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 09:19 108-67-80.0055 1 Vinyl acetate ND mg/kg 07/29/16 09:19 108-05-40.11 1 Vinyl chloride ND mg/kg 07/29/16 09:19 75-01-40.0055 1 Xylene (Total)ND mg/kg 07/29/16 09:19 1330-20-70.011 1 Surrogates Dibromofluoromethane (S)105 %.07/29/16 09:19 1868-53-770-128 1 Toluene-d8 (S)101 %.07/29/16 09:19 2037-26-572-139 1 4-Bromofluorobenzene (S)96 %.07/29/16 09:19 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 8.2 %07/28/16 11:390.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 26 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-8(010012)Lab ID:50150004008 Collected:07/19/16 14:44 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 7.8 mg/kg 07/26/16 03:12 7439-92-107/23/16 11:201.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 21:29 83-32-907/21/16 10:300.0054 1 Acenaphthylene ND mg/kg 07/22/16 21:29 208-96-807/21/16 10:300.0054 1 Anthracene ND mg/kg 07/22/16 21:29 120-12-707/21/16 10:300.0054 1 Benzo(a)anthracene ND mg/kg 07/22/16 21:29 56-55-307/21/16 10:300.0054 1 Benzo(a)pyrene ND mg/kg 07/22/16 21:29 50-32-807/21/16 10:300.0054 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 21:29 205-99-207/21/16 10:300.0054 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 21:29 191-24-207/21/16 10:300.0054 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 21:29 207-08-907/21/16 10:300.0054 1 Chrysene ND mg/kg 07/22/16 21:29 218-01-907/21/16 10:300.0054 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 21:29 53-70-307/21/16 10:300.0054 1 Fluoranthene ND mg/kg 07/22/16 21:29 206-44-007/21/16 10:300.0054 1 Fluorene ND mg/kg 07/22/16 21:29 86-73-707/21/16 10:300.0054 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 21:29 193-39-507/21/16 10:300.0054 1 1-Methylnaphthalene 0.0061 mg/kg 07/22/16 21:29 90-12-0 N207/21/16 10:300.0054 1 2-Methylnaphthalene ND mg/kg 07/22/16 21:29 91-57-607/21/16 10:300.0054 1 Naphthalene ND mg/kg 07/22/16 21:29 91-20-307/21/16 10:300.0054 1 Phenanthrene ND mg/kg 07/22/16 21:29 85-01-807/21/16 10:300.0054 1 Pyrene ND mg/kg 07/22/16 21:29 129-00-007/21/16 10:300.0054 1 Surrogates 2-Fluorobiphenyl (S)72 %.07/22/16 21:29 321-60-807/21/16 10:3025-121 1 p-Terphenyl-d14 (S)80 %.07/22/16 21:29 1718-51-007/21/16 10:3027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 09:57 67-64-10.16 1 Acrolein ND mg/kg 07/29/16 09:57 107-02-80.16 1 Acrylonitrile ND mg/kg 07/29/16 09:57 107-13-10.16 1 Benzene ND mg/kg 07/29/16 09:57 71-43-20.0082 1 Bromobenzene ND mg/kg 07/29/16 09:57 108-86-10.0082 1 Bromochloromethane ND mg/kg 07/29/16 09:57 74-97-50.0082 1 Bromodichloromethane ND mg/kg 07/29/16 09:57 75-27-40.0082 1 Bromoform ND mg/kg 07/29/16 09:57 75-25-20.0082 1 Bromomethane ND mg/kg 07/29/16 09:57 74-83-90.0082 1 2-Butanone (MEK)ND mg/kg 07/29/16 09:57 78-93-30.041 1 n-Butylbenzene ND mg/kg 07/29/16 09:57 104-51-80.0082 1 sec-Butylbenzene ND mg/kg 07/29/16 09:57 135-98-80.0082 1 tert-Butylbenzene ND mg/kg 07/29/16 09:57 98-06-60.0082 1 Carbon disulfide ND mg/kg 07/29/16 09:57 75-15-00.016 1 Carbon tetrachloride ND mg/kg 07/29/16 09:57 56-23-50.0082 1 Chlorobenzene ND mg/kg 07/29/16 09:57 108-90-70.0082 1 Chloroethane ND mg/kg 07/29/16 09:57 75-00-30.0082 1 Chloroform ND mg/kg 07/29/16 09:57 67-66-30.0082 1 Chloromethane ND mg/kg 07/29/16 09:57 74-87-30.0082 1 2-Chlorotoluene ND mg/kg 07/29/16 09:57 95-49-80.0082 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 27 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-8(010012)Lab ID:50150004008 Collected:07/19/16 14:44 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 09:57 106-43-40.0082 1 Dibromochloromethane ND mg/kg 07/29/16 09:57 124-48-10.0082 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 09:57 106-93-40.0082 1 Dibromomethane ND mg/kg 07/29/16 09:57 74-95-30.0082 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 09:57 95-50-10.0082 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 09:57 541-73-10.0082 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 09:57 106-46-70.0082 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 09:57 110-57-60.16 1 Dichlorodifluoromethane ND mg/kg 07/29/16 09:57 75-71-80.0082 1 1,1-Dichloroethane ND mg/kg 07/29/16 09:57 75-34-30.0082 1 1,2-Dichloroethane ND mg/kg 07/29/16 09:57 107-06-20.0082 1 1,1-Dichloroethene ND mg/kg 07/29/16 09:57 75-35-40.0082 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 09:57 156-59-20.0082 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 09:57 156-60-50.0082 1 1,2-Dichloropropane ND mg/kg 07/29/16 09:57 78-87-50.0082 1 1,3-Dichloropropane ND mg/kg 07/29/16 09:57 142-28-90.0082 1 2,2-Dichloropropane ND mg/kg 07/29/16 09:57 594-20-70.0082 1 1,1-Dichloropropene ND mg/kg 07/29/16 09:57 563-58-60.0082 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 09:57 10061-01-50.0082 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 09:57 10061-02-60.0082 1 Ethylbenzene ND mg/kg 07/29/16 09:57 100-41-40.0082 1 Ethyl methacrylate ND mg/kg 07/29/16 09:57 97-63-20.16 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 09:57 87-68-30.0082 1 n-Hexane ND mg/kg 07/29/16 09:57 110-54-30.0082 1 2-Hexanone ND mg/kg 07/29/16 09:57 591-78-60.16 1 Iodomethane ND mg/kg 07/29/16 09:57 74-88-40.16 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 09:57 98-82-80.0082 1 p-Isopropyltoluene ND mg/kg 07/29/16 09:57 99-87-60.0082 1 Methylene Chloride ND mg/kg 07/29/16 09:57 75-09-20.033 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 09:57 108-10-10.041 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 09:57 1634-04-40.0082 1 Naphthalene ND mg/kg 07/29/16 09:57 91-20-30.0082 1 n-Propylbenzene ND mg/kg 07/29/16 09:57 103-65-10.0082 1 Styrene ND mg/kg 07/29/16 09:57 100-42-50.0082 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 09:57 630-20-60.0082 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 09:57 79-34-50.0082 1 Tetrachloroethene ND mg/kg 07/29/16 09:57 127-18-40.0082 1 Toluene ND mg/kg 07/29/16 09:57 108-88-30.0082 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 09:57 87-61-60.0082 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 09:57 120-82-10.0082 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 09:57 71-55-60.0082 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 09:57 79-00-50.0082 1 Trichloroethene ND mg/kg 07/29/16 09:57 79-01-60.0082 1 Trichlorofluoromethane ND mg/kg 07/29/16 09:57 75-69-40.0082 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 09:57 96-18-40.0082 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 09:57 95-63-60.0082 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 28 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-8(010012)Lab ID:50150004008 Collected:07/19/16 14:44 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 09:57 108-67-80.0082 1 Vinyl acetate ND mg/kg 07/29/16 09:57 108-05-40.16 1 Vinyl chloride ND mg/kg 07/29/16 09:57 75-01-40.0082 1 Xylene (Total)ND mg/kg 07/29/16 09:57 1330-20-70.016 1 Surrogates Dibromofluoromethane (S)109 %.07/29/16 09:57 1868-53-770-128 1 Toluene-d8 (S)101 %.07/29/16 09:57 2037-26-572-139 1 4-Bromofluorobenzene (S)102 %.07/29/16 09:57 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 8.1 %07/28/16 11:390.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 29 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-9(010012)Lab ID:50150004009 Collected:07/19/16 15:20 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 9.6 mg/kg 07/26/16 03:14 7439-92-107/23/16 11:201.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 21:45 83-32-907/21/16 10:300.0055 1 Acenaphthylene ND mg/kg 07/22/16 21:45 208-96-807/21/16 10:300.0055 1 Anthracene ND mg/kg 07/22/16 21:45 120-12-707/21/16 10:300.0055 1 Benzo(a)anthracene ND mg/kg 07/22/16 21:45 56-55-307/21/16 10:300.0055 1 Benzo(a)pyrene ND mg/kg 07/22/16 21:45 50-32-807/21/16 10:300.0055 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 21:45 205-99-207/21/16 10:300.0055 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 21:45 191-24-207/21/16 10:300.0055 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 21:45 207-08-907/21/16 10:300.0055 1 Chrysene ND mg/kg 07/22/16 21:45 218-01-907/21/16 10:300.0055 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 21:45 53-70-307/21/16 10:300.0055 1 Fluoranthene ND mg/kg 07/22/16 21:45 206-44-007/21/16 10:300.0055 1 Fluorene ND mg/kg 07/22/16 21:45 86-73-707/21/16 10:300.0055 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 21:45 193-39-507/21/16 10:300.0055 1 1-Methylnaphthalene ND mg/kg 07/22/16 21:45 90-12-0 N207/21/16 10:300.0055 1 2-Methylnaphthalene ND mg/kg 07/22/16 21:45 91-57-607/21/16 10:300.0055 1 Naphthalene ND mg/kg 07/22/16 21:45 91-20-307/21/16 10:300.0055 1 Phenanthrene ND mg/kg 07/22/16 21:45 85-01-807/21/16 10:300.0055 1 Pyrene ND mg/kg 07/22/16 21:45 129-00-007/21/16 10:300.0055 1 Surrogates 2-Fluorobiphenyl (S)76 %.07/22/16 21:45 321-60-807/21/16 10:3025-121 1 p-Terphenyl-d14 (S)85 %.07/22/16 21:45 1718-51-007/21/16 10:3027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 10:35 67-64-10.10 1 Acrolein ND mg/kg 07/29/16 10:35 107-02-80.10 1 Acrylonitrile ND mg/kg 07/29/16 10:35 107-13-10.10 1 Benzene ND mg/kg 07/29/16 10:35 71-43-20.0050 1 Bromobenzene ND mg/kg 07/29/16 10:35 108-86-10.0050 1 Bromochloromethane ND mg/kg 07/29/16 10:35 74-97-50.0050 1 Bromodichloromethane ND mg/kg 07/29/16 10:35 75-27-40.0050 1 Bromoform ND mg/kg 07/29/16 10:35 75-25-20.0050 1 Bromomethane ND mg/kg 07/29/16 10:35 74-83-90.0050 1 2-Butanone (MEK)ND mg/kg 07/29/16 10:35 78-93-30.025 1 n-Butylbenzene ND mg/kg 07/29/16 10:35 104-51-80.0050 1 sec-Butylbenzene ND mg/kg 07/29/16 10:35 135-98-80.0050 1 tert-Butylbenzene ND mg/kg 07/29/16 10:35 98-06-60.0050 1 Carbon disulfide ND mg/kg 07/29/16 10:35 75-15-00.010 1 Carbon tetrachloride ND mg/kg 07/29/16 10:35 56-23-50.0050 1 Chlorobenzene ND mg/kg 07/29/16 10:35 108-90-70.0050 1 Chloroethane ND mg/kg 07/29/16 10:35 75-00-30.0050 1 Chloroform ND mg/kg 07/29/16 10:35 67-66-30.0050 1 Chloromethane ND mg/kg 07/29/16 10:35 74-87-30.0050 1 2-Chlorotoluene ND mg/kg 07/29/16 10:35 95-49-80.0050 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 30 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-9(010012)Lab ID:50150004009 Collected:07/19/16 15:20 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 10:35 106-43-40.0050 1 Dibromochloromethane ND mg/kg 07/29/16 10:35 124-48-10.0050 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 10:35 106-93-40.0050 1 Dibromomethane ND mg/kg 07/29/16 10:35 74-95-30.0050 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 10:35 95-50-10.0050 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 10:35 541-73-10.0050 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 10:35 106-46-70.0050 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 10:35 110-57-60.10 1 Dichlorodifluoromethane ND mg/kg 07/29/16 10:35 75-71-80.0050 1 1,1-Dichloroethane ND mg/kg 07/29/16 10:35 75-34-30.0050 1 1,2-Dichloroethane ND mg/kg 07/29/16 10:35 107-06-20.0050 1 1,1-Dichloroethene ND mg/kg 07/29/16 10:35 75-35-40.0050 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 10:35 156-59-20.0050 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 10:35 156-60-50.0050 1 1,2-Dichloropropane ND mg/kg 07/29/16 10:35 78-87-50.0050 1 1,3-Dichloropropane ND mg/kg 07/29/16 10:35 142-28-90.0050 1 2,2-Dichloropropane ND mg/kg 07/29/16 10:35 594-20-70.0050 1 1,1-Dichloropropene ND mg/kg 07/29/16 10:35 563-58-60.0050 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 10:35 10061-01-50.0050 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 10:35 10061-02-60.0050 1 Ethylbenzene ND mg/kg 07/29/16 10:35 100-41-40.0050 1 Ethyl methacrylate ND mg/kg 07/29/16 10:35 97-63-20.10 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 10:35 87-68-30.0050 1 n-Hexane ND mg/kg 07/29/16 10:35 110-54-30.0050 1 2-Hexanone ND mg/kg 07/29/16 10:35 591-78-60.10 1 Iodomethane ND mg/kg 07/29/16 10:35 74-88-40.10 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 10:35 98-82-80.0050 1 p-Isopropyltoluene ND mg/kg 07/29/16 10:35 99-87-60.0050 1 Methylene Chloride ND mg/kg 07/29/16 10:35 75-09-20.020 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 10:35 108-10-10.025 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 10:35 1634-04-40.0050 1 Naphthalene ND mg/kg 07/29/16 10:35 91-20-30.0050 1 n-Propylbenzene ND mg/kg 07/29/16 10:35 103-65-10.0050 1 Styrene ND mg/kg 07/29/16 10:35 100-42-50.0050 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 10:35 630-20-60.0050 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 10:35 79-34-50.0050 1 Tetrachloroethene ND mg/kg 07/29/16 10:35 127-18-40.0050 1 Toluene ND mg/kg 07/29/16 10:35 108-88-30.0050 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 10:35 87-61-60.0050 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 10:35 120-82-10.0050 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 10:35 71-55-60.0050 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 10:35 79-00-50.0050 1 Trichloroethene ND mg/kg 07/29/16 10:35 79-01-60.0050 1 Trichlorofluoromethane ND mg/kg 07/29/16 10:35 75-69-40.0050 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 10:35 96-18-40.0050 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 10:35 95-63-60.0050 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 31 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-SB-9(010012)Lab ID:50150004009 Collected:07/19/16 15:20 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 10:35 108-67-80.0050 1 Vinyl acetate ND mg/kg 07/29/16 10:35 108-05-40.10 1 Vinyl chloride ND mg/kg 07/29/16 10:35 75-01-40.0050 1 Xylene (Total)ND mg/kg 07/29/16 10:35 1330-20-70.010 1 Surrogates Dibromofluoromethane (S)107 %.07/29/16 10:35 1868-53-770-128 1 Toluene-d8 (S)96 %.07/29/16 10:35 2037-26-572-139 1 4-Bromofluorobenzene (S)96 %.07/29/16 10:35 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 9.8 %07/28/16 11:390.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 32 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-FD-1 Lab ID:50150004010 Collected:07/19/16 11:00 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 3.5 mg/kg 07/26/16 03:16 7439-92-107/23/16 11:200.90 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/26/16 15:15 83-32-907/21/16 10:300.0053 1 Acenaphthylene ND mg/kg 07/26/16 15:15 208-96-807/21/16 10:300.0053 1 Anthracene ND mg/kg 07/26/16 15:15 120-12-707/21/16 10:300.0053 1 Benzo(a)anthracene ND mg/kg 07/26/16 15:15 56-55-307/21/16 10:300.0053 1 Benzo(a)pyrene ND mg/kg 07/26/16 15:15 50-32-807/21/16 10:300.0053 1 Benzo(b)fluoranthene ND mg/kg 07/26/16 15:15 205-99-207/21/16 10:300.0053 1 Benzo(g,h,i)perylene ND mg/kg 07/26/16 15:15 191-24-207/21/16 10:300.0053 1 Benzo(k)fluoranthene ND mg/kg 07/26/16 15:15 207-08-907/21/16 10:300.0053 1 Chrysene ND mg/kg 07/26/16 15:15 218-01-907/21/16 10:300.0053 1 Dibenz(a,h)anthracene ND mg/kg 07/26/16 15:15 53-70-307/21/16 10:300.0053 1 Fluoranthene ND mg/kg 07/26/16 15:15 206-44-007/21/16 10:300.0053 1 Fluorene ND mg/kg 07/26/16 15:15 86-73-707/21/16 10:300.0053 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/26/16 15:15 193-39-507/21/16 10:300.0053 1 1-Methylnaphthalene 0.012 mg/kg 07/26/16 15:15 90-12-0 N207/21/16 10:300.0053 1 2-Methylnaphthalene 0.010 mg/kg 07/26/16 15:15 91-57-607/21/16 10:300.0053 1 Naphthalene ND mg/kg 07/26/16 15:15 91-20-307/21/16 10:300.0053 1 Phenanthrene ND mg/kg 07/26/16 15:15 85-01-807/21/16 10:300.0053 1 Pyrene ND mg/kg 07/26/16 15:15 129-00-007/21/16 10:300.0053 1 Surrogates 2-Fluorobiphenyl (S)52 %.07/26/16 15:15 321-60-807/21/16 10:3025-121 1 p-Terphenyl-d14 (S)60 %.07/26/16 15:15 1718-51-007/21/16 10:3027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 11:12 67-64-10.11 1 Acrolein ND mg/kg 07/29/16 11:12 107-02-80.11 1 Acrylonitrile ND mg/kg 07/29/16 11:12 107-13-10.11 1 Benzene ND mg/kg 07/29/16 11:12 71-43-20.0054 1 Bromobenzene ND mg/kg 07/29/16 11:12 108-86-10.0054 1 Bromochloromethane ND mg/kg 07/29/16 11:12 74-97-50.0054 1 Bromodichloromethane ND mg/kg 07/29/16 11:12 75-27-40.0054 1 Bromoform ND mg/kg 07/29/16 11:12 75-25-20.0054 1 Bromomethane ND mg/kg 07/29/16 11:12 74-83-90.0054 1 2-Butanone (MEK)ND mg/kg 07/29/16 11:12 78-93-30.027 1 n-Butylbenzene ND mg/kg 07/29/16 11:12 104-51-80.0054 1 sec-Butylbenzene ND mg/kg 07/29/16 11:12 135-98-80.0054 1 tert-Butylbenzene ND mg/kg 07/29/16 11:12 98-06-60.0054 1 Carbon disulfide ND mg/kg 07/29/16 11:12 75-15-00.011 1 Carbon tetrachloride ND mg/kg 07/29/16 11:12 56-23-50.0054 1 Chlorobenzene ND mg/kg 07/29/16 11:12 108-90-70.0054 1 Chloroethane ND mg/kg 07/29/16 11:12 75-00-30.0054 1 Chloroform ND mg/kg 07/29/16 11:12 67-66-30.0054 1 Chloromethane ND mg/kg 07/29/16 11:12 74-87-30.0054 1 2-Chlorotoluene ND mg/kg 07/29/16 11:12 95-49-80.0054 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 33 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-FD-1 Lab ID:50150004010 Collected:07/19/16 11:00 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 11:12 106-43-40.0054 1 Dibromochloromethane ND mg/kg 07/29/16 11:12 124-48-10.0054 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 11:12 106-93-40.0054 1 Dibromomethane ND mg/kg 07/29/16 11:12 74-95-30.0054 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 11:12 95-50-10.0054 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 11:12 541-73-10.0054 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 11:12 106-46-70.0054 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 11:12 110-57-60.11 1 Dichlorodifluoromethane ND mg/kg 07/29/16 11:12 75-71-80.0054 1 1,1-Dichloroethane ND mg/kg 07/29/16 11:12 75-34-30.0054 1 1,2-Dichloroethane ND mg/kg 07/29/16 11:12 107-06-20.0054 1 1,1-Dichloroethene ND mg/kg 07/29/16 11:12 75-35-40.0054 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 11:12 156-59-20.0054 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 11:12 156-60-50.0054 1 1,2-Dichloropropane ND mg/kg 07/29/16 11:12 78-87-50.0054 1 1,3-Dichloropropane ND mg/kg 07/29/16 11:12 142-28-90.0054 1 2,2-Dichloropropane ND mg/kg 07/29/16 11:12 594-20-70.0054 1 1,1-Dichloropropene ND mg/kg 07/29/16 11:12 563-58-60.0054 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 11:12 10061-01-50.0054 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 11:12 10061-02-60.0054 1 Ethylbenzene ND mg/kg 07/29/16 11:12 100-41-40.0054 1 Ethyl methacrylate ND mg/kg 07/29/16 11:12 97-63-20.11 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 11:12 87-68-30.0054 1 n-Hexane ND mg/kg 07/29/16 11:12 110-54-30.0054 1 2-Hexanone ND mg/kg 07/29/16 11:12 591-78-60.11 1 Iodomethane ND mg/kg 07/29/16 11:12 74-88-40.11 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 11:12 98-82-80.0054 1 p-Isopropyltoluene ND mg/kg 07/29/16 11:12 99-87-60.0054 1 Methylene Chloride ND mg/kg 07/29/16 11:12 75-09-20.021 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 11:12 108-10-10.027 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 11:12 1634-04-40.0054 1 Naphthalene ND mg/kg 07/29/16 11:12 91-20-30.0054 1 n-Propylbenzene ND mg/kg 07/29/16 11:12 103-65-10.0054 1 Styrene ND mg/kg 07/29/16 11:12 100-42-50.0054 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 11:12 630-20-60.0054 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 11:12 79-34-50.0054 1 Tetrachloroethene ND mg/kg 07/29/16 11:12 127-18-40.0054 1 Toluene ND mg/kg 07/29/16 11:12 108-88-30.0054 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 11:12 87-61-60.0054 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 11:12 120-82-10.0054 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 11:12 71-55-60.0054 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 11:12 79-00-50.0054 1 Trichloroethene ND mg/kg 07/29/16 11:12 79-01-60.0054 1 Trichlorofluoromethane ND mg/kg 07/29/16 11:12 75-69-40.0054 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 11:12 96-18-40.0054 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 11:12 95-63-60.0054 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 34 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:WT-FD-1 Lab ID:50150004010 Collected:07/19/16 11:00 Received:07/20/16 08:50 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 11:12 108-67-80.0054 1 Vinyl acetate ND mg/kg 07/29/16 11:12 108-05-40.11 1 Vinyl chloride ND mg/kg 07/29/16 11:12 75-01-40.0054 1 Xylene (Total)ND mg/kg 07/29/16 11:12 1330-20-70.011 1 Surrogates Dibromofluoromethane (S)109 %.07/29/16 11:12 1868-53-770-128 1 Toluene-d8 (S)96 %.07/29/16 11:12 2037-26-572-139 1 4-Bromofluorobenzene (S)93 %.07/29/16 11:12 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 5.5 %07/28/16 11:390.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 35 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:TRIP BLANK Lab ID:50150004011 Collected:07/19/16 08:00 Received:07/20/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana Acetone ND ug/L 07/29/16 14:53 67-64-11001 Acrolein ND ug/L 07/29/16 14:53 107-02-850.0 1 Acrylonitrile ND ug/L 07/29/16 14:53 107-13-11001 Benzene ND ug/L 07/29/16 14:53 71-43-25.0 1 Bromobenzene ND ug/L 07/29/16 14:53 108-86-15.0 1 Bromochloromethane ND ug/L 07/29/16 14:53 74-97-55.0 1 Bromodichloromethane ND ug/L 07/29/16 14:53 75-27-45.0 1 Bromoform ND ug/L 07/29/16 14:53 75-25-25.0 1 Bromomethane ND ug/L 07/29/16 14:53 74-83-95.0 1 2-Butanone (MEK)ND ug/L 07/29/16 14:53 78-93-325.0 1 n-Butylbenzene ND ug/L 07/29/16 14:53 104-51-85.0 1 sec-Butylbenzene ND ug/L 07/29/16 14:53 135-98-85.0 1 tert-Butylbenzene ND ug/L 07/29/16 14:53 98-06-65.0 1 Carbon disulfide ND ug/L 07/29/16 14:53 75-15-010.0 1 Carbon tetrachloride ND ug/L 07/29/16 14:53 56-23-55.0 1 Chlorobenzene ND ug/L 07/29/16 14:53 108-90-75.0 1 Chloroethane ND ug/L 07/29/16 14:53 75-00-35.0 1 Chloroform ND ug/L 07/29/16 14:53 67-66-35.0 1 Chloromethane ND ug/L 07/29/16 14:53 74-87-35.0 1 2-Chlorotoluene ND ug/L 07/29/16 14:53 95-49-85.0 1 4-Chlorotoluene ND ug/L 07/29/16 14:53 106-43-45.0 1 Dibromochloromethane ND ug/L 07/29/16 14:53 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/29/16 14:53 106-93-45.0 1 Dibromomethane ND ug/L 07/29/16 14:53 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 07/29/16 14:53 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 07/29/16 14:53 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 07/29/16 14:53 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 07/29/16 14:53 110-57-61001 Dichlorodifluoromethane ND ug/L 07/29/16 14:53 75-71-85.0 1 1,1-Dichloroethane ND ug/L 07/29/16 14:53 75-34-35.0 1 1,2-Dichloroethane ND ug/L 07/29/16 14:53 107-06-25.0 1 1,1-Dichloroethene ND ug/L 07/29/16 14:53 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 07/29/16 14:53 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 07/29/16 14:53 156-60-55.0 1 1,2-Dichloropropane ND ug/L 07/29/16 14:53 78-87-55.0 1 1,3-Dichloropropane ND ug/L 07/29/16 14:53 142-28-95.0 1 2,2-Dichloropropane ND ug/L 07/29/16 14:53 594-20-75.0 1 1,1-Dichloropropene ND ug/L 07/29/16 14:53 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 07/29/16 14:53 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 07/29/16 14:53 10061-02-65.0 1 Ethylbenzene ND ug/L 07/29/16 14:53 100-41-45.0 1 Ethyl methacrylate ND ug/L 07/29/16 14:53 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 07/29/16 14:53 87-68-35.0 1 n-Hexane ND ug/L 07/29/16 14:53 110-54-35.0 1 2-Hexanone ND ug/L 07/29/16 14:53 591-78-625.0 1 Iodomethane ND ug/L 07/29/16 14:53 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 07/29/16 14:53 98-82-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 36 of 56 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Sample:TRIP BLANK Lab ID:50150004011 Collected:07/19/16 08:00 Received:07/20/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana p-Isopropyltoluene ND ug/L 07/29/16 14:53 99-87-65.0 1 Methylene Chloride ND ug/L 07/29/16 14:53 75-09-25.0 1 1-Methylnaphthalene ND ug/L 07/29/16 14:53 90-12-0 N25.0 1 2-Methylnaphthalene ND ug/L 07/29/16 14:53 91-57-610.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/29/16 14:53 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 07/29/16 14:53 1634-04-44.0 1 Naphthalene ND ug/L 07/29/16 14:53 91-20-31.7 1 n-Propylbenzene ND ug/L 07/29/16 14:53 103-65-15.0 1 Styrene ND ug/L 07/29/16 14:53 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/29/16 14:53 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/29/16 14:53 79-34-55.0 1 Tetrachloroethene ND ug/L 07/29/16 14:53 127-18-45.0 1 Toluene ND ug/L 07/29/16 14:53 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 07/29/16 14:53 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 07/29/16 14:53 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 07/29/16 14:53 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 07/29/16 14:53 79-00-55.0 1 Trichloroethene ND ug/L 07/29/16 14:53 79-01-65.0 1 Trichlorofluoromethane ND ug/L 07/29/16 14:53 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 07/29/16 14:53 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 07/29/16 14:53 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 07/29/16 14:53 108-67-85.0 1 Vinyl acetate ND ug/L 07/29/16 14:53 108-05-450.0 1 Vinyl chloride ND ug/L 07/29/16 14:53 75-01-42.0 1 Xylene (Total)ND ug/L 07/29/16 14:53 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)107 %.07/29/16 14:53 1868-53-784-118 1 4-Bromofluorobenzene (S)100 %.07/29/16 14:53 460-00-479-116 1 Toluene-d8 (S)98 %.07/29/16 14:53 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 37 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342982 EPA 3050 EPA 6010 6010 MET Associated Lab Samples:50150004001, 50150004002, 50150004003, 50150004004, 50150004005, 50150004006, 50150004007, 50150004008, 50150004009, 50150004010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1588487 Associated Lab Samples:50150004001, 50150004002, 50150004003, 50150004004, 50150004005, 50150004006, 50150004007, 50150004008, 50150004009, 50150004010 Matrix:Solid Analyzed Lead mg/kg ND 1.0 07/26/16 02:37 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1588488LABORATORY CONTROL SAMPLE: LCSSpike Lead mg/kg 50.050 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1588489MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150004004 1588490 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead mg/kg 46 114 75-12599 4 2050.29.7 62.0 59.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 38 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344427 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50150004011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1594746 Associated Lab Samples:50150004011 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 07/29/16 13:38 1,1,1-Trichloroethane ug/L ND 5.0 07/29/16 13:38 1,1,2,2-Tetrachloroethane ug/L ND 5.0 07/29/16 13:38 1,1,2-Trichloroethane ug/L ND 5.0 07/29/16 13:38 1,1-Dichloroethane ug/L ND 5.0 07/29/16 13:38 1,1-Dichloroethene ug/L ND 5.0 07/29/16 13:38 1,1-Dichloropropene ug/L ND 5.0 07/29/16 13:38 1,2,3-Trichlorobenzene ug/L ND 5.0 07/29/16 13:38 1,2,3-Trichloropropane ug/L ND 5.0 07/29/16 13:38 1,2,4-Trichlorobenzene ug/L ND 5.0 07/29/16 13:38 1,2,4-Trimethylbenzene ug/L ND 5.0 07/29/16 13:38 1,2-Dibromoethane (EDB)ug/L ND 5.0 07/29/16 13:38 1,2-Dichlorobenzene ug/L ND 5.0 07/29/16 13:38 1,2-Dichloroethane ug/L ND 5.0 07/29/16 13:38 1,2-Dichloropropane ug/L ND 5.0 07/29/16 13:38 1,3,5-Trimethylbenzene ug/L ND 5.0 07/29/16 13:38 1,3-Dichlorobenzene ug/L ND 5.0 07/29/16 13:38 1,3-Dichloropropane ug/L ND 5.0 07/29/16 13:38 1,4-Dichlorobenzene ug/L ND 5.0 07/29/16 13:38 1-Methylnaphthalene ug/L ND 5.0 N207/29/16 13:38 2,2-Dichloropropane ug/L ND 5.0 07/29/16 13:38 2-Butanone (MEK)ug/L ND 25.0 07/29/16 13:38 2-Chlorotoluene ug/L ND 5.0 07/29/16 13:38 2-Hexanone ug/L ND 25.0 07/29/16 13:38 2-Methylnaphthalene ug/L ND 10.0 07/29/16 13:38 4-Chlorotoluene ug/L ND 5.0 07/29/16 13:38 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 07/29/16 13:38 Acetone ug/L ND 100 07/29/16 13:38 Acrolein ug/L ND 50.0 07/29/16 13:38 Acrylonitrile ug/L ND 100 07/29/16 13:38 Benzene ug/L ND 5.0 07/29/16 13:38 Bromobenzene ug/L ND 5.0 07/29/16 13:38 Bromochloromethane ug/L ND 5.0 07/29/16 13:38 Bromodichloromethane ug/L ND 5.0 07/29/16 13:38 Bromoform ug/L ND 5.0 07/29/16 13:38 Bromomethane ug/L ND 5.0 07/29/16 13:38 Carbon disulfide ug/L ND 10.0 07/29/16 13:38 Carbon tetrachloride ug/L ND 5.0 07/29/16 13:38 Chlorobenzene ug/L ND 5.0 07/29/16 13:38 Chloroethane ug/L ND 5.0 07/29/16 13:38 Chloroform ug/L ND 5.0 07/29/16 13:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 39 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1594746 Associated Lab Samples:50150004011 Matrix:Water Analyzed Chloromethane ug/L ND 5.0 07/29/16 13:38 cis-1,2-Dichloroethene ug/L ND 5.0 07/29/16 13:38 cis-1,3-Dichloropropene ug/L ND 5.0 07/29/16 13:38 Dibromochloromethane ug/L ND 5.0 07/29/16 13:38 Dibromomethane ug/L ND 5.0 07/29/16 13:38 Dichlorodifluoromethane ug/L ND 5.0 07/29/16 13:38 Ethyl methacrylate ug/L ND 100 07/29/16 13:38 Ethylbenzene ug/L ND 5.0 07/29/16 13:38 Hexachloro-1,3-butadiene ug/L ND 5.0 07/29/16 13:38 Iodomethane ug/L ND 10.0 07/29/16 13:38 Isopropylbenzene (Cumene)ug/L ND 5.0 07/29/16 13:38 Methyl-tert-butyl ether ug/L ND 4.0 07/29/16 13:38 Methylene Chloride ug/L ND 5.0 07/29/16 13:38 n-Butylbenzene ug/L ND 5.0 07/29/16 13:38 n-Hexane ug/L ND 5.0 07/29/16 13:38 n-Propylbenzene ug/L ND 5.0 07/29/16 13:38 Naphthalene ug/L ND 1.7 07/29/16 13:38 p-Isopropyltoluene ug/L ND 5.0 07/29/16 13:38 sec-Butylbenzene ug/L ND 5.0 07/29/16 13:38 Styrene ug/L ND 5.0 07/29/16 13:38 tert-Butylbenzene ug/L ND 5.0 07/29/16 13:38 Tetrachloroethene ug/L ND 5.0 07/29/16 13:38 Toluene ug/L ND 5.0 07/29/16 13:38 trans-1,2-Dichloroethene ug/L ND 5.0 07/29/16 13:38 trans-1,3-Dichloropropene ug/L ND 5.0 07/29/16 13:38 trans-1,4-Dichloro-2-butene ug/L ND 100 07/29/16 13:38 Trichloroethene ug/L ND 5.0 07/29/16 13:38 Trichlorofluoromethane ug/L ND 5.0 07/29/16 13:38 Vinyl acetate ug/L ND 50.0 07/29/16 13:38 Vinyl chloride ug/L ND 2.0 07/29/16 13:38 Xylene (Total)ug/L ND 10.0 07/29/16 13:38 4-Bromofluorobenzene (S)%.100 79-116 07/29/16 13:38 Dibromofluoromethane (S)%.102 84-118 07/29/16 13:38 Toluene-d8 (S)%.100 86-110 07/29/16 13:38 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1594747LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1-Trichloroethane ug/L 48.450 97 72-123 1,1,2,2-Tetrachloroethane ug/L 46.550 93 72-124 1,1-Dichloroethene ug/L 50.850 102 69-127 1,2,4-Trimethylbenzene ug/L 46.250 92 73-125 1,2-Dichloropropane ug/L 44.050 88 77-124 Benzene ug/L 45.650 91 76-122 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 40 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1594747LABORATORY CONTROL SAMPLE: LCSSpike Chlorobenzene ug/L 45.650 91 76-118 Chloroform ug/L 43.250 86 70-119 cis-1,2-Dichloroethene ug/L 50.650 101 74-120 Ethylbenzene ug/L 46.150 92 75-123 Isopropylbenzene (Cumene)ug/L 45.350 91 84-134 Methyl-tert-butyl ether ug/L 45.050 90 65-131 Naphthalene ug/L 42.550 85 65-134 Tetrachloroethene ug/L 46.650 93 69-119 Toluene ug/L 46.450 93 74-122 trans-1,2-Dichloroethene ug/L 46.850 94 72-122 Trichloroethene ug/L 46.950 94 75-123 Vinyl chloride ug/L 52.750 105 61-147 Xylene (Total)ug/L 135150 90 75-127 4-Bromofluorobenzene (S)%.102 79-116 Dibromofluoromethane (S)%.95 84-118 Toluene-d8 (S)%.99 86-110 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 41 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344235 EPA 8260 EPA 8260 8260 MSV 5035A Volatile Organics Associated Lab Samples:50150004001, 50150004002, 50150004003, 50150004004, 50150004005, 50150004006, 50150004007, 50150004008, 50150004009, 50150004010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1593725 Associated Lab Samples:50150004001, 50150004002, 50150004003, 50150004004, 50150004005, 50150004006, 50150004007, 50150004008, 50150004009, 50150004010 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 07/29/16 01:47 1,1,1-Trichloroethane mg/kg ND 0.0050 07/29/16 01:47 1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 07/29/16 01:47 1,1,2-Trichloroethane mg/kg ND 0.0050 07/29/16 01:47 1,1-Dichloroethane mg/kg ND 0.0050 07/29/16 01:47 1,1-Dichloroethene mg/kg ND 0.0050 07/29/16 01:47 1,1-Dichloropropene mg/kg ND 0.0050 07/29/16 01:47 1,2,3-Trichlorobenzene mg/kg ND 0.0050 07/29/16 01:47 1,2,3-Trichloropropane mg/kg ND 0.0050 07/29/16 01:47 1,2,4-Trichlorobenzene mg/kg ND 0.0050 07/29/16 01:47 1,2,4-Trimethylbenzene mg/kg ND 0.0050 07/29/16 01:47 1,2-Dibromoethane (EDB)mg/kg ND 0.0050 07/29/16 01:47 1,2-Dichlorobenzene mg/kg ND 0.0050 07/29/16 01:47 1,2-Dichloroethane mg/kg ND 0.0050 07/29/16 01:47 1,2-Dichloropropane mg/kg ND 0.0050 07/29/16 01:47 1,3,5-Trimethylbenzene mg/kg ND 0.0050 07/29/16 01:47 1,3-Dichlorobenzene mg/kg ND 0.0050 07/29/16 01:47 1,3-Dichloropropane mg/kg ND 0.0050 07/29/16 01:47 1,4-Dichlorobenzene mg/kg ND 0.0050 07/29/16 01:47 2,2-Dichloropropane mg/kg ND 0.0050 07/29/16 01:47 2-Butanone (MEK)mg/kg ND 0.025 07/29/16 01:47 2-Chlorotoluene mg/kg ND 0.0050 07/29/16 01:47 2-Hexanone mg/kg ND 0.10 07/29/16 01:47 4-Chlorotoluene mg/kg ND 0.0050 07/29/16 01:47 4-Methyl-2-pentanone (MIBK)mg/kg ND 0.025 07/29/16 01:47 Acetone mg/kg ND 0.10 07/29/16 01:47 Acrolein mg/kg ND 0.10 07/29/16 01:47 Acrylonitrile mg/kg ND 0.10 07/29/16 01:47 Benzene mg/kg ND 0.0050 07/29/16 01:47 Bromobenzene mg/kg ND 0.0050 07/29/16 01:47 Bromochloromethane mg/kg ND 0.0050 07/29/16 01:47 Bromodichloromethane mg/kg ND 0.0050 07/29/16 01:47 Bromoform mg/kg ND 0.0050 07/29/16 01:47 Bromomethane mg/kg ND 0.0050 07/29/16 01:47 Carbon disulfide mg/kg ND 0.010 07/29/16 01:47 Carbon tetrachloride mg/kg ND 0.0050 07/29/16 01:47 Chlorobenzene mg/kg ND 0.0050 07/29/16 01:47 Chloroethane mg/kg ND 0.0050 07/29/16 01:47 Chloroform mg/kg ND 0.0050 07/29/16 01:47 Chloromethane mg/kg ND 0.0050 07/29/16 01:47 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 42 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1593725 Associated Lab Samples:50150004001, 50150004002, 50150004003, 50150004004, 50150004005, 50150004006, 50150004007, 50150004008, 50150004009, 50150004010 Matrix:Solid Analyzed cis-1,2-Dichloroethene mg/kg ND 0.0050 07/29/16 01:47 cis-1,3-Dichloropropene mg/kg ND 0.0050 07/29/16 01:47 Dibromochloromethane mg/kg ND 0.0050 07/29/16 01:47 Dibromomethane mg/kg ND 0.0050 07/29/16 01:47 Dichlorodifluoromethane mg/kg ND 0.0050 07/29/16 01:47 Ethyl methacrylate mg/kg ND 0.10 07/29/16 01:47 Ethylbenzene mg/kg ND 0.0050 07/29/16 01:47 Hexachloro-1,3-butadiene mg/kg ND 0.0050 07/29/16 01:47 Iodomethane mg/kg ND 0.10 07/29/16 01:47 Isopropylbenzene (Cumene)mg/kg ND 0.0050 07/29/16 01:47 Methyl-tert-butyl ether mg/kg ND 0.0050 07/29/16 01:47 Methylene Chloride mg/kg ND 0.020 07/29/16 01:47 n-Butylbenzene mg/kg ND 0.0050 07/29/16 01:47 n-Hexane mg/kg ND 0.0050 07/29/16 01:47 n-Propylbenzene mg/kg ND 0.0050 07/29/16 01:47 Naphthalene mg/kg ND 0.0050 07/29/16 01:47 p-Isopropyltoluene mg/kg ND 0.0050 07/29/16 01:47 sec-Butylbenzene mg/kg ND 0.0050 07/29/16 01:47 Styrene mg/kg ND 0.0050 07/29/16 01:47 tert-Butylbenzene mg/kg ND 0.0050 07/29/16 01:47 Tetrachloroethene mg/kg ND 0.0050 07/29/16 01:47 Toluene mg/kg ND 0.0050 07/29/16 01:47 trans-1,2-Dichloroethene mg/kg ND 0.0050 07/29/16 01:47 trans-1,3-Dichloropropene mg/kg ND 0.0050 07/29/16 01:47 trans-1,4-Dichloro-2-butene mg/kg ND 0.10 07/29/16 01:47 Trichloroethene mg/kg ND 0.0050 07/29/16 01:47 Trichlorofluoromethane mg/kg ND 0.0050 07/29/16 01:47 Vinyl acetate mg/kg ND 0.10 07/29/16 01:47 Vinyl chloride mg/kg ND 0.0050 07/29/16 01:47 Xylene (Total)mg/kg ND 0.010 07/29/16 01:47 4-Bromofluorobenzene (S)%.99 65-127 07/29/16 01:47 Dibromofluoromethane (S)%.113 70-128 07/29/16 01:47 Toluene-d8 (S)%.98 72-139 07/29/16 01:47 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1593726LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1-Trichloroethane mg/kg 0.056.05 112 67-123 1,1,2,2-Tetrachloroethane mg/kg 0.048.05 96 67-129 1,1-Dichloroethene mg/kg 0.056.05 113 64-133 1,2,4-Trimethylbenzene mg/kg 0.046.05 93 66-118 1,2-Dichloropropane mg/kg 0.053.05 105 74-119 Benzene mg/kg 0.051.05 102 72-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 43 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1593726LABORATORY CONTROL SAMPLE: LCSSpike Chlorobenzene mg/kg 0.050.05 99 72-115 Chloroform mg/kg 0.050.05 99 66-116 cis-1,2-Dichloroethene mg/kg 0.053.05 106 74-115 Ethylbenzene mg/kg 0.049.05 99 70-121 Isopropylbenzene (Cumene)mg/kg 0.047.05 95 78-130 Methyl-tert-butyl ether mg/kg 0.052.05 105 68-123 Naphthalene mg/kg 0.046.05 91 63-125 Tetrachloroethene mg/kg 0.049.05 99 66-118 Toluene mg/kg 0.048.05 96 68-121 trans-1,2-Dichloroethene mg/kg 0.055.05 110 71-120 Trichloroethene mg/kg 0.052.05 105 73-120 Vinyl chloride mg/kg 0.052.05 104 54-155 Xylene (Total)mg/kg 0.14.15 94 69-122 4-Bromofluorobenzene (S)%.101 65-127 Dibromofluoromethane (S)%.105 70-128 Toluene-d8 (S)%.101 72-139 Parameter Units MS Result % Rec Limits Qual% RecConc. 1593727MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150004004 1593728 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1-Trichloroethane mg/kg .054 109 37-144112 3 20.054ND 0.058 0.060 1,1,2,2-Tetrachloroethane mg/kg .054 97 12-17491 6 20.054ND 0.052 0.049 1,1-Dichloroethene mg/kg .054 108 36-162115 7 20.054ND 0.058 0.062 1,2,4-Trimethylbenzene mg/kg .054 90 10-15788 2 20.054ND 0.048 0.047 1,2-Dichloropropane mg/kg .054 100 43-138102 2 20.054ND 0.053 0.054 Benzene mg/kg .054 97 36-14499 2 20.054ND 0.052 0.053 Chlorobenzene mg/kg .054 96 16-14099 3 20.054ND 0.051 0.053 Chloroform mg/kg .054 96 39-13698 3 20.054ND 0.051 0.052 cis-1,2-Dichloroethene mg/kg .054 102 34-143104 2 20.054ND 0.054 0.055 Ethylbenzene mg/kg .054 94 15-14793 1 20.054ND 0.050 0.050 Isopropylbenzene (Cumene)mg/kg .054 91 10-16395 4 20.054ND 0.049 0.051 Methyl-tert-butyl ether mg/kg .054 102 48-145102 1 20.054ND 0.055 0.054 Naphthalene mg/kg .054 80 10-13273 9 20.054ND 0.044 0.040 Tetrachloroethene mg/kg .054 96 14-15694 1 20.054ND 0.051 0.050 Toluene mg/kg .054 93 24-15189 4 20.054ND 0.050 0.048 trans-1,2-Dichloroethene mg/kg .054 105 33-147109 4 20.054ND 0.056 0.058 Trichloroethene mg/kg .054 96 21-164101 5 20.054ND 0.051 0.054 Vinyl chloride mg/kg .054 101 32-177104 3 20.054ND 0.054 0.056 Xylene (Total)mg/kg .16 92 12-14893 1 20.16ND 0.15 0.15 4-Bromofluorobenzene (S)%.95 65-127100 Dibromofluoromethane (S)%.100 70-128104 Toluene-d8 (S)%.97 72-139102 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 44 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342949 EPA 3546 EPA 8270 by SIM 8270 MSSV PAH by SIM Associated Lab Samples:50150004001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1588418 Associated Lab Samples:50150004001 Matrix:Solid Analyzed 1-Methylnaphthalene mg/kg ND 0.0050 N207/21/16 11:35 2-Methylnaphthalene mg/kg ND 0.0050 07/21/16 11:35 Acenaphthene mg/kg ND 0.0050 07/21/16 11:35 Acenaphthylene mg/kg ND 0.0050 07/21/16 11:35 Anthracene mg/kg ND 0.0050 07/21/16 11:35 Benzo(a)anthracene mg/kg ND 0.0050 07/21/16 11:35 Benzo(a)pyrene mg/kg ND 0.0050 07/21/16 11:35 Benzo(b)fluoranthene mg/kg ND 0.0050 07/21/16 11:35 Benzo(g,h,i)perylene mg/kg ND 0.0050 07/21/16 11:35 Benzo(k)fluoranthene mg/kg ND 0.0050 07/21/16 11:35 Chrysene mg/kg ND 0.0050 07/21/16 11:35 Dibenz(a,h)anthracene mg/kg ND 0.0050 07/21/16 11:35 Fluoranthene mg/kg ND 0.0050 07/21/16 11:35 Fluorene mg/kg ND 0.0050 07/21/16 11:35 Indeno(1,2,3-cd)pyrene mg/kg ND 0.0050 07/21/16 11:35 Naphthalene mg/kg ND 0.0050 07/21/16 11:35 Phenanthrene mg/kg ND 0.0050 07/21/16 11:35 Pyrene mg/kg ND 0.0050 07/21/16 11:35 2-Fluorobiphenyl (S)%.67 25-121 07/21/16 11:35 p-Terphenyl-d14 (S)%.76 27-124 07/21/16 11:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1588419LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene mg/kg 0.25 N2.33 75 41-109 2-Methylnaphthalene mg/kg 0.25.33 76 39-109 Acenaphthene mg/kg 0.26.33 78 44-127 Acenaphthylene mg/kg 0.26.33 77 43-128 Anthracene mg/kg 0.27.33 82 49-131 Benzo(a)anthracene mg/kg 0.30.33 90 52-128 Benzo(a)pyrene mg/kg 0.25.33 76 54-141 Benzo(b)fluoranthene mg/kg 0.26.33 77 50-146 Benzo(g,h,i)perylene mg/kg 0.25.33 74 51-141 Benzo(k)fluoranthene mg/kg 0.25.33 74 55-139 Chrysene mg/kg 0.29.33 87 56-131 Dibenz(a,h)anthracene mg/kg 0.25.33 74 53-142 Fluoranthene mg/kg 0.29.33 87 51-139 Fluorene mg/kg 0.27.33 81 45-131 Indeno(1,2,3-cd)pyrene mg/kg 0.25.33 75 51-141 Naphthalene mg/kg 0.24.33 72 43-112 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 45 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1588419LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene mg/kg 0.28.33 84 47-132 Pyrene mg/kg 0.29.33 86 55-130 2-Fluorobiphenyl (S)%.68 25-121 p-Terphenyl-d14 (S)%.75 27-124 Parameter Units MS Result % Rec Limits Qual% RecConc. 1588420MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150019008 1588421 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene mg/kg N2.4 34 17-11835 3 20.4ND 0.14 0.14 2-Methylnaphthalene mg/kg .4 36 15-11837 2 20.4ND 0.15 0.15 Acenaphthene mg/kg .4 33 21-12534 4 20.4ND 0.13 0.14 Acenaphthylene mg/kg .4 32 21-12633 4 20.4ND 0.13 0.14 Anthracene mg/kg .4 34 15-13436 4 20.4ND 0.14 0.14 Benzo(a)anthracene mg/kg .4 37 14-12938 4 20.4ND 0.15 0.15 Benzo(a)pyrene mg/kg .4 30 10-14631 4 20.4ND 0.12 0.13 Benzo(b)fluoranthene mg/kg .4 30 10-14632 5 20.4ND 0.12 0.13 Benzo(g,h,i)perylene mg/kg .4 30 10-14231 4 20.4ND 0.12 0.13 Benzo(k)fluoranthene mg/kg .4 31 10-14732 4 20.4ND 0.12 0.13 Chrysene mg/kg .4 36 11-14038 5 20.4ND 0.15 0.15 Dibenz(a,h)anthracene mg/kg .4 30 16-13631 3 20.4ND 0.12 0.13 Fluoranthene mg/kg .4 36 10-14638 3 20.4ND 0.15 0.15 Fluorene mg/kg .4 34 20-13136 5 20.4ND 0.14 0.15 Indeno(1,2,3-cd)pyrene mg/kg .4 30 10-14631 5 20.4ND 0.12 0.13 Naphthalene mg/kg .4 33 15-12634 4 20.4ND 0.13 0.14 Phenanthrene mg/kg .4 35 10-14836 4 20.4ND 0.14 0.15 Pyrene mg/kg .4 36 14-13638 5 20.4ND 0.15 0.15 2-Fluorobiphenyl (S)%.29 25-12130 p-Terphenyl-d14 (S)%.31 27-12432 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 46 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343000 EPA 3546 EPA 8270 by SIM 8270 MSSV PAH by SIM Associated Lab Samples:50150004002, 50150004003, 50150004004, 50150004005, 50150004006, 50150004007, 50150004008, 50150004009, 50150004010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1588524 Associated Lab Samples:50150004002, 50150004003, 50150004004, 50150004005, 50150004006, 50150004007, 50150004008, 50150004009, 50150004010 Matrix:Solid Analyzed 1-Methylnaphthalene mg/kg ND 0.0050 N207/22/16 18:44 2-Methylnaphthalene mg/kg ND 0.0050 07/22/16 18:44 Acenaphthene mg/kg ND 0.0050 07/22/16 18:44 Acenaphthylene mg/kg ND 0.0050 07/22/16 18:44 Anthracene mg/kg ND 0.0050 07/22/16 18:44 Benzo(a)anthracene mg/kg ND 0.0050 07/22/16 18:44 Benzo(a)pyrene mg/kg ND 0.0050 07/22/16 18:44 Benzo(b)fluoranthene mg/kg ND 0.0050 07/22/16 18:44 Benzo(g,h,i)perylene mg/kg ND 0.0050 07/22/16 18:44 Benzo(k)fluoranthene mg/kg ND 0.0050 07/22/16 18:44 Chrysene mg/kg ND 0.0050 07/22/16 18:44 Dibenz(a,h)anthracene mg/kg ND 0.0050 07/22/16 18:44 Fluoranthene mg/kg ND 0.0050 07/22/16 18:44 Fluorene mg/kg ND 0.0050 07/22/16 18:44 Indeno(1,2,3-cd)pyrene mg/kg ND 0.0050 07/22/16 18:44 Naphthalene mg/kg ND 0.0050 07/22/16 18:44 Phenanthrene mg/kg ND 0.0050 07/22/16 18:44 Pyrene mg/kg ND 0.0050 07/22/16 18:44 2-Fluorobiphenyl (S)%.76 25-121 07/22/16 18:44 p-Terphenyl-d14 (S)%.87 27-124 07/22/16 18:44 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1588525LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene mg/kg 0.27 N2.33 80 41-109 2-Methylnaphthalene mg/kg 0.27.33 81 39-109 Acenaphthene mg/kg 0.28.33 83 44-127 Acenaphthylene mg/kg 0.27.33 82 43-128 Anthracene mg/kg 0.30.33 90 49-131 Benzo(a)anthracene mg/kg 0.33.33 98 52-128 Benzo(a)pyrene mg/kg 0.29.33 86 54-141 Benzo(b)fluoranthene mg/kg 0.28.33 84 50-146 Benzo(g,h,i)perylene mg/kg 0.28.33 85 51-141 Benzo(k)fluoranthene mg/kg 0.29.33 88 55-139 Chrysene mg/kg 0.32.33 96 56-131 Dibenz(a,h)anthracene mg/kg 0.28.33 85 53-142 Fluoranthene mg/kg 0.32.33 95 51-139 Fluorene mg/kg 0.29.33 87 45-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 47 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1588525LABORATORY CONTROL SAMPLE: LCSSpike Indeno(1,2,3-cd)pyrene mg/kg 0.29.33 86 51-141 Naphthalene mg/kg 0.25.33 76 43-112 Phenanthrene mg/kg 0.30.33 91 47-132 Pyrene mg/kg 0.32.33 95 55-130 2-Fluorobiphenyl (S)%.74 25-121 p-Terphenyl-d14 (S)%.83 27-124 Parameter Units MS Result % Rec Limits Qual% RecConc. 1588526MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150004004 1588527 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene mg/kg N2.35 77 17-11886 12 20.35ND 0.27 0.30 2-Methylnaphthalene mg/kg .35 77 15-11887 12 20.35ND 0.27 0.31 Acenaphthene mg/kg .35 80 21-12589 11 20.35ND 0.28 0.31 Acenaphthylene mg/kg .35 79 21-12687 10 20.35ND 0.28 0.31 Anthracene mg/kg .35 83 15-13493 11 20.35ND 0.29 0.33 Benzo(a)anthracene mg/kg .35 90 14-129100 10 20.35ND 0.32 0.35 Benzo(a)pyrene mg/kg .35 80 10-14687 9 20.35ND 0.28 0.31 Benzo(b)fluoranthene mg/kg .35 79 10-14686 8 20.35ND 0.28 0.30 Benzo(g,h,i)perylene mg/kg .35 79 10-14287 10 20.35ND 0.28 0.31 Benzo(k)fluoranthene mg/kg .35 80 10-14790 12 20.35ND 0.28 0.32 Chrysene mg/kg .35 89 11-14098 10 20.35ND 0.31 0.34 Dibenz(a,h)anthracene mg/kg .35 78 16-13686 11 20.35ND 0.27 0.31 Fluoranthene mg/kg .35 87 10-14697 12 20.35ND 0.31 0.34 Fluorene mg/kg .35 83 20-13193 12 20.35ND 0.29 0.33 Indeno(1,2,3-cd)pyrene mg/kg .35 79 10-14687 10 20.35ND 0.28 0.31 Naphthalene mg/kg .35 72 15-12681 13 20.35ND 0.25 0.29 Phenanthrene mg/kg .35 83 10-14893 11 20.35ND 0.29 0.33 Pyrene mg/kg .35 87 14-13696 11 20.35ND 0.31 0.34 2-Fluorobiphenyl (S)%.69 25-12177 p-Terphenyl-d14 (S)%.75 27-12482 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 48 of 56 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343973 SM 2540G SM 2540G Dry Weight/Percent Moisture Associated Lab Samples:50150004001, 50150004002, 50150004003, 50150004004, 50150004005, 50150004006, 50150004007, 50150004008, 50150004009, 50150004010 Parameter Units Dup Result Max RPD QualifiersRPDResult 50149955007 1592555SAMPLE DUPLICATE: Percent Moisture %14.4 2 514.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 50150004004 1592556SAMPLE DUPLICATE: Percent Moisture %6.6 1 56.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 49 of 56 #=QL# QUALIFIERS Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - IndianapolisPASI-I ANALYTE QUALIFIERS Due to the extract's physical characteristics, the analysis was performed at dilution.ED The lab does not hold TNI accreditation for this parameter.N2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 50 of 56 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 50150004 204 Roosevelt Road (Walkerton) Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 50150004001 342982 343678WT-SB-1(008010)EPA 3050 EPA 6010 50150004002 342982 343678WT-SB-2(012014)EPA 3050 EPA 6010 50150004003 342982 343678WT-SB-3(012014)EPA 3050 EPA 6010 50150004004 342982 343678WT-SB-4(014016)EPA 3050 EPA 6010 50150004005 342982 343678WT-SB-5(014016)EPA 3050 EPA 6010 50150004006 342982 343678WT-SB-6(010012)EPA 3050 EPA 6010 50150004007 342982 343678WT-SB-7(010012)EPA 3050 EPA 6010 50150004008 342982 343678WT-SB-8(010012)EPA 3050 EPA 6010 50150004009 342982 343678WT-SB-9(010012)EPA 3050 EPA 6010 50150004010 342982 343678WT-FD-1 EPA 3050 EPA 6010 50150004001 342949 342984WT-SB-1(008010)EPA 3546 EPA 8270 by SIM 50150004002 343000 343353WT-SB-2(012014)EPA 3546 EPA 8270 by SIM 50150004003 343000 343353WT-SB-3(012014)EPA 3546 EPA 8270 by SIM 50150004004 343000 343353WT-SB-4(014016)EPA 3546 EPA 8270 by SIM 50150004005 343000 343353WT-SB-5(014016)EPA 3546 EPA 8270 by SIM 50150004006 343000 343353WT-SB-6(010012)EPA 3546 EPA 8270 by SIM 50150004007 343000 343353WT-SB-7(010012)EPA 3546 EPA 8270 by SIM 50150004008 343000 343353WT-SB-8(010012)EPA 3546 EPA 8270 by SIM 50150004009 343000 343353WT-SB-9(010012)EPA 3546 EPA 8270 by SIM 50150004010 343000 343353WT-FD-1 EPA 3546 EPA 8270 by SIM 50150004011 344427TRIP BLANK EPA 8260 50150004001 344235WT-SB-1(008010)EPA 8260 50150004002 344235WT-SB-2(012014)EPA 8260 50150004003 344235WT-SB-3(012014)EPA 8260 50150004004 344235WT-SB-4(014016)EPA 8260 50150004005 344235WT-SB-5(014016)EPA 8260 50150004006 344235WT-SB-6(010012)EPA 8260 50150004007 344235WT-SB-7(010012)EPA 8260 50150004008 344235WT-SB-8(010012)EPA 8260 50150004009 344235WT-SB-9(010012)EPA 8260 50150004010 344235WT-FD-1 EPA 8260 50150004001 343973WT-SB-1(008010)SM 2540G 50150004002 343973WT-SB-2(012014)SM 2540G 50150004003 343973WT-SB-3(012014)SM 2540G 50150004004 343973WT-SB-4(014016)SM 2540G 50150004005 343973WT-SB-5(014016)SM 2540G 50150004006 343973WT-SB-6(010012)SM 2540G 50150004007 343973WT-SB-7(010012)SM 2540G 50150004008 343973WT-SB-8(010012)SM 2540G 50150004009 343973WT-SB-9(010012)SM 2540G 50150004010 343973WT-FD-1 SM 2540G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:13 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 51 of 56 Page 52 of 56 Page 53 of 56 Page 54 of 56 Page 55 of 56 Page 56 of 56 #=CL# August 02, 2016 LIMS USE: FR - GREG WAGGLE LIMS OBJECT ID: 50150127 50150127 Project: Pace Project No.: RE: Mr. Greg Waggle Symbiont 6737 W. Washington St. Suite 3440 Milwaukee, WI 53214 204 Roosevelt Road (Walkerton) Dear Mr. Waggle: Enclosed are the analytical results for sample(s) received by the laboratory on July 21, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Mick Mayse mick.mayse@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 1 of 31 #=CP# CERTIFICATIONS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Indiana Certification IDs 7726 Moller Road, Indianapolis, IN 46268 Illinois Certification #: 200074 Indiana Certification #: C-49-06 Kansas/NELAP Certification #:E-10177 Kentucky UST Certification #: 0042 Kentucky WW Certification #:98019 Ohio VAP Certification #: CL-0065 Oklahoma Certification #: 2014-148 Texas Certification #: T104704355-15-9 West Virginia Certification #: 330 Wisconsin Certification #: 999788130 USDA Soil Permit #: P330-10-00128 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 2 of 31 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Lab ID Sample ID Matrix Date Collected Date Received 50150127001 WT-SB-10(012014)Solid 07/20/16 08:45 07/21/16 08:35 50150127002 WT-SB-11(012014)Solid 07/20/16 09:18 07/21/16 08:35 50150127003 WT-SB-12(010012)Solid 07/20/16 09:43 07/21/16 08:35 50150127004 WT-SB-13(010012)Solid 07/20/16 10:15 07/21/16 08:35 50150127005 WT-SB-14(010012)Solid 07/20/16 10:50 07/21/16 08:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 3 of 31 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 50150127001 WT-SB-10(012014)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 72 PASI-IJLZ SM 2540G 1 PASI-IWDB 50150127002 WT-SB-11(012014)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 72 PASI-IJLZ SM 2540G 1 PASI-IWDB 50150127003 WT-SB-12(010012)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 72 PASI-IJLZ SM 2540G 1 PASI-IWDB 50150127004 WT-SB-13(010012)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 72 PASI-IJLZ SM 2540G 1 PASI-IWDB 50150127005 WT-SB-14(010012)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 72 PASI-IJLZ SM 2540G 1 PASI-IWDB REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 4 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-10(012014)Lab ID:50150127001 Collected:07/20/16 08:45 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 6.6 mg/kg 07/28/16 22:30 7439-92-107/27/16 07:401.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 16:30 83-32-907/21/16 11:450.0063 1 Acenaphthylene ND mg/kg 07/22/16 16:30 208-96-807/21/16 11:450.0063 1 Anthracene ND mg/kg 07/22/16 16:30 120-12-707/21/16 11:450.0063 1 Benzo(a)anthracene ND mg/kg 07/22/16 16:30 56-55-307/21/16 11:450.0063 1 Benzo(a)pyrene ND mg/kg 07/22/16 16:30 50-32-807/21/16 11:450.0063 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 16:30 205-99-207/21/16 11:450.0063 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 16:30 191-24-207/21/16 11:450.0063 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 16:30 207-08-907/21/16 11:450.0063 1 Chrysene ND mg/kg 07/22/16 16:30 218-01-907/21/16 11:450.0063 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 16:30 53-70-307/21/16 11:450.0063 1 Fluoranthene ND mg/kg 07/22/16 16:30 206-44-007/21/16 11:450.0063 1 Fluorene ND mg/kg 07/22/16 16:30 86-73-707/21/16 11:450.0063 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 16:30 193-39-507/21/16 11:450.0063 1 1-Methylnaphthalene ND mg/kg 07/22/16 16:30 90-12-0 N207/21/16 11:450.0063 1 2-Methylnaphthalene ND mg/kg 07/22/16 16:30 91-57-607/21/16 11:450.0063 1 Naphthalene ND mg/kg 07/22/16 16:30 91-20-307/21/16 11:450.0063 1 Phenanthrene ND mg/kg 07/22/16 16:30 85-01-807/21/16 11:450.0063 1 Pyrene ND mg/kg 07/22/16 16:30 129-00-007/21/16 11:450.0063 1 Surrogates 2-Fluorobiphenyl (S)69 %.07/22/16 16:30 321-60-807/21/16 11:4525-121 1 p-Terphenyl-d14 (S)71 %.07/22/16 16:30 1718-51-007/21/16 11:4527-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 20:30 67-64-10.13 1 Acrolein ND mg/kg 07/29/16 20:30 107-02-80.13 1 Acrylonitrile ND mg/kg 07/29/16 20:30 107-13-10.13 1 Benzene ND mg/kg 07/29/16 20:30 71-43-20.0066 1 Bromobenzene ND mg/kg 07/29/16 20:30 108-86-10.0066 1 Bromochloromethane ND mg/kg 07/29/16 20:30 74-97-50.0066 1 Bromodichloromethane ND mg/kg 07/29/16 20:30 75-27-40.0066 1 Bromoform ND mg/kg 07/29/16 20:30 75-25-20.0066 1 Bromomethane ND mg/kg 07/29/16 20:30 74-83-90.0066 1 2-Butanone (MEK)ND mg/kg 07/29/16 20:30 78-93-30.033 1 n-Butylbenzene ND mg/kg 07/29/16 20:30 104-51-80.0066 1 sec-Butylbenzene ND mg/kg 07/29/16 20:30 135-98-80.0066 1 tert-Butylbenzene ND mg/kg 07/29/16 20:30 98-06-60.0066 1 Carbon disulfide ND mg/kg 07/29/16 20:30 75-15-00.013 1 Carbon tetrachloride ND mg/kg 07/29/16 20:30 56-23-50.0066 1 Chlorobenzene ND mg/kg 07/29/16 20:30 108-90-70.0066 1 Chloroethane ND mg/kg 07/29/16 20:30 75-00-30.0066 1 Chloroform ND mg/kg 07/29/16 20:30 67-66-30.0066 1 Chloromethane ND mg/kg 07/29/16 20:30 74-87-30.0066 1 2-Chlorotoluene ND mg/kg 07/29/16 20:30 95-49-80.0066 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 5 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-10(012014)Lab ID:50150127001 Collected:07/20/16 08:45 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 20:30 106-43-40.0066 1 Dibromochloromethane ND mg/kg 07/29/16 20:30 124-48-10.0066 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 20:30 106-93-40.0066 1 Dibromomethane ND mg/kg 07/29/16 20:30 74-95-30.0066 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 20:30 95-50-10.0066 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 20:30 541-73-10.0066 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 20:30 106-46-70.0066 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 20:30 110-57-60.13 1 Dichlorodifluoromethane ND mg/kg 07/29/16 20:30 75-71-80.0066 1 1,1-Dichloroethane ND mg/kg 07/29/16 20:30 75-34-30.0066 1 1,2-Dichloroethane ND mg/kg 07/29/16 20:30 107-06-20.0066 1 1,1-Dichloroethene ND mg/kg 07/29/16 20:30 75-35-40.0066 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 20:30 156-59-20.0066 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 20:30 156-60-50.0066 1 1,2-Dichloropropane ND mg/kg 07/29/16 20:30 78-87-50.0066 1 1,3-Dichloropropane ND mg/kg 07/29/16 20:30 142-28-90.0066 1 2,2-Dichloropropane ND mg/kg 07/29/16 20:30 594-20-70.0066 1 1,1-Dichloropropene ND mg/kg 07/29/16 20:30 563-58-60.0066 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 20:30 10061-01-50.0066 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 20:30 10061-02-60.0066 1 Ethylbenzene ND mg/kg 07/29/16 20:30 100-41-40.0066 1 Ethyl methacrylate ND mg/kg 07/29/16 20:30 97-63-20.13 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 20:30 87-68-30.0066 1 n-Hexane ND mg/kg 07/29/16 20:30 110-54-30.0066 1 2-Hexanone ND mg/kg 07/29/16 20:30 591-78-60.13 1 Iodomethane ND mg/kg 07/29/16 20:30 74-88-40.13 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 20:30 98-82-80.0066 1 p-Isopropyltoluene ND mg/kg 07/29/16 20:30 99-87-60.0066 1 Methylene Chloride ND mg/kg 07/29/16 20:30 75-09-20.026 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 20:30 108-10-10.033 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 20:30 1634-04-40.0066 1 n-Propylbenzene ND mg/kg 07/29/16 20:30 103-65-10.0066 1 Styrene ND mg/kg 07/29/16 20:30 100-42-50.0066 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 20:30 630-20-60.0066 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 20:30 79-34-50.0066 1 Tetrachloroethene ND mg/kg 07/29/16 20:30 127-18-40.0066 1 Toluene ND mg/kg 07/29/16 20:30 108-88-30.0066 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 20:30 87-61-60.0066 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 20:30 120-82-10.0066 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 20:30 71-55-60.0066 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 20:30 79-00-50.0066 1 Trichloroethene ND mg/kg 07/29/16 20:30 79-01-60.0066 1 Trichlorofluoromethane ND mg/kg 07/29/16 20:30 75-69-40.0066 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 20:30 96-18-40.0066 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 20:30 95-63-60.0066 1 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 20:30 108-67-80.0066 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 6 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-10(012014)Lab ID:50150127001 Collected:07/20/16 08:45 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA Vinyl acetate ND mg/kg 07/29/16 20:30 108-05-40.13 1 Vinyl chloride ND mg/kg 07/29/16 20:30 75-01-40.0066 1 Xylene (Total)ND mg/kg 07/29/16 20:30 1330-20-70.013 1 Surrogates Dibromofluoromethane (S)90 %.07/29/16 20:30 1868-53-770-128 1 Toluene-d8 (S)100 %.07/29/16 20:30 2037-26-572-139 1 4-Bromofluorobenzene (S)97 %.07/29/16 20:30 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 21.2 %07/28/16 13:580.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 7 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-11(012014)Lab ID:50150127002 Collected:07/20/16 09:18 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 5.9 mg/kg 07/28/16 22:36 7439-92-107/27/16 07:401.2 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 16:47 83-32-907/21/16 11:450.0065 1 Acenaphthylene ND mg/kg 07/22/16 16:47 208-96-807/21/16 11:450.0065 1 Anthracene ND mg/kg 07/22/16 16:47 120-12-707/21/16 11:450.0065 1 Benzo(a)anthracene ND mg/kg 07/22/16 16:47 56-55-307/21/16 11:450.0065 1 Benzo(a)pyrene ND mg/kg 07/22/16 16:47 50-32-807/21/16 11:450.0065 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 16:47 205-99-207/21/16 11:450.0065 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 16:47 191-24-207/21/16 11:450.0065 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 16:47 207-08-907/21/16 11:450.0065 1 Chrysene ND mg/kg 07/22/16 16:47 218-01-907/21/16 11:450.0065 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 16:47 53-70-307/21/16 11:450.0065 1 Fluoranthene ND mg/kg 07/22/16 16:47 206-44-007/21/16 11:450.0065 1 Fluorene ND mg/kg 07/22/16 16:47 86-73-707/21/16 11:450.0065 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 16:47 193-39-507/21/16 11:450.0065 1 1-Methylnaphthalene ND mg/kg 07/22/16 16:47 90-12-0 N207/21/16 11:450.0065 1 2-Methylnaphthalene ND mg/kg 07/22/16 16:47 91-57-607/21/16 11:450.0065 1 Naphthalene ND mg/kg 07/22/16 16:47 91-20-307/21/16 11:450.0065 1 Phenanthrene ND mg/kg 07/22/16 16:47 85-01-807/21/16 11:450.0065 1 Pyrene ND mg/kg 07/22/16 16:47 129-00-007/21/16 11:450.0065 1 Surrogates 2-Fluorobiphenyl (S)77 %.07/22/16 16:47 321-60-807/21/16 11:4525-121 1 p-Terphenyl-d14 (S)66 %.07/22/16 16:47 1718-51-007/21/16 11:4527-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 21:02 67-64-10.094 1 Acrolein ND mg/kg 07/29/16 21:02 107-02-80.094 1 Acrylonitrile ND mg/kg 07/29/16 21:02 107-13-10.094 1 Benzene ND mg/kg 07/29/16 21:02 71-43-20.0047 1 Bromobenzene ND mg/kg 07/29/16 21:02 108-86-10.0047 1 Bromochloromethane ND mg/kg 07/29/16 21:02 74-97-50.0047 1 Bromodichloromethane ND mg/kg 07/29/16 21:02 75-27-40.0047 1 Bromoform ND mg/kg 07/29/16 21:02 75-25-20.0047 1 Bromomethane ND mg/kg 07/29/16 21:02 74-83-90.0047 1 2-Butanone (MEK)ND mg/kg 07/29/16 21:02 78-93-30.024 1 n-Butylbenzene ND mg/kg 07/29/16 21:02 104-51-80.0047 1 sec-Butylbenzene ND mg/kg 07/29/16 21:02 135-98-80.0047 1 tert-Butylbenzene ND mg/kg 07/29/16 21:02 98-06-60.0047 1 Carbon disulfide ND mg/kg 07/29/16 21:02 75-15-00.0094 1 Carbon tetrachloride ND mg/kg 07/29/16 21:02 56-23-50.0047 1 Chlorobenzene ND mg/kg 07/29/16 21:02 108-90-70.0047 1 Chloroethane ND mg/kg 07/29/16 21:02 75-00-30.0047 1 Chloroform ND mg/kg 07/29/16 21:02 67-66-30.0047 1 Chloromethane ND mg/kg 07/29/16 21:02 74-87-30.0047 1 2-Chlorotoluene ND mg/kg 07/29/16 21:02 95-49-80.0047 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 8 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-11(012014)Lab ID:50150127002 Collected:07/20/16 09:18 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 21:02 106-43-40.0047 1 Dibromochloromethane ND mg/kg 07/29/16 21:02 124-48-10.0047 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 21:02 106-93-40.0047 1 Dibromomethane ND mg/kg 07/29/16 21:02 74-95-30.0047 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 21:02 95-50-10.0047 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 21:02 541-73-10.0047 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 21:02 106-46-70.0047 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 21:02 110-57-60.094 1 Dichlorodifluoromethane ND mg/kg 07/29/16 21:02 75-71-80.0047 1 1,1-Dichloroethane ND mg/kg 07/29/16 21:02 75-34-30.0047 1 1,2-Dichloroethane ND mg/kg 07/29/16 21:02 107-06-20.0047 1 1,1-Dichloroethene ND mg/kg 07/29/16 21:02 75-35-40.0047 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 21:02 156-59-20.0047 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 21:02 156-60-50.0047 1 1,2-Dichloropropane ND mg/kg 07/29/16 21:02 78-87-50.0047 1 1,3-Dichloropropane ND mg/kg 07/29/16 21:02 142-28-90.0047 1 2,2-Dichloropropane ND mg/kg 07/29/16 21:02 594-20-70.0047 1 1,1-Dichloropropene ND mg/kg 07/29/16 21:02 563-58-60.0047 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 21:02 10061-01-50.0047 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 21:02 10061-02-60.0047 1 Ethylbenzene ND mg/kg 07/29/16 21:02 100-41-40.0047 1 Ethyl methacrylate ND mg/kg 07/29/16 21:02 97-63-20.094 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 21:02 87-68-30.0047 1 n-Hexane ND mg/kg 07/29/16 21:02 110-54-30.0047 1 2-Hexanone ND mg/kg 07/29/16 21:02 591-78-60.094 1 Iodomethane ND mg/kg 07/29/16 21:02 74-88-40.094 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 21:02 98-82-80.0047 1 p-Isopropyltoluene ND mg/kg 07/29/16 21:02 99-87-60.0047 1 Methylene Chloride ND mg/kg 07/29/16 21:02 75-09-20.019 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 21:02 108-10-10.024 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 21:02 1634-04-40.0047 1 n-Propylbenzene ND mg/kg 07/29/16 21:02 103-65-10.0047 1 Styrene ND mg/kg 07/29/16 21:02 100-42-50.0047 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 21:02 630-20-60.0047 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 21:02 79-34-50.0047 1 Tetrachloroethene ND mg/kg 07/29/16 21:02 127-18-40.0047 1 Toluene ND mg/kg 07/29/16 21:02 108-88-30.0047 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 21:02 87-61-60.0047 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 21:02 120-82-10.0047 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 21:02 71-55-60.0047 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 21:02 79-00-50.0047 1 Trichloroethene ND mg/kg 07/29/16 21:02 79-01-60.0047 1 Trichlorofluoromethane ND mg/kg 07/29/16 21:02 75-69-40.0047 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 21:02 96-18-40.0047 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 21:02 95-63-60.0047 1 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 21:02 108-67-80.0047 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 9 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-11(012014)Lab ID:50150127002 Collected:07/20/16 09:18 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA Vinyl acetate ND mg/kg 07/29/16 21:02 108-05-40.094 1 Vinyl chloride ND mg/kg 07/29/16 21:02 75-01-40.0047 1 Xylene (Total)ND mg/kg 07/29/16 21:02 1330-20-70.0094 1 Surrogates Dibromofluoromethane (S)117 %.07/29/16 21:02 1868-53-770-128 1 Toluene-d8 (S)95 %.07/29/16 21:02 2037-26-572-139 1 4-Bromofluorobenzene (S)108 %.07/29/16 21:02 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 23.1 %07/28/16 13:580.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 10 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-12(010012)Lab ID:50150127003 Collected:07/20/16 09:43 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 4.5 mg/kg 07/28/16 22:38 7439-92-107/27/16 07:401.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 17:04 83-32-907/21/16 11:450.0060 1 Acenaphthylene ND mg/kg 07/22/16 17:04 208-96-807/21/16 11:450.0060 1 Anthracene ND mg/kg 07/22/16 17:04 120-12-707/21/16 11:450.0060 1 Benzo(a)anthracene ND mg/kg 07/22/16 17:04 56-55-307/21/16 11:450.0060 1 Benzo(a)pyrene ND mg/kg 07/22/16 17:04 50-32-807/21/16 11:450.0060 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 17:04 205-99-207/21/16 11:450.0060 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 17:04 191-24-207/21/16 11:450.0060 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 17:04 207-08-907/21/16 11:450.0060 1 Chrysene ND mg/kg 07/22/16 17:04 218-01-907/21/16 11:450.0060 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 17:04 53-70-307/21/16 11:450.0060 1 Fluoranthene ND mg/kg 07/22/16 17:04 206-44-007/21/16 11:450.0060 1 Fluorene ND mg/kg 07/22/16 17:04 86-73-707/21/16 11:450.0060 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 17:04 193-39-507/21/16 11:450.0060 1 1-Methylnaphthalene ND mg/kg 07/22/16 17:04 90-12-0 N207/21/16 11:450.0060 1 2-Methylnaphthalene ND mg/kg 07/22/16 17:04 91-57-607/21/16 11:450.0060 1 Naphthalene ND mg/kg 07/22/16 17:04 91-20-307/21/16 11:450.0060 1 Phenanthrene ND mg/kg 07/22/16 17:04 85-01-807/21/16 11:450.0060 1 Pyrene ND mg/kg 07/22/16 17:04 129-00-007/21/16 11:450.0060 1 Surrogates 2-Fluorobiphenyl (S)78 %.07/22/16 17:04 321-60-807/21/16 11:4525-121 1 p-Terphenyl-d14 (S)74 %.07/22/16 17:04 1718-51-007/21/16 11:4527-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 21:34 67-64-10.12 1 Acrolein ND mg/kg 07/29/16 21:34 107-02-80.12 1 Acrylonitrile ND mg/kg 07/29/16 21:34 107-13-10.12 1 Benzene ND mg/kg 07/29/16 21:34 71-43-20.0059 1 Bromobenzene ND mg/kg 07/29/16 21:34 108-86-10.0059 1 Bromochloromethane ND mg/kg 07/29/16 21:34 74-97-50.0059 1 Bromodichloromethane ND mg/kg 07/29/16 21:34 75-27-40.0059 1 Bromoform ND mg/kg 07/29/16 21:34 75-25-20.0059 1 Bromomethane ND mg/kg 07/29/16 21:34 74-83-90.0059 1 2-Butanone (MEK)ND mg/kg 07/29/16 21:34 78-93-30.029 1 n-Butylbenzene ND mg/kg 07/29/16 21:34 104-51-80.0059 1 sec-Butylbenzene ND mg/kg 07/29/16 21:34 135-98-80.0059 1 tert-Butylbenzene ND mg/kg 07/29/16 21:34 98-06-60.0059 1 Carbon disulfide ND mg/kg 07/29/16 21:34 75-15-00.012 1 Carbon tetrachloride ND mg/kg 07/29/16 21:34 56-23-50.0059 1 Chlorobenzene ND mg/kg 07/29/16 21:34 108-90-70.0059 1 Chloroethane ND mg/kg 07/29/16 21:34 75-00-30.0059 1 Chloroform ND mg/kg 07/29/16 21:34 67-66-30.0059 1 Chloromethane ND mg/kg 07/29/16 21:34 74-87-30.0059 1 2-Chlorotoluene ND mg/kg 07/29/16 21:34 95-49-80.0059 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 11 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-12(010012)Lab ID:50150127003 Collected:07/20/16 09:43 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 21:34 106-43-40.0059 1 Dibromochloromethane ND mg/kg 07/29/16 21:34 124-48-10.0059 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 21:34 106-93-40.0059 1 Dibromomethane ND mg/kg 07/29/16 21:34 74-95-30.0059 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 21:34 95-50-10.0059 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 21:34 541-73-10.0059 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 21:34 106-46-70.0059 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 21:34 110-57-60.12 1 Dichlorodifluoromethane ND mg/kg 07/29/16 21:34 75-71-80.0059 1 1,1-Dichloroethane ND mg/kg 07/29/16 21:34 75-34-30.0059 1 1,2-Dichloroethane ND mg/kg 07/29/16 21:34 107-06-20.0059 1 1,1-Dichloroethene ND mg/kg 07/29/16 21:34 75-35-40.0059 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 21:34 156-59-20.0059 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 21:34 156-60-50.0059 1 1,2-Dichloropropane ND mg/kg 07/29/16 21:34 78-87-50.0059 1 1,3-Dichloropropane ND mg/kg 07/29/16 21:34 142-28-90.0059 1 2,2-Dichloropropane ND mg/kg 07/29/16 21:34 594-20-70.0059 1 1,1-Dichloropropene ND mg/kg 07/29/16 21:34 563-58-60.0059 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 21:34 10061-01-50.0059 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 21:34 10061-02-60.0059 1 Ethylbenzene ND mg/kg 07/29/16 21:34 100-41-40.0059 1 Ethyl methacrylate ND mg/kg 07/29/16 21:34 97-63-20.12 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 21:34 87-68-30.0059 1 n-Hexane ND mg/kg 07/29/16 21:34 110-54-30.0059 1 2-Hexanone ND mg/kg 07/29/16 21:34 591-78-60.12 1 Iodomethane ND mg/kg 07/29/16 21:34 74-88-40.12 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 21:34 98-82-80.0059 1 p-Isopropyltoluene ND mg/kg 07/29/16 21:34 99-87-60.0059 1 Methylene Chloride ND mg/kg 07/29/16 21:34 75-09-20.024 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 21:34 108-10-10.029 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 21:34 1634-04-40.0059 1 n-Propylbenzene ND mg/kg 07/29/16 21:34 103-65-10.0059 1 Styrene ND mg/kg 07/29/16 21:34 100-42-50.0059 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 21:34 630-20-60.0059 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 21:34 79-34-50.0059 1 Tetrachloroethene ND mg/kg 07/29/16 21:34 127-18-40.0059 1 Toluene ND mg/kg 07/29/16 21:34 108-88-30.0059 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 21:34 87-61-60.0059 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 21:34 120-82-10.0059 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 21:34 71-55-60.0059 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 21:34 79-00-50.0059 1 Trichloroethene ND mg/kg 07/29/16 21:34 79-01-60.0059 1 Trichlorofluoromethane ND mg/kg 07/29/16 21:34 75-69-40.0059 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 21:34 96-18-40.0059 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 21:34 95-63-60.0059 1 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 21:34 108-67-80.0059 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 12 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-12(010012)Lab ID:50150127003 Collected:07/20/16 09:43 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA Vinyl acetate ND mg/kg 07/29/16 21:34 108-05-40.12 1 Vinyl chloride ND mg/kg 07/29/16 21:34 75-01-40.0059 1 Xylene (Total)ND mg/kg 07/29/16 21:34 1330-20-70.012 1 Surrogates Dibromofluoromethane (S)95 %.07/29/16 21:34 1868-53-770-128 1 Toluene-d8 (S)97 %.07/29/16 21:34 2037-26-572-139 1 4-Bromofluorobenzene (S)94 %.07/29/16 21:34 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 17.9 %07/28/16 13:590.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 13 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-13(010012)Lab ID:50150127004 Collected:07/20/16 10:15 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 4.9 mg/kg 07/28/16 22:49 7439-92-107/27/16 07:400.90 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 17:22 83-32-907/21/16 11:450.0053 1 Acenaphthylene ND mg/kg 07/22/16 17:22 208-96-807/21/16 11:450.0053 1 Anthracene ND mg/kg 07/22/16 17:22 120-12-707/21/16 11:450.0053 1 Benzo(a)anthracene ND mg/kg 07/22/16 17:22 56-55-307/21/16 11:450.0053 1 Benzo(a)pyrene ND mg/kg 07/22/16 17:22 50-32-807/21/16 11:450.0053 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 17:22 205-99-207/21/16 11:450.0053 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 17:22 191-24-207/21/16 11:450.0053 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 17:22 207-08-907/21/16 11:450.0053 1 Chrysene ND mg/kg 07/22/16 17:22 218-01-907/21/16 11:450.0053 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 17:22 53-70-307/21/16 11:450.0053 1 Fluoranthene ND mg/kg 07/22/16 17:22 206-44-007/21/16 11:450.0053 1 Fluorene ND mg/kg 07/22/16 17:22 86-73-707/21/16 11:450.0053 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 17:22 193-39-507/21/16 11:450.0053 1 1-Methylnaphthalene ND mg/kg 07/22/16 17:22 90-12-0 N207/21/16 11:450.0053 1 2-Methylnaphthalene ND mg/kg 07/22/16 17:22 91-57-607/21/16 11:450.0053 1 Naphthalene ND mg/kg 07/22/16 17:22 91-20-307/21/16 11:450.0053 1 Phenanthrene ND mg/kg 07/22/16 17:22 85-01-807/21/16 11:450.0053 1 Pyrene ND mg/kg 07/22/16 17:22 129-00-007/21/16 11:450.0053 1 Surrogates 2-Fluorobiphenyl (S)79 %.07/22/16 17:22 321-60-807/21/16 11:4525-121 1 p-Terphenyl-d14 (S)80 %.07/22/16 17:22 1718-51-007/21/16 11:4527-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 22:06 67-64-10.14 1 Acrolein ND mg/kg 07/29/16 22:06 107-02-80.14 1 Acrylonitrile ND mg/kg 07/29/16 22:06 107-13-10.14 1 Benzene ND mg/kg 07/29/16 22:06 71-43-20.0069 1 Bromobenzene ND mg/kg 07/29/16 22:06 108-86-10.0069 1 Bromochloromethane ND mg/kg 07/29/16 22:06 74-97-50.0069 1 Bromodichloromethane ND mg/kg 07/29/16 22:06 75-27-40.0069 1 Bromoform ND mg/kg 07/29/16 22:06 75-25-20.0069 1 Bromomethane ND mg/kg 07/29/16 22:06 74-83-90.0069 1 2-Butanone (MEK)ND mg/kg 07/29/16 22:06 78-93-30.034 1 n-Butylbenzene ND mg/kg 07/29/16 22:06 104-51-80.0069 1 sec-Butylbenzene ND mg/kg 07/29/16 22:06 135-98-80.0069 1 tert-Butylbenzene ND mg/kg 07/29/16 22:06 98-06-60.0069 1 Carbon disulfide ND mg/kg 07/29/16 22:06 75-15-00.014 1 Carbon tetrachloride ND mg/kg 07/29/16 22:06 56-23-50.0069 1 Chlorobenzene ND mg/kg 07/29/16 22:06 108-90-70.0069 1 Chloroethane ND mg/kg 07/29/16 22:06 75-00-30.0069 1 Chloroform ND mg/kg 07/29/16 22:06 67-66-30.0069 1 Chloromethane ND mg/kg 07/29/16 22:06 74-87-30.0069 1 2-Chlorotoluene ND mg/kg 07/29/16 22:06 95-49-80.0069 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 14 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-13(010012)Lab ID:50150127004 Collected:07/20/16 10:15 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 22:06 106-43-40.0069 1 Dibromochloromethane ND mg/kg 07/29/16 22:06 124-48-10.0069 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 22:06 106-93-40.0069 1 Dibromomethane ND mg/kg 07/29/16 22:06 74-95-30.0069 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 22:06 95-50-10.0069 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 22:06 541-73-10.0069 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 22:06 106-46-70.0069 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 22:06 110-57-60.14 1 Dichlorodifluoromethane ND mg/kg 07/29/16 22:06 75-71-80.0069 1 1,1-Dichloroethane ND mg/kg 07/29/16 22:06 75-34-30.0069 1 1,2-Dichloroethane ND mg/kg 07/29/16 22:06 107-06-20.0069 1 1,1-Dichloroethene ND mg/kg 07/29/16 22:06 75-35-40.0069 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 22:06 156-59-20.0069 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 22:06 156-60-50.0069 1 1,2-Dichloropropane ND mg/kg 07/29/16 22:06 78-87-50.0069 1 1,3-Dichloropropane ND mg/kg 07/29/16 22:06 142-28-90.0069 1 2,2-Dichloropropane ND mg/kg 07/29/16 22:06 594-20-70.0069 1 1,1-Dichloropropene ND mg/kg 07/29/16 22:06 563-58-60.0069 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 22:06 10061-01-50.0069 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 22:06 10061-02-60.0069 1 Ethylbenzene ND mg/kg 07/29/16 22:06 100-41-40.0069 1 Ethyl methacrylate ND mg/kg 07/29/16 22:06 97-63-20.14 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 22:06 87-68-30.0069 1 n-Hexane ND mg/kg 07/29/16 22:06 110-54-30.0069 1 2-Hexanone ND mg/kg 07/29/16 22:06 591-78-60.14 1 Iodomethane ND mg/kg 07/29/16 22:06 74-88-40.14 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 22:06 98-82-80.0069 1 p-Isopropyltoluene ND mg/kg 07/29/16 22:06 99-87-60.0069 1 Methylene Chloride ND mg/kg 07/29/16 22:06 75-09-20.027 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 22:06 108-10-10.034 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 22:06 1634-04-40.0069 1 n-Propylbenzene ND mg/kg 07/29/16 22:06 103-65-10.0069 1 Styrene ND mg/kg 07/29/16 22:06 100-42-50.0069 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 22:06 630-20-60.0069 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 22:06 79-34-50.0069 1 Tetrachloroethene ND mg/kg 07/29/16 22:06 127-18-40.0069 1 Toluene ND mg/kg 07/29/16 22:06 108-88-30.0069 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 22:06 87-61-60.0069 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 22:06 120-82-10.0069 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 22:06 71-55-60.0069 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 22:06 79-00-50.0069 1 Trichloroethene ND mg/kg 07/29/16 22:06 79-01-60.0069 1 Trichlorofluoromethane ND mg/kg 07/29/16 22:06 75-69-40.0069 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 22:06 96-18-40.0069 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 22:06 95-63-60.0069 1 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 22:06 108-67-80.0069 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 15 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-13(010012)Lab ID:50150127004 Collected:07/20/16 10:15 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA Vinyl acetate ND mg/kg 07/29/16 22:06 108-05-40.14 1 Vinyl chloride ND mg/kg 07/29/16 22:06 75-01-40.0069 1 Xylene (Total)ND mg/kg 07/29/16 22:06 1330-20-70.014 1 Surrogates Dibromofluoromethane (S)93 %.07/29/16 22:06 1868-53-770-128 1 Toluene-d8 (S)100 %.07/29/16 22:06 2037-26-572-139 1 4-Bromofluorobenzene (S)93 %.07/29/16 22:06 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 6.6 %07/28/16 13:590.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 16 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-14(010012)Lab ID:50150127005 Collected:07/20/16 10:50 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 7.6 mg/kg 07/28/16 22:51 7439-92-107/27/16 07:401.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/22/16 17:39 83-32-907/21/16 11:450.0053 1 Acenaphthylene ND mg/kg 07/22/16 17:39 208-96-807/21/16 11:450.0053 1 Anthracene ND mg/kg 07/22/16 17:39 120-12-707/21/16 11:450.0053 1 Benzo(a)anthracene ND mg/kg 07/22/16 17:39 56-55-307/21/16 11:450.0053 1 Benzo(a)pyrene ND mg/kg 07/22/16 17:39 50-32-807/21/16 11:450.0053 1 Benzo(b)fluoranthene ND mg/kg 07/22/16 17:39 205-99-207/21/16 11:450.0053 1 Benzo(g,h,i)perylene ND mg/kg 07/22/16 17:39 191-24-207/21/16 11:450.0053 1 Benzo(k)fluoranthene ND mg/kg 07/22/16 17:39 207-08-907/21/16 11:450.0053 1 Chrysene ND mg/kg 07/22/16 17:39 218-01-907/21/16 11:450.0053 1 Dibenz(a,h)anthracene ND mg/kg 07/22/16 17:39 53-70-307/21/16 11:450.0053 1 Fluoranthene ND mg/kg 07/22/16 17:39 206-44-007/21/16 11:450.0053 1 Fluorene ND mg/kg 07/22/16 17:39 86-73-707/21/16 11:450.0053 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/22/16 17:39 193-39-507/21/16 11:450.0053 1 1-Methylnaphthalene 0.021 mg/kg 07/22/16 17:39 90-12-0 N207/21/16 11:450.0053 1 2-Methylnaphthalene 0.051 mg/kg 07/22/16 17:39 91-57-607/21/16 11:450.0053 1 Naphthalene 0.020 mg/kg 07/22/16 17:39 91-20-307/21/16 11:450.0053 1 Phenanthrene ND mg/kg 07/22/16 17:39 85-01-807/21/16 11:450.0053 1 Pyrene ND mg/kg 07/22/16 17:39 129-00-007/21/16 11:450.0053 1 Surrogates 2-Fluorobiphenyl (S)79 %.07/22/16 17:39 321-60-807/21/16 11:4525-121 1 p-Terphenyl-d14 (S)81 %.07/22/16 17:39 1718-51-007/21/16 11:4527-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 22:39 67-64-10.10 1 Acrolein ND mg/kg 07/29/16 22:39 107-02-80.10 1 Acrylonitrile ND mg/kg 07/29/16 22:39 107-13-10.10 1 Benzene ND mg/kg 07/29/16 22:39 71-43-20.0050 1 Bromobenzene ND mg/kg 07/29/16 22:39 108-86-10.0050 1 Bromochloromethane ND mg/kg 07/29/16 22:39 74-97-50.0050 1 Bromodichloromethane ND mg/kg 07/29/16 22:39 75-27-40.0050 1 Bromoform ND mg/kg 07/29/16 22:39 75-25-20.0050 1 Bromomethane ND mg/kg 07/29/16 22:39 74-83-90.0050 1 2-Butanone (MEK)ND mg/kg 07/29/16 22:39 78-93-30.025 1 n-Butylbenzene ND mg/kg 07/29/16 22:39 104-51-80.0050 1 sec-Butylbenzene ND mg/kg 07/29/16 22:39 135-98-80.0050 1 tert-Butylbenzene ND mg/kg 07/29/16 22:39 98-06-60.0050 1 Carbon disulfide ND mg/kg 07/29/16 22:39 75-15-00.010 1 Carbon tetrachloride ND mg/kg 07/29/16 22:39 56-23-50.0050 1 Chlorobenzene ND mg/kg 07/29/16 22:39 108-90-70.0050 1 Chloroethane ND mg/kg 07/29/16 22:39 75-00-30.0050 1 Chloroform ND mg/kg 07/29/16 22:39 67-66-30.0050 1 Chloromethane ND mg/kg 07/29/16 22:39 74-87-30.0050 1 2-Chlorotoluene ND mg/kg 07/29/16 22:39 95-49-80.0050 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 17 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-14(010012)Lab ID:50150127005 Collected:07/20/16 10:50 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 22:39 106-43-40.0050 1 Dibromochloromethane ND mg/kg 07/29/16 22:39 124-48-10.0050 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 22:39 106-93-40.0050 1 Dibromomethane ND mg/kg 07/29/16 22:39 74-95-30.0050 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 22:39 95-50-10.0050 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 22:39 541-73-10.0050 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 22:39 106-46-70.0050 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 22:39 110-57-60.10 1 Dichlorodifluoromethane ND mg/kg 07/29/16 22:39 75-71-80.0050 1 1,1-Dichloroethane ND mg/kg 07/29/16 22:39 75-34-30.0050 1 1,2-Dichloroethane ND mg/kg 07/29/16 22:39 107-06-20.0050 1 1,1-Dichloroethene ND mg/kg 07/29/16 22:39 75-35-40.0050 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 22:39 156-59-20.0050 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 22:39 156-60-50.0050 1 1,2-Dichloropropane ND mg/kg 07/29/16 22:39 78-87-50.0050 1 1,3-Dichloropropane ND mg/kg 07/29/16 22:39 142-28-90.0050 1 2,2-Dichloropropane ND mg/kg 07/29/16 22:39 594-20-70.0050 1 1,1-Dichloropropene ND mg/kg 07/29/16 22:39 563-58-60.0050 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 22:39 10061-01-50.0050 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 22:39 10061-02-60.0050 1 Ethylbenzene ND mg/kg 07/29/16 22:39 100-41-40.0050 1 Ethyl methacrylate ND mg/kg 07/29/16 22:39 97-63-20.10 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 22:39 87-68-30.0050 1 n-Hexane ND mg/kg 07/29/16 22:39 110-54-30.0050 1 2-Hexanone ND mg/kg 07/29/16 22:39 591-78-60.10 1 Iodomethane ND mg/kg 07/29/16 22:39 74-88-40.10 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 22:39 98-82-80.0050 1 p-Isopropyltoluene ND mg/kg 07/29/16 22:39 99-87-60.0050 1 Methylene Chloride ND mg/kg 07/29/16 22:39 75-09-20.020 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 22:39 108-10-10.025 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 22:39 1634-04-40.0050 1 n-Propylbenzene ND mg/kg 07/29/16 22:39 103-65-10.0050 1 Styrene ND mg/kg 07/29/16 22:39 100-42-50.0050 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 22:39 630-20-60.0050 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 22:39 79-34-50.0050 1 Tetrachloroethene ND mg/kg 07/29/16 22:39 127-18-40.0050 1 Toluene ND mg/kg 07/29/16 22:39 108-88-30.0050 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 22:39 87-61-60.0050 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 22:39 120-82-10.0050 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 22:39 71-55-60.0050 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 22:39 79-00-50.0050 1 Trichloroethene ND mg/kg 07/29/16 22:39 79-01-60.0050 1 Trichlorofluoromethane ND mg/kg 07/29/16 22:39 75-69-40.0050 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 22:39 96-18-40.0050 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 22:39 95-63-60.0050 1 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 22:39 108-67-80.0050 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 18 of 31 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Sample:WT-SB-14(010012)Lab ID:50150127005 Collected:07/20/16 10:50 Received:07/21/16 08:35 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA Vinyl acetate ND mg/kg 07/29/16 22:39 108-05-40.10 1 Vinyl chloride ND mg/kg 07/29/16 22:39 75-01-40.0050 1 Xylene (Total)ND mg/kg 07/29/16 22:39 1330-20-70.010 1 Surrogates Dibromofluoromethane (S)94 %.07/29/16 22:39 1868-53-770-128 1 Toluene-d8 (S)98 %.07/29/16 22:39 2037-26-572-139 1 4-Bromofluorobenzene (S)92 %.07/29/16 22:39 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 6.5 %07/28/16 13:590.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 19 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343461 EPA 3050 EPA 6010 6010 MET Associated Lab Samples:50150127001, 50150127002, 50150127003, 50150127004, 50150127005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1590903 Associated Lab Samples:50150127001, 50150127002, 50150127003, 50150127004, 50150127005 Matrix:Solid Analyzed Lead mg/kg ND 1.0 07/28/16 22:23 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1590904LABORATORY CONTROL SAMPLE: LCSSpike Lead mg/kg 50.050 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1590905MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150127003 1590906 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead mg/kg 59.5 94 75-12593 6 2056.14.5 60.4 56.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 20 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344475 EPA 8260 EPA 8260 8260 MSV 5035A Volatile Organics Associated Lab Samples:50150127001, 50150127002, 50150127003, 50150127004, 50150127005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1594999 Associated Lab Samples:50150127001, 50150127002, 50150127003, 50150127004, 50150127005 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 07/29/16 15:07 1,1,1-Trichloroethane mg/kg ND 0.0050 07/29/16 15:07 1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 07/29/16 15:07 1,1,2-Trichloroethane mg/kg ND 0.0050 07/29/16 15:07 1,1-Dichloroethane mg/kg ND 0.0050 07/29/16 15:07 1,1-Dichloroethene mg/kg ND 0.0050 07/29/16 15:07 1,1-Dichloropropene mg/kg ND 0.0050 07/29/16 15:07 1,2,3-Trichlorobenzene mg/kg ND 0.0050 07/29/16 15:07 1,2,3-Trichloropropane mg/kg ND 0.0050 07/29/16 15:07 1,2,4-Trichlorobenzene mg/kg ND 0.0050 07/29/16 15:07 1,2,4-Trimethylbenzene mg/kg ND 0.0050 07/29/16 15:07 1,2-Dibromoethane (EDB)mg/kg ND 0.0050 07/29/16 15:07 1,2-Dichlorobenzene mg/kg ND 0.0050 07/29/16 15:07 1,2-Dichloroethane mg/kg ND 0.0050 07/29/16 15:07 1,2-Dichloropropane mg/kg ND 0.0050 07/29/16 15:07 1,3,5-Trimethylbenzene mg/kg ND 0.0050 07/29/16 15:07 1,3-Dichlorobenzene mg/kg ND 0.0050 07/29/16 15:07 1,3-Dichloropropane mg/kg ND 0.0050 07/29/16 15:07 1,4-Dichlorobenzene mg/kg ND 0.0050 07/29/16 15:07 2,2-Dichloropropane mg/kg ND 0.0050 07/29/16 15:07 2-Butanone (MEK)mg/kg ND 0.025 07/29/16 15:07 2-Chlorotoluene mg/kg ND 0.0050 07/29/16 15:07 2-Hexanone mg/kg ND 0.10 07/29/16 15:07 4-Chlorotoluene mg/kg ND 0.0050 07/29/16 15:07 4-Methyl-2-pentanone (MIBK)mg/kg ND 0.025 07/29/16 15:07 Acetone mg/kg ND 0.10 07/29/16 15:07 Acrolein mg/kg ND 0.10 07/29/16 15:07 Acrylonitrile mg/kg ND 0.10 07/29/16 15:07 Benzene mg/kg ND 0.0050 07/29/16 15:07 Bromobenzene mg/kg ND 0.0050 07/29/16 15:07 Bromochloromethane mg/kg ND 0.0050 07/29/16 15:07 Bromodichloromethane mg/kg ND 0.0050 07/29/16 15:07 Bromoform mg/kg ND 0.0050 07/29/16 15:07 Bromomethane mg/kg ND 0.0050 07/29/16 15:07 Carbon disulfide mg/kg ND 0.010 07/29/16 15:07 Carbon tetrachloride mg/kg ND 0.0050 07/29/16 15:07 Chlorobenzene mg/kg ND 0.0050 07/29/16 15:07 Chloroethane mg/kg ND 0.0050 07/29/16 15:07 Chloroform mg/kg ND 0.0050 07/29/16 15:07 Chloromethane mg/kg ND 0.0050 07/29/16 15:07 cis-1,2-Dichloroethene mg/kg ND 0.0050 07/29/16 15:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 21 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1594999 Associated Lab Samples:50150127001, 50150127002, 50150127003, 50150127004, 50150127005 Matrix:Solid Analyzed cis-1,3-Dichloropropene mg/kg ND 0.0050 07/29/16 15:07 Dibromochloromethane mg/kg ND 0.0050 07/29/16 15:07 Dibromomethane mg/kg ND 0.0050 07/29/16 15:07 Dichlorodifluoromethane mg/kg ND 0.0050 07/29/16 15:07 Ethyl methacrylate mg/kg ND 0.10 07/29/16 15:07 Ethylbenzene mg/kg ND 0.0050 07/29/16 15:07 Hexachloro-1,3-butadiene mg/kg ND 0.0050 07/29/16 15:07 Iodomethane mg/kg ND 0.10 07/29/16 15:07 Isopropylbenzene (Cumene)mg/kg ND 0.0050 07/29/16 15:07 Methyl-tert-butyl ether mg/kg ND 0.0050 07/29/16 15:07 Methylene Chloride mg/kg ND 0.020 07/29/16 15:07 n-Butylbenzene mg/kg ND 0.0050 07/29/16 15:07 n-Hexane mg/kg ND 0.0050 07/29/16 15:07 n-Propylbenzene mg/kg ND 0.0050 07/29/16 15:07 p-Isopropyltoluene mg/kg ND 0.0050 07/29/16 15:07 sec-Butylbenzene mg/kg ND 0.0050 07/29/16 15:07 Styrene mg/kg ND 0.0050 07/29/16 15:07 tert-Butylbenzene mg/kg ND 0.0050 07/29/16 15:07 Tetrachloroethene mg/kg ND 0.0050 07/29/16 15:07 Toluene mg/kg ND 0.0050 07/29/16 15:07 trans-1,2-Dichloroethene mg/kg ND 0.0050 07/29/16 15:07 trans-1,3-Dichloropropene mg/kg ND 0.0050 07/29/16 15:07 trans-1,4-Dichloro-2-butene mg/kg ND 0.10 07/29/16 15:07 Trichloroethene mg/kg ND 0.0050 07/29/16 15:07 Trichlorofluoromethane mg/kg ND 0.0050 07/29/16 15:07 Vinyl acetate mg/kg ND 0.10 07/29/16 15:07 Vinyl chloride mg/kg ND 0.0050 07/29/16 15:07 Xylene (Total)mg/kg ND 0.010 07/29/16 15:07 4-Bromofluorobenzene (S)%.93 65-127 07/29/16 15:07 Dibromofluoromethane (S)%.94 70-128 07/29/16 15:07 Toluene-d8 (S)%.100 72-139 07/29/16 15:07 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595000LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1-Trichloroethane mg/kg 0.051.05 101 67-123 1,1,2,2-Tetrachloroethane mg/kg 0.062.05 124 67-129 1,1-Dichloroethene mg/kg 0.056.05 113 64-133 1,2,4-Trimethylbenzene mg/kg 0.058.05 116 66-118 1,2-Dichloropropane mg/kg 0.058.05 115 74-119 Benzene mg/kg 0.058.05 116 72-120 Chlorobenzene mg/kg 0.057.05 114 72-115 Chloroform mg/kg 0.047.05 94 66-116 cis-1,2-Dichloroethene mg/kg 0.057.05 113 74-115 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 22 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595000LABORATORY CONTROL SAMPLE: LCSSpike Ethylbenzene mg/kg 0.060.05 120 70-121 Isopropylbenzene (Cumene)mg/kg 0.062.05 124 78-130 Methyl-tert-butyl ether mg/kg 0.051.05 102 68-123 Tetrachloroethene mg/kg 0.056.05 113 66-118 Toluene mg/kg 0.051.05 101 68-121 trans-1,2-Dichloroethene mg/kg 0.058.05 117 71-120 Trichloroethene mg/kg 0.054.05 108 73-120 Vinyl chloride mg/kg 0.048.05 97 54-155 Xylene (Total)mg/kg 0.18.15 121 69-122 4-Bromofluorobenzene (S)%.99 65-127 Dibromofluoromethane (S)%.93 70-128 Toluene-d8 (S)%.102 72-139 Parameter Units MS Result % Rec Limits Qual% RecConc. 1595001MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150137004 1595002 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1-Trichloroethane mg/kg .052 101 37-144111 9 20.052ND 0.057 0.062 1,1,2,2-Tetrachloroethane mg/kg .052 113 12-174114 1 20.052ND 0.059 0.059 1,1-Dichloroethene mg/kg .052 113 36-162127 12 20.052ND 0.058 0.066 1,2,4-Trimethylbenzene mg/kg .052 111 10-157104 6 20.052ND 0.058 0.055 1,2-Dichloropropane mg/kg .052 110 43-138119 8 20.052ND 0.057 0.062 Benzene mg/kg .052 116 36-144122 5 20.052ND 0.060 0.063 Chlorobenzene mg/kg .052 108 16-140103 5 20.052ND 0.056 0.053 Chloroform mg/kg .052 93 39-13698 5 20.052ND 0.048 0.051 cis-1,2-Dichloroethene mg/kg .052 112 34-143121 7 20.052ND 0.062 0.067 Ethylbenzene mg/kg .052 116 15-147114 2 20.052ND 0.060 0.059 Isopropylbenzene (Cumene)mg/kg .052 112 10-163110 1 20.052ND 0.058 0.057 Methyl-tert-butyl ether mg/kg .052 101 48-145111 10 20.052ND 0.052 0.058 Tetrachloroethene mg/kg .052 116 14-156112 3 20.0527.2 ug/kg 0.067 0.065 Toluene mg/kg .052 101 24-151102 0 20.052ND 0.053 0.053 trans-1,2-Dichloroethene mg/kg .052 121 33-147125 3 20.052ND 0.063 0.065 Vinyl chloride mg/kg .052 101 32-177105 3 20.052ND 0.052 0.054 Xylene (Total)mg/kg .16 113 12-148111 2 20.16ND 0.18 0.17 4-Bromofluorobenzene (S)%.95 65-12794 Dibromofluoromethane (S)%.90 70-12891 Toluene-d8 (S)%.104 72-139103 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 23 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343063 EPA 3546 EPA 8270 by SIM 8270 MSSV PAH by SIM Associated Lab Samples:50150127001, 50150127002, 50150127003, 50150127004, 50150127005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1588742 Associated Lab Samples:50150127001, 50150127002, 50150127003, 50150127004, 50150127005 Matrix:Solid Analyzed 1-Methylnaphthalene mg/kg ND 0.0050 N207/21/16 15:50 2-Methylnaphthalene mg/kg ND 0.0050 07/21/16 15:50 Acenaphthene mg/kg ND 0.0050 07/21/16 15:50 Acenaphthylene mg/kg ND 0.0050 07/21/16 15:50 Anthracene mg/kg ND 0.0050 07/21/16 15:50 Benzo(a)anthracene mg/kg ND 0.0050 07/21/16 15:50 Benzo(a)pyrene mg/kg ND 0.0050 07/21/16 15:50 Benzo(b)fluoranthene mg/kg ND 0.0050 07/21/16 15:50 Benzo(g,h,i)perylene mg/kg ND 0.0050 07/21/16 15:50 Benzo(k)fluoranthene mg/kg ND 0.0050 07/21/16 15:50 Chrysene mg/kg ND 0.0050 07/21/16 15:50 Dibenz(a,h)anthracene mg/kg ND 0.0050 07/21/16 15:50 Fluoranthene mg/kg ND 0.0050 07/21/16 15:50 Fluorene mg/kg ND 0.0050 07/21/16 15:50 Indeno(1,2,3-cd)pyrene mg/kg ND 0.0050 07/21/16 15:50 Naphthalene mg/kg ND 0.0050 07/21/16 15:50 Phenanthrene mg/kg ND 0.0050 07/21/16 15:50 Pyrene mg/kg ND 0.0050 07/21/16 15:50 2-Fluorobiphenyl (S)%.83 25-121 07/21/16 15:50 p-Terphenyl-d14 (S)%.77 27-124 07/21/16 15:50 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1588743LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene mg/kg 0.26 N2.33 79 41-109 2-Methylnaphthalene mg/kg 0.25.33 77 39-109 Acenaphthene mg/kg 0.30.33 90 44-127 Acenaphthylene mg/kg 0.30.33 90 43-128 Anthracene mg/kg 0.31.33 92 49-131 Benzo(a)anthracene mg/kg 0.36.33 107 52-128 Benzo(a)pyrene mg/kg 0.30.33 89 54-141 Benzo(b)fluoranthene mg/kg 0.29.33 87 50-146 Benzo(g,h,i)perylene mg/kg 0.31.33 94 51-141 Benzo(k)fluoranthene mg/kg 0.33.33 100 55-139 Chrysene mg/kg 0.32.33 97 56-131 Dibenz(a,h)anthracene mg/kg 0.30.33 91 53-142 Fluoranthene mg/kg 0.33.33 100 51-139 Fluorene mg/kg 0.31.33 93 45-131 Indeno(1,2,3-cd)pyrene mg/kg 0.30.33 91 51-141 Naphthalene mg/kg 0.26.33 80 43-112 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 24 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1588743LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene mg/kg 0.31.33 95 47-132 Pyrene mg/kg 0.33.33 98 55-130 2-Fluorobiphenyl (S)%.86 25-121 p-Terphenyl-d14 (S)%.91 27-124 Parameter Units MS Result % Rec Limits Qual% RecConc. 1588744MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150105001 1588745 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene mg/kg N2.38 77 17-11876 2 20.38ND 0.29 0.29 2-Methylnaphthalene mg/kg .38 75 15-11875 1 20.38ND 0.28 0.29 Acenaphthene mg/kg .38 78 21-12575 4 20.38ND 0.30 0.28 Acenaphthylene mg/kg .38 77 21-12676 2 20.38ND 0.29 0.29 Anthracene mg/kg .38 80 15-13477 3 20.38ND 0.30 0.29 Benzo(a)anthracene mg/kg .38 92 14-12984 9 20.38ND 0.35 0.32 Benzo(a)pyrene mg/kg .38 76 10-14667 13 20.38ND 0.29 0.25 Benzo(b)fluoranthene mg/kg R1.38 81 10-14664 24 20.38ND 0.31 0.24 Benzo(g,h,i)perylene mg/kg .38 78 10-14267 15 20.38ND 0.29 0.25 Benzo(k)fluoranthene mg/kg .38 74 10-14776 2 20.38ND 0.28 0.29 Chrysene mg/kg .38 82 11-14078 6 20.38ND 0.31 0.29 Dibenz(a,h)anthracene mg/kg .38 76 16-13670 8 20.38ND 0.29 0.26 Fluoranthene mg/kg .38 84 10-14679 7 20.38ND 0.32 0.30 Fluorene mg/kg .38 81 20-13179 3 20.38ND 0.31 0.30 Indeno(1,2,3-cd)pyrene mg/kg .38 75 10-14666 13 20.38ND 0.29 0.25 Naphthalene mg/kg .38 72 15-12673 1 20.38ND 0.27 0.28 Phenanthrene mg/kg .38 82 10-14878 5 20.38ND 0.31 0.30 Pyrene mg/kg .38 83 14-13678 6 20.38ND 0.32 0.30 2-Fluorobiphenyl (S)%.73 25-12172 p-Terphenyl-d14 (S)%.67 27-12469 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 25 of 31 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344090 SM 2540G SM 2540G Dry Weight/Percent Moisture Associated Lab Samples:50150127001, 50150127002, 50150127003, 50150127004, 50150127005 Parameter Units Dup Result Max RPD QualifiersRPDResult 50150095003 1593121SAMPLE DUPLICATE: Percent Moisture %10.6 3 510.3 Parameter Units Dup Result Max RPD QualifiersRPDResult 50150137004 1593122SAMPLE DUPLICATE: Percent Moisture %3.8 4 53.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 26 of 31 #=QL# QUALIFIERS Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - IndianapolisPASI-I ANALYTE QUALIFIERS The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 27 of 31 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 50150127 204 Roosevelt Road (Walkerton) Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 50150127001 343461 344097WT-SB-10(012014)EPA 3050 EPA 6010 50150127002 343461 344097WT-SB-11(012014)EPA 3050 EPA 6010 50150127003 343461 344097WT-SB-12(010012)EPA 3050 EPA 6010 50150127004 343461 344097WT-SB-13(010012)EPA 3050 EPA 6010 50150127005 343461 344097WT-SB-14(010012)EPA 3050 EPA 6010 50150127001 343063 343148WT-SB-10(012014)EPA 3546 EPA 8270 by SIM 50150127002 343063 343148WT-SB-11(012014)EPA 3546 EPA 8270 by SIM 50150127003 343063 343148WT-SB-12(010012)EPA 3546 EPA 8270 by SIM 50150127004 343063 343148WT-SB-13(010012)EPA 3546 EPA 8270 by SIM 50150127005 343063 343148WT-SB-14(010012)EPA 3546 EPA 8270 by SIM 50150127001 344475WT-SB-10(012014)EPA 8260 50150127002 344475WT-SB-11(012014)EPA 8260 50150127003 344475WT-SB-12(010012)EPA 8260 50150127004 344475WT-SB-13(010012)EPA 8260 50150127005 344475WT-SB-14(010012)EPA 8260 50150127001 344090WT-SB-10(012014)SM 2540G 50150127002 344090WT-SB-11(012014)SM 2540G 50150127003 344090WT-SB-12(010012)SM 2540G 50150127004 344090WT-SB-13(010012)SM 2540G 50150127005 344090WT-SB-14(010012)SM 2540G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:51 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 28 of 31 Page 29 of 31 Page 30 of 31 Page 31 of 31 #=CL# August 04, 2016 LIMS USE: FR - GREG WAGGLE LIMS OBJECT ID: 50150268 50150268 Project: Pace Project No.: RE: Mr. Greg Waggle Symbiont 6737 W. Washington St. Suite 3440 Milwaukee, WI 53214 204 Roosevelt Rd Walkerton, IN Dear Mr. Waggle: Enclosed are the analytical results for sample(s) received by the laboratory on July 22, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Mick Mayse mick.mayse@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 1 of 64 #=CP# CERTIFICATIONS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Indiana Certification IDs 7726 Moller Road, Indianapolis, IN 46268 Illinois Certification #: 200074 Indiana Certification #: C-49-06 Kansas/NELAP Certification #:E-10177 Kentucky UST Certification #: 0042 Kentucky WW Certification #:98019 Ohio VAP Certification #: CL-0065 Oklahoma Certification #: 2014-148 Texas Certification #: T104704355-15-9 West Virginia Certification #: 330 Wisconsin Certification #: 999788130 USDA Soil Permit #: P330-10-00128 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 2 of 64 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Lab ID Sample ID Matrix Date Collected Date Received 50150268001 WK-GW-SB-2 Water 07/20/16 18:55 07/22/16 08:20 50150268002 WK-GW-SB-14 Water 07/20/16 20:50 07/22/16 08:20 50150268003 WK-GW-SB-1 Water 07/20/16 21:15 07/22/16 08:20 50150268004 WK-GW-SB-7 Water 07/21/16 08:55 07/22/16 08:20 50150268005 WK-GW-SB-8 Water 07/21/16 09:10 07/22/16 08:20 50150268006 WK-GW-FD-1 Water 07/21/16 09:50 07/22/16 08:20 50150268007 WK-GW-SB-9 Water 07/21/16 10:50 07/22/16 08:20 50150268008 WK-GW-SB-13 Water 07/21/16 12:10 07/22/16 08:20 50150268009 WK-GW-SB-4 Water 07/21/16 13:05 07/22/16 08:20 50150268010 WK-GW-SB-6 Water 07/21/16 13:50 07/22/16 08:20 50150268011 WK-GW-ERB Water 07/21/16 14:20 07/22/16 08:20 50150268012 WK-GW-TB Water 07/20/16 08:00 07/22/16 08:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 3 of 64 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 50150268001 WK-GW-SB-2 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268002 WK-GW-SB-14 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268003 WK-GW-SB-1 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268004 WK-GW-SB-7 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268005 WK-GW-SB-8 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268006 WK-GW-FD-1 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268007 WK-GW-SB-9 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268008 WK-GW-SB-13 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268009 WK-GW-SB-4 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268010 WK-GW-SB-6 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268011 WK-GW-ERB EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW 50150268012 WK-GW-TB EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ITMW REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 4 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-2 Lab ID:50150268001 Collected:07/20/16 18:55 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 13.0 ug/L 07/30/16 01:40 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 04:38 83-32-907/22/16 21:471.0 1 Acenaphthylene ND ug/L 07/26/16 04:38 208-96-807/22/16 21:471.0 1 Anthracene ND ug/L 07/26/16 04:38 120-12-707/22/16 21:470.10 1 Benzo(a)anthracene ND ug/L 07/26/16 04:38 56-55-307/22/16 21:470.10 1 Benzo(a)pyrene ND ug/L 07/26/16 04:38 50-32-807/22/16 21:470.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 04:38 205-99-207/22/16 21:470.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 04:38 191-24-207/22/16 21:470.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 04:38 207-08-907/22/16 21:470.10 1 Chrysene ND ug/L 07/26/16 04:38 218-01-907/22/16 21:470.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 04:38 53-70-307/22/16 21:470.10 1 Fluoranthene ND ug/L 07/26/16 04:38 206-44-007/22/16 21:471.0 1 Fluorene ND ug/L 07/26/16 04:38 86-73-707/22/16 21:471.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 04:38 193-39-507/22/16 21:470.10 1 1-Methylnaphthalene ND ug/L 07/26/16 04:38 90-12-0 N207/22/16 21:471.0 1 2-Methylnaphthalene ND ug/L 07/26/16 04:38 91-57-607/22/16 21:471.0 1 Naphthalene ND ug/L 07/26/16 04:38 91-20-307/22/16 21:471.0 1 Phenanthrene ND ug/L 07/26/16 04:38 85-01-807/22/16 21:471.0 1 Pyrene ND ug/L 07/26/16 04:38 129-00-007/22/16 21:471.0 1 Surrogates 2-Fluorobiphenyl (S)57 %.07/26/16 04:38 321-60-807/22/16 21:4718-117 1 p-Terphenyl-d14 (S)62 %.07/26/16 04:38 1718-51-007/22/16 21:4710-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 03:21 67-64-11001 Acrolein ND ug/L 08/02/16 03:21 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 03:21 107-13-11001 Benzene ND ug/L 08/02/16 03:21 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 03:21 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 03:21 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 03:21 75-27-45.0 1 Bromoform ND ug/L 08/02/16 03:21 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 03:21 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 03:21 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 03:21 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 03:21 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 03:21 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 03:21 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 03:21 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 03:21 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 03:21 75-00-35.0 1 Chloroform ND ug/L 08/02/16 03:21 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 03:21 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 03:21 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 5 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-2 Lab ID:50150268001 Collected:07/20/16 18:55 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 03:21 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 03:21 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 03:21 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 03:21 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 03:21 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 03:21 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 03:21 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 03:21 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 03:21 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 03:21 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 03:21 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 03:21 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 03:21 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 03:21 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 03:21 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 03:21 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 03:21 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 03:21 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 03:21 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 03:21 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 03:21 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 03:21 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 03:21 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 03:21 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 03:21 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 03:21 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 03:21 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 03:21 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 03:21 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 03:21 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 03:21 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 03:21 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 03:21 103-65-15.0 1 Styrene ND ug/L 08/02/16 03:21 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 03:21 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 03:21 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 03:21 127-18-45.0 1 Toluene ND ug/L 08/02/16 03:21 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 03:21 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 03:21 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 03:21 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 03:21 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 03:21 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 03:21 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 03:21 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 03:21 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 03:21 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 6 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-2 Lab ID:50150268001 Collected:07/20/16 18:55 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 03:21 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 03:21 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 03:21 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)110 %.08/02/16 03:21 1868-53-784-118 1 4-Bromofluorobenzene (S)97 %.08/02/16 03:21 460-00-479-116 1 Toluene-d8 (S)97 %.08/02/16 03:21 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 7 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-14 Lab ID:50150268002 Collected:07/20/16 20:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 41.0 ug/L 07/30/16 01:43 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 05:18 83-32-907/22/16 21:471.1 1 Acenaphthylene ND ug/L 07/26/16 05:18 208-96-807/22/16 21:471.1 1 Anthracene ND ug/L 07/26/16 05:18 120-12-707/22/16 21:470.11 1 Benzo(a)anthracene ND ug/L 07/26/16 05:18 56-55-307/22/16 21:470.11 1 Benzo(a)pyrene ND ug/L 07/26/16 05:18 50-32-807/22/16 21:470.11 1 Benzo(b)fluoranthene ND ug/L 07/26/16 05:18 205-99-207/22/16 21:470.11 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 05:18 191-24-207/22/16 21:470.11 1 Benzo(k)fluoranthene ND ug/L 07/26/16 05:18 207-08-907/22/16 21:470.11 1 Chrysene ND ug/L 07/26/16 05:18 218-01-907/22/16 21:470.53 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 05:18 53-70-307/22/16 21:470.11 1 Fluoranthene ND ug/L 07/26/16 05:18 206-44-007/22/16 21:471.1 1 Fluorene ND ug/L 07/26/16 05:18 86-73-707/22/16 21:471.1 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 05:18 193-39-507/22/16 21:470.11 1 1-Methylnaphthalene ND ug/L 07/26/16 05:18 90-12-0 N207/22/16 21:471.1 1 2-Methylnaphthalene ND ug/L 07/26/16 05:18 91-57-607/22/16 21:471.1 1 Naphthalene 1.7 ug/L 07/26/16 05:18 91-20-307/22/16 21:471.1 1 Phenanthrene ND ug/L 07/26/16 05:18 85-01-807/22/16 21:471.1 1 Pyrene ND ug/L 07/26/16 05:18 129-00-007/22/16 21:471.1 1 Surrogates 2-Fluorobiphenyl (S)57 %.07/26/16 05:18 321-60-807/22/16 21:4718-117 1 p-Terphenyl-d14 (S)64 %.07/26/16 05:18 1718-51-007/22/16 21:4710-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 03:59 67-64-11001 Acrolein ND ug/L 08/02/16 03:59 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 03:59 107-13-11001 Benzene ND ug/L 08/02/16 03:59 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 03:59 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 03:59 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 03:59 75-27-45.0 1 Bromoform ND ug/L 08/02/16 03:59 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 03:59 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 03:59 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 03:59 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 03:59 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 03:59 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 03:59 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 03:59 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 03:59 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 03:59 75-00-35.0 1 Chloroform ND ug/L 08/02/16 03:59 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 03:59 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 03:59 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 8 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-14 Lab ID:50150268002 Collected:07/20/16 20:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 03:59 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 03:59 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 03:59 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 03:59 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 03:59 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 03:59 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 03:59 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 03:59 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 03:59 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 03:59 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 03:59 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 03:59 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 03:59 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 03:59 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 03:59 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 03:59 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 03:59 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 03:59 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 03:59 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 03:59 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 03:59 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 03:59 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 03:59 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 03:59 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 03:59 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 03:59 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 03:59 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 03:59 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 03:59 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 03:59 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 03:59 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 03:59 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 03:59 103-65-15.0 1 Styrene ND ug/L 08/02/16 03:59 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 03:59 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 03:59 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 03:59 127-18-45.0 1 Toluene ND ug/L 08/02/16 03:59 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 03:59 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 03:59 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 03:59 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 03:59 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 03:59 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 03:59 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 03:59 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 03:59 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 03:59 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 9 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-14 Lab ID:50150268002 Collected:07/20/16 20:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 03:59 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 03:59 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 03:59 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)104 %.08/02/16 03:59 1868-53-784-118 1 4-Bromofluorobenzene (S)100 %.08/02/16 03:59 460-00-479-116 1 Toluene-d8 (S)98 %.08/02/16 03:59 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 10 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-1 Lab ID:50150268003 Collected:07/20/16 21:15 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 272 ug/L 07/30/16 01:45 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/28/16 12:10 83-32-907/27/16 22:101.0 1 Acenaphthylene ND ug/L 07/28/16 12:10 208-96-807/27/16 22:101.0 1 Anthracene ND ug/L 07/28/16 12:10 120-12-707/27/16 22:100.10 1 Benzo(a)anthracene ND ug/L 07/28/16 12:10 56-55-307/27/16 22:100.10 1 Benzo(a)pyrene ND ug/L 07/28/16 12:10 50-32-807/27/16 22:100.10 1 Benzo(b)fluoranthene ND ug/L 07/28/16 12:10 205-99-207/27/16 22:100.10 1 Benzo(g,h,i)perylene ND ug/L 07/28/16 12:10 191-24-207/27/16 22:100.10 1 Benzo(k)fluoranthene ND ug/L 07/28/16 12:10 207-08-907/27/16 22:100.10 1 Chrysene ND ug/L 07/28/16 12:10 218-01-907/27/16 22:100.50 1 Dibenz(a,h)anthracene ND ug/L 07/28/16 12:10 53-70-307/27/16 22:100.10 1 Fluoranthene ND ug/L 07/28/16 12:10 206-44-007/27/16 22:101.0 1 Fluorene ND ug/L 07/28/16 12:10 86-73-707/27/16 22:101.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/28/16 12:10 193-39-507/27/16 22:100.10 1 1-Methylnaphthalene ND ug/L 07/28/16 12:10 90-12-0 N207/27/16 22:101.0 1 2-Methylnaphthalene ND ug/L 07/28/16 12:10 91-57-607/27/16 22:101.0 1 Naphthalene ND ug/L 07/28/16 12:10 91-20-307/27/16 22:101.0 1 Phenanthrene ND ug/L 07/28/16 12:10 85-01-807/27/16 22:101.0 1 Pyrene ND ug/L 07/28/16 12:10 129-00-007/27/16 22:101.0 1 Surrogates 2-Fluorobiphenyl (S)62 %.07/28/16 12:10 321-60-807/27/16 22:1018-117 1 p-Terphenyl-d14 (S)56 %.07/28/16 12:10 1718-51-007/27/16 22:1010-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 17:06 67-64-11001 Acrolein ND ug/L 08/02/16 17:06 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 17:06 107-13-11001 Benzene ND ug/L 08/02/16 17:06 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 17:06 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 17:06 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 17:06 75-27-45.0 1 Bromoform ND ug/L 08/02/16 17:06 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 17:06 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 17:06 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 17:06 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 17:06 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 17:06 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 17:06 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 17:06 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 17:06 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 17:06 75-00-35.0 1 Chloroform ND ug/L 08/02/16 17:06 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 17:06 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 17:06 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 11 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-1 Lab ID:50150268003 Collected:07/20/16 21:15 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 17:06 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 17:06 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 17:06 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 17:06 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 17:06 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 17:06 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 17:06 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 17:06 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 17:06 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 17:06 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 17:06 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 17:06 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 17:06 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 17:06 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 17:06 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 17:06 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 17:06 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 17:06 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 17:06 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 17:06 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 17:06 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 17:06 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 17:06 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 17:06 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 17:06 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 17:06 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 17:06 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 17:06 99-87-65.0 1 Methylene Chloride 5.5 ug/L 08/02/16 17:06 75-09-2 C95.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 17:06 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 17:06 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 17:06 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 17:06 103-65-15.0 1 Styrene ND ug/L 08/02/16 17:06 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 17:06 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 17:06 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 17:06 127-18-45.0 1 Toluene ND ug/L 08/02/16 17:06 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 17:06 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 17:06 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 17:06 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 17:06 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 17:06 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 17:06 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 17:06 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 17:06 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 17:06 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 12 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-1 Lab ID:50150268003 Collected:07/20/16 21:15 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 17:06 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 17:06 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 17:06 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)109 %.08/02/16 17:06 1868-53-7 H1,HS, pH 84-118 1 4-Bromofluorobenzene (S)98 %.08/02/16 17:06 460-00-479-116 1 Toluene-d8 (S)97 %.08/02/16 17:06 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 13 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-7 Lab ID:50150268004 Collected:07/21/16 08:55 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 358 ug/L 07/30/16 01:47 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 06:12 83-32-907/22/16 21:471.0 1 Acenaphthylene ND ug/L 07/26/16 06:12 208-96-807/22/16 21:471.0 1 Anthracene ND ug/L 07/26/16 06:12 120-12-707/22/16 21:470.10 1 Benzo(a)anthracene ND ug/L 07/26/16 06:12 56-55-307/22/16 21:470.10 1 Benzo(a)pyrene ND ug/L 07/26/16 06:12 50-32-807/22/16 21:470.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 06:12 205-99-207/22/16 21:470.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 06:12 191-24-207/22/16 21:470.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 06:12 207-08-907/22/16 21:470.10 1 Chrysene ND ug/L 07/26/16 06:12 218-01-907/22/16 21:470.51 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 06:12 53-70-307/22/16 21:470.10 1 Fluoranthene ND ug/L 07/26/16 06:12 206-44-007/22/16 21:471.0 1 Fluorene ND ug/L 07/26/16 06:12 86-73-707/22/16 21:471.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 06:12 193-39-507/22/16 21:470.10 1 1-Methylnaphthalene ND ug/L 07/26/16 06:12 90-12-0 N207/22/16 21:471.0 1 2-Methylnaphthalene ND ug/L 07/26/16 06:12 91-57-607/22/16 21:471.0 1 Naphthalene ND ug/L 07/26/16 06:12 91-20-307/22/16 21:471.0 1 Phenanthrene ND ug/L 07/26/16 06:12 85-01-807/22/16 21:471.0 1 Pyrene ND ug/L 07/26/16 06:12 129-00-007/22/16 21:471.0 1 Surrogates 2-Fluorobiphenyl (S)48 %.07/26/16 06:12 321-60-807/22/16 21:4718-117 1 p-Terphenyl-d14 (S)50 %.07/26/16 06:12 1718-51-007/22/16 21:4710-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 17:44 67-64-11001 Acrolein ND ug/L 08/02/16 17:44 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 17:44 107-13-11001 Benzene ND ug/L 08/02/16 17:44 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 17:44 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 17:44 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 17:44 75-27-45.0 1 Bromoform ND ug/L 08/02/16 17:44 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 17:44 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 17:44 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 17:44 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 17:44 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 17:44 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 17:44 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 17:44 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 17:44 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 17:44 75-00-35.0 1 Chloroform ND ug/L 08/02/16 17:44 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 17:44 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 17:44 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 14 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-7 Lab ID:50150268004 Collected:07/21/16 08:55 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 17:44 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 17:44 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 17:44 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 17:44 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 17:44 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 17:44 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 17:44 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 17:44 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 17:44 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 17:44 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 17:44 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 17:44 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 17:44 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 17:44 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 17:44 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 17:44 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 17:44 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 17:44 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 17:44 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 17:44 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 17:44 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 17:44 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 17:44 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 17:44 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 17:44 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 17:44 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 17:44 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 17:44 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 17:44 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 17:44 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 17:44 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 17:44 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 17:44 103-65-15.0 1 Styrene ND ug/L 08/02/16 17:44 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 17:44 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 17:44 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 17:44 127-18-45.0 1 Toluene ND ug/L 08/02/16 17:44 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 17:44 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 17:44 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 17:44 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 17:44 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 17:44 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 17:44 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 17:44 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 17:44 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 17:44 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 15 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-7 Lab ID:50150268004 Collected:07/21/16 08:55 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 17:44 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 17:44 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 17:44 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)112 %.08/02/16 17:44 1868-53-7 H1,HS, pH 84-118 1 4-Bromofluorobenzene (S)101 %.08/02/16 17:44 460-00-479-116 1 Toluene-d8 (S)100 %.08/02/16 17:44 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 16 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-8 Lab ID:50150268005 Collected:07/21/16 09:10 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 1140 ug/L 07/30/16 01:49 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 06:25 83-32-907/22/16 21:471.0 1 Acenaphthylene ND ug/L 07/26/16 06:25 208-96-807/22/16 21:471.0 1 Anthracene ND ug/L 07/26/16 06:25 120-12-707/22/16 21:470.10 1 Benzo(a)anthracene ND ug/L 07/26/16 06:25 56-55-307/22/16 21:470.10 1 Benzo(a)pyrene ND ug/L 07/26/16 06:25 50-32-807/22/16 21:470.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 06:25 205-99-207/22/16 21:470.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 06:25 191-24-207/22/16 21:470.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 06:25 207-08-907/22/16 21:470.10 1 Chrysene ND ug/L 07/26/16 06:25 218-01-907/22/16 21:470.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 06:25 53-70-307/22/16 21:470.10 1 Fluoranthene ND ug/L 07/26/16 06:25 206-44-007/22/16 21:471.0 1 Fluorene ND ug/L 07/26/16 06:25 86-73-707/22/16 21:471.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 06:25 193-39-507/22/16 21:470.10 1 1-Methylnaphthalene ND ug/L 07/26/16 06:25 90-12-0 N207/22/16 21:471.0 1 2-Methylnaphthalene ND ug/L 07/26/16 06:25 91-57-607/22/16 21:471.0 1 Naphthalene ND ug/L 07/26/16 06:25 91-20-307/22/16 21:471.0 1 Phenanthrene ND ug/L 07/26/16 06:25 85-01-807/22/16 21:471.0 1 Pyrene ND ug/L 07/26/16 06:25 129-00-007/22/16 21:471.0 1 Surrogates 2-Fluorobiphenyl (S)41 %.07/26/16 06:25 321-60-807/22/16 21:4718-117 1 p-Terphenyl-d14 (S)33 %.07/26/16 06:25 1718-51-007/22/16 21:4710-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 18:21 67-64-11001 Acrolein ND ug/L 08/02/16 18:21 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 18:21 107-13-11001 Benzene ND ug/L 08/02/16 18:21 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 18:21 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 18:21 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 18:21 75-27-45.0 1 Bromoform ND ug/L 08/02/16 18:21 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 18:21 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 18:21 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 18:21 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 18:21 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 18:21 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 18:21 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 18:21 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 18:21 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 18:21 75-00-35.0 1 Chloroform ND ug/L 08/02/16 18:21 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 18:21 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 18:21 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 17 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-8 Lab ID:50150268005 Collected:07/21/16 09:10 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 18:21 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 18:21 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 18:21 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 18:21 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 18:21 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 18:21 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 18:21 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 18:21 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 18:21 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 18:21 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 18:21 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 18:21 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 18:21 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 18:21 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 18:21 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 18:21 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 18:21 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 18:21 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 18:21 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 18:21 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 18:21 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 18:21 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 18:21 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 18:21 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 18:21 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 18:21 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 18:21 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 18:21 99-87-65.0 1 Methylene Chloride 6.9 ug/L 08/02/16 18:21 75-09-2 C95.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 18:21 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 18:21 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 18:21 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 18:21 103-65-15.0 1 Styrene ND ug/L 08/02/16 18:21 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 18:21 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 18:21 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 18:21 127-18-45.0 1 Toluene ND ug/L 08/02/16 18:21 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 18:21 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 18:21 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 18:21 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 18:21 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 18:21 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 18:21 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 18:21 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 18:21 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 18:21 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 18 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-8 Lab ID:50150268005 Collected:07/21/16 09:10 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 18:21 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 18:21 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 18:21 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)111 %.08/02/16 18:21 1868-53-784-118 1 4-Bromofluorobenzene (S)102 %.08/02/16 18:21 460-00-479-116 1 Toluene-d8 (S)98 %.08/02/16 18:21 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 19 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-FD-1 Lab ID:50150268006 Collected:07/21/16 09:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 260 ug/L 07/30/16 01:52 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 08:38 83-32-907/24/16 18:181.0 1 Acenaphthylene ND ug/L 07/26/16 08:38 208-96-807/24/16 18:181.0 1 Anthracene ND ug/L 07/26/16 08:38 120-12-707/24/16 18:180.10 1 Benzo(a)anthracene ND ug/L 07/26/16 08:38 56-55-307/24/16 18:180.10 1 Benzo(a)pyrene ND ug/L 07/26/16 08:38 50-32-807/24/16 18:180.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 08:38 205-99-207/24/16 18:180.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 08:38 191-24-207/24/16 18:180.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 08:38 207-08-907/24/16 18:180.10 1 Chrysene ND ug/L 07/26/16 08:38 218-01-907/24/16 18:180.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 08:38 53-70-307/24/16 18:180.10 1 Fluoranthene ND ug/L 07/26/16 08:38 206-44-007/24/16 18:181.0 1 Fluorene ND ug/L 07/26/16 08:38 86-73-707/24/16 18:181.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 08:38 193-39-507/24/16 18:180.10 1 1-Methylnaphthalene ND ug/L 07/26/16 08:38 90-12-0 N207/24/16 18:181.0 1 2-Methylnaphthalene ND ug/L 07/26/16 08:38 91-57-607/24/16 18:181.0 1 Naphthalene ND ug/L 07/26/16 08:38 91-20-307/24/16 18:181.0 1 Phenanthrene ND ug/L 07/26/16 08:38 85-01-807/24/16 18:181.0 1 Pyrene ND ug/L 07/26/16 08:38 129-00-007/24/16 18:181.0 1 Surrogates 2-Fluorobiphenyl (S)39 %.07/26/16 08:38 321-60-807/24/16 18:1818-117 1 p-Terphenyl-d14 (S)46 %.07/26/16 08:38 1718-51-007/24/16 18:1810-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 04:37 67-64-11001 Acrolein ND ug/L 08/02/16 04:37 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 04:37 107-13-11001 Benzene ND ug/L 08/02/16 04:37 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 04:37 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 04:37 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 04:37 75-27-45.0 1 Bromoform ND ug/L 08/02/16 04:37 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 04:37 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 04:37 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 04:37 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 04:37 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 04:37 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 04:37 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 04:37 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 04:37 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 04:37 75-00-35.0 1 Chloroform ND ug/L 08/02/16 04:37 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 04:37 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 04:37 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 20 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-FD-1 Lab ID:50150268006 Collected:07/21/16 09:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 04:37 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 04:37 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 04:37 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 04:37 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 04:37 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 04:37 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 04:37 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 04:37 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 04:37 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 04:37 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 04:37 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 04:37 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 04:37 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 04:37 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 04:37 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 04:37 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 04:37 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 04:37 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 04:37 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 04:37 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 04:37 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 04:37 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 04:37 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 04:37 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 04:37 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 04:37 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 04:37 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 04:37 99-87-65.0 1 Methylene Chloride 5.4 ug/L 08/02/16 04:37 75-09-2 C95.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 04:37 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 04:37 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 04:37 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 04:37 103-65-15.0 1 Styrene ND ug/L 08/02/16 04:37 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 04:37 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 04:37 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 04:37 127-18-45.0 1 Toluene ND ug/L 08/02/16 04:37 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 04:37 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 04:37 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 04:37 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 04:37 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 04:37 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 04:37 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 04:37 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 04:37 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 04:37 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 21 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-FD-1 Lab ID:50150268006 Collected:07/21/16 09:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 04:37 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 04:37 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 04:37 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)113 %.08/02/16 04:37 1868-53-784-118 1 4-Bromofluorobenzene (S)100 %.08/02/16 04:37 460-00-479-116 1 Toluene-d8 (S)97 %.08/02/16 04:37 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 22 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-9 Lab ID:50150268007 Collected:07/21/16 10:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 3590 ug/L 07/30/16 02:10 7439-92-107/28/16 07:1850.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 06:38 83-32-907/22/16 21:471.0 1 Acenaphthylene ND ug/L 07/26/16 06:38 208-96-807/22/16 21:471.0 1 Anthracene ND ug/L 07/26/16 06:38 120-12-707/22/16 21:470.10 1 Benzo(a)anthracene ND ug/L 07/26/16 06:38 56-55-307/22/16 21:470.10 1 Benzo(a)pyrene ND ug/L 07/26/16 06:38 50-32-807/22/16 21:470.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 06:38 205-99-207/22/16 21:470.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 06:38 191-24-207/22/16 21:470.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 06:38 207-08-907/22/16 21:470.10 1 Chrysene ND ug/L 07/26/16 06:38 218-01-907/22/16 21:470.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 06:38 53-70-307/22/16 21:470.10 1 Fluoranthene ND ug/L 07/26/16 06:38 206-44-007/22/16 21:471.0 1 Fluorene ND ug/L 07/26/16 06:38 86-73-707/22/16 21:471.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 06:38 193-39-507/22/16 21:470.10 1 1-Methylnaphthalene ND ug/L 07/26/16 06:38 90-12-0 N207/22/16 21:471.0 1 2-Methylnaphthalene ND ug/L 07/26/16 06:38 91-57-607/22/16 21:471.0 1 Naphthalene ND ug/L 07/26/16 06:38 91-20-307/22/16 21:471.0 1 Phenanthrene ND ug/L 07/26/16 06:38 85-01-807/22/16 21:471.0 1 Pyrene ND ug/L 07/26/16 06:38 129-00-007/22/16 21:471.0 1 Surrogates 2-Fluorobiphenyl (S)1 %.07/26/16 06:38 321-60-8 S507/22/16 21:4718-117 1 p-Terphenyl-d14 (S)0 %.07/26/16 06:38 1718-51-0 S507/22/16 21:4710-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 18:59 67-64-11001 Acrolein ND ug/L 08/02/16 18:59 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 18:59 107-13-11001 Benzene ND ug/L 08/02/16 18:59 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 18:59 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 18:59 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 18:59 75-27-45.0 1 Bromoform ND ug/L 08/02/16 18:59 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 18:59 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 18:59 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 18:59 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 18:59 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 18:59 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 18:59 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 18:59 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 18:59 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 18:59 75-00-35.0 1 Chloroform ND ug/L 08/02/16 18:59 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 18:59 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 18:59 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 23 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-9 Lab ID:50150268007 Collected:07/21/16 10:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 18:59 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 18:59 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 18:59 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 18:59 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 18:59 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 18:59 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 18:59 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 18:59 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 18:59 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 18:59 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 18:59 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 18:59 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 18:59 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 18:59 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 18:59 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 18:59 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 18:59 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 18:59 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 18:59 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 18:59 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 18:59 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 18:59 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 18:59 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 18:59 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 18:59 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 18:59 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 18:59 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 18:59 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 18:59 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 18:59 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 18:59 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 18:59 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 18:59 103-65-15.0 1 Styrene ND ug/L 08/02/16 18:59 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 18:59 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 18:59 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 18:59 127-18-45.0 1 Toluene ND ug/L 08/02/16 18:59 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 18:59 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 18:59 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 18:59 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 18:59 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 18:59 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 18:59 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 18:59 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 18:59 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 18:59 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 24 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-9 Lab ID:50150268007 Collected:07/21/16 10:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 18:59 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 18:59 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 18:59 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)111 %.08/02/16 18:59 1868-53-7 H1,pH84-118 1 4-Bromofluorobenzene (S)104 %.08/02/16 18:59 460-00-479-116 1 Toluene-d8 (S)98 %.08/02/16 18:59 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 25 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-13 Lab ID:50150268008 Collected:07/21/16 12:10 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 45.2 ug/L 07/30/16 02:12 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 06:52 83-32-907/22/16 21:471.1 1 Acenaphthylene ND ug/L 07/26/16 06:52 208-96-807/22/16 21:471.1 1 Anthracene ND ug/L 07/26/16 06:52 120-12-707/22/16 21:470.11 1 Benzo(a)anthracene ND ug/L 07/26/16 06:52 56-55-307/22/16 21:470.11 1 Benzo(a)pyrene ND ug/L 07/26/16 06:52 50-32-807/22/16 21:470.11 1 Benzo(b)fluoranthene ND ug/L 07/26/16 06:52 205-99-207/22/16 21:470.11 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 06:52 191-24-207/22/16 21:470.11 1 Benzo(k)fluoranthene ND ug/L 07/26/16 06:52 207-08-907/22/16 21:470.11 1 Chrysene ND ug/L 07/26/16 06:52 218-01-907/22/16 21:470.53 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 06:52 53-70-307/22/16 21:470.11 1 Fluoranthene ND ug/L 07/26/16 06:52 206-44-007/22/16 21:471.1 1 Fluorene ND ug/L 07/26/16 06:52 86-73-707/22/16 21:471.1 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 06:52 193-39-507/22/16 21:470.11 1 1-Methylnaphthalene ND ug/L 07/26/16 06:52 90-12-0 N207/22/16 21:471.1 1 2-Methylnaphthalene ND ug/L 07/26/16 06:52 91-57-607/22/16 21:471.1 1 Naphthalene ND ug/L 07/26/16 06:52 91-20-307/22/16 21:471.1 1 Phenanthrene ND ug/L 07/26/16 06:52 85-01-807/22/16 21:471.1 1 Pyrene ND ug/L 07/26/16 06:52 129-00-007/22/16 21:471.1 1 Surrogates 2-Fluorobiphenyl (S)55 %.07/26/16 06:52 321-60-807/22/16 21:4718-117 1 p-Terphenyl-d14 (S)56 %.07/26/16 06:52 1718-51-007/22/16 21:4710-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 19:37 67-64-11001 Acrolein ND ug/L 08/02/16 19:37 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 19:37 107-13-11001 Benzene ND ug/L 08/02/16 19:37 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 19:37 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 19:37 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 19:37 75-27-45.0 1 Bromoform ND ug/L 08/02/16 19:37 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 19:37 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 19:37 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 19:37 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 19:37 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 19:37 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 19:37 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 19:37 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 19:37 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 19:37 75-00-35.0 1 Chloroform ND ug/L 08/02/16 19:37 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 19:37 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 19:37 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 26 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-13 Lab ID:50150268008 Collected:07/21/16 12:10 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 19:37 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 19:37 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 19:37 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 19:37 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 19:37 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 19:37 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 19:37 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 19:37 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 19:37 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 19:37 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 19:37 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 19:37 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 19:37 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 19:37 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 19:37 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 19:37 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 19:37 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 19:37 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 19:37 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 19:37 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 19:37 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 19:37 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 19:37 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 19:37 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 19:37 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 19:37 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 19:37 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 19:37 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 19:37 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 19:37 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 19:37 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 19:37 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 19:37 103-65-15.0 1 Styrene ND ug/L 08/02/16 19:37 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 19:37 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 19:37 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 19:37 127-18-45.0 1 Toluene ND ug/L 08/02/16 19:37 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 19:37 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 19:37 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 19:37 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 19:37 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 19:37 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 19:37 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 19:37 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 19:37 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 19:37 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 27 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-13 Lab ID:50150268008 Collected:07/21/16 12:10 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 19:37 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 19:37 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 19:37 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)108 %.08/02/16 19:37 1868-53-784-118 1 4-Bromofluorobenzene (S)103 %.08/02/16 19:37 460-00-479-116 1 Toluene-d8 (S)104 %.08/02/16 19:37 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 28 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-4 Lab ID:50150268009 Collected:07/21/16 13:05 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 490 ug/L 07/30/16 02:14 7439-92-107/28/16 07:1850.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/25/16 17:46 83-32-907/24/16 18:501.0 1 Acenaphthylene ND ug/L 07/25/16 17:46 208-96-807/24/16 18:501.0 1 Anthracene ND ug/L 07/25/16 17:46 120-12-707/24/16 18:500.10 1 Benzo(a)anthracene ND ug/L 07/25/16 17:46 56-55-307/24/16 18:500.10 1 Benzo(a)pyrene ND ug/L 07/25/16 17:46 50-32-807/24/16 18:500.10 1 Benzo(b)fluoranthene ND ug/L 07/25/16 17:46 205-99-207/24/16 18:500.10 1 Benzo(g,h,i)perylene ND ug/L 07/25/16 17:46 191-24-207/24/16 18:500.10 1 Benzo(k)fluoranthene ND ug/L 07/25/16 17:46 207-08-907/24/16 18:500.10 1 Chrysene ND ug/L 07/25/16 17:46 218-01-907/24/16 18:500.50 1 Dibenz(a,h)anthracene ND ug/L 07/25/16 17:46 53-70-307/24/16 18:500.10 1 Fluoranthene ND ug/L 07/25/16 17:46 206-44-007/24/16 18:501.0 1 Fluorene ND ug/L 07/25/16 17:46 86-73-707/24/16 18:501.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/25/16 17:46 193-39-507/24/16 18:500.10 1 1-Methylnaphthalene ND ug/L 07/25/16 17:46 90-12-0 N207/24/16 18:501.0 1 2-Methylnaphthalene ND ug/L 07/25/16 17:46 91-57-607/24/16 18:501.0 1 Naphthalene ND ug/L 07/25/16 17:46 91-20-307/24/16 18:501.0 1 Phenanthrene ND ug/L 07/25/16 17:46 85-01-807/24/16 18:501.0 1 Pyrene ND ug/L 07/25/16 17:46 129-00-007/24/16 18:501.0 1 Surrogates 2-Fluorobiphenyl (S)39 %.07/25/16 17:46 321-60-807/24/16 18:5018-117 1 p-Terphenyl-d14 (S)48 %.07/25/16 17:46 1718-51-007/24/16 18:5010-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 20:14 67-64-11001 Acrolein ND ug/L 08/02/16 20:14 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 20:14 107-13-11001 Benzene ND ug/L 08/02/16 20:14 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 20:14 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 20:14 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 20:14 75-27-45.0 1 Bromoform ND ug/L 08/02/16 20:14 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 20:14 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 20:14 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 20:14 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 20:14 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 20:14 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 20:14 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 20:14 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 20:14 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 20:14 75-00-35.0 1 Chloroform ND ug/L 08/02/16 20:14 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 20:14 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 20:14 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 29 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-4 Lab ID:50150268009 Collected:07/21/16 13:05 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 20:14 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 20:14 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 20:14 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 20:14 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 20:14 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 20:14 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 20:14 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 20:14 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 20:14 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 20:14 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 20:14 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 20:14 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 20:14 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 20:14 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 20:14 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 20:14 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 20:14 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 20:14 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 20:14 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 20:14 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 20:14 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 20:14 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 20:14 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 20:14 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 20:14 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 20:14 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 20:14 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 20:14 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 20:14 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 20:14 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 20:14 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 20:14 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 20:14 103-65-15.0 1 Styrene ND ug/L 08/02/16 20:14 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 20:14 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 20:14 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 20:14 127-18-45.0 1 Toluene ND ug/L 08/02/16 20:14 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 20:14 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 20:14 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 20:14 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 20:14 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 20:14 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 20:14 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 20:14 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 20:14 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 20:14 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 30 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-4 Lab ID:50150268009 Collected:07/21/16 13:05 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 20:14 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 20:14 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 20:14 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)111 %.08/02/16 20:14 1868-53-784-118 1 4-Bromofluorobenzene (S)97 %.08/02/16 20:14 460-00-479-116 1 Toluene-d8 (S)102 %.08/02/16 20:14 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 31 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-6 Lab ID:50150268010 Collected:07/21/16 13:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 67.4 ug/L 07/30/16 02:16 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/25/16 17:59 83-32-907/24/16 18:501.0 1 Acenaphthylene ND ug/L 07/25/16 17:59 208-96-807/24/16 18:501.0 1 Anthracene ND ug/L 07/25/16 17:59 120-12-707/24/16 18:500.10 1 Benzo(a)anthracene ND ug/L 07/25/16 17:59 56-55-307/24/16 18:500.10 1 Benzo(a)pyrene ND ug/L 07/25/16 17:59 50-32-807/24/16 18:500.10 1 Benzo(b)fluoranthene ND ug/L 07/25/16 17:59 205-99-207/24/16 18:500.10 1 Benzo(g,h,i)perylene ND ug/L 07/25/16 17:59 191-24-207/24/16 18:500.10 1 Benzo(k)fluoranthene ND ug/L 07/25/16 17:59 207-08-907/24/16 18:500.10 1 Chrysene ND ug/L 07/25/16 17:59 218-01-907/24/16 18:500.50 1 Dibenz(a,h)anthracene ND ug/L 07/25/16 17:59 53-70-307/24/16 18:500.10 1 Fluoranthene ND ug/L 07/25/16 17:59 206-44-007/24/16 18:501.0 1 Fluorene ND ug/L 07/25/16 17:59 86-73-707/24/16 18:501.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/25/16 17:59 193-39-507/24/16 18:500.10 1 1-Methylnaphthalene ND ug/L 07/25/16 17:59 90-12-0 N207/24/16 18:501.0 1 2-Methylnaphthalene ND ug/L 07/25/16 17:59 91-57-607/24/16 18:501.0 1 Naphthalene ND ug/L 07/25/16 17:59 91-20-307/24/16 18:501.0 1 Phenanthrene ND ug/L 07/25/16 17:59 85-01-807/24/16 18:501.0 1 Pyrene ND ug/L 07/25/16 17:59 129-00-007/24/16 18:501.0 1 Surrogates 2-Fluorobiphenyl (S)38 %.07/25/16 17:59 321-60-807/24/16 18:5018-117 1 p-Terphenyl-d14 (S)46 %.07/25/16 17:59 1718-51-007/24/16 18:5010-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 20:52 67-64-11001 Acrolein ND ug/L 08/02/16 20:52 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 20:52 107-13-11001 Benzene ND ug/L 08/02/16 20:52 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 20:52 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 20:52 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 20:52 75-27-45.0 1 Bromoform ND ug/L 08/02/16 20:52 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 20:52 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 20:52 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 20:52 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 20:52 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 20:52 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 20:52 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 20:52 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 20:52 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 20:52 75-00-35.0 1 Chloroform ND ug/L 08/02/16 20:52 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 20:52 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 20:52 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 32 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-6 Lab ID:50150268010 Collected:07/21/16 13:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 20:52 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 20:52 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 20:52 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 20:52 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 20:52 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 20:52 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 20:52 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 20:52 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 20:52 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 20:52 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 20:52 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 20:52 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 20:52 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 20:52 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 20:52 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 20:52 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 20:52 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 20:52 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 20:52 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 20:52 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 20:52 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 20:52 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 20:52 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 20:52 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 20:52 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 20:52 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 20:52 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 20:52 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 20:52 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 20:52 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 20:52 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 20:52 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 20:52 103-65-15.0 1 Styrene ND ug/L 08/02/16 20:52 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 20:52 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 20:52 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 20:52 127-18-45.0 1 Toluene ND ug/L 08/02/16 20:52 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 20:52 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 20:52 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 20:52 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 20:52 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 20:52 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 20:52 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 20:52 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 20:52 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 20:52 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 33 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-SB-6 Lab ID:50150268010 Collected:07/21/16 13:50 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 20:52 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 20:52 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 20:52 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)112 %.08/02/16 20:52 1868-53-784-118 1 4-Bromofluorobenzene (S)102 %.08/02/16 20:52 460-00-479-116 1 Toluene-d8 (S)104 %.08/02/16 20:52 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 34 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-ERB Lab ID:50150268011 Collected:07/21/16 14:20 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead ND ug/L 07/30/16 02:18 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/25/16 18:12 83-32-907/24/16 18:501.0 1 Acenaphthylene ND ug/L 07/25/16 18:12 208-96-807/24/16 18:501.0 1 Anthracene ND ug/L 07/25/16 18:12 120-12-707/24/16 18:500.10 1 Benzo(a)anthracene ND ug/L 07/25/16 18:12 56-55-307/24/16 18:500.10 1 Benzo(a)pyrene ND ug/L 07/25/16 18:12 50-32-807/24/16 18:500.10 1 Benzo(b)fluoranthene ND ug/L 07/25/16 18:12 205-99-207/24/16 18:500.10 1 Benzo(g,h,i)perylene ND ug/L 07/25/16 18:12 191-24-207/24/16 18:500.10 1 Benzo(k)fluoranthene ND ug/L 07/25/16 18:12 207-08-907/24/16 18:500.10 1 Chrysene ND ug/L 07/25/16 18:12 218-01-907/24/16 18:500.50 1 Dibenz(a,h)anthracene ND ug/L 07/25/16 18:12 53-70-307/24/16 18:500.10 1 Fluoranthene ND ug/L 07/25/16 18:12 206-44-007/24/16 18:501.0 1 Fluorene ND ug/L 07/25/16 18:12 86-73-707/24/16 18:501.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/25/16 18:12 193-39-507/24/16 18:500.10 1 1-Methylnaphthalene ND ug/L 07/25/16 18:12 90-12-0 N207/24/16 18:501.0 1 2-Methylnaphthalene ND ug/L 07/25/16 18:12 91-57-607/24/16 18:501.0 1 Naphthalene ND ug/L 07/25/16 18:12 91-20-307/24/16 18:501.0 1 Phenanthrene ND ug/L 07/25/16 18:12 85-01-807/24/16 18:501.0 1 Pyrene ND ug/L 07/25/16 18:12 129-00-007/24/16 18:501.0 1 Surrogates 2-Fluorobiphenyl (S)47 %.07/25/16 18:12 321-60-807/24/16 18:5018-117 1 p-Terphenyl-d14 (S)67 %.07/25/16 18:12 1718-51-007/24/16 18:5010-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 21:30 67-64-11001 Acrolein ND ug/L 08/02/16 21:30 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 21:30 107-13-11001 Benzene ND ug/L 08/02/16 21:30 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 21:30 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 21:30 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 21:30 75-27-45.0 1 Bromoform ND ug/L 08/02/16 21:30 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 21:30 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 21:30 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 21:30 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 21:30 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 21:30 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 21:30 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 21:30 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 21:30 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 21:30 75-00-35.0 1 Chloroform ND ug/L 08/02/16 21:30 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 21:30 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 21:30 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 35 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-ERB Lab ID:50150268011 Collected:07/21/16 14:20 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 21:30 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 21:30 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 21:30 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 21:30 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 21:30 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 21:30 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 21:30 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 21:30 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 21:30 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 21:30 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 21:30 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 21:30 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 21:30 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 21:30 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 21:30 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 21:30 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 21:30 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 21:30 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 21:30 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 21:30 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 21:30 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 21:30 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 21:30 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 21:30 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 21:30 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 21:30 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 21:30 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 21:30 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 21:30 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 21:30 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 21:30 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 21:30 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 21:30 103-65-15.0 1 Styrene ND ug/L 08/02/16 21:30 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 21:30 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 21:30 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 21:30 127-18-45.0 1 Toluene ND ug/L 08/02/16 21:30 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 21:30 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 21:30 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 21:30 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 21:30 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 21:30 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 21:30 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 21:30 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 21:30 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 21:30 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 36 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-ERB Lab ID:50150268011 Collected:07/21/16 14:20 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 21:30 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 21:30 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 21:30 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)115 %.08/02/16 21:30 1868-53-784-118 1 4-Bromofluorobenzene (S)97 %.08/02/16 21:30 460-00-479-116 1 Toluene-d8 (S)101 %.08/02/16 21:30 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 37 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-TB Lab ID:50150268012 Collected:07/20/16 08:00 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead ND ug/L 07/30/16 02:21 7439-92-107/28/16 07:1810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 05:45 83-32-907/22/16 21:471.0 1 Acenaphthylene ND ug/L 07/26/16 05:45 208-96-807/22/16 21:471.0 1 Anthracene ND ug/L 07/26/16 05:45 120-12-707/22/16 21:470.10 1 Benzo(a)anthracene ND ug/L 07/26/16 05:45 56-55-307/22/16 21:470.10 1 Benzo(a)pyrene ND ug/L 07/26/16 05:45 50-32-807/22/16 21:470.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 05:45 205-99-207/22/16 21:470.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 05:45 191-24-207/22/16 21:470.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 05:45 207-08-907/22/16 21:470.10 1 Chrysene ND ug/L 07/26/16 05:45 218-01-907/22/16 21:470.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 05:45 53-70-307/22/16 21:470.10 1 Fluoranthene ND ug/L 07/26/16 05:45 206-44-007/22/16 21:471.0 1 Fluorene ND ug/L 07/26/16 05:45 86-73-707/22/16 21:471.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 05:45 193-39-507/22/16 21:470.10 1 1-Methylnaphthalene ND ug/L 07/26/16 05:45 90-12-0 N207/22/16 21:471.0 1 2-Methylnaphthalene ND ug/L 07/26/16 05:45 91-57-607/22/16 21:471.0 1 Naphthalene ND ug/L 07/26/16 05:45 91-20-307/22/16 21:471.0 1 Phenanthrene ND ug/L 07/26/16 05:45 85-01-807/22/16 21:471.0 1 Pyrene ND ug/L 07/26/16 05:45 129-00-007/22/16 21:471.0 1 Surrogates 2-Fluorobiphenyl (S)61 %.07/26/16 05:45 321-60-807/22/16 21:4718-117 1 p-Terphenyl-d14 (S)65 %.07/26/16 05:45 1718-51-007/22/16 21:4710-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 22:07 67-64-11001 Acrolein ND ug/L 08/02/16 22:07 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 22:07 107-13-11001 Benzene ND ug/L 08/02/16 22:07 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 22:07 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 22:07 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 22:07 75-27-45.0 1 Bromoform ND ug/L 08/02/16 22:07 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 22:07 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 22:07 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 22:07 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 22:07 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 22:07 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 22:07 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 22:07 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 22:07 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 22:07 75-00-35.0 1 Chloroform ND ug/L 08/02/16 22:07 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 22:07 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 22:07 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 38 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-TB Lab ID:50150268012 Collected:07/20/16 08:00 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 22:07 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 22:07 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 22:07 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 22:07 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 22:07 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 22:07 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 22:07 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 22:07 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 22:07 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 22:07 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 22:07 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 22:07 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 22:07 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 22:07 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 22:07 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 22:07 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 22:07 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 22:07 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 22:07 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 22:07 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 22:07 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 22:07 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 22:07 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 22:07 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 22:07 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 22:07 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 22:07 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 22:07 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 22:07 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 22:07 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 22:07 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 22:07 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 22:07 103-65-15.0 1 Styrene ND ug/L 08/02/16 22:07 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 22:07 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 22:07 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 22:07 127-18-45.0 1 Toluene ND ug/L 08/02/16 22:07 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 22:07 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 22:07 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 22:07 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 22:07 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 22:07 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 22:07 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 22:07 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 22:07 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 22:07 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 39 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Sample:WK-GW-TB Lab ID:50150268012 Collected:07/20/16 08:00 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 22:07 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 22:07 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 22:07 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)113 %.08/02/16 22:07 1868-53-784-118 1 4-Bromofluorobenzene (S)97 %.08/02/16 22:07 460-00-479-116 1 Toluene-d8 (S)100 %.08/02/16 22:07 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 40 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343459 EPA 3010 EPA 6010 6010 MET Associated Lab Samples:50150268001, 50150268002, 50150268003, 50150268004, 50150268005, 50150268006, 50150268007, 50150268008, 50150268009, 50150268010, 50150268011, 50150268012 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1590891 Associated Lab Samples:50150268001, 50150268002, 50150268003, 50150268004, 50150268005, 50150268006, 50150268007, 50150268008, 50150268009, 50150268010, 50150268011, 50150268012 Matrix:Water Analyzed Lead ug/L ND 10.0 07/30/16 01:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1590892LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 9821000 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1590893MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150268006 1590894 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead ug/L 1000 87 75-12589 1 20100026011301150 Parameter Units MS Result % Rec Limits Qual% RecConc. 1590895MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150340002 1590896 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead ug/L 1000 97 75-12595 2 201000<1.9 971 949 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 41 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344670 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50150268001, 50150268002, 50150268006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595628 Associated Lab Samples:50150268001, 50150268002, 50150268006 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/02/16 02:06 1,1,1-Trichloroethane ug/L ND 5.0 08/02/16 02:06 1,1,2,2-Tetrachloroethane ug/L ND 5.0 08/02/16 02:06 1,1,2-Trichloroethane ug/L ND 5.0 08/02/16 02:06 1,1-Dichloroethane ug/L ND 5.0 08/02/16 02:06 1,1-Dichloroethene ug/L ND 5.0 08/02/16 02:06 1,1-Dichloropropene ug/L ND 5.0 08/02/16 02:06 1,2,3-Trichlorobenzene ug/L ND 5.0 08/02/16 02:06 1,2,3-Trichloropropane ug/L ND 5.0 08/02/16 02:06 1,2,4-Trichlorobenzene ug/L ND 5.0 08/02/16 02:06 1,2,4-Trimethylbenzene ug/L ND 5.0 08/02/16 02:06 1,2-Dibromoethane (EDB)ug/L ND 5.0 08/02/16 02:06 1,2-Dichlorobenzene ug/L ND 5.0 08/02/16 02:06 1,2-Dichloroethane ug/L ND 5.0 08/02/16 02:06 1,2-Dichloropropane ug/L ND 5.0 08/02/16 02:06 1,3,5-Trimethylbenzene ug/L ND 5.0 08/02/16 02:06 1,3-Dichlorobenzene ug/L ND 5.0 08/02/16 02:06 1,3-Dichloropropane ug/L ND 5.0 08/02/16 02:06 1,4-Dichlorobenzene ug/L ND 5.0 08/02/16 02:06 2,2-Dichloropropane ug/L ND 5.0 08/02/16 02:06 2-Butanone (MEK)ug/L ND 25.0 08/02/16 02:06 2-Chlorotoluene ug/L ND 5.0 08/02/16 02:06 2-Hexanone ug/L ND 25.0 08/02/16 02:06 4-Chlorotoluene ug/L ND 5.0 08/02/16 02:06 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 08/02/16 02:06 Acetone ug/L ND 100 08/02/16 02:06 Acrolein ug/L ND 50.0 08/02/16 02:06 Acrylonitrile ug/L ND 100 08/02/16 02:06 Benzene ug/L ND 5.0 08/02/16 02:06 Bromobenzene ug/L ND 5.0 08/02/16 02:06 Bromochloromethane ug/L ND 5.0 08/02/16 02:06 Bromodichloromethane ug/L ND 5.0 08/02/16 02:06 Bromoform ug/L ND 5.0 08/02/16 02:06 Bromomethane ug/L ND 5.0 08/02/16 02:06 Carbon disulfide ug/L ND 10.0 08/02/16 02:06 Carbon tetrachloride ug/L ND 5.0 08/02/16 02:06 Chlorobenzene ug/L ND 5.0 08/02/16 02:06 Chloroethane ug/L ND 5.0 08/02/16 02:06 Chloroform ug/L ND 5.0 08/02/16 02:06 Chloromethane ug/L ND 5.0 08/02/16 02:06 cis-1,2-Dichloroethene ug/L ND 5.0 08/02/16 02:06 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 42 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595628 Associated Lab Samples:50150268001, 50150268002, 50150268006 Matrix:Water Analyzed cis-1,3-Dichloropropene ug/L ND 5.0 08/02/16 02:06 Dibromochloromethane ug/L ND 5.0 08/02/16 02:06 Dibromomethane ug/L ND 5.0 08/02/16 02:06 Dichlorodifluoromethane ug/L ND 5.0 08/02/16 02:06 Ethyl methacrylate ug/L ND 100 08/02/16 02:06 Ethylbenzene ug/L ND 5.0 08/02/16 02:06 Hexachloro-1,3-butadiene ug/L ND 5.0 08/02/16 02:06 Iodomethane ug/L ND 10.0 08/02/16 02:06 Isopropylbenzene (Cumene)ug/L ND 5.0 08/02/16 02:06 Methyl-tert-butyl ether ug/L ND 4.0 08/02/16 02:06 Methylene Chloride ug/L ND 5.0 08/02/16 02:06 n-Butylbenzene ug/L ND 5.0 08/02/16 02:06 n-Hexane ug/L ND 5.0 08/02/16 02:06 n-Propylbenzene ug/L ND 5.0 08/02/16 02:06 Naphthalene ug/L ND 5.0 08/02/16 02:06 p-Isopropyltoluene ug/L ND 5.0 08/02/16 02:06 sec-Butylbenzene ug/L ND 5.0 08/02/16 02:06 Styrene ug/L ND 5.0 08/02/16 02:06 tert-Butylbenzene ug/L ND 5.0 08/02/16 02:06 Tetrachloroethene ug/L ND 5.0 08/02/16 02:06 Toluene ug/L ND 5.0 08/02/16 02:06 trans-1,2-Dichloroethene ug/L ND 5.0 08/02/16 02:06 trans-1,3-Dichloropropene ug/L ND 5.0 08/02/16 02:06 trans-1,4-Dichloro-2-butene ug/L ND 100 08/02/16 02:06 Trichloroethene ug/L ND 5.0 08/02/16 02:06 Trichlorofluoromethane ug/L ND 5.0 08/02/16 02:06 Vinyl acetate ug/L ND 50.0 08/02/16 02:06 Vinyl chloride ug/L ND 2.0 08/02/16 02:06 Xylene (Total)ug/L ND 10.0 08/02/16 02:06 4-Bromofluorobenzene (S)%.100 79-116 08/02/16 02:06 Dibromofluoromethane (S)%.107 84-118 08/02/16 02:06 Toluene-d8 (S)%.99 86-110 08/02/16 02:06 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595629LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1-Trichloroethane ug/L 52.150 104 72-123 1,1,2,2-Tetrachloroethane ug/L 46.150 92 72-124 1,1-Dichloroethene ug/L 51.750 103 69-127 1,2,4-Trimethylbenzene ug/L 45.750 91 73-125 1,2-Dichloropropane ug/L 45.950 92 77-124 Benzene ug/L 47.950 96 76-122 Chlorobenzene ug/L 45.450 91 76-118 Chloroform ug/L 46.150 92 70-119 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 43 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595629LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 50.350 101 74-120 Ethylbenzene ug/L 47.250 94 75-123 Isopropylbenzene (Cumene)ug/L 47.950 96 84-134 Methyl-tert-butyl ether ug/L 50.750 101 65-131 Naphthalene ug/L 42.950 86 65-134 Tetrachloroethene ug/L 49.350 99 69-119 Toluene ug/L 45.950 92 74-122 trans-1,2-Dichloroethene ug/L 50.650 101 72-122 Trichloroethene ug/L 48.750 97 75-123 Vinyl chloride ug/L 54.050 108 61-147 Xylene (Total)ug/L 141150 94 75-127 4-Bromofluorobenzene (S)%.100 79-116 Dibromofluoromethane (S)%.99 84-118 Toluene-d8 (S)%.97 86-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1595630MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150268006 1595631 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1-Trichloroethane ug/L 50 100 51-140106 5 2050ND50.2 52.9 1,1,2,2-Tetrachloroethane ug/L 50 84 49-13889 7 2050ND41.8 44.7 1,1-Dichloroethene ug/L 50 105 51-144103 2 2050ND52.5 51.4 1,2,4-Trimethylbenzene ug/L 50 88 32-14392 3 2050ND44.2 45.8 1,2-Dichloropropane ug/L 50 94 56-13890 4 2050ND46.9 45.1 Benzene ug/L 50 91 51-14092 1 2050ND45.7 46.1 Chlorobenzene ug/L 50 87 45-13891 4 2050ND43.6 45.3 Chloroform ug/L 50 90 50-13592 2 2050ND44.9 45.9 cis-1,2-Dichloroethene ug/L 50 100 43-144100 0 2050ND50.1 50.2 Ethylbenzene ug/L 50 89 36-14691 2 2050ND44.5 45.5 Isopropylbenzene (Cumene)ug/L 50 92 43-15991 1 2050ND45.8 45.5 Methyl-tert-butyl ether ug/L 50 103 43-14696 7 2050ND51.4 47.9 Naphthalene ug/L 50 75 38-14181 8 2050ND37.6 40.7 Tetrachloroethene ug/L 50 90 38-13994 4 2050ND45.2 47.0 Toluene ug/L 50 88 44-14090 2 2050ND44.4 45.2 trans-1,2-Dichloroethene ug/L 50 102 50-13994 8 2050ND50.8 46.9 Trichloroethene ug/L 50 99 44-14696 3 2050ND49.7 48.0 Vinyl chloride ug/L 50 105 43-166108 2 2050ND52.7 53.9 Xylene (Total)ug/L 150 88 35-14690 3 20150ND132135 4-Bromofluorobenzene (S)%.99 79-116101 Dibromofluoromethane (S)%.98 84-118103 Toluene-d8 (S)%.98 86-11099 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 44 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344917 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50150268003, 50150268004, 50150268005, 50150268007, 50150268008, 50150268009, 50150268010, 50150268011, 50150268012 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596583 Associated Lab Samples:50150268003, 50150268004, 50150268005, 50150268007, 50150268008, 50150268009, 50150268010, 50150268011, 50150268012 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/02/16 14:35 1,1,1-Trichloroethane ug/L ND 5.0 08/02/16 14:35 1,1,2,2-Tetrachloroethane ug/L ND 5.0 08/02/16 14:35 1,1,2-Trichloroethane ug/L ND 5.0 08/02/16 14:35 1,1-Dichloroethane ug/L ND 5.0 08/02/16 14:35 1,1-Dichloroethene ug/L ND 5.0 08/02/16 14:35 1,1-Dichloropropene ug/L ND 5.0 08/02/16 14:35 1,2,3-Trichlorobenzene ug/L ND 5.0 08/02/16 14:35 1,2,3-Trichloropropane ug/L ND 5.0 08/02/16 14:35 1,2,4-Trichlorobenzene ug/L ND 5.0 08/02/16 14:35 1,2,4-Trimethylbenzene ug/L ND 5.0 08/02/16 14:35 1,2-Dibromoethane (EDB)ug/L ND 5.0 08/02/16 14:35 1,2-Dichlorobenzene ug/L ND 5.0 08/02/16 14:35 1,2-Dichloroethane ug/L ND 5.0 08/02/16 14:35 1,2-Dichloropropane ug/L ND 5.0 08/02/16 14:35 1,3,5-Trimethylbenzene ug/L ND 5.0 08/02/16 14:35 1,3-Dichlorobenzene ug/L ND 5.0 08/02/16 14:35 1,3-Dichloropropane ug/L ND 5.0 08/02/16 14:35 1,4-Dichlorobenzene ug/L ND 5.0 08/02/16 14:35 2,2-Dichloropropane ug/L ND 5.0 08/02/16 14:35 2-Butanone (MEK)ug/L ND 25.0 08/02/16 14:35 2-Chlorotoluene ug/L ND 5.0 08/02/16 14:35 2-Hexanone ug/L ND 25.0 08/02/16 14:35 4-Chlorotoluene ug/L ND 5.0 08/02/16 14:35 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 08/02/16 14:35 Acetone ug/L ND 100 08/02/16 14:35 Acrolein ug/L ND 50.0 08/02/16 14:35 Acrylonitrile ug/L ND 100 08/02/16 14:35 Benzene ug/L ND 5.0 08/02/16 14:35 Bromobenzene ug/L ND 5.0 08/02/16 14:35 Bromochloromethane ug/L ND 5.0 08/02/16 14:35 Bromodichloromethane ug/L ND 5.0 08/02/16 14:35 Bromoform ug/L ND 5.0 08/02/16 14:35 Bromomethane ug/L ND 5.0 08/02/16 14:35 Carbon disulfide ug/L ND 10.0 08/02/16 14:35 Carbon tetrachloride ug/L ND 5.0 08/02/16 14:35 Chlorobenzene ug/L ND 5.0 08/02/16 14:35 Chloroethane ug/L ND 5.0 08/02/16 14:35 Chloroform ug/L ND 5.0 08/02/16 14:35 Chloromethane ug/L ND 5.0 08/02/16 14:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 45 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596583 Associated Lab Samples:50150268003, 50150268004, 50150268005, 50150268007, 50150268008, 50150268009, 50150268010, 50150268011, 50150268012 Matrix:Water Analyzed cis-1,2-Dichloroethene ug/L ND 5.0 08/02/16 14:35 cis-1,3-Dichloropropene ug/L ND 5.0 08/02/16 14:35 Dibromochloromethane ug/L ND 5.0 08/02/16 14:35 Dibromomethane ug/L ND 5.0 08/02/16 14:35 Dichlorodifluoromethane ug/L ND 5.0 08/02/16 14:35 Ethyl methacrylate ug/L ND 100 08/02/16 14:35 Ethylbenzene ug/L ND 5.0 08/02/16 14:35 Hexachloro-1,3-butadiene ug/L ND 5.0 08/02/16 14:35 Iodomethane ug/L ND 10.0 08/02/16 14:35 Isopropylbenzene (Cumene)ug/L ND 5.0 08/02/16 14:35 Methyl-tert-butyl ether ug/L ND 4.0 08/02/16 14:35 Methylene Chloride ug/L ND 5.0 08/02/16 14:35 n-Butylbenzene ug/L ND 5.0 08/02/16 14:35 n-Hexane ug/L ND 5.0 08/02/16 14:35 n-Propylbenzene ug/L ND 5.0 08/02/16 14:35 Naphthalene ug/L ND 5.0 08/02/16 14:35 p-Isopropyltoluene ug/L ND 5.0 08/02/16 14:35 sec-Butylbenzene ug/L ND 5.0 08/02/16 14:35 Styrene ug/L ND 5.0 08/02/16 14:35 tert-Butylbenzene ug/L ND 5.0 08/02/16 14:35 Tetrachloroethene ug/L ND 5.0 08/02/16 14:35 Toluene ug/L ND 5.0 08/02/16 14:35 trans-1,2-Dichloroethene ug/L ND 5.0 08/02/16 14:35 trans-1,3-Dichloropropene ug/L ND 5.0 08/02/16 14:35 trans-1,4-Dichloro-2-butene ug/L ND 100 08/02/16 14:35 Trichloroethene ug/L ND 5.0 08/02/16 14:35 Trichlorofluoromethane ug/L ND 5.0 08/02/16 14:35 Vinyl acetate ug/L ND 50.0 08/02/16 14:35 Vinyl chloride ug/L ND 2.0 08/02/16 14:35 Xylene (Total)ug/L ND 10.0 08/02/16 14:35 4-Bromofluorobenzene (S)%.98 79-116 08/02/16 14:35 Dibromofluoromethane (S)%.107 84-118 08/02/16 14:35 Toluene-d8 (S)%.100 86-110 08/02/16 14:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596584LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.950 102 74-130 1,1,1-Trichloroethane ug/L 55.150 110 72-123 1,1,2,2-Tetrachloroethane ug/L 48.050 96 72-124 1,1,2-Trichloroethane ug/L 49.150 98 75-125 1,1-Dichloroethane ug/L 52.050 104 70-120 1,1-Dichloroethene ug/L 56.350 113 69-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 46 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596584LABORATORY CONTROL SAMPLE: LCSSpike 1,1-Dichloropropene ug/L 56.250 112 81-129 1,2,3-Trichlorobenzene ug/L 50.350 101 71-130 1,2,3-Trichloropropane ug/L 51.450 103 77-127 1,2,4-Trichlorobenzene ug/L 49.250 98 66-126 1,2,4-Trimethylbenzene ug/L 49.250 98 73-125 1,2-Dibromoethane (EDB)ug/L 50.250 100 76-125 1,2-Dichlorobenzene ug/L 47.950 96 77-122 1,2-Dichloroethane ug/L 54.250 108 70-123 1,2-Dichloropropane ug/L 50.450 101 77-124 1,3,5-Trimethylbenzene ug/L 50.650 101 75-124 1,3-Dichlorobenzene ug/L 48.750 97 76-124 1,3-Dichloropropane ug/L 48.550 97 77-123 1,4-Dichlorobenzene ug/L 49.150 98 75-117 2,2-Dichloropropane ug/L 55.650 111 44-147 2-Butanone (MEK)ug/L 244250 98 60-135 2-Chlorotoluene ug/L 48.550 97 75-124 2-Hexanone ug/L 245250 98 65-139 4-Chlorotoluene ug/L 47.050 94 75-124 4-Methyl-2-pentanone (MIBK)ug/L 246250 99 66-134 Acetone ug/L 244250 98 47-144 Acrolein ug/L 15001000 150 31-200 Acrylonitrile ug/L 198200 99 64-133 Benzene ug/L 48.850 98 76-122 Bromobenzene ug/L 41.950 84 75-117 Bromochloromethane ug/L 47.850 96 74-134 Bromodichloromethane ug/L 51.250 102 71-124 Bromoform ug/L 50.150 100 60-125 Bromomethane ug/L 65.150 130 23-194 Carbon disulfide ug/L 48.250 96 63-130 Carbon tetrachloride ug/L 58.750 117 73-133 Chlorobenzene ug/L 49.150 98 76-118 Chloroethane ug/L 50.050 100 50-147 Chloroform ug/L 49.350 99 70-119 Chloromethane ug/L 47.350 95 52-136 cis-1,2-Dichloroethene ug/L 51.650 103 74-120 cis-1,3-Dichloropropene ug/L 51.550 103 71-134 Dibromochloromethane ug/L 49.550 99 73-127 Dibromomethane ug/L 53.250 106 75-124 Dichlorodifluoromethane ug/L 62.250 124 39-166 Ethyl methacrylate ug/L 193200 96 73-136 Ethylbenzene ug/L 48.150 96 75-123 Hexachloro-1,3-butadiene ug/L 51.050 102 70-125 Iodomethane ug/L 109100 109 56-142 Isopropylbenzene (Cumene)ug/L 49.250 98 84-134 Methyl-tert-butyl ether ug/L 55.550 111 65-131 Methylene Chloride ug/L 48.350 97 66-130 n-Butylbenzene ug/L 49.450 99 70-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 47 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596584LABORATORY CONTROL SAMPLE: LCSSpike n-Hexane ug/L 55.450 111 64-131 n-Propylbenzene ug/L 49.050 98 78-131 Naphthalene ug/L 48.950 98 65-134 p-Isopropyltoluene ug/L 49.750 99 75-124 sec-Butylbenzene ug/L 48.350 97 83-135 Styrene ug/L 48.150 96 78-128 tert-Butylbenzene ug/L 49.250 98 62-114 Tetrachloroethene ug/L 52.950 106 69-119 Toluene ug/L 47.150 94 74-122 trans-1,2-Dichloroethene ug/L 56.650 113 72-122 trans-1,3-Dichloropropene ug/L 53.050 106 66-135 trans-1,4-Dichloro-2-butene ug/L 214200 107 39-153 Trichloroethene ug/L 52.450 105 75-123 Trichlorofluoromethane ug/L 63.450 127 58-148 Vinyl acetate ug/L 220200 110 67-154 Vinyl chloride ug/L 49.750 99 61-147 Xylene (Total)ug/L 147150 98 75-127 4-Bromofluorobenzene (S)%.102 79-116 Dibromofluoromethane (S)%.102 84-118 Toluene-d8 (S)%.100 86-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1596585MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150219001 1596586 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 50 104 44-142102 2 2050ND51.9 50.9 1,1,1-Trichloroethane ug/L 50 115 51-140115 1 2050ND57.3 57.6 1,1,2,2-Tetrachloroethane ug/L 50 91 49-13892 1 2050ND45.7 45.9 1,1,2-Trichloroethane ug/L 50 95 51-13898 3 2050ND47.7 49.0 1,1-Dichloroethane ug/L 50 101 48-137103 1 2050ND50.6 51.3 1,1-Dichloroethene ug/L 50 108 51-144111 3 2050ND53.8 55.4 1,1-Dichloropropene ug/L 50 109 54-150114 5 2050ND54.3 57.2 1,2,3-Trichlorobenzene ug/L 50 98 32-14092 7 2050ND48.9 45.8 1,2,3-Trichloropropane ug/L 50 109 51-139104 5 2050ND54.4 51.8 1,2,4-Trichlorobenzene ug/L 50 96 27-13492 4 2050ND48.1 46.2 1,2,4-Trimethylbenzene ug/L 50 97 32-14395 2 2050ND48.6 47.7 1,2-Dibromoethane (EDB)ug/L 50 98 52-13496 1 2050ND48.9 48.1 1,2-Dichlorobenzene ug/L 50 97 38-13894 3 2050ND48.4 46.8 1,2-Dichloroethane ug/L 50 108 44-144112 4 2050ND54.0 56.2 1,2-Dichloropropane ug/L 50 99 56-138106 6 2050ND49.7 53.0 1,3,5-Trimethylbenzene ug/L 50 95 28-14693 2 2050ND47.5 46.7 1,3-Dichlorobenzene ug/L 50 99 36-13994 5 2050ND49.3 47.0 1,3-Dichloropropane ug/L 50 99 54-13796 3 2050ND49.5 48.0 1,4-Dichlorobenzene ug/L 50 95 34-13494 1 2050ND47.4 47.0 2,2-Dichloropropane ug/L 50 104 20-142107 2 2050ND52.2 53.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 48 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596585MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150219001 1596586 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 2-Butanone (MEK)ug/L 250 99 44-142110 11 20250ND247275 2-Chlorotoluene ug/L 50 95 36-14394 1 2050ND47.6 46.9 2-Hexanone ug/L 250 92 43-15089 3 20250ND229222 4-Chlorotoluene ug/L 50 92 34-14388 5 2050ND46.2 44.1 4-Methyl-2-pentanone (MIBK) ug/L 250 90 46-14390 0 20250ND224224 Acetone ug/L 250 90 33-15089 1 20250ND232230 Acrolein ug/L 1000 128 32-200130 2 201000ND12801300 Acrylonitrile ug/L 200 95 47-14391 4 20200ND190182 Benzene ug/L 50 96 51-14098 2 2050ND48.2 49.2 Bromobenzene ug/L 50 81 41-13485 4 2050ND40.7 42.5 Bromochloromethane ug/L 50 96 53-148103 7 2050ND48.0 51.3 Bromodichloromethane ug/L 50 105 46-137108 3 2050ND52.3 53.9 Bromoform ug/L 50 100 36-12796 4 2050ND50.0 47.9 Bromomethane ug/L 50 129 10-188133 3 2050ND64.7 66.5 Carbon disulfide ug/L 50 93 35-14896 4 2050ND46.3 48.0 Carbon tetrachloride ug/L 50 116 45-151121 4 2050ND58.0 60.7 Chlorobenzene ug/L 50 98 45-13898 0 2050ND49.0 48.8 Chloroethane ug/L 50 102 33-164105 3 2050ND51.0 52.5 Chloroform ug/L 50 98 50-135104 6 2050ND49.2 52.2 Chloromethane ug/L 50 87 38-14689 2 2050ND43.7 44.7 cis-1,2-Dichloroethene ug/L 50 99 43-144101 2 2050ND49.7 50.5 cis-1,3-Dichloropropene ug/L 50 98 42-136102 4 2050ND48.9 50.8 Dibromochloromethane ug/L 50 99 45-136100 1 2050ND49.6 49.9 Dibromomethane ug/L 50 107 51-139105 2 2050ND53.5 52.7 Dichlorodifluoromethane ug/L 50 124 29-174124 0 2050ND62.1 61.9 Ethyl methacrylate ug/L 200 94 44-15090 4 20200ND187180 Ethylbenzene ug/L 50 93 36-14694 1 2050ND46.6 47.1 Hexachloro-1,3-butadiene ug/L 50 101 14-15098 3 2050ND50.4 49.0 Iodomethane ug/L 100 108 28-153105 2 20100ND108105 Isopropylbenzene (Cumene)ug/L 50 95 43-15994 1 2050ND47.3 46.8 Methyl-tert-butyl ether ug/L 50 104 43-146103 1 2050ND51.8 51.4 Methylene Chloride ug/L 50 95 48-14097 1 2050ND50.3 51.0 n-Butylbenzene ug/L 50 97 16-15294 3 2050ND48.3 47.1 n-Hexane ug/L 50 101 40-144105 4 2050ND50.6 52.4 n-Propylbenzene ug/L 50 99 28-15797 2 2050ND49.3 48.4 Naphthalene ug/L 50 94 38-14188 7 2050ND47.1 44.0 p-Isopropyltoluene ug/L 50 97 21-15197 1 2050ND48.7 48.3 sec-Butylbenzene ug/L 50 98 27-16596 2 2050ND49.2 48.0 Styrene ug/L 50 90 31-14892 2 2050ND44.8 45.8 tert-Butylbenzene ug/L 50 100 24-13196 4 2050ND49.8 47.9 Tetrachloroethene ug/L 50 100 38-139103 3 2050ND50.1 51.5 Toluene ug/L 50 88 44-14095 8 2050ND44.1 47.9 trans-1,2-Dichloroethene ug/L 50 104 50-139106 2 2050ND52.1 52.9 trans-1,3-Dichloropropene ug/L 50 103 37-138100 3 2050ND51.6 49.9 trans-1,4-Dichloro-2-butene ug/L 200 97 10-15798 1 20200ND194196 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 49 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596585MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150219001 1596586 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Trichloroethene ug/L 50 101 44-146105 4 2050ND50.6 52.5 Trichlorofluoromethane ug/L 50 117 41-164126 7 2050ND58.7 63.2 Vinyl acetate ug/L 200 87 15-14685 2 20200ND173170 Vinyl chloride ug/L 50 99 43-166103 4 2050ND49.4 51.6 Xylene (Total)ug/L 150 93 35-14696 3 20150ND140143 4-Bromofluorobenzene (S)%.102 79-116103 Dibromofluoromethane (S)%.108 84-118108 Toluene-d8 (S)%.97 86-110101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 50 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343428 EPA 3510 EPA 8270 by SIM LVE 8270 Water PAH LV by SIM MSSV Associated Lab Samples:50150268001, 50150268002, 50150268004, 50150268005, 50150268007, 50150268008, 50150268012 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1590726 Associated Lab Samples:50150268001, 50150268002, 50150268004, 50150268005, 50150268007, 50150268008, 50150268012 Matrix:Water Analyzed 1-Methylnaphthalene ug/L ND 1.0 N207/26/16 01:45 2-Methylnaphthalene ug/L ND 1.0 07/26/16 01:45 Acenaphthene ug/L ND 1.0 07/26/16 01:45 Acenaphthylene ug/L ND 1.0 07/26/16 01:45 Anthracene ug/L ND 0.10 07/26/16 01:45 Benzo(a)anthracene ug/L ND 0.10 07/26/16 01:45 Benzo(a)pyrene ug/L ND 0.10 07/26/16 01:45 Benzo(b)fluoranthene ug/L ND 0.10 07/26/16 01:45 Benzo(g,h,i)perylene ug/L ND 0.10 07/26/16 01:45 Benzo(k)fluoranthene ug/L ND 0.10 07/26/16 01:45 Chrysene ug/L ND 0.50 07/26/16 01:45 Dibenz(a,h)anthracene ug/L ND 0.10 07/26/16 01:45 Fluoranthene ug/L ND 1.0 07/26/16 01:45 Fluorene ug/L ND 1.0 07/26/16 01:45 Indeno(1,2,3-cd)pyrene ug/L ND 0.10 07/26/16 01:45 Naphthalene ug/L ND 1.0 07/26/16 01:45 Phenanthrene ug/L ND 1.0 07/26/16 01:45 Pyrene ug/L ND 1.0 07/26/16 01:45 2-Fluorobiphenyl (S)%.73 18-117 07/26/16 01:45 p-Terphenyl-d14 (S)%.79 10-112 07/26/16 01:45 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1590727LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene ug/L 7.4 N2107435-115 2-Methylnaphthalene ug/L 7.310 73 25-120 Acenaphthene ug/L 7.910 79 37-129 Acenaphthylene ug/L 8.210 82 36-139 Anthracene ug/L 7.910 79 43-147 Benzo(a)anthracene ug/L 7.910 79 49-149 Benzo(a)pyrene ug/L 7.210 72 28-150 Benzo(b)fluoranthene ug/L 5.810 58 35-147 Benzo(g,h,i)perylene ug/L 6.310 63 15-133 Benzo(k)fluoranthene ug/L 7.510 75 24-149 Chrysene ug/L 7.410 74 45-139 Dibenz(a,h)anthracene ug/L 6.210 62 14-139 Fluoranthene ug/L 7.810 78 46-166 Fluorene ug/L 7.810 78 38-138 Indeno(1,2,3-cd)pyrene ug/L 6.310 63 17-139 Naphthalene ug/L 7.510 75 29-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 51 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1590727LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene ug/L 8.510 85 48-145 Pyrene ug/L 7.910 79 48-152 2-Fluorobiphenyl (S)%.73 18-117 p-Terphenyl-d14 (S)%.64 10-112 Parameter Units MS Result % Rec Limits Qual% RecConc. 1590728MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150253007 1590729 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2106416-12174 14 2010ND6.4 7.4 2-Methylnaphthalene ug/L 10 62 11-12273 15 2010ND6.3 7.3 Acenaphthene ug/L 10 69 14-13779 13 2010ND6.9 7.9 Acenaphthylene ug/L 10 69 17-14184 20 2010ND6.9 8.4 Anthracene ug/L R1106622-14593 34 2010ND6.6 9.3 Benzo(a)anthracene ug/L R1107016-12891 27 2010ND7.0 9.1 Benzo(a)pyrene ug/L R1105910-9780 30 2010ND5.9 8.0 Benzo(b)fluoranthene ug/L R1104910-10377 44 2010ND4.9 7.7 Benzo(g,h,i)perylene ug/L R1104810-7066 32 2010ND4.8 6.6 Benzo(k)fluoranthene ug/L 10 58 10-9569 17 2010ND5.8 6.9 Chrysene ug/L R1106315-11884 28 2010ND6.3 8.4 Dibenz(a,h)anthracene ug/L R1104710-7365 32 2010ND4.7 6.5 Fluoranthene ug/L R1106924-15990 27 2010ND6.9 9.0 Fluorene ug/L 10 68 19-14083 20 2010ND6.8 8.3 Indeno(1,2,3-cd)pyrene ug/L R1104710-7468 37 2010ND4.7 6.8 Naphthalene ug/L 10 64 10-13271 10 2010ND6.4 7.1 Phenanthrene ug/L 10 74 31-14188 17 2010ND7.4 8.8 Pyrene ug/L R1106629-14491 32 2010ND6.6 9.1 2-Fluorobiphenyl (S)%.64 18-11755 p-Terphenyl-d14 (S)%.57 10-11263 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 52 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343474 EPA 3510 EPA 8270 by SIM LVE 8270 Water PAH LV by SIM MSSV Associated Lab Samples:50150268009, 50150268010, 50150268011 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1591013 Associated Lab Samples:50150268009, 50150268010, 50150268011 Matrix:Water Analyzed 1-Methylnaphthalene ug/L ND 1.0 N207/25/16 14:52 2-Methylnaphthalene ug/L ND 1.0 07/25/16 14:52 Acenaphthene ug/L ND 1.0 07/25/16 14:52 Acenaphthylene ug/L ND 1.0 07/25/16 14:52 Anthracene ug/L ND 0.10 07/25/16 14:52 Benzo(a)anthracene ug/L ND 0.10 07/25/16 14:52 Benzo(a)pyrene ug/L ND 0.10 07/25/16 14:52 Benzo(b)fluoranthene ug/L ND 0.10 07/25/16 14:52 Benzo(g,h,i)perylene ug/L ND 0.10 07/25/16 14:52 Benzo(k)fluoranthene ug/L ND 0.10 07/25/16 14:52 Chrysene ug/L ND 0.50 07/25/16 14:52 Dibenz(a,h)anthracene ug/L ND 0.10 07/25/16 14:52 Fluoranthene ug/L ND 1.0 07/25/16 14:52 Fluorene ug/L ND 1.0 07/25/16 14:52 Indeno(1,2,3-cd)pyrene ug/L ND 0.10 07/25/16 14:52 Naphthalene ug/L ND 1.0 07/25/16 14:52 Phenanthrene ug/L ND 1.0 07/25/16 14:52 Pyrene ug/L ND 1.0 07/25/16 14:52 2-Fluorobiphenyl (S)%.44 18-117 07/25/16 14:52 p-Terphenyl-d14 (S)%.56 10-112 07/25/16 14:52 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591014LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene ug/L 4.4 N2104435-115 2-Methylnaphthalene ug/L 4.110 41 25-120 Acenaphthene ug/L 5.710 57 37-129 Acenaphthylene ug/L 5.910 59 36-139 Anthracene ug/L 7.010 70 43-147 Benzo(a)anthracene ug/L 7.510 75 49-149 Benzo(a)pyrene ug/L 7.410 74 28-150 Benzo(b)fluoranthene ug/L 7.510 75 35-147 Benzo(g,h,i)perylene ug/L 6.810 68 15-133 Benzo(k)fluoranthene ug/L 7.110 71 24-149 Chrysene ug/L 7.810 78 45-139 Dibenz(a,h)anthracene ug/L 6.410 64 14-139 Fluoranthene ug/L 7.210 72 46-166 Fluorene ug/L 6.210 62 38-138 Indeno(1,2,3-cd)pyrene ug/L 6.510 65 17-139 Naphthalene ug/L 4.810 48 29-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 53 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591014LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene ug/L 7.210 72 48-145 Pyrene ug/L 7.910 79 48-152 2-Fluorobiphenyl (S)%.56 18-117 p-Terphenyl-d14 (S)%.69 10-112 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591015MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150350003 1591016 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2102216-12123 6 2010ND2.2 2.3 2-Methylnaphthalene ug/L 10 21 11-12222 1 2010ND2.1 2.2 Acenaphthene ug/L 10 27 14-13729 7 2010ND2.7 2.9 Acenaphthylene ug/L 10 32 17-14135 10 2010ND3.2 3.5 Anthracene ug/L 10 48 22-14557 16 2010ND4.8 5.7 Benzo(a)anthracene ug/L 10 54 16-12863 14 2010ND5.4 6.3 Benzo(a)pyrene ug/L R1105010-9762 22 2010ND5.0 6.2 Benzo(b)fluoranthene ug/L R1104210-10357 31 2010ND4.2 5.7 Benzo(g,h,i)perylene ug/L R1104410-7057 25 2010ND4.4 5.7 Benzo(k)fluoranthene ug/L 10 57 10-9565 13 2010ND5.7 6.5 Chrysene ug/L 10 57 15-11868 18 2010ND5.7 6.8 Dibenz(a,h)anthracene ug/L R1104310-7355 25 2010ND4.3 5.5 Fluoranthene ug/L 10 53 24-15964 20 2010ND5.3 6.4 Fluorene ug/L 10 35 19-14039 10 2010ND3.5 3.9 Indeno(1,2,3-cd)pyrene ug/L R1104310-7455 23 2010ND4.3 5.5 Naphthalene ug/L 10 27 10-13230 11 2010ND2.7 3.0 Phenanthrene ug/L 10 47 31-14156 18 2010ND4.7 5.6 Pyrene ug/L 10 56 29-14467 18 2010ND5.6 6.7 2-Fluorobiphenyl (S)%.35 18-11741 p-Terphenyl-d14 (S)%.48 10-11260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 54 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343476 EPA 3510 EPA 8270 by SIM LVE 8270 Water PAH LV by SIM MSSV Associated Lab Samples:50150268006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1591021 Associated Lab Samples:50150268006 Matrix:Water Analyzed 1-Methylnaphthalene ug/L ND 1.0 N207/26/16 08:12 2-Methylnaphthalene ug/L ND 1.0 07/26/16 08:12 Acenaphthene ug/L ND 1.0 07/26/16 08:12 Acenaphthylene ug/L ND 1.0 07/26/16 08:12 Anthracene ug/L ND 0.10 07/26/16 08:12 Benzo(a)anthracene ug/L ND 0.10 07/26/16 08:12 Benzo(a)pyrene ug/L ND 0.10 07/26/16 08:12 Benzo(b)fluoranthene ug/L ND 0.10 07/26/16 08:12 Benzo(g,h,i)perylene ug/L ND 0.10 07/26/16 08:12 Benzo(k)fluoranthene ug/L ND 0.10 07/26/16 08:12 Chrysene ug/L ND 0.50 07/26/16 08:12 Dibenz(a,h)anthracene ug/L ND 0.10 07/26/16 08:12 Fluoranthene ug/L ND 1.0 07/26/16 08:12 Fluorene ug/L ND 1.0 07/26/16 08:12 Indeno(1,2,3-cd)pyrene ug/L ND 0.10 07/26/16 08:12 Naphthalene ug/L ND 1.0 07/26/16 08:12 Phenanthrene ug/L ND 1.0 07/26/16 08:12 Pyrene ug/L ND 1.0 07/26/16 08:12 2-Fluorobiphenyl (S)%.49 18-117 07/26/16 08:12 p-Terphenyl-d14 (S)%.57 10-112 07/26/16 08:12 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591022LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene ug/L 4.5 N2104535-115 2-Methylnaphthalene ug/L 4.210 42 25-120 Acenaphthene ug/L 5.410 54 37-129 Acenaphthylene ug/L 6.010 60 36-139 Anthracene ug/L 6.910 69 43-147 Benzo(a)anthracene ug/L 7.410 74 49-149 Benzo(a)pyrene ug/L 6.910 69 28-150 Benzo(b)fluoranthene ug/L 6.310 63 35-147 Benzo(g,h,i)perylene ug/L 5.910 59 15-133 Benzo(k)fluoranthene ug/L 6.810 68 24-149 Chrysene ug/L 7.510 75 45-139 Dibenz(a,h)anthracene ug/L 5.810 58 14-139 Fluoranthene ug/L 7.210 72 46-166 Fluorene ug/L 6.210 62 38-138 Indeno(1,2,3-cd)pyrene ug/L 5.910 59 17-139 Naphthalene ug/L 4.910 49 29-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 55 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591022LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene ug/L 7.210 72 48-145 Pyrene ug/L 7.610 76 48-152 2-Fluorobiphenyl (S)%.54 18-117 p-Terphenyl-d14 (S)%.66 10-112 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591023MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150268006 1591024 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2102116-12123 7 2010ND2.1 2.3 2-Methylnaphthalene ug/L 10 21 11-12222 4 2010ND2.1 2.2 Acenaphthene ug/L 10 29 14-13731 8 2010ND2.9 3.1 Acenaphthylene ug/L 10 34 17-14137 7 2010ND3.4 3.7 Anthracene ug/L 10 47 22-14554 14 2010ND4.7 5.4 Benzo(a)anthracene ug/L 10 54 16-12858 9 2010ND5.4 5.8 Benzo(a)pyrene ug/L 10 50 10-9755 10 2010ND5.0 5.5 Benzo(b)fluoranthene ug/L 10 46 10-10356 19 2010ND4.6 5.6 Benzo(g,h,i)perylene ug/L 10 40 10-7045 13 2010ND4.0 4.5 Benzo(k)fluoranthene ug/L 10 48 10-9551 5 2010ND4.8 5.1 Chrysene ug/L 10 54 15-11858 7 2010ND5.4 5.8 Dibenz(a,h)anthracene ug/L 10 41 10-7345 8 2010ND4.1 4.5 Fluoranthene ug/L 10 50 24-15960 17 2010ND5.0 6.0 Fluorene ug/L 10 36 19-14041 11 2010ND3.6 4.1 Indeno(1,2,3-cd)pyrene ug/L 10 42 10-7447 10 2010ND4.2 4.7 Naphthalene ug/L 10 26 10-13228 9 2010ND2.6 2.8 Phenanthrene ug/L 10 47 31-14155 15 2010ND4.7 5.5 Pyrene ug/L 10 51 29-14456 10 2010ND5.1 5.6 2-Fluorobiphenyl (S)%.34 18-11740 p-Terphenyl-d14 (S)%.43 10-11248 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591025MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150340002 1591026 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2102416-12128 15 2010<0.057 2.4 2.8 2-Methylnaphthalene ug/L 10 23 11-12227 16 2010<0.065 2.3 2.7 Acenaphthene ug/L 10 33 14-13738 14 2010<0.072 3.3 3.8 Acenaphthylene ug/L 10 38 17-14144 16 2010<0.069 3.8 4.4 Anthracene ug/L 10 49 22-14560 20 2010<0.057 4.9 6.0 Benzo(a)anthracene ug/L 10 57 16-12866 15 2010<0.056 5.7 6.6 Benzo(a)pyrene ug/L 10 53 10-9761 14 2010<0.038 5.3 6.1 Benzo(b)fluoranthene ug/L 10 49 10-10352 6 2010<0.061 4.9 5.2 Benzo(g,h,i)perylene ug/L 10 44 10-7052 18 2010<0.036 4.4 5.2 Benzo(k)fluoranthene ug/L R1105210-9567 25 2010<0.031 5.2 6.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 56 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1591025MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150340002 1591026 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chrysene ug/L 10 58 15-11866 13 2010<0.061 5.8 6.6 Dibenz(a,h)anthracene ug/L 10 45 10-7351 14 2010<0.040 4.5 5.1 Fluoranthene ug/L 10 55 24-15964 14 2010<0.076 5.5 6.4 Fluorene ug/L 10 40 19-14046 14 2010<0.067 4.0 4.6 Indeno(1,2,3-cd)pyrene ug/L 10 45 10-7453 17 2010<0.035 4.5 5.3 Naphthalene ug/L 10 29 10-13234 16 2010<0.078 2.9 3.4 Phenanthrene ug/L 10 51 31-14160 16 2010<0.11 5.1 6.0 Pyrene ug/L 10 55 29-14465 16 2010<0.069 5.5 6.5 2-Fluorobiphenyl (S)%.38 18-11744 p-Terphenyl-d14 (S)%.50 10-11255 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591027MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150369008 1591028 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2102216-12125 12 2010ND2.2 2.5 2-Methylnaphthalene ug/L 10 21 11-12224 15 2010ND2.1 2.4 Acenaphthene ug/L 10 30 14-13733 10 2010ND3.0 3.3 Acenaphthylene ug/L 10 35 17-14139 10 2010ND3.5 3.9 Anthracene ug/L 10 54 22-14559 8 2010ND5.4 5.9 Benzo(a)anthracene ug/L 10 60 16-12866 9 2010ND6.0 6.6 Benzo(a)pyrene ug/L 10 58 10-9762 7 2010ND5.8 6.2 Benzo(b)fluoranthene ug/L 10 49 10-10359 19 2010ND4.9 5.9 Benzo(g,h,i)perylene ug/L 10 49 10-7054 11 2010ND4.9 5.4 Benzo(k)fluoranthene ug/L 10 62 10-9560 3 2010ND6.2 6.0 Chrysene ug/L 10 62 15-11868 10 2010ND6.2 6.8 Dibenz(a,h)anthracene ug/L 10 46 10-7353 13 2010ND4.6 5.3 Fluoranthene ug/L 10 62 24-15965 4 2010ND6.2 6.5 Fluorene ug/L 10 39 19-14042 9 2010ND3.9 4.2 Indeno(1,2,3-cd)pyrene ug/L 10 48 10-7454 11 2010ND4.8 5.4 Naphthalene ug/L 10 28 10-13231 10 2010ND2.8 3.1 Phenanthrene ug/L 10 54 31-14158 7 2010ND5.4 5.8 Pyrene ug/L 10 60 29-14466 10 2010ND6.0 6.6 2-Fluorobiphenyl (S)%.38 18-11741 p-Terphenyl-d14 (S)%.53 10-11254 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 57 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344068 EPA 3510 EPA 8270 by SIM LVE 8270 Water PAH LV by SIM MSSV Associated Lab Samples:50150268003 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1593064 Associated Lab Samples:50150268003 Matrix:Water Analyzed 1-Methylnaphthalene ug/L ND 1.0 N207/28/16 11:30 2-Methylnaphthalene ug/L ND 1.0 07/28/16 11:30 Acenaphthene ug/L ND 1.0 07/28/16 11:30 Acenaphthylene ug/L ND 1.0 07/28/16 11:30 Anthracene ug/L ND 0.10 07/28/16 11:30 Benzo(a)anthracene ug/L ND 0.10 07/28/16 11:30 Benzo(a)pyrene ug/L ND 0.10 07/28/16 11:30 Benzo(b)fluoranthene ug/L ND 0.10 07/28/16 11:30 Benzo(g,h,i)perylene ug/L ND 0.10 07/28/16 11:30 Benzo(k)fluoranthene ug/L ND 0.10 07/28/16 11:30 Chrysene ug/L ND 0.50 07/28/16 11:30 Dibenz(a,h)anthracene ug/L ND 0.10 07/28/16 11:30 Fluoranthene ug/L ND 1.0 07/28/16 11:30 Fluorene ug/L ND 1.0 07/28/16 11:30 Indeno(1,2,3-cd)pyrene ug/L ND 0.10 07/28/16 11:30 Naphthalene ug/L ND 1.0 07/28/16 11:30 Phenanthrene ug/L ND 1.0 07/28/16 11:30 Pyrene ug/L ND 1.0 07/28/16 11:30 2-Fluorobiphenyl (S)%.76 18-117 07/28/16 11:30 p-Terphenyl-d14 (S)%.77 10-112 07/28/16 11:30 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1593065LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene ug/L 7.2 N2107235-115 2-Methylnaphthalene ug/L 7.110 71 25-120 Acenaphthene ug/L 8.110 81 37-129 Acenaphthylene ug/L 8.610 86 36-139 Anthracene ug/L 8.910 89 43-147 Benzo(a)anthracene ug/L 9.710 97 49-149 Benzo(a)pyrene ug/L 9.110 91 28-150 Benzo(b)fluoranthene ug/L 8.010 80 35-147 Benzo(g,h,i)perylene ug/L 7.810 78 15-133 Benzo(k)fluoranthene ug/L 8.610 86 24-149 Chrysene ug/L 9.510 95 45-139 Dibenz(a,h)anthracene ug/L 7.610 76 14-139 Fluoranthene ug/L 10.310 103 46-166 Fluorene ug/L 8.510 85 38-138 Indeno(1,2,3-cd)pyrene ug/L 7.910 79 17-139 Naphthalene ug/L 7.210 72 29-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 58 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1593065LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene ug/L 9.410 94 48-145 Pyrene ug/L 8.710 87 48-152 2-Fluorobiphenyl (S)%.74 18-117 p-Terphenyl-d14 (S)%.81 10-112 Parameter Units MS Result % Rec Limits Qual% RecConc. 1593066MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150571018 1593067 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L M6,N2, R110-5810 16-121-10600 41 201019701390910 2-Methylnaphthalene ug/L M6,R110-7490 11-122-14400 46 2010261018601160 Acenaphthene ug/L M6,R110-215 14-137-404 25 201010584.0 65.1 Acenaphthylene ug/L M6,R11034717-141263 27 2010ND34.7 26.3 Anthracene ug/L M6,R11049722-145343 37 2010ND49.7 34.3 Benzo(a)anthracene ug/L R1102616-12851 48 20101.5 4.1 6.6 Benzo(a)pyrene ug/L R1101910-9734 47 2010ND2.4 3.9 Benzo(b)fluoranthene ug/L R1101810-10331 40 2010ND2.6 3.9 Benzo(g,h,i)perylene ug/L R1102410-7038 46 2010ND2.4 3.8 Benzo(k)fluoranthene ug/L R1102110-9538 46 2010ND2.7 4.3 Chrysene ug/L 10 19 15-11828 13 2010ND6.5 7.5 Dibenz(a,h)anthracene ug/L R1102010-7335 54 2010ND2.0 3.5 Fluoranthene ug/L M610-48 24-159-72 15 201022.4 17.5 15.1 Fluorene ug/L M610-699 19-140-1000 19 2010244174144 Indeno(1,2,3-cd)pyrene ug/L R1102310-7438 47 2010ND2.3 3.8 Naphthalene ug/L D3,M6, R1 10 -1600 10-132-2510 30 2010510350260 Phenanthrene ug/L M6,R110-2000 31-141-3370 33 2010689488352 Pyrene ug/L M6,R110-128 29-144-351 42 201076.4 63.6 41.3 2-Fluorobiphenyl (S)%.36 18-11758 p-Terphenyl-d14 (S)%.33 10-11244 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 59 of 64 #=QL# QUALIFIERS Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - IndianapolisPASI-I ANALYTE QUALIFIERS Common Laboratory Contaminant.C9 Sample was diluted due to the presence of high levels of non-target analytes or other matrix interference.D3 Analysis conducted outside the EPA method holding time.H1 Results are from sample aliquot taken from VOA vial with headspace (air bubble greater than 6 mm diameter).HS Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6 The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 Surrogate recovery outside control limits due to matrix interferences (not confirmed by re-analysis).S5 Post-analysis pH measurement indicates insufficient VOA sample preservation.pH REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 60 of 64 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 50150268 204 Roosevelt Rd Walkerton, IN Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 50150268001 343459 344510WK-GW-SB-2 EPA 3010 EPA 6010 50150268002 343459 344510WK-GW-SB-14 EPA 3010 EPA 6010 50150268003 343459 344510WK-GW-SB-1 EPA 3010 EPA 6010 50150268004 343459 344510WK-GW-SB-7 EPA 3010 EPA 6010 50150268005 343459 344510WK-GW-SB-8 EPA 3010 EPA 6010 50150268006 343459 344510WK-GW-FD-1 EPA 3010 EPA 6010 50150268007 343459 344510WK-GW-SB-9 EPA 3010 EPA 6010 50150268008 343459 344510WK-GW-SB-13 EPA 3010 EPA 6010 50150268009 343459 344510WK-GW-SB-4 EPA 3010 EPA 6010 50150268010 343459 344510WK-GW-SB-6 EPA 3010 EPA 6010 50150268011 343459 344510WK-GW-ERB EPA 3010 EPA 6010 50150268012 343459 344510WK-GW-TB EPA 3010 EPA 6010 50150268001 343428 343574WK-GW-SB-2 EPA 3510 EPA 8270 by SIM LVE 50150268002 343428 343574WK-GW-SB-14 EPA 3510 EPA 8270 by SIM LVE 50150268003 344068 344148WK-GW-SB-1 EPA 3510 EPA 8270 by SIM LVE 50150268004 343428 343574WK-GW-SB-7 EPA 3510 EPA 8270 by SIM LVE 50150268005 343428 343574WK-GW-SB-8 EPA 3510 EPA 8270 by SIM LVE 50150268006 343476 343582WK-GW-FD-1 EPA 3510 EPA 8270 by SIM LVE 50150268007 343428 343574WK-GW-SB-9 EPA 3510 EPA 8270 by SIM LVE 50150268008 343428 343574WK-GW-SB-13 EPA 3510 EPA 8270 by SIM LVE 50150268009 343474 343571WK-GW-SB-4 EPA 3510 EPA 8270 by SIM LVE 50150268010 343474 343571WK-GW-SB-6 EPA 3510 EPA 8270 by SIM LVE 50150268011 343474 343571WK-GW-ERB EPA 3510 EPA 8270 by SIM LVE 50150268012 343428 343574WK-GW-TB EPA 3510 EPA 8270 by SIM LVE 50150268001 344670WK-GW-SB-2 EPA 8260 50150268002 344670WK-GW-SB-14 EPA 8260 50150268003 344917WK-GW-SB-1 EPA 8260 50150268004 344917WK-GW-SB-7 EPA 8260 50150268005 344917WK-GW-SB-8 EPA 8260 50150268006 344670WK-GW-FD-1 EPA 8260 50150268007 344917WK-GW-SB-9 EPA 8260 50150268008 344917WK-GW-SB-13 EPA 8260 50150268009 344917WK-GW-SB-4 EPA 8260 50150268010 344917WK-GW-SB-6 EPA 8260 50150268011 344917WK-GW-ERB EPA 8260 50150268012 344917WK-GW-TB EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:07 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. 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