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HomeMy WebLinkAbout214 W Patterson Phase II Rpt Prepared for: City of South Bend Brownfields Coalition 227 West Jefferson Boulevard, 13th Floor South Bend, Indiana 46601 Phase II Environmental Site Assessment Report 214 West Patterson Street Lakeville, Indiana 46536 Symbiont Project No. W150460 September 27, 2016 Prepared for: City of South Bend Brownfields Coalition 227 West Jefferson Boulevard, 13th Floor South Bend, Indiana 46601 Phase II Environmental Site Assessment Report 214 West Patterson Street Lakeville, Indiana 46536 Symbiont Project No. W150460 September 27, 2016 Ryan Eckdale-Dudley, GISP Project Manager Symbiont Nivas R. Vijay, CHMM Project Manager Heartland Environmental Associates, Inc. P:\214 W Patterson Phase II Rpt Symbiont TABLE OF CONTENTS Section Page EXECUTIVE SUMMARY ...................................................................................... i 1.0 INTRODUCTION .................................................................................................. 1 2.0 BACKGROUND INFORMATION ......................................................................... 2 2.1 Site Description/Background .................................................................... 2 2.2 Physical Setting ........................................................................................ 2 2.3 Recognized Environmental Conditions .................................................... 2 2.4 Objective and Scope of Work ................................................................... 2 3.0 METHODS OF INVESTIGATION ........................................................................ 4 3.1 Soil Assessment ....................................................................................... 4 3.2 Groundwater Assessment ........................................................................ 5 4.0 PHASE II ENVIRONMENTAL SITE ASSESSMENT RESULTS .......................... 7 4.1 Soil Conditions ......................................................................................... 7 4.1.1 Field Observations ........................................................................ 7 4.1.2 Laboratory Analytical Results ....................................................... 7 4.2 Groundwater Conditions ........................................................................... 8 4.2.1 Site Hydrogeology ........................................................................ 8 4.2.2 Laboratory Analytical Results ....................................................... 8 5.0 CONCLUSIONS AND RECOMMENDATIONS .................................................... 9 5.1 Conclusions .............................................................................................. 9 5.2 Recommendations ................................................................................. 10 6.0 LIMITATIONS .................................................................................................... 11 7.0 REFERENCES ................................................................................................... 12 TABLES 1 Detected Constituents in Soil, 214 West Patterson Street, Lakeville, Indiana 2 Detected Constituents in Groundwater, 214 West Patterson Street, Lakeville, Indiana 3 Groundwater Level Data, 214 West Patterson Street, Lakeville, Indiana P:\214 W Patterson Phase II Rpt Symbiont TABLE OF CONTENTS (CONTINUED) FIGURES 1 Site Location Map 2 Soil Boring Location Map APPENDICES A Soil Boring Logs B Laboratory Reports P:\214 W Patterson Phase II Rpt Symbiont ACRONYMS AND ABBREVIATIONS AST Aboveground Storage Tank amsl Above Mean Sea Level bgs Below Ground Surface Coalition City of South Bend Brownfields Coalition ESA Environmental Site Assessment EPA United States Environmental Protection Agency GPR Ground Penetrating Radar HEA Heartland Environmental Associates, Inc IDEM Indiana Department of Environmental Management LUST Leaking Underground Storage Tank mg/kg Milligrams per Kilogram MS Matrix Spike MSD Matrix Spike Duplicate PAH Polycyclic Aromatic Hydrocarbon PID Photoionization Detector ppm Parts Per Million Pace Pace Analytical, Indianapolis, IN PVC Polyvinyl Chloride QAPP Quality Assurance Project Plan QA/QC Quality Assurance/Quality Control RCG Remediation Closure Guide REC Recognized Environmental Condition RSL Residential Screening Level RMGSL Residential Migration to Groundwater Screening Levels SAG Site Assessment Grant SAP Sampling and Analysis Plan Site 214 West Patterson Street, South Bend, IN Symbiont Symbiont Science, Engineering and Construction µg/l Micrograms per Liter UST Underground Storage Tank VOC Volatile Organic Compound P:\214 W Patterson Phase II Rpt.doc Symbiont i EXECUTIVE SUMMARY This Phase II Environmental Site Assessment (ESA) Report summarizes the results of an environmental investigation of the property located at 214 West Patterson Street, Lakeville, Indiana (referred to as the “Site” or the “property”) (Figure 1). The Phase II ESA was conducted in accordance with a site-specific Sampling and Analysis Plan prepared by Symbiont and Heartland Environmental Associates, Inc. (Heartland, Symbiont, 2016) and approved by the United States Environmental Protection Agency (EPA). The Phase II ESA was completed under the City of South Bend Brownfields Coalition’s EPA Community- Wide Brownfield Site Assessment Grant. The purpose of the Phase II ESA was to evaluate recognized environmental conditions (RECs) identified in the Phase I Environmental Site Assessment (Heartland, 2015). CONCLUSIONS The following conclusions regarding Site conditions are based on the results of the Phase II ESA. Soil  Volatile organic compounds (VOCs) including: 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene and benzene were detected in one soil sample collected at the Site at concentrations exceeding their respective Indiana Department of Environmental Management (IDEM), Remediation Closure Guide (RCG), Residential Migration to Groundwater Screening Levels (RMGSLs). The presence of VOCs in soil at this location is likely related to the prior Site use of petroleum product aboveground storage tanks (ASTs).  Polycyclic aromatic hydrocarbon (PAH) naphthalene was detected in one soil sample collected at the Site at a concentration exceeding its respective IDEM RCG RMGSL. The presence of naphthalene is likely related to the prior Site use of petroleum product ASTs.  Lead was detected in each of the soil samples collected at the Site. Detected concentrations of lead did not exceed its IDEM RCG RMGSL. Groundwater  VOCs including: 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, benzene and ethylbenzene were detected in one groundwater sample collected at the Site at concentrations exceeding their respective IDEM RCG Residential Screening Levels (RSL). The presence of VOCs in Site groundwater at this location is likely related to the prior Site use of petroleum product ASTs. P:\214 W Patterson Phase II Rpt.doc Symbiont ii  PAHs including: 1-methylnaphthalene, 2-methylnaphthalene and naphthalene were detected one groundwater sample collected at the Site at concentrations exceeding their respective IDEM RCG RSLs. The presence of PAHs in Site groundwater at this location is likely related to the prior Site use of petroleum product ASTs.  Lead was detected in each of the groundwater samples collected at the Site at concentrations exceeding the IDEM RCG RSL. The potential exists, due to the limited lead impacts encountered in soil, that lead impacts in groundwater are a result of elevated turbidity in groundwater samples collected from temporary groundwater piezometers and are not a result of impacts due to historic site usage. RECOMMENDATIONS Based on the results of field observations, and soil and groundwater analytical data, there appears to be impacts to soil and groundwater associated with the REC (former ASTs). This Site is located in a mixed-use residential and commercial area. The Site is provided with municipal water by the Town of Lakeville. Potential exposure pathways to impacted groundwater are limited due to the Site being service by municipal water. However; the extent of groundwater impacts at the Site should be further assessed through additional groundwater sampling. In particular, the area downgradient (south, southwest) of the identified impacts should be further assessed. Interested parties may wish to retain legal counsel in this matter as Symbiont and Heartland are not qualified to provide legal advice. P:\214 W Patterson Phase II Rpt.doc Symbiont 1 Section 1.0 INTRODUCTION This Phase II Environmental Site Assessment (ESA) Report summarizes the results of an environmental investigation of the property located at 214 West Patterson Street, Lakeville, Indiana (herein referred to as the “Site” or “property”). The Phase II ESA was completed in accordance with a site-specific Sampling and Analysis Plan (SAP) prepared by Symbiont (Symbiont, 2016) and approved by the United States Environmental Protection Agency (EPA). The Phase II ESA was completed as part of an EPA Community-Wide Brownfield Site Assessment Grant awarded to the City of South Bend Brownfields Coalition (Coalition) in September 2014 under Cooperative Agreement BF-00E01371. The Site location map is provided as Figure 1. The purpose of the Phase II ESA was to evaluate recognized environmental conditions (RECs) identified in the Phase I ESA (Heartland, 2016). Specifically, the purpose of the assessment was to determine if there is evidence of petroleum product impacts at the Site that constitute a release, or provide sufficient information to render a professional opinion that there is no reasonable basis to suspect the presence of petroleum products at the Site. Supporting documentation is presented in the following appendices:  Appendix A – Soil Boring Logs  Appendix B – Laboratory Reports P:\214 W Patterson Phase II Rpt.doc Symbiont 2 Section 2.0 BACKGROUND INFORMATION 2.1 SITE DESCRIPTION/BACKGROUND The site is located on approximately 4.5-acres situated on one parcel (Parcel # 020-1057-0005). The Site was historically utilized as an agricultural barn used for storage of machining implements and agricultural related items. This barn was constructed in the mid to the late 1930s. The northern portion of the site historically operated at least two aboveground storage tanks (ASTs) for storage of bulk petroleum, which was utilized by neighboring farms for fueling farm machinery. The barn is currently being utilized for the storage of resin, and the central and southern portion of the site remain undeveloped. The property is currently owned by Jeff Ritschard. A site location map is provided as Figure 1. 2.2 PHYSICAL SETTING The Site elevation is approximately 838 feet above mean sea level. The Site is generally flat and gently slopes to the south. 2.3 RECOGNIZED ENVIRONMENTAL CONDITIONS A Phase I ESA conducted in November 2015 (Heartland, 2015), identified the following RECs at the Site. Historical Property Use and Historical Presence of Two Aboveground Storage Tanks  According to historic site documentation and site interviews, the northern portion of the Site operated as a barn used to store agricultural implements. The Site operated at least two ASTs, located directly east of the barn building (Figure 2). The ASTs were utilized for the storage of bulk petroleum products, and were used to serve the local farming community. These ASTs were of unknown size, and operated from at least the 1950s through the 1970s. No record of the removal or disposal of these ASTs was uncovered as part of this Phase I ESA. The Phase I ESA recommended that a Phase II ESA be conducted to assess the Site for the presence of petroleum impacts to soil and/or groundwater based on historic usage of the Site, specifically the ASTs. This report has been prepared to describe field investigation activities and investigation results. Phase II ESA activities were conducted in accordance with the Phase II Sampling and Analysis Plan (SAP) (Symbiont and Heartland, 2016). 2.4 OBJECTIVE AND SCOPE OF WORK The objective of this Phase II ESA was to evaluate the REC identified in the Phase I ESA (Heartland, 2016). Specifically, the purpose of the assessment is to determine if there were petroleum product releases associated with the former ASTs located on the Site. P:\214 W Patterson Phase II Rpt.doc Symbiont 3 Field investigation activities and laboratory analyses were conducted in accordance with the SAP (Symbiont and Heartland 2016) and the Quality Assurance Project Plan (QAPP) (Heartland, 2016). The scope of work for investigation of potential Site soil impacts included:  Sample collection and descriptive logging of soil at three boring locations within the vicinity of the former ASTs.  Field screening of soil samples in each boring using a photoionization detector (PID) for the presence of volatile organic compounds (VOCs).  Soil samples collected in the vicinity of the former AST were submitted to an analytical laboratory for lead, polycyclic aromatic hydrocarbons (PAHs), and VOC analysis.  Field duplicate, trip blank, matrix-spike (MS) and matrix-spike duplicate (MSD) samples were collected and also analyzed in accordance with the SAP and QAPP.  Surveying of boring locations. The scope of work for investigation of potential Site groundwater impacts included:  Completion of all three soil borings as temporary one-inch diameter polyvinyl chloride (PVC) groundwater monitoring wells.  Measurement of water levels and confirmation of the presence/absences of light non- aqueous phase liquids (LNAPL), and development and sampling of temporary wells.  Laboratory analysis of groundwater samples for dissolved lead, PAHs and VOCs. Field duplicate, trip blank, MS and MSD samples were collected and submitted to the laboratory for analysis in accordance with the SAP and QAPP. P:\214 W Patterson Phase II Rpt.doc Symbiont 4 Section 3.0 METHODS OF INVESTIGATION This section summarizes the methods of investigation used to perform the field and laboratory portions of the Phase II ESA. 3.1 SOIL ASSESSMENT Soil Boring Installation Three soil borings were installed using Geoprobe® direct-push drilling techniques. The soil types and observations were described and recorded by an onsite geologist. Soil boring logs are provided in Appendix A. The locations of boreholes are shown in Figure 2. All probe drilling rods and soil sampling equipment were decontaminated prior to arrival onsite and between soil boring locations. Sampling equipment was decontaminated with an Alconox equivalent wash followed by clean tap water or distilled water rinses. Field Screening Soil samples from approximately every one to two-foot interval of subsurface were field screened for the presence of VOCs using a PID. The results were recorded in parts per million (ppm) and are reported on the soil boring logs (Appendix A). Sampling and Laboratory Analysis One soil sample was collected from each soil boring for laboratory analysis. Soil samples for laboratory analyses were collected from immediately above the water table, which was estimated at approximately 7 feet below ground surface (bgs). Soil samples for laboratory analysis were placed directly into laboratory-supplied containers, preserved as appropriate, and immediately placed in a cooler on ice for shipping to Pace Analytical Services, Inc. in Indianapolis, Indiana (Pace) under a chain of custody for analysis. Soil samples were analyzed for lead using EPA Method 6010B, PAHs using EPA Method 8270 SIM and VOCs using EPA Method 8260B. Field duplicate samples were submitted for lead, PAHs and VOCs. Trip blanks were submitted to the laboratory for VOC analysis. In order to ensure that the laboratory’s data precision and accuracy were maintained, soil MS and MSD samples were submitted to the laboratory for analysis. Laboratory reports are provided in Appendix B. Evaluation Criteria Potential environmental impacts to soil were evaluated by comparing the concentrations of the detected constituents with their respective Indiana Department of Environmental Management (IDEM) Remediation Closure Guide (RCG) Residential Migration to Groundwater Screening P:\214 W Patterson Phase II Rpt.doc Symbiont 5 Levels (RMGSLs) and Residential Direct Contact Screening Levels, as issued March 2012 and amended March 2016. 3.2 GROUNDWATER ASSESSMENT Temporary Monitoring Well Installation Temporary monitoring wells constructed of 1-inch diameter schedule 40 polyvinyl chloride blank well casing and 0.010-inch slotted well screens were installed at each of the three soil boring locations. Quartz filter sand was placed in the annular space between the borehole wall and the outside of each screen. The annular space above the filter pack was filled to the ground surface with granular bentonite to serve as a seal to prevent infiltration of surface water runoff into the borings. The locations of the temporary wells provided in Figure 2. Water Level Measurements After the wells were developed and given time to recharge, static groundwater level measurements were collected. The water level recorded at each monitoring well was used to determine the surface elevation of the water table at each well. Measurements were recorded using a Solinist™ water level indicator which was decontaminated between each well. The approximate depth to the water table is presented in Table 3. An oil/water interface probe was used to determine the presence or absence of LNAPL in each of the temporary monitoring wells. LNAPL was not detected in any of the temporary monitoring wells. Sampling and Laboratory Analysis Temporary groundwater monitoring wells were allowed to stabilize following well installation for at least 24-hours prior to sampling. Groundwater samples were collected from each temporary well utilizing dedicated disposable bailers after allowing for the 24-hour stabilization period. Groundwater samples for lead analysis were collected with a disposable bailer and placed into a non-preserved container and filtered by the laboratory prior to analysis. Groundwater samples collected for PAH analysis were collected with a disposable bailer and samples were placed directly into laboratory supplied non-preserved amber glass jars. Groundwater samples collected for VOC analysis were collected with a disposable bailer and samples were placed directly into laboratory-supplied sample jars containing a hydrochloric acid preservative. Samples were then labeled and placed in a cooler on ice for shipping to Pace under a chain of custody for analysis. Groundwater sample analyses included lead, PAHs and VOCs. Field sampling precision and data quality was evaluated through the use of sample duplicates and trip blanks. Field duplicate samples were submitted for lead PAHs and VOCs analysis. Trip blanks were submitted to the laboratory for VOC analysis. Groundwater MS and MSD samples were also submitted to the laboratory for analysis. Laboratory reports are provided in Appendix B. P:\214 W Patterson Phase II Rpt.doc Symbiont 6 Evaluation Criteria Potential environmental impacts to groundwater were evaluated by comparing the concentrations of the detected constituents with their respective IDEM RCG Residential Screening Levels (RSLs), as issued March 2012 and amended March 2016. P:\214 W Patterson Phase II Rpt.doc Symbiont 7 Section 4.0 PHASE II ENVIRONMENTAL SITE ASSESSMENT RESULTS Soil and groundwater sample locations are depicted on Figure 2. Laboratory reports for soil and groundwater are provided in Appendix B and summarized in Tables 1 and 2. Water level measurements are summarized in Table 3. 4.1 SOIL CONDITIONS The following sections describe the results of the Phase II ESA soil investigation. 4.1.1 Field Observations Two borings, SB-1 and SB-3, were drilled to a depth of 16 feet bgs. Soil boring SB-2 was drilled to a depth of approximately 15 feet bgs. All boring locations are capped with approximately 8-inches of topsoil (Appendix A). The Site is generally underlain by discontinuous hard clays, fine sands, coarse sands, and some coarse gravels. The water table is generally encountered in a coarse grained sand that occurs at approximately 6 to 8 feet bgs (Appendix A). VOC were detected using a PID at concentrations exceeding 1.0 ppm in soil samples from boring SB-1. The maximum PID reading in soil samples collected at SB-1 were 885 ppm at approximately 13 feet bgs (Appendix A). 4.1.2 Laboratory Analytical Results Laboratory analytical results for soil samples are summarized in Table 1. Sample results are discussed in the following paragraphs. Lead in Soil Lead was detected in all soil samples collected from each of the soil borings drilled and sampled on Site. Concentrations of lead ranged from 8.9 milligrams per kilogram (mg/kg) in a soil sample collected from 10 to 12 feet bgs from soil boring SB-2 to 10.4 mg/kg in a soil sample collected from 12 to 14 feet bgs from soil boring SB-1 (Table 1; Appendix B). VOCs in Soil VOCs including 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, and benzene were detected in one soil sample collected at the Site. Concentrations of these compounds were 33.8 mg/kg, 12.5 mg/kg, and 0.21 mg/kg, respectively; in a soil sample collected from SB-1 from 12 to 14 feet bgs. The benzene detection of 0.21 was flagged by the laboratory as estimated since the detected value was between the method detection limit and the laboratory reporting limit (Table 1; Appendix B). VOCs were not detected above analytical method detection limits in soil samples collected from borings SB-2 and SB-3 P:\214 W Patterson Phase II Rpt.doc Symbiont 8 PAHs in Soil Naphthalene was detected in one soil sample collected at the Site. The concentration of naphthalene was 0.71 mg/kg in a sample collected at SB-1 from 12 to 14 feet bgs. PAHs were not detected above analytical method detection limits in soil samples collected from borings SB-2 and SB-3 4.2 GROUNDWATER CONDITIONS The following sections describe the results of the groundwater investigation. 4.2.1 Site Hydrogeology Depth to groundwater was measured in Site temporary monitoring wells on July 20, 2016. The Depth to groundwater at the site ranged from approximately 7.42 feet bgs to 9.35 feet bgs. The apparent flow direction of groundwater across the Site is primarily to the south-southwest (Table 3). 4.2.2 Laboratory Analytical Results Laboratory analytical results for groundwater samples are summarized in Table 2. Sample results are discussed in detail in the following paragraphs. Lead in Groundwater Lead was detected in each of the groundwater samples collected at the Site. Concentrations of lead in groundwater ranged from 217 micrograms per liter (µg/l) in a groundwater sample collected from temporary well SB-2 to 2,970 µg/l in a groundwater sample collected from temporary well SB-3 (Table 2). VOCs in Groundwater Multiple VOCs including: 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene,, benzene and ethylbenzene were detected in the groundwater sample collected from temporary monitoring well SB-1 (Table 2; Appendix B). VOCs were not detected above analytical method detection limits in the groundwater samples collected from temporary monitoring wells SB-2 and SB-3. PAHs in Groundwater PAHs including 1-methylnaphthalene, 2-methylnaphthalene and naphthalene were detected in the groundwater sample collected from temporary monitoring well SB-1 (Table 2; Appendix B). PAHs were not detected above analytical method detection limits in the groundwater samples collected from temporary monitoring wells SB-2 and SB-3. P:\214 W Patterson Phase II Rpt.doc Symbiont 9 Section 5.0 CONCLUSIONS AND RECOMMENDATIONS The following paragraphs summarize the conclusions and recommendations of this Phase II ESA. 5.1 CONCLUSIONS Soil  VOCs including: 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene and benzene were detected in one soil sample collected at the Site at concentrations exceeding their respective IDEM RCG RMGSLs. The presence of VOCs in soil at this location is likely related to the prior Site use of petroleum product ASTs.  Naphthalene was detected in one soil sample collected at the Site at a concentration exceeding its respective IDEM RCG RMGSL. The presence of naphthalene is likely related to the prior Site use of petroleum product ASTs.  Lead was detected in each of the soil samples collected at the Site. Detected concentrations of lead did not exceed its IDEM RCG RMGSL. Groundwater  VOCs including: 1,2,4-trimethylbenzene, 1,3,5-trimethylbenzene, benzene and ethylbenzene were detected in one groundwater sample collected at the Site at concentrations exceeding their respective IDEM RGC RSL. The presence of VOCs in Site groundwater at this location is likely related to the prior Site use of petroleum product ASTs.  PAHs including: 1-methylnaphthalene, 2-methylnaphthalene and naphthalene were detected one groundwater sample collected at the Site at concentrations exceeding their respective IDEM RCG RSLs. The presence of PAHs in Site groundwater at this location is likely related to the prior Site use of petroleum product ASTs.  Lead was detected in each of the groundwater samples collected at the Site at concentrations exceeding the IDEM RCG RSL. The potential exists, due to the limited lead impacts encountered in soil, that lead impacts in groundwater are a result of elevated turbidity in groundwater samples collected from temporary groundwater piezometers and are not a result of impacts due to historic site usage. 5.2 RECOMMENDATIONS Based on the results of field observations, and soil and groundwater analytical data, there appears to be impacts to soil and groundwater associated with the REC (former ASTs). This Site is located in a mixed-use residential and commercial area. The Site is provided with municipal water by the Town of Lakeville. Potential exposure pathways to impacted groundwater is limited due to the Site being service by municipal water. However; the extent of P:\214 W Patterson Phase II Rpt.doc Symbiont 10 groundwater impacts at the Site should be further assessed through additional groundwater sampling. In particular, the area downgradient (south, southwest) of the identified impacts should be further assessed. Interested parties may wish to retain legal counsel in this matter as Symbiont and Heartland are not qualified to provide legal advice. P:\214 W Patterson Phase II Rpt.doc Symbiont 11 Section 6.0 LIMITATIONS The Phase II ESA was performed in accordance with generally accepted practices for the environmental consulting profession, undertaking similar studies at the same time and in the same geographical area as the work conducted by Symbiont and Heartland. Symbiont and Heartland observed the degree of care and skill that are generally exercised by the profession under similar circumstances and conditions. No other warranty is expressed or implied. Symbiont and Heartland’s observations, findings, and opinions should not be considered as scientific certainties, but only as opinion based upon our professional judgment concerning the significance of the data gathered during the course of this investigation. Specifically, Symbiont and Heartland cannot represent that the Property contains hazardous or toxic materials or other latent conditions beyond that observed by Symbiont and Heartland during the course of the investigation. Additionally, due to limitations of the investigation process and the necessary use of data furnished by others, Symbiont, Heartland, and its subcontractors cannot assume liability if actual conditions differ from the information presented in this report. P:\214 W Patterson Phase II Rpt.doc Symbiont 12 Section 7.0 REFERENCES Heartland, 2015, Quality Assurance Project Plan, City of South Bend Brownfields Coalition, Community-Wide Brownfields Assessment Project, prepared for The City of South Bend and Coalition Partners, The City of Mishiwaka, and Saint Joseph County, Indiana, February 2015. Heartland, 2015, Phase I Environmental Site Assessment, Jeff Ritschard Vacant Property and Vacant Undeveloped Property, 214 West Patterson Street, Lakeville, Indiana, November 13, 2015. Symbiont, 2016, Sampling and Analysis Plan for Phase II Environmental Site Assessment, 214 West Patterson Street, Lakeville, Indiana 46536, March 23, 2016. TABLES TABLE 1DETECTED CONSTITUENTS IN SOIL214 WEST PATTERSON STREETLAKEVILLE, INDIANAGROUNDWATERRESIDENTIAL (mg/kg)COMMERCIAL/ INDUSTRIAL (mg/kg)EXCAVATION(mg/kg)SOIL MTG RESIDENTIAL (mg/kg)SB-1 12 - 14 7/18/2016 Lead 10.4 400 800 1000 270SB-2 10 - 12 7/18/2016 Lead 8.9 400 800 1000 270SB-3 10 - 12 7/18/2016Lead9.4 400 800 1000 270SB-1 12 - 14 7/18/2016 1,2,4-Trimethylbenzene33.881 220 220 .44SB-1 12 - 14 7/18/2016 1,3,5-Trimethylbenzene12.5180 180 180 3.4SB-1 12 - 14 7/18/2016 Benzene0.21 J17 51 1800 .051SB-1 12 - 14 7/18/2016 Ethylbenzene 8.8 81 250 480 16SB-1 12 - 14 7/18/2016 Isopropylbenzene (Cumene) 1.5 270 270 270 15SB-1 12 - 14 7/18/2016 Naphthalene5.053 170 3100 .11SB-1 12 - 14 7/18/2016 Xylene (Total) 18.0 260 260 260 200SB-1 12 - 14 7/18/2016 n-Hexane 41.9 140 140 140 210SB-1 12 - 14 7/18/2016 n-Propylbenzene 5.4 260 260 260 25SB-1 12 - 14 7/18/2016 p-Isopropyltoluene 0.69 NE NE NE NESB-1 12 - 147/18/2016sec-Butylbenzene0.96 150 150 150 120SB-1 12 - 14 7/18/2016 1-Methylnaphthalene 0.85 250 390 390 1.2SB-1 12 - 14 7/18/2016 2-Methylnaphthalene 1.5 340 3000 6800 3.7SB-1 12 - 14 7/18/2016 Fluorene 0.078 3400 30000 68000 110SB-1 12 - 14 7/18/2016 Naphthalene0.7153 170 3100 .11SB-1 12 - 147/18/2016Phenanthrene0.27 NE NE NE NEIDEM RCG = Indiana Department of Environmental Management, Remediation Closure GuideBOLD =Indicates detected concentration exceeded screening level.bgs = below ground surfacemg/kg = milligrams per kilogramMTG = migration to groundwaterNE =Not establishedJ = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.BORING IDENTIFERVolatile Organic CompoundsPolycyclic Aromatic HydrocarbonsIDEM RCG SCREENING LEVELS, MARCH 2016SOIL EXPOSURE, DIRECT CONTACTRESULT (mg/kg)CONSTITUENTSAMPLE DATESAMPLE DEPTH(feet bgs)1 of 1 TABLE 2DETECTED CONSTITUENTS IN GROUNDWATER214 WEST PATTERSON STREETLAKEVILLE, INDIANAIDEM RCG SCREENING LEVELS, MARCH 2016GROUNDWATERRESIDENTIAL TAP (ug/L)SB-1273015SB-221715SB-32970151,2,4-Trimethylbenzene1050151,3,5-Trimethylbenzene3381201-Methylnaphthalene132112-Methylnaphthalene21936Benzene1185Ethylbenzene769700Isopropylbenzene (Cumene) 49.8 450Naphthalene3271.7Xylene (Total) 1920 10000n-Hexane 138 1500n-Propylbenzene145 6601-Methylnaphthalene30.1112-Methylnaphthalene48.736Anthracene 0.19 1800Naphthalene69.91.7Phenanthrene1.6 NEBOLD =Indicates detected concentration exceeds screening level.IDEM RCG = Indiana Department of Environmental Management, Remediation Closure Guideug/l = micrograms per liter7/20/2016SB-1SB-1LeadBORING/TEMPORARY WELL IDENTIFIERSAMPLE DATE CONSTITUENTRESULT(ug/l)Polycyclic Aromatic HydrocarbonsVolatile Organic Compounds7/20/20167/20/20161 of 1 TABLE 3 GROUNDWATER LEVEL DATA 214 WEST PATTERSON STREET LAKEVILLE, INDIANA TEMPORARY WELL IDENTIFIER TOTAL DEPTH OF WELL (feet below ground surface) DEPTH TO WATER (feet below ground surface) SB-1 11.06 9.35 SB-2 11.87 7.42 SB-3 14.65 8.75 1 of 1 FIGURES SYM810NT APPENDIX A SOIL BORING LOGS Topsoil Clay, dark yellow-brown, 10YR 4/6, dry Clay, very dark yellow-brown, 10YR 3/4, slightly moist Clay, dark olive, 2.5Y 4/4, strong petroleum odor, very moist Clay, gray olive, 5Y 5/2, strong petroleum odor, very moist Clay, brown olive, 2.5Y 4/4, very moist Clay, brown olive, 2.5Y 4/4, strong petroleum odor Medium to coarse sand, yellow-brown, 10YR 4/4, wet Total depth 16-ft, Temporary piezometer set 5 10 15 3.4 4.0 4.0 4.0 0.0 0.0 169 802 569 14.6 885 5.4 SB-1 Jeff Ritschard Property Drilling Contractor 5200-16-06 Geologist John R. Barnhart, L.P.G. Date Drilled 7/18/2016 Boring Diameter 2 Inches 90.65 Geoprobe Static Water Level Lakeville, IN214 West Patterson Street Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\Lakeville Wetlands Phase I ESA\Phase II ESA\Lakeville.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 99.01DrillerChris Chambers 2067 Drill Rig Topsoil Sand, clayey, dark yellow-brown, 10YR 4/4 Sand, clayey, hard, dark yellow-brown, 10YR 4/4, slightly moist Silt, clayey, dark gray, 10YR 4/1 Clay, dark yellow-brown, 10YR 4/4, very moist, sand seam at 10-ft Clay, brown olive, Medium sand, clayey, hard, dark yellow-brown, 10YR 4/4 Medium sand to medium gravel, dark yellow-brown, 10YR 4/4, wet Total depth 15-ft, Piezometer set 5 10 15 2.9 3.5 4.0 4.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 0.1 SB-2 Jeff Ritschard Property Drilling Contractor 5200-16-06 Geologist John R. Barnhart, L.P.G. Date Drilled 7/18/2016 Boring Diameter 2 Inches 92.00 Geoprobe Static Water Level Lakeville, IN214 West Patterson Street Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\Lakeville Wetlands Phase I ESA\Phase II ESA\Lakeville.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.56DrillerChris Chambers 2067 Drill Rig Cinders, topsoil, very loose Silt, clayey, dak yellow-brown, 10YR 4/4, dry Fine to medium sand, dark brown, 10YR 4/4, dry, friable Clay, silty Fine to medium sand, dark yellow-brown, 10YR 4/4, wet Clay, yellow-brown, 10YR 5/4 Clay, blue gray, very moist Medium to coarse sand, abnt pebbles, dark yellow brown, 10YR 4/6 Total depth 16-ft 5 10 15 2.0 4.0 4.0 4.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.1 SB-3 Jeff Ritschard Property Drilling Contractor 5200-16-06 Geologist John R. Barnhart, L.P.G. Date Drilled 7/18/2016 Boring Diameter 2 Inches 90.06 Geoprobe Static Water Level Lakeville, IN214 West Patterson Street Ark Engineering Services Inc. Total Depth of borehole 16 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\Lakeville Wetlands Phase I ESA\Phase II ESA\Lakeville.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.64DrillerChris Chambers 2067 Drill Rig APPENDIX B LABORATORY REPORTS #=CL# August 02, 2016 LIMS USE: FR - GREG WAGGLE LIMS OBJECT ID: 50149912 50149912 Project: Pace Project No.: RE: Mr. Greg Waggle Symbiont 6737 W. Washington St. Suite 3440 Milwaukee, WI 53214 LAKEVILLE Dear Mr. Waggle: Enclosed are the analytical results for sample(s) received by the laboratory on July 19, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Mick Mayse mick.mayse@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 1 of 42 #=CP# CERTIFICATIONS Pace Project No.: Project: 50149912 LAKEVILLE Indiana Certification IDs 7726 Moller Road, Indianapolis, IN 46268 Illinois Certification #: 200074 Indiana Certification #: C-49-06 Kansas/NELAP Certification #:E-10177 Kentucky UST Certification #: 0042 Kentucky WW Certification #:98019 Ohio VAP Certification #: CL-0065 Oklahoma Certification #: 2014-148 Texas Certification #: T104704355-15-9 West Virginia Certification #: 330 Wisconsin Certification #: 999788130 USDA Soil Permit #: P330-10-00128 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 2 of 42 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 50149912 LAKEVILLE Lab ID Sample ID Matrix Date Collected Date Received 50149912001 LV-SB-1(012014)Solid 07/18/16 14:44 07/19/16 09:30 50149912002 LV-SB-2(010012)Solid 07/18/16 15:22 07/19/16 09:30 50149912003 LV-SB-3(010012)Solid 07/18/16 16:12 07/19/16 09:30 50149912004 LV-FD-1 Solid 07/18/16 15:00 07/19/16 09:30 50149912005 TRIP BLANK Water 07/18/16 08:00 07/19/16 09:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 3 of 42 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 50149912 LAKEVILLE Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 50149912001 LV-SB-1(012014)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-ISKK 50149912002 LV-SB-2(010012)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-ISKK 50149912003 LV-SB-3(010012)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-ISKK 50149912004 LV-FD-1 EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-IMDG 50149912005 TRIP BLANK EPA 8260 75 PASI-IDAE REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 4 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-SB-1(012014)Lab ID:50149912001 Collected:07/18/16 14:44 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 10.4 mg/kg 07/26/16 04:32 7439-92-107/23/16 08:201.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/26/16 17:19 83-32-907/22/16 10:390.0058 1 Acenaphthylene ND mg/kg 07/26/16 17:19 208-96-807/22/16 10:390.0058 1 Anthracene ND mg/kg 07/26/16 17:19 120-12-707/22/16 10:390.0058 1 Benzo(a)anthracene ND mg/kg 07/26/16 17:19 56-55-307/22/16 10:390.0058 1 Benzo(a)pyrene ND mg/kg 07/26/16 17:19 50-32-807/22/16 10:390.0058 1 Benzo(b)fluoranthene ND mg/kg 07/26/16 17:19 205-99-207/22/16 10:390.0058 1 Benzo(g,h,i)perylene ND mg/kg 07/26/16 17:19 191-24-207/22/16 10:390.0058 1 Benzo(k)fluoranthene ND mg/kg 07/26/16 17:19 207-08-907/22/16 10:390.0058 1 Chrysene ND mg/kg 07/26/16 17:19 218-01-907/22/16 10:390.0058 1 Dibenz(a,h)anthracene ND mg/kg 07/26/16 17:19 53-70-307/22/16 10:390.0058 1 Fluoranthene ND mg/kg 07/26/16 17:19 206-44-007/22/16 10:390.0058 1 Fluorene 0.078 mg/kg 07/26/16 17:19 86-73-707/22/16 10:390.0058 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/26/16 17:19 193-39-507/22/16 10:390.0058 1 1-Methylnaphthalene 0.85 mg/kg 07/26/16 17:19 90-12-0 N207/22/16 10:390.0058 1 2-Methylnaphthalene 1.5 mg/kg 07/26/16 17:19 91-57-607/22/16 10:390.0058 1 Naphthalene 0.71 mg/kg 07/26/16 17:19 91-20-307/22/16 10:390.0058 1 Phenanthrene 0.27 mg/kg 07/26/16 17:19 85-01-807/22/16 10:390.0058 1 Pyrene ND mg/kg 07/26/16 17:19 129-00-007/22/16 10:390.0058 1 Surrogates 2-Fluorobiphenyl (S)72 %.07/26/16 17:19 321-60-807/22/16 10:3925-121 1 p-Terphenyl-d14 (S)64 %.07/26/16 17:19 1718-51-007/22/16 10:3927-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/28/16 16:02 67-64-110.8 100 Acrolein ND mg/kg 07/28/16 16:02 107-02-810.8 100 Acrylonitrile ND mg/kg 07/28/16 16:02 107-13-110.8 100 Benzene 0.21J mg/kg 07/28/16 16:02 71-43-2 J0.54 100 Bromobenzene ND mg/kg 07/28/16 16:02 108-86-10.54 100 Bromochloromethane ND mg/kg 07/28/16 16:02 74-97-50.54 100 Bromodichloromethane ND mg/kg 07/28/16 16:02 75-27-40.54 100 Bromoform ND mg/kg 07/28/16 16:02 75-25-20.54 100 Bromomethane ND mg/kg 07/28/16 16:02 74-83-90.54 100 2-Butanone (MEK)ND mg/kg 07/28/16 16:02 78-93-32.7 100 n-Butylbenzene ND mg/kg 07/28/16 16:02 104-51-80.54 100 sec-Butylbenzene 0.96 mg/kg 07/28/16 16:02 135-98-80.54 100 tert-Butylbenzene ND mg/kg 07/28/16 16:02 98-06-60.54 100 Carbon disulfide ND mg/kg 07/28/16 16:02 75-15-01.1 100 Carbon tetrachloride ND mg/kg 07/28/16 16:02 56-23-50.54 100 Chlorobenzene ND mg/kg 07/28/16 16:02 108-90-70.54 100 Chloroethane ND mg/kg 07/28/16 16:02 75-00-30.54 100 Chloroform ND mg/kg 07/28/16 16:02 67-66-30.54 100 Chloromethane ND mg/kg 07/28/16 16:02 74-87-30.54 100 2-Chlorotoluene ND mg/kg 07/28/16 16:02 95-49-80.54 100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 5 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-SB-1(012014)Lab ID:50149912001 Collected:07/18/16 14:44 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/28/16 16:02 106-43-40.54 100 Dibromochloromethane ND mg/kg 07/28/16 16:02 124-48-10.54 100 1,2-Dibromoethane (EDB)ND mg/kg 07/28/16 16:02 106-93-40.54 100 Dibromomethane ND mg/kg 07/28/16 16:02 74-95-30.54 100 1,2-Dichlorobenzene ND mg/kg 07/28/16 16:02 95-50-10.54 100 1,3-Dichlorobenzene ND mg/kg 07/28/16 16:02 541-73-10.54 100 1,4-Dichlorobenzene ND mg/kg 07/28/16 16:02 106-46-70.54 100 trans-1,4-Dichloro-2-butene ND mg/kg 07/28/16 16:02 110-57-610.8 100 Dichlorodifluoromethane ND mg/kg 07/28/16 16:02 75-71-80.54 100 1,1-Dichloroethane ND mg/kg 07/28/16 16:02 75-34-30.54 100 1,2-Dichloroethane ND mg/kg 07/28/16 16:02 107-06-20.54 100 1,1-Dichloroethene ND mg/kg 07/28/16 16:02 75-35-40.54 100 cis-1,2-Dichloroethene ND mg/kg 07/28/16 16:02 156-59-20.54 100 trans-1,2-Dichloroethene ND mg/kg 07/28/16 16:02 156-60-50.54 100 1,2-Dichloropropane ND mg/kg 07/28/16 16:02 78-87-50.54 100 1,3-Dichloropropane ND mg/kg 07/28/16 16:02 142-28-90.54 100 2,2-Dichloropropane ND mg/kg 07/28/16 16:02 594-20-70.54 100 1,1-Dichloropropene ND mg/kg 07/28/16 16:02 563-58-60.54 100 cis-1,3-Dichloropropene ND mg/kg 07/28/16 16:02 10061-01-50.54 100 trans-1,3-Dichloropropene ND mg/kg 07/28/16 16:02 10061-02-60.54 100 Ethylbenzene 8.8 mg/kg 07/28/16 16:02 100-41-40.54 100 Ethyl methacrylate ND mg/kg 07/28/16 16:02 97-63-210.8 100 Hexachloro-1,3-butadiene ND mg/kg 07/28/16 16:02 87-68-30.54 100 n-Hexane 41.9 mg/kg 07/28/16 16:40 110-54-35.4 1000 2-Hexanone ND mg/kg 07/28/16 16:02 591-78-610.8 100 Iodomethane ND mg/kg 07/28/16 16:02 74-88-410.8 100 Isopropylbenzene (Cumene)1.5 mg/kg 07/28/16 16:02 98-82-80.54 100 p-Isopropyltoluene 0.69 mg/kg 07/28/16 16:02 99-87-60.54 100 Methylene Chloride ND mg/kg 07/28/16 16:02 75-09-22.2 100 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/28/16 16:02 108-10-12.7 100 Methyl-tert-butyl ether ND mg/kg 07/28/16 16:02 1634-04-40.54 100 Naphthalene 5.0 mg/kg 07/28/16 16:02 91-20-30.54 100 n-Propylbenzene 5.4 mg/kg 07/28/16 16:02 103-65-10.54 100 Styrene ND mg/kg 07/28/16 16:02 100-42-50.54 100 1,1,1,2-Tetrachloroethane ND mg/kg 07/28/16 16:02 630-20-60.54 100 1,1,2,2-Tetrachloroethane ND mg/kg 07/28/16 16:02 79-34-50.54 100 Tetrachloroethene ND mg/kg 07/28/16 16:02 127-18-40.54 100 Toluene ND mg/kg 07/28/16 16:02 108-88-30.54 100 1,2,3-Trichlorobenzene ND mg/kg 07/28/16 16:02 87-61-60.54 100 1,2,4-Trichlorobenzene ND mg/kg 07/28/16 16:02 120-82-10.54 100 1,1,1-Trichloroethane ND mg/kg 07/28/16 16:02 71-55-60.54 100 1,1,2-Trichloroethane ND mg/kg 07/28/16 16:02 79-00-50.54 100 Trichloroethene ND mg/kg 07/28/16 16:02 79-01-60.54 100 Trichlorofluoromethane ND mg/kg 07/28/16 16:02 75-69-40.54 100 1,2,3-Trichloropropane ND mg/kg 07/28/16 16:02 96-18-40.54 100 1,2,4-Trimethylbenzene 33.8 mg/kg 07/28/16 16:40 95-63-65.4 1000 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 6 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-SB-1(012014)Lab ID:50149912001 Collected:07/18/16 14:44 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene 12.5 mg/kg 07/28/16 16:02 108-67-80.54 100 Vinyl acetate ND mg/kg 07/28/16 16:02 108-05-410.8 100 Vinyl chloride ND mg/kg 07/28/16 16:02 75-01-40.54 100 Xylene (Total)18.0 mg/kg 07/28/16 16:02 1330-20-71.1 100 Surrogates Dibromofluoromethane (S)98 %.07/28/16 16:02 1868-53-7 D470-128 100 Toluene-d8 (S)111 %.07/28/16 16:02 2037-26-572-139 100 4-Bromofluorobenzene (S)106 %.07/28/16 16:02 460-00-465-127 100 Analytical Method: SM 2540GPercent Moisture Percent Moisture 14.8 %07/26/16 16:250.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 7 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-SB-2(010012)Lab ID:50149912002 Collected:07/18/16 15:22 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 8.9 mg/kg 07/26/16 04:34 7439-92-107/23/16 08:201.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/26/16 17:37 83-32-907/22/16 10:390.0061 1 Acenaphthylene ND mg/kg 07/26/16 17:37 208-96-807/22/16 10:390.0061 1 Anthracene ND mg/kg 07/26/16 17:37 120-12-707/22/16 10:390.0061 1 Benzo(a)anthracene ND mg/kg 07/26/16 17:37 56-55-307/22/16 10:390.0061 1 Benzo(a)pyrene ND mg/kg 07/26/16 17:37 50-32-807/22/16 10:390.0061 1 Benzo(b)fluoranthene ND mg/kg 07/26/16 17:37 205-99-207/22/16 10:390.0061 1 Benzo(g,h,i)perylene ND mg/kg 07/26/16 17:37 191-24-207/22/16 10:390.0061 1 Benzo(k)fluoranthene ND mg/kg 07/26/16 17:37 207-08-907/22/16 10:390.0061 1 Chrysene ND mg/kg 07/26/16 17:37 218-01-907/22/16 10:390.0061 1 Dibenz(a,h)anthracene ND mg/kg 07/26/16 17:37 53-70-307/22/16 10:390.0061 1 Fluoranthene ND mg/kg 07/26/16 17:37 206-44-007/22/16 10:390.0061 1 Fluorene ND mg/kg 07/26/16 17:37 86-73-707/22/16 10:390.0061 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/26/16 17:37 193-39-507/22/16 10:390.0061 1 1-Methylnaphthalene ND mg/kg 07/26/16 17:37 90-12-0 N207/22/16 10:390.0061 1 2-Methylnaphthalene ND mg/kg 07/26/16 17:37 91-57-607/22/16 10:390.0061 1 Naphthalene ND mg/kg 07/26/16 17:37 91-20-307/22/16 10:390.0061 1 Phenanthrene ND mg/kg 07/26/16 17:37 85-01-807/22/16 10:390.0061 1 Pyrene ND mg/kg 07/26/16 17:37 129-00-007/22/16 10:390.0061 1 Surrogates 2-Fluorobiphenyl (S)70 %.07/26/16 17:37 321-60-807/22/16 10:3925-121 1 p-Terphenyl-d14 (S)78 %.07/26/16 17:37 1718-51-007/22/16 10:3927-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/29/16 16:27 67-64-10.10 1 Acrolein ND mg/kg 07/29/16 16:27 107-02-80.10 1 Acrylonitrile ND mg/kg 07/29/16 16:27 107-13-10.10 1 Benzene ND mg/kg 07/29/16 16:27 71-43-20.0050 1 Bromobenzene ND mg/kg 07/29/16 16:27 108-86-10.0050 1 Bromochloromethane ND mg/kg 07/29/16 16:27 74-97-50.0050 1 Bromodichloromethane ND mg/kg 07/29/16 16:27 75-27-40.0050 1 Bromoform ND mg/kg 07/29/16 16:27 75-25-20.0050 1 Bromomethane ND mg/kg 07/29/16 16:27 74-83-90.0050 1 2-Butanone (MEK)ND mg/kg 07/29/16 16:27 78-93-30.025 1 n-Butylbenzene ND mg/kg 07/29/16 16:27 104-51-80.0050 1 sec-Butylbenzene ND mg/kg 07/29/16 16:27 135-98-80.0050 1 tert-Butylbenzene ND mg/kg 07/29/16 16:27 98-06-60.0050 1 Carbon disulfide ND mg/kg 07/29/16 16:27 75-15-00.010 1 Carbon tetrachloride ND mg/kg 07/29/16 16:27 56-23-50.0050 1 Chlorobenzene ND mg/kg 07/29/16 16:27 108-90-70.0050 1 Chloroethane ND mg/kg 07/29/16 16:27 75-00-30.0050 1 Chloroform ND mg/kg 07/29/16 16:27 67-66-30.0050 1 Chloromethane ND mg/kg 07/29/16 16:27 74-87-30.0050 1 2-Chlorotoluene ND mg/kg 07/29/16 16:27 95-49-80.0050 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 8 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-SB-2(010012)Lab ID:50149912002 Collected:07/18/16 15:22 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/29/16 16:27 106-43-40.0050 1 Dibromochloromethane ND mg/kg 07/29/16 16:27 124-48-10.0050 1 1,2-Dibromoethane (EDB)ND mg/kg 07/29/16 16:27 106-93-40.0050 1 Dibromomethane ND mg/kg 07/29/16 16:27 74-95-30.0050 1 1,2-Dichlorobenzene ND mg/kg 07/29/16 16:27 95-50-10.0050 1 1,3-Dichlorobenzene ND mg/kg 07/29/16 16:27 541-73-10.0050 1 1,4-Dichlorobenzene ND mg/kg 07/29/16 16:27 106-46-70.0050 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/29/16 16:27 110-57-60.10 1 Dichlorodifluoromethane ND mg/kg 07/29/16 16:27 75-71-80.0050 1 1,1-Dichloroethane ND mg/kg 07/29/16 16:27 75-34-30.0050 1 1,2-Dichloroethane ND mg/kg 07/29/16 16:27 107-06-20.0050 1 1,1-Dichloroethene ND mg/kg 07/29/16 16:27 75-35-40.0050 1 cis-1,2-Dichloroethene ND mg/kg 07/29/16 16:27 156-59-20.0050 1 trans-1,2-Dichloroethene ND mg/kg 07/29/16 16:27 156-60-50.0050 1 1,2-Dichloropropane ND mg/kg 07/29/16 16:27 78-87-50.0050 1 1,3-Dichloropropane ND mg/kg 07/29/16 16:27 142-28-90.0050 1 2,2-Dichloropropane ND mg/kg 07/29/16 16:27 594-20-70.0050 1 1,1-Dichloropropene ND mg/kg 07/29/16 16:27 563-58-60.0050 1 cis-1,3-Dichloropropene ND mg/kg 07/29/16 16:27 10061-01-50.0050 1 trans-1,3-Dichloropropene ND mg/kg 07/29/16 16:27 10061-02-60.0050 1 Ethylbenzene ND mg/kg 07/29/16 16:27 100-41-40.0050 1 Ethyl methacrylate ND mg/kg 07/29/16 16:27 97-63-20.10 1 Hexachloro-1,3-butadiene ND mg/kg 07/29/16 16:27 87-68-30.0050 1 n-Hexane ND mg/kg 07/29/16 16:27 110-54-30.0050 1 2-Hexanone ND mg/kg 07/29/16 16:27 591-78-60.10 1 Iodomethane ND mg/kg 07/29/16 16:27 74-88-40.10 1 Isopropylbenzene (Cumene)ND mg/kg 07/29/16 16:27 98-82-80.0050 1 p-Isopropyltoluene ND mg/kg 07/29/16 16:27 99-87-60.0050 1 Methylene Chloride ND mg/kg 07/29/16 16:27 75-09-20.020 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/29/16 16:27 108-10-10.025 1 Methyl-tert-butyl ether ND mg/kg 07/29/16 16:27 1634-04-40.0050 1 Naphthalene ND mg/kg 07/29/16 16:27 91-20-30.0050 1 n-Propylbenzene ND mg/kg 07/29/16 16:27 103-65-10.0050 1 Styrene ND mg/kg 07/29/16 16:27 100-42-50.0050 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/29/16 16:27 630-20-60.0050 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/29/16 16:27 79-34-50.0050 1 Tetrachloroethene ND mg/kg 07/29/16 16:27 127-18-40.0050 1 Toluene ND mg/kg 07/29/16 16:27 108-88-30.0050 1 1,2,3-Trichlorobenzene ND mg/kg 07/29/16 16:27 87-61-60.0050 1 1,2,4-Trichlorobenzene ND mg/kg 07/29/16 16:27 120-82-10.0050 1 1,1,1-Trichloroethane ND mg/kg 07/29/16 16:27 71-55-60.0050 1 1,1,2-Trichloroethane ND mg/kg 07/29/16 16:27 79-00-50.0050 1 Trichloroethene ND mg/kg 07/29/16 16:27 79-01-60.0050 1 Trichlorofluoromethane ND mg/kg 07/29/16 16:27 75-69-40.0050 1 1,2,3-Trichloropropane ND mg/kg 07/29/16 16:27 96-18-40.0050 1 1,2,4-Trimethylbenzene ND mg/kg 07/29/16 16:27 95-63-60.0050 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 9 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-SB-2(010012)Lab ID:50149912002 Collected:07/18/16 15:22 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/29/16 16:27 108-67-80.0050 1 Vinyl acetate ND mg/kg 07/29/16 16:27 108-05-40.10 1 Vinyl chloride ND mg/kg 07/29/16 16:27 75-01-40.0050 1 Xylene (Total)ND mg/kg 07/29/16 16:27 1330-20-70.010 1 Surrogates Dibromofluoromethane (S)112 %.07/29/16 16:27 1868-53-770-128 1 Toluene-d8 (S)101 %.07/29/16 16:27 2037-26-572-139 1 4-Bromofluorobenzene (S)90 %.07/29/16 16:27 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 18.1 %07/26/16 16:250.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 10 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-SB-3(010012)Lab ID:50149912003 Collected:07/18/16 16:12 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 9.4 mg/kg 07/26/16 04:45 7439-92-107/23/16 08:201.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/26/16 18:29 83-32-907/22/16 10:390.0057 1 Acenaphthylene ND mg/kg 07/26/16 18:29 208-96-807/22/16 10:390.0057 1 Anthracene ND mg/kg 07/26/16 18:29 120-12-707/22/16 10:390.0057 1 Benzo(a)anthracene ND mg/kg 07/26/16 18:29 56-55-307/22/16 10:390.0057 1 Benzo(a)pyrene ND mg/kg 07/26/16 18:29 50-32-807/22/16 10:390.0057 1 Benzo(b)fluoranthene ND mg/kg 07/26/16 18:29 205-99-207/22/16 10:390.0057 1 Benzo(g,h,i)perylene ND mg/kg 07/26/16 18:29 191-24-207/22/16 10:390.0057 1 Benzo(k)fluoranthene ND mg/kg 07/26/16 18:29 207-08-907/22/16 10:390.0057 1 Chrysene ND mg/kg 07/26/16 18:29 218-01-907/22/16 10:390.0057 1 Dibenz(a,h)anthracene ND mg/kg 07/26/16 18:29 53-70-307/22/16 10:390.0057 1 Fluoranthene ND mg/kg 07/26/16 18:29 206-44-007/22/16 10:390.0057 1 Fluorene ND mg/kg 07/26/16 18:29 86-73-707/22/16 10:390.0057 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/26/16 18:29 193-39-507/22/16 10:390.0057 1 1-Methylnaphthalene ND mg/kg 07/26/16 18:29 90-12-0 N207/22/16 10:390.0057 1 2-Methylnaphthalene ND mg/kg 07/26/16 18:29 91-57-607/22/16 10:390.0057 1 Naphthalene ND mg/kg 07/26/16 18:29 91-20-307/22/16 10:390.0057 1 Phenanthrene ND mg/kg 07/26/16 18:29 85-01-807/22/16 10:390.0057 1 Pyrene ND mg/kg 07/26/16 18:29 129-00-007/22/16 10:390.0057 1 Surrogates 2-Fluorobiphenyl (S)79 %.07/26/16 18:29 321-60-807/22/16 10:3925-121 1 p-Terphenyl-d14 (S)84 %.07/26/16 18:29 1718-51-007/22/16 10:3927-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/28/16 19:49 67-64-10.097 1 Acrolein ND mg/kg 07/28/16 19:49 107-02-80.097 1 Acrylonitrile ND mg/kg 07/28/16 19:49 107-13-10.097 1 Benzene ND mg/kg 07/28/16 19:49 71-43-20.0049 1 Bromobenzene ND mg/kg 07/28/16 19:49 108-86-10.0049 1 Bromochloromethane ND mg/kg 07/28/16 19:49 74-97-50.0049 1 Bromodichloromethane ND mg/kg 07/28/16 19:49 75-27-40.0049 1 Bromoform ND mg/kg 07/28/16 19:49 75-25-20.0049 1 Bromomethane ND mg/kg 07/28/16 19:49 74-83-90.0049 1 2-Butanone (MEK)ND mg/kg 07/28/16 19:49 78-93-30.024 1 n-Butylbenzene ND mg/kg 07/28/16 19:49 104-51-80.0049 1 sec-Butylbenzene ND mg/kg 07/28/16 19:49 135-98-80.0049 1 tert-Butylbenzene ND mg/kg 07/28/16 19:49 98-06-60.0049 1 Carbon disulfide ND mg/kg 07/28/16 19:49 75-15-00.0097 1 Carbon tetrachloride ND mg/kg 07/28/16 19:49 56-23-50.0049 1 Chlorobenzene ND mg/kg 07/28/16 19:49 108-90-70.0049 1 Chloroethane ND mg/kg 07/28/16 19:49 75-00-30.0049 1 Chloroform ND mg/kg 07/28/16 19:49 67-66-30.0049 1 Chloromethane ND mg/kg 07/28/16 19:49 74-87-30.0049 1 2-Chlorotoluene ND mg/kg 07/28/16 19:49 95-49-80.0049 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 11 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-SB-3(010012)Lab ID:50149912003 Collected:07/18/16 16:12 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/28/16 19:49 106-43-40.0049 1 Dibromochloromethane ND mg/kg 07/28/16 19:49 124-48-10.0049 1 1,2-Dibromoethane (EDB)ND mg/kg 07/28/16 19:49 106-93-40.0049 1 Dibromomethane ND mg/kg 07/28/16 19:49 74-95-30.0049 1 1,2-Dichlorobenzene ND mg/kg 07/28/16 19:49 95-50-10.0049 1 1,3-Dichlorobenzene ND mg/kg 07/28/16 19:49 541-73-10.0049 1 1,4-Dichlorobenzene ND mg/kg 07/28/16 19:49 106-46-70.0049 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/28/16 19:49 110-57-60.097 1 Dichlorodifluoromethane ND mg/kg 07/28/16 19:49 75-71-80.0049 1 1,1-Dichloroethane ND mg/kg 07/28/16 19:49 75-34-30.0049 1 1,2-Dichloroethane ND mg/kg 07/28/16 19:49 107-06-20.0049 1 1,1-Dichloroethene ND mg/kg 07/28/16 19:49 75-35-40.0049 1 cis-1,2-Dichloroethene ND mg/kg 07/28/16 19:49 156-59-20.0049 1 trans-1,2-Dichloroethene ND mg/kg 07/28/16 19:49 156-60-50.0049 1 1,2-Dichloropropane ND mg/kg 07/28/16 19:49 78-87-50.0049 1 1,3-Dichloropropane ND mg/kg 07/28/16 19:49 142-28-90.0049 1 2,2-Dichloropropane ND mg/kg 07/28/16 19:49 594-20-70.0049 1 1,1-Dichloropropene ND mg/kg 07/28/16 19:49 563-58-60.0049 1 cis-1,3-Dichloropropene ND mg/kg 07/28/16 19:49 10061-01-50.0049 1 trans-1,3-Dichloropropene ND mg/kg 07/28/16 19:49 10061-02-60.0049 1 Ethylbenzene ND mg/kg 07/28/16 19:49 100-41-40.0049 1 Ethyl methacrylate ND mg/kg 07/28/16 19:49 97-63-20.097 1 Hexachloro-1,3-butadiene ND mg/kg 07/28/16 19:49 87-68-30.0049 1 n-Hexane ND mg/kg 07/28/16 19:49 110-54-30.0049 1 2-Hexanone ND mg/kg 07/28/16 19:49 591-78-60.097 1 Iodomethane ND mg/kg 07/28/16 19:49 74-88-40.097 1 Isopropylbenzene (Cumene)ND mg/kg 07/28/16 19:49 98-82-80.0049 1 p-Isopropyltoluene ND mg/kg 07/28/16 19:49 99-87-60.0049 1 Methylene Chloride ND mg/kg 07/28/16 19:49 75-09-20.019 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/28/16 19:49 108-10-10.024 1 Methyl-tert-butyl ether ND mg/kg 07/28/16 19:49 1634-04-40.0049 1 Naphthalene ND mg/kg 07/28/16 19:49 91-20-30.0049 1 n-Propylbenzene ND mg/kg 07/28/16 19:49 103-65-10.0049 1 Styrene ND mg/kg 07/28/16 19:49 100-42-50.0049 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/28/16 19:49 630-20-60.0049 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/28/16 19:49 79-34-50.0049 1 Tetrachloroethene ND mg/kg 07/28/16 19:49 127-18-40.0049 1 Toluene ND mg/kg 07/28/16 19:49 108-88-30.0049 1 1,2,3-Trichlorobenzene ND mg/kg 07/28/16 19:49 87-61-60.0049 1 1,2,4-Trichlorobenzene ND mg/kg 07/28/16 19:49 120-82-10.0049 1 1,1,1-Trichloroethane ND mg/kg 07/28/16 19:49 71-55-60.0049 1 1,1,2-Trichloroethane ND mg/kg 07/28/16 19:49 79-00-50.0049 1 Trichloroethene ND mg/kg 07/28/16 19:49 79-01-60.0049 1 Trichlorofluoromethane ND mg/kg 07/28/16 19:49 75-69-40.0049 1 1,2,3-Trichloropropane ND mg/kg 07/28/16 19:49 96-18-40.0049 1 1,2,4-Trimethylbenzene ND mg/kg 07/28/16 19:49 95-63-60.0049 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 12 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-SB-3(010012)Lab ID:50149912003 Collected:07/18/16 16:12 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 07/28/16 19:49 108-67-80.0049 1 Vinyl acetate ND mg/kg 07/28/16 19:49 108-05-40.097 1 Vinyl chloride ND mg/kg 07/28/16 19:49 75-01-40.0049 1 Xylene (Total)ND mg/kg 07/28/16 19:49 1330-20-70.0097 1 Surrogates Dibromofluoromethane (S)107 %.07/28/16 19:49 1868-53-770-128 1 Toluene-d8 (S)102 %.07/28/16 19:49 2037-26-572-139 1 4-Bromofluorobenzene (S)98 %.07/28/16 19:49 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 12.2 %07/26/16 16:250.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 13 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-FD-1 Lab ID:50149912004 Collected:07/18/16 15:00 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 11.9 mg/kg 07/26/16 04:51 7439-92-107/23/16 08:201.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene 0.065 mg/kg 07/26/16 18:47 83-32-907/22/16 10:390.0058 1 Acenaphthylene ND mg/kg 07/26/16 18:47 208-96-807/22/16 10:390.0058 1 Anthracene ND mg/kg 07/26/16 18:47 120-12-707/22/16 10:390.0058 1 Benzo(a)anthracene ND mg/kg 07/26/16 18:47 56-55-307/22/16 10:390.0058 1 Benzo(a)pyrene ND mg/kg 07/26/16 18:47 50-32-807/22/16 10:390.0058 1 Benzo(b)fluoranthene ND mg/kg 07/26/16 18:47 205-99-207/22/16 10:390.0058 1 Benzo(g,h,i)perylene ND mg/kg 07/26/16 18:47 191-24-207/22/16 10:390.0058 1 Benzo(k)fluoranthene ND mg/kg 07/26/16 18:47 207-08-907/22/16 10:390.0058 1 Chrysene ND mg/kg 07/26/16 18:47 218-01-907/22/16 10:390.0058 1 Dibenz(a,h)anthracene ND mg/kg 07/26/16 18:47 53-70-307/22/16 10:390.0058 1 Fluoranthene ND mg/kg 07/26/16 18:47 206-44-007/22/16 10:390.0058 1 Fluorene 0.055 mg/kg 07/26/16 18:47 86-73-707/22/16 10:390.0058 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/26/16 18:47 193-39-507/22/16 10:390.0058 1 1-Methylnaphthalene 0.55 mg/kg 07/26/16 18:47 90-12-0 N207/22/16 10:390.0058 1 2-Methylnaphthalene 0.99 mg/kg 07/26/16 18:47 91-57-607/22/16 10:390.0058 1 Naphthalene 0.52 mg/kg 07/26/16 18:47 91-20-307/22/16 10:390.0058 1 Phenanthrene 0.20 mg/kg 07/26/16 18:47 85-01-807/22/16 10:390.0058 1 Pyrene ND mg/kg 07/26/16 18:47 129-00-007/22/16 10:390.0058 1 Surrogates 2-Fluorobiphenyl (S)83 %.07/26/16 18:47 321-60-807/22/16 10:3925-121 1 p-Terphenyl-d14 (S)76 %.07/26/16 18:47 1718-51-007/22/16 10:3927-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/28/16 20:26 67-64-15.2 50 Acrolein ND mg/kg 07/28/16 20:26 107-02-85.2 50 Acrylonitrile ND mg/kg 07/28/16 20:26 107-13-15.2 50 Benzene 0.17J mg/kg 07/28/16 20:26 71-43-2 J0.26 50 Bromobenzene ND mg/kg 07/28/16 20:26 108-86-10.26 50 Bromochloromethane ND mg/kg 07/28/16 20:26 74-97-50.26 50 Bromodichloromethane ND mg/kg 07/28/16 20:26 75-27-40.26 50 Bromoform ND mg/kg 07/28/16 20:26 75-25-20.26 50 Bromomethane ND mg/kg 07/28/16 20:26 74-83-90.26 50 2-Butanone (MEK)ND mg/kg 07/28/16 20:26 78-93-31.3 50 n-Butylbenzene ND mg/kg 07/28/16 20:26 104-51-80.26 50 sec-Butylbenzene 1.1 mg/kg 07/28/16 20:26 135-98-80.26 50 tert-Butylbenzene ND mg/kg 07/28/16 20:26 98-06-60.26 50 Carbon disulfide ND mg/kg 07/28/16 20:26 75-15-00.52 50 Carbon tetrachloride ND mg/kg 07/28/16 20:26 56-23-50.26 50 Chlorobenzene ND mg/kg 07/28/16 20:26 108-90-70.26 50 Chloroethane ND mg/kg 07/28/16 20:26 75-00-30.26 50 Chloroform ND mg/kg 07/28/16 20:26 67-66-30.26 50 Chloromethane ND mg/kg 07/28/16 20:26 74-87-30.26 50 2-Chlorotoluene ND mg/kg 07/28/16 20:26 95-49-80.26 50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 14 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-FD-1 Lab ID:50149912004 Collected:07/18/16 15:00 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 07/28/16 20:26 106-43-40.26 50 Dibromochloromethane ND mg/kg 07/28/16 20:26 124-48-10.26 50 1,2-Dibromoethane (EDB)ND mg/kg 07/28/16 20:26 106-93-40.26 50 Dibromomethane ND mg/kg 07/28/16 20:26 74-95-30.26 50 1,2-Dichlorobenzene ND mg/kg 07/28/16 20:26 95-50-10.26 50 1,3-Dichlorobenzene ND mg/kg 07/28/16 20:26 541-73-10.26 50 1,4-Dichlorobenzene ND mg/kg 07/28/16 20:26 106-46-70.26 50 trans-1,4-Dichloro-2-butene ND mg/kg 07/28/16 20:26 110-57-65.2 50 Dichlorodifluoromethane ND mg/kg 07/28/16 20:26 75-71-80.26 50 1,1-Dichloroethane ND mg/kg 07/28/16 20:26 75-34-30.26 50 1,2-Dichloroethane ND mg/kg 07/28/16 20:26 107-06-20.26 50 1,1-Dichloroethene ND mg/kg 07/28/16 20:26 75-35-40.26 50 cis-1,2-Dichloroethene ND mg/kg 07/28/16 20:26 156-59-20.26 50 trans-1,2-Dichloroethene ND mg/kg 07/28/16 20:26 156-60-50.26 50 1,2-Dichloropropane ND mg/kg 07/28/16 20:26 78-87-50.26 50 1,3-Dichloropropane ND mg/kg 07/28/16 20:26 142-28-90.26 50 2,2-Dichloropropane ND mg/kg 07/28/16 20:26 594-20-70.26 50 1,1-Dichloropropene ND mg/kg 07/28/16 20:26 563-58-60.26 50 cis-1,3-Dichloropropene ND mg/kg 07/28/16 20:26 10061-01-50.26 50 trans-1,3-Dichloropropene ND mg/kg 07/28/16 20:26 10061-02-60.26 50 Ethylbenzene 9.9 mg/kg 07/28/16 20:26 100-41-40.26 50 Ethyl methacrylate ND mg/kg 07/28/16 20:26 97-63-25.2 50 Hexachloro-1,3-butadiene ND mg/kg 07/28/16 20:26 87-68-30.26 50 n-Hexane 40.1 mg/kg 07/28/16 21:04 110-54-32.6 500 2-Hexanone ND mg/kg 07/28/16 20:26 591-78-65.2 50 Iodomethane ND mg/kg 07/28/16 20:26 74-88-45.2 50 Isopropylbenzene (Cumene)1.9 mg/kg 07/28/16 20:26 98-82-80.26 50 p-Isopropyltoluene 0.82 mg/kg 07/28/16 20:26 99-87-60.26 50 Methylene Chloride ND mg/kg 07/28/16 20:26 75-09-21.0 50 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/28/16 20:26 108-10-11.3 50 Methyl-tert-butyl ether ND mg/kg 07/28/16 20:26 1634-04-40.26 50 Naphthalene 5.6 mg/kg 07/28/16 20:26 91-20-30.26 50 n-Propylbenzene 6.4 mg/kg 07/28/16 20:26 103-65-10.26 50 Styrene ND mg/kg 07/28/16 20:26 100-42-50.26 50 1,1,1,2-Tetrachloroethane ND mg/kg 07/28/16 20:26 630-20-60.26 50 1,1,2,2-Tetrachloroethane ND mg/kg 07/28/16 20:26 79-34-50.26 50 Tetrachloroethene ND mg/kg 07/28/16 20:26 127-18-40.26 50 Toluene ND mg/kg 07/28/16 20:26 108-88-30.26 50 1,2,3-Trichlorobenzene ND mg/kg 07/28/16 20:26 87-61-60.26 50 1,2,4-Trichlorobenzene ND mg/kg 07/28/16 20:26 120-82-10.26 50 1,1,1-Trichloroethane ND mg/kg 07/28/16 20:26 71-55-60.26 50 1,1,2-Trichloroethane ND mg/kg 07/28/16 20:26 79-00-50.26 50 Trichloroethene ND mg/kg 07/28/16 20:26 79-01-60.26 50 Trichlorofluoromethane ND mg/kg 07/28/16 20:26 75-69-40.26 50 1,2,3-Trichloropropane ND mg/kg 07/28/16 20:26 96-18-40.26 50 1,2,4-Trimethylbenzene 38.0 mg/kg 07/28/16 21:04 95-63-62.6 500 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 15 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:LV-FD-1 Lab ID:50149912004 Collected:07/18/16 15:00 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene 14.2 mg/kg 07/28/16 20:26 108-67-80.26 50 Vinyl acetate ND mg/kg 07/28/16 20:26 108-05-45.2 50 Vinyl chloride ND mg/kg 07/28/16 20:26 75-01-40.26 50 Xylene (Total)21.9 mg/kg 07/28/16 20:26 1330-20-70.52 50 Surrogates Dibromofluoromethane (S)102 %.07/28/16 20:26 1868-53-7 D470-128 50 Toluene-d8 (S)128 %.07/28/16 20:26 2037-26-572-139 50 4-Bromofluorobenzene (S)119 %.07/28/16 20:26 460-00-465-127 50 Analytical Method: SM 2540GPercent Moisture Percent Moisture 14.7 %07/27/16 16:140.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 16 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:TRIP BLANK Lab ID:50149912005 Collected:07/18/16 08:00 Received:07/19/16 09:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana Acetone ND ug/L 07/26/16 18:40 67-64-11001 Acrolein ND ug/L 07/26/16 18:40 107-02-850.0 1 Acrylonitrile ND ug/L 07/26/16 18:40 107-13-11001 Benzene ND ug/L 07/26/16 18:40 71-43-25.0 1 Bromobenzene ND ug/L 07/26/16 18:40 108-86-15.0 1 Bromochloromethane ND ug/L 07/26/16 18:40 74-97-55.0 1 Bromodichloromethane ND ug/L 07/26/16 18:40 75-27-45.0 1 Bromoform ND ug/L 07/26/16 18:40 75-25-25.0 1 Bromomethane ND ug/L 07/26/16 18:40 74-83-95.0 1 2-Butanone (MEK)ND ug/L 07/26/16 18:40 78-93-325.0 1 n-Butylbenzene ND ug/L 07/26/16 18:40 104-51-85.0 1 sec-Butylbenzene ND ug/L 07/26/16 18:40 135-98-85.0 1 tert-Butylbenzene ND ug/L 07/26/16 18:40 98-06-65.0 1 Carbon disulfide ND ug/L 07/26/16 18:40 75-15-010.0 1 Carbon tetrachloride ND ug/L 07/26/16 18:40 56-23-55.0 1 Chlorobenzene ND ug/L 07/26/16 18:40 108-90-75.0 1 Chloroethane ND ug/L 07/26/16 18:40 75-00-35.0 1 Chloroform ND ug/L 07/26/16 18:40 67-66-35.0 1 Chloromethane ND ug/L 07/26/16 18:40 74-87-35.0 1 2-Chlorotoluene ND ug/L 07/26/16 18:40 95-49-85.0 1 4-Chlorotoluene ND ug/L 07/26/16 18:40 106-43-45.0 1 Dibromochloromethane ND ug/L 07/26/16 18:40 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 07/26/16 18:40 106-93-45.0 1 Dibromomethane ND ug/L 07/26/16 18:40 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 07/26/16 18:40 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 07/26/16 18:40 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 07/26/16 18:40 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 07/26/16 18:40 110-57-61001 Dichlorodifluoromethane ND ug/L 07/26/16 18:40 75-71-85.0 1 1,1-Dichloroethane ND ug/L 07/26/16 18:40 75-34-35.0 1 1,2-Dichloroethane ND ug/L 07/26/16 18:40 107-06-25.0 1 1,1-Dichloroethene ND ug/L 07/26/16 18:40 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 07/26/16 18:40 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 07/26/16 18:40 156-60-55.0 1 1,2-Dichloropropane ND ug/L 07/26/16 18:40 78-87-55.0 1 1,3-Dichloropropane ND ug/L 07/26/16 18:40 142-28-95.0 1 2,2-Dichloropropane ND ug/L 07/26/16 18:40 594-20-75.0 1 1,1-Dichloropropene ND ug/L 07/26/16 18:40 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 07/26/16 18:40 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 07/26/16 18:40 10061-02-65.0 1 Ethylbenzene ND ug/L 07/26/16 18:40 100-41-45.0 1 Ethyl methacrylate ND ug/L 07/26/16 18:40 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 07/26/16 18:40 87-68-35.0 1 n-Hexane ND ug/L 07/26/16 18:40 110-54-35.0 1 2-Hexanone ND ug/L 07/26/16 18:40 591-78-625.0 1 Iodomethane ND ug/L 07/26/16 18:40 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 07/26/16 18:40 98-82-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 17 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149912 LAKEVILLE Sample:TRIP BLANK Lab ID:50149912005 Collected:07/18/16 08:00 Received:07/19/16 09:30 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana p-Isopropyltoluene ND ug/L 07/26/16 18:40 99-87-65.0 1 Methylene Chloride ND ug/L 07/26/16 18:40 75-09-25.0 1 1-Methylnaphthalene ND ug/L 07/26/16 18:40 90-12-0 N25.0 1 2-Methylnaphthalene ND ug/L 07/26/16 18:40 91-57-610.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 07/26/16 18:40 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 07/26/16 18:40 1634-04-44.0 1 Naphthalene ND ug/L 07/26/16 18:40 91-20-31.7 1 n-Propylbenzene ND ug/L 07/26/16 18:40 103-65-15.0 1 Styrene ND ug/L 07/26/16 18:40 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 07/26/16 18:40 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 07/26/16 18:40 79-34-55.0 1 Tetrachloroethene ND ug/L 07/26/16 18:40 127-18-45.0 1 Toluene ND ug/L 07/26/16 18:40 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 07/26/16 18:40 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 07/26/16 18:40 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 07/26/16 18:40 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 07/26/16 18:40 79-00-55.0 1 Trichloroethene ND ug/L 07/26/16 18:40 79-01-65.0 1 Trichlorofluoromethane ND ug/L 07/26/16 18:40 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 07/26/16 18:40 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 07/26/16 18:40 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 07/26/16 18:40 108-67-85.0 1 Vinyl acetate ND ug/L 07/26/16 18:40 108-05-450.0 1 Vinyl chloride ND ug/L 07/26/16 18:40 75-01-42.0 1 Xylene (Total)ND ug/L 07/26/16 18:40 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)99 %.07/26/16 18:40 1868-53-784-118 1 4-Bromofluorobenzene (S)100 %.07/26/16 18:40 460-00-479-116 1 Toluene-d8 (S)96 %.07/26/16 18:40 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 18 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342639 EPA 3050 EPA 6010 6010 MET Associated Lab Samples:50149912001, 50149912002, 50149912003, 50149912004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1587162 Associated Lab Samples:50149912001, 50149912002, 50149912003, 50149912004 Matrix:Solid Analyzed Lead mg/kg ND 1.0 07/26/16 03:41 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1587163LABORATORY CONTROL SAMPLE: LCSSpike Lead mg/kg 51.650 103 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1587164MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50149903002 1587165 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead mg/kg M344.2 37 75-12528 7 2047.330.1 46.4 43.4 Parameter Units MS Result % Rec Limits Qual% RecConc. 1587166MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50149912002 1587167 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead mg/kg 58.9 87 75-12587 2 2058.28.9 60.4 59.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 19 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343833 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50149912005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1592148 Associated Lab Samples:50149912005 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 07/26/16 12:07 1,1,1-Trichloroethane ug/L ND 5.0 07/26/16 12:07 1,1,2,2-Tetrachloroethane ug/L ND 5.0 07/26/16 12:07 1,1,2-Trichloroethane ug/L ND 5.0 07/26/16 12:07 1,1-Dichloroethane ug/L ND 5.0 07/26/16 12:07 1,1-Dichloroethene ug/L ND 5.0 07/26/16 12:07 1,1-Dichloropropene ug/L ND 5.0 07/26/16 12:07 1,2,3-Trichlorobenzene ug/L ND 5.0 07/26/16 12:07 1,2,3-Trichloropropane ug/L ND 5.0 07/26/16 12:07 1,2,4-Trichlorobenzene ug/L ND 5.0 07/26/16 12:07 1,2,4-Trimethylbenzene ug/L ND 5.0 07/26/16 12:07 1,2-Dibromoethane (EDB)ug/L ND 5.0 07/26/16 12:07 1,2-Dichlorobenzene ug/L ND 5.0 07/26/16 12:07 1,2-Dichloroethane ug/L ND 5.0 07/26/16 12:07 1,2-Dichloropropane ug/L ND 5.0 07/26/16 12:07 1,3,5-Trimethylbenzene ug/L ND 5.0 07/26/16 12:07 1,3-Dichlorobenzene ug/L ND 5.0 07/26/16 12:07 1,3-Dichloropropane ug/L ND 5.0 07/26/16 12:07 1,4-Dichlorobenzene ug/L ND 5.0 07/26/16 12:07 1-Methylnaphthalene ug/L ND 5.0 N207/26/16 12:07 2,2-Dichloropropane ug/L ND 5.0 07/26/16 12:07 2-Butanone (MEK)ug/L ND 25.0 07/26/16 12:07 2-Chlorotoluene ug/L ND 5.0 07/26/16 12:07 2-Hexanone ug/L ND 25.0 07/26/16 12:07 2-Methylnaphthalene ug/L ND 10.0 07/26/16 12:07 4-Chlorotoluene ug/L ND 5.0 07/26/16 12:07 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 07/26/16 12:07 Acetone ug/L ND 100 07/26/16 12:07 Acrolein ug/L ND 50.0 07/26/16 12:07 Acrylonitrile ug/L ND 100 07/26/16 12:07 Benzene ug/L ND 5.0 07/26/16 12:07 Bromobenzene ug/L ND 5.0 07/26/16 12:07 Bromochloromethane ug/L ND 5.0 07/26/16 12:07 Bromodichloromethane ug/L ND 5.0 07/26/16 12:07 Bromoform ug/L ND 5.0 07/26/16 12:07 Bromomethane ug/L ND 5.0 07/26/16 12:07 Carbon disulfide ug/L ND 10.0 07/26/16 12:07 Carbon tetrachloride ug/L ND 5.0 07/26/16 12:07 Chlorobenzene ug/L ND 5.0 07/26/16 12:07 Chloroethane ug/L ND 5.0 07/26/16 12:07 Chloroform ug/L ND 5.0 07/26/16 12:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 20 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1592148 Associated Lab Samples:50149912005 Matrix:Water Analyzed Chloromethane ug/L ND 5.0 07/26/16 12:07 cis-1,2-Dichloroethene ug/L ND 5.0 07/26/16 12:07 cis-1,3-Dichloropropene ug/L ND 5.0 07/26/16 12:07 Dibromochloromethane ug/L ND 5.0 07/26/16 12:07 Dibromomethane ug/L ND 5.0 07/26/16 12:07 Dichlorodifluoromethane ug/L ND 5.0 07/26/16 12:07 Ethyl methacrylate ug/L ND 100 07/26/16 12:07 Ethylbenzene ug/L ND 5.0 07/26/16 12:07 Hexachloro-1,3-butadiene ug/L ND 5.0 07/26/16 12:07 Iodomethane ug/L ND 10.0 07/26/16 12:07 Isopropylbenzene (Cumene)ug/L ND 5.0 07/26/16 12:07 Methyl-tert-butyl ether ug/L ND 4.0 07/26/16 12:07 Methylene Chloride ug/L ND 5.0 07/26/16 12:07 n-Butylbenzene ug/L ND 5.0 07/26/16 12:07 n-Hexane ug/L ND 5.0 07/26/16 12:07 n-Propylbenzene ug/L ND 5.0 07/26/16 12:07 Naphthalene ug/L ND 1.7 07/26/16 12:07 p-Isopropyltoluene ug/L ND 5.0 07/26/16 12:07 sec-Butylbenzene ug/L ND 5.0 07/26/16 12:07 Styrene ug/L ND 5.0 07/26/16 12:07 tert-Butylbenzene ug/L ND 5.0 07/26/16 12:07 Tetrachloroethene ug/L ND 5.0 07/26/16 12:07 Toluene ug/L ND 5.0 07/26/16 12:07 trans-1,2-Dichloroethene ug/L ND 5.0 07/26/16 12:07 trans-1,3-Dichloropropene ug/L ND 5.0 07/26/16 12:07 trans-1,4-Dichloro-2-butene ug/L ND 100 07/26/16 12:07 Trichloroethene ug/L ND 5.0 07/26/16 12:07 Trichlorofluoromethane ug/L ND 5.0 07/26/16 12:07 Vinyl acetate ug/L ND 50.0 07/26/16 12:07 Vinyl chloride ug/L ND 2.0 07/26/16 12:07 Xylene (Total)ug/L ND 10.0 07/26/16 12:07 4-Bromofluorobenzene (S)%.101 79-116 07/26/16 12:07 Dibromofluoromethane (S)%.99 84-118 07/26/16 12:07 Toluene-d8 (S)%.99 86-110 07/26/16 12:07 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1592149LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.150 100 74-130 1,1,1-Trichloroethane ug/L 64.0 L05012872-123 1,1,2,2-Tetrachloroethane ug/L 50.650 101 72-124 1,1,2-Trichloroethane ug/L 47.350 95 75-125 1,1-Dichloroethane ug/L 49.350 99 70-120 1,1-Dichloroethene ug/L 45.250 90 69-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 21 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1592149LABORATORY CONTROL SAMPLE: LCSSpike 1,1-Dichloropropene ug/L 51.050 102 81-129 1,2,3-Trichlorobenzene ug/L 54.750 109 71-130 1,2,3-Trichloropropane ug/L 51.850 104 77-127 1,2,4-Trichlorobenzene ug/L 51.250 102 66-126 1,2,4-Trimethylbenzene ug/L 49.850 100 73-125 1,2-Dibromoethane (EDB)ug/L 52.850 106 76-125 1,2-Dichlorobenzene ug/L 47.850 96 77-122 1,2-Dichloroethane ug/L 51.750 103 70-123 1,2-Dichloropropane ug/L 57.650 115 77-124 1,3,5-Trimethylbenzene ug/L 50.150 100 75-124 1,3-Dichlorobenzene ug/L 49.050 98 76-124 1,3-Dichloropropane ug/L 53.050 106 77-123 1,4-Dichlorobenzene ug/L 47.950 96 75-117 1-Methylnaphthalene ug/L 43.9 N2508855-151 2,2-Dichloropropane ug/L 57.350 115 44-147 2-Butanone (MEK)ug/L 276250 110 60-135 2-Chlorotoluene ug/L 46.050 92 75-124 2-Hexanone ug/L 262250 105 65-139 2-Methylnaphthalene ug/L 37.950 76 58-148 4-Chlorotoluene ug/L 50.650 101 75-124 4-Methyl-2-pentanone (MIBK)ug/L 288250 115 66-134 Acetone ug/L 308250 123 47-144 Acrolein ug/L 4261000 43 31-200 Acrylonitrile ug/L 211200 106 64-133 Benzene ug/L 49.950 100 76-122 Bromobenzene ug/L 53.150 106 75-117 Bromochloromethane ug/L 54.250 108 74-134 Bromodichloromethane ug/L 56.650 113 71-124 Bromoform ug/L 43.550 87 60-125 Bromomethane ug/L 44.850 90 23-194 Carbon disulfide ug/L 41.950 84 63-130 Carbon tetrachloride ug/L 66.150 132 73-133 Chlorobenzene ug/L 50.250 100 76-118 Chloroethane ug/L 42.850 86 50-147 Chloroform ug/L 48.950 98 70-119 Chloromethane ug/L 36.650 73 52-136 cis-1,2-Dichloroethene ug/L 51.550 103 74-120 cis-1,3-Dichloropropene ug/L 49.950 100 71-134 Dibromochloromethane ug/L 47.950 96 73-127 Dibromomethane ug/L 50.750 101 75-124 Dichlorodifluoromethane ug/L 50.550 101 39-166 Ethyl methacrylate ug/L 206200 103 73-136 Ethylbenzene ug/L 51.450 103 75-123 Hexachloro-1,3-butadiene ug/L 53.450 107 70-125 Iodomethane ug/L 102100 102 56-142 Isopropylbenzene (Cumene)ug/L 56.050 112 84-134 Methyl-tert-butyl ether ug/L 55.650 111 65-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 22 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1592149LABORATORY CONTROL SAMPLE: LCSSpike Methylene Chloride ug/L 49.050 98 66-130 n-Butylbenzene ug/L 52.450 105 70-127 n-Hexane ug/L 49.850 100 64-131 n-Propylbenzene ug/L 50.050 100 78-131 Naphthalene ug/L 51.050 102 65-134 p-Isopropyltoluene ug/L 51.450 103 75-124 sec-Butylbenzene ug/L 51.450 103 83-135 Styrene ug/L 52.650 105 78-128 tert-Butylbenzene ug/L 44.950 90 62-114 Tetrachloroethene ug/L 51.950 104 69-119 Toluene ug/L 47.350 95 74-122 trans-1,2-Dichloroethene ug/L 52.250 104 72-122 trans-1,3-Dichloropropene ug/L 50.550 101 66-135 trans-1,4-Dichloro-2-butene ug/L 196200 98 39-153 Trichloroethene ug/L 49.550 99 75-123 Trichlorofluoromethane ug/L 60.250 120 58-148 Vinyl acetate ug/L 227200 114 67-154 Vinyl chloride ug/L 48.450 97 61-147 Xylene (Total)ug/L 151150 101 75-127 4-Bromofluorobenzene (S)%.106 79-116 Dibromofluoromethane (S)%.102 84-118 Toluene-d8 (S)%.97 86-110 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1592151MATRIX SPIKE SAMPLE: MSSpike Result 50149885003 1,1,1,2-Tetrachloroethane ug/L 44.950 90 44-142ND 1,1,1-Trichloroethane ug/L 57.250 114 51-140ND 1,1,2,2-Tetrachloroethane ug/L 43.350 87 49-138ND 1,1,2-Trichloroethane ug/L 42.450 85 51-138ND 1,1-Dichloroethane ug/L 43.650 87 48-137ND 1,1-Dichloroethene ug/L 43.350 87 51-144ND 1,1-Dichloropropene ug/L 47.050 94 54-150ND 1,2,3-Trichlorobenzene ug/L 44.050 88 32-140ND 1,2,3-Trichloropropane ug/L 46.050 92 51-139ND 1,2,4-Trichlorobenzene ug/L 40.350 81 27-134ND 1,2,4-Trimethylbenzene ug/L 45.350 91 32-143ND 1,2-Dibromoethane (EDB)ug/L 43.950 88 52-134ND 1,2-Dichlorobenzene ug/L 42.750 85 38-138ND 1,2-Dichloroethane ug/L 44.850 90 44-144ND 1,2-Dichloropropane ug/L 49.750 99 56-138ND 1,3,5-Trimethylbenzene ug/L 46.150 92 28-146ND 1,3-Dichlorobenzene ug/L 43.050 86 36-139ND 1,3-Dichloropropane ug/L 46.050 92 54-137ND 1,4-Dichlorobenzene ug/L 41.250 82 34-134ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 23 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1592151MATRIX SPIKE SAMPLE: MSSpike Result 50149885003 1-Methylnaphthalene ug/L 36.3 N2507332-150ND 2,2-Dichloropropane ug/L 45.950 92 20-142ND 2-Butanone (MEK)ug/L 214250 86 44-142ND 2-Chlorotoluene ug/L 41.550 83 36-143ND 2-Hexanone ug/L 220250 88 43-150ND 2-Methylnaphthalene ug/L 31.750 63 27-148ND 4-Chlorotoluene ug/L 45.150 90 34-143ND 4-Methyl-2-pentanone (MIBK)ug/L 248250 99 46-143ND Acetone ug/L 203250 81 33-150ND Acrolein ug/L 7821000 78 32-200ND Acrylonitrile ug/L 181200 91 47-143ND Benzene ug/L 45.050 90 51-140ND Bromobenzene ug/L 44.450 89 41-134ND Bromochloromethane ug/L 50.050 100 53-148ND Bromodichloromethane ug/L 48.550 97 46-137ND Bromoform ug/L 36.750 73 36-127ND Bromomethane ug/L 39.750 79 10-188ND Carbon disulfide ug/L 39.650 79 35-148ND Carbon tetrachloride ug/L 59.750 119 45-151ND Chlorobenzene ug/L 43.450 87 45-138ND Chloroethane ug/L 40.450 81 33-164ND Chloroform ug/L 43.250 86 50-135ND Chloromethane ug/L 35.650 71 38-146ND cis-1,2-Dichloroethene ug/L 45.750 91 43-144ND cis-1,3-Dichloropropene ug/L 42.050 84 42-136ND Dibromochloromethane ug/L 41.250 82 45-136ND Dibromomethane ug/L 44.450 89 51-139ND Dichlorodifluoromethane ug/L 42.850 86 29-174ND Ethyl methacrylate ug/L 177200 88 44-150ND Ethylbenzene ug/L 44.850 90 36-146ND Hexachloro-1,3-butadiene ug/L 42.750 85 14-150ND Iodomethane ug/L 56.1100 56 28-153ND Isopropylbenzene (Cumene)ug/L 49.450 99 43-159ND Methyl-tert-butyl ether ug/L 45.550 91 43-146ND Methylene Chloride ug/L 45.450 91 48-140ND n-Butylbenzene ug/L 45.950 92 16-152ND n-Hexane ug/L 45.650 91 40-144ND n-Propylbenzene ug/L 45.650 91 28-157ND Naphthalene ug/L 42.450 85 38-141ND p-Isopropyltoluene ug/L 45.950 92 21-151ND sec-Butylbenzene ug/L 46.550 93 27-165ND Styrene ug/L 46.350 93 31-148ND tert-Butylbenzene ug/L 40.950 82 24-131ND Tetrachloroethene ug/L 45.750 91 38-139ND Toluene ug/L 41.850 84 44-140ND trans-1,2-Dichloroethene ug/L 47.150 94 50-139ND trans-1,3-Dichloropropene ug/L 42.050 84 37-138ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 24 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1592151MATRIX SPIKE SAMPLE: MSSpike Result 50149885003 trans-1,4-Dichloro-2-butene ug/L 139200 70 10-157ND Trichloroethene ug/L 43.050 86 44-146ND Trichlorofluoromethane ug/L 58.950 118 41-164ND Vinyl acetate ug/L 172200 86 15-146ND Vinyl chloride ug/L 45.050 90 43-166ND Xylene (Total)ug/L 136150 90 35-146ND 4-Bromofluorobenzene (S)%.104 79-116 Dibromofluoromethane (S)%.101 84-118 Toluene-d8 (S)%.97 86-110 Parameter Units Dup Result Max RPD QualifiersRPDResult 50149885002 1592150SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 20ND 1,1,1-Trichloroethane ug/L ND 20ND 1,1,2,2-Tetrachloroethane ug/L ND 20ND 1,1,2-Trichloroethane ug/L ND 20ND 1,1-Dichloroethane ug/L ND 20ND 1,1-Dichloroethene ug/L ND 20ND 1,1-Dichloropropene ug/L ND 20ND 1,2,3-Trichlorobenzene ug/L ND 20ND 1,2,3-Trichloropropane ug/L ND 20ND 1,2,4-Trichlorobenzene ug/L ND 20ND 1,2,4-Trimethylbenzene ug/L 3.4J 20ND 1,2-Dibromoethane (EDB)ug/L ND 20ND 1,2-Dichlorobenzene ug/L ND 20ND 1,2-Dichloroethane ug/L ND 20ND 1,2-Dichloropropane ug/L ND 20ND 1,3,5-Trimethylbenzene ug/L ND 20ND 1,3-Dichlorobenzene ug/L ND 20ND 1,3-Dichloropropane ug/L ND 20ND 1,4-Dichlorobenzene ug/L ND 20ND 1-Methylnaphthalene ug/L ND N220ND 2,2-Dichloropropane ug/L ND 20ND 2-Butanone (MEK)ug/L ND 20ND 2-Chlorotoluene ug/L ND 20ND 2-Hexanone ug/L ND 20ND 2-Methylnaphthalene ug/L ND 20ND 4-Chlorotoluene ug/L ND 20ND 4-Methyl-2-pentanone (MIBK)ug/L ND 20ND Acetone ug/L ND 20ND Acrolein ug/L ND 20ND Acrylonitrile ug/L ND 20ND Benzene ug/L ND 20ND Bromobenzene ug/L ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 25 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 50149885002 1592150SAMPLE DUPLICATE: Bromochloromethane ug/L ND 20ND Bromodichloromethane ug/L ND 20ND Bromoform ug/L ND 20ND Bromomethane ug/L ND 20ND Carbon disulfide ug/L ND 20ND Carbon tetrachloride ug/L ND 20ND Chlorobenzene ug/L ND 20ND Chloroethane ug/L ND 20ND Chloroform ug/L ND 20ND Chloromethane ug/L ND 20ND cis-1,2-Dichloroethene ug/L ND 20ND cis-1,3-Dichloropropene ug/L ND 20ND Dibromochloromethane ug/L ND 20ND Dibromomethane ug/L ND 20ND Dichlorodifluoromethane ug/L ND 20ND Ethyl methacrylate ug/L ND 20ND Ethylbenzene ug/L ND 20ND Hexachloro-1,3-butadiene ug/L ND 20ND Iodomethane ug/L ND 20ND Isopropylbenzene (Cumene)ug/L ND 20ND Methyl-tert-butyl ether ug/L ND 20ND Methylene Chloride ug/L ND 20ND n-Butylbenzene ug/L ND 20ND n-Hexane ug/L ND 20ND n-Propylbenzene ug/L ND 20ND Naphthalene ug/L ND 20ND p-Isopropyltoluene ug/L ND 20ND sec-Butylbenzene ug/L ND 20ND Styrene ug/L ND 20ND tert-Butylbenzene ug/L ND 20ND Tetrachloroethene ug/L ND 20ND Toluene ug/L 17.8 9 2019.4 trans-1,2-Dichloroethene ug/L ND 20ND trans-1,3-Dichloropropene ug/L ND 20ND trans-1,4-Dichloro-2-butene ug/L ND 20ND Trichloroethene ug/L ND 20ND Trichlorofluoromethane ug/L ND 20ND Vinyl acetate ug/L ND 20ND Vinyl chloride ug/L ND 20ND Xylene (Total)ug/L 60.6 7 2064.7 4-Bromofluorobenzene (S)%.100 2102 Dibromofluoromethane (S)%.100 397 Toluene-d8 (S)%.97 097 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 26 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344221 EPA 8260 EPA 8260 8260 MSV 5035A Volatile Organics Associated Lab Samples:50149912001, 50149912003, 50149912004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1593658 Associated Lab Samples:50149912001, 50149912003, 50149912004 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 07/28/16 14:47 1,1,1-Trichloroethane mg/kg ND 0.0050 07/28/16 14:47 1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 07/28/16 14:47 1,1,2-Trichloroethane mg/kg ND 0.0050 07/28/16 14:47 1,1-Dichloroethane mg/kg ND 0.0050 07/28/16 14:47 1,1-Dichloroethene mg/kg ND 0.0050 07/28/16 14:47 1,1-Dichloropropene mg/kg ND 0.0050 07/28/16 14:47 1,2,3-Trichlorobenzene mg/kg ND 0.0050 07/28/16 14:47 1,2,3-Trichloropropane mg/kg ND 0.0050 07/28/16 14:47 1,2,4-Trichlorobenzene mg/kg ND 0.0050 07/28/16 14:47 1,2,4-Trimethylbenzene mg/kg ND 0.0050 07/28/16 14:47 1,2-Dibromoethane (EDB)mg/kg ND 0.0050 07/28/16 14:47 1,2-Dichlorobenzene mg/kg ND 0.0050 07/28/16 14:47 1,2-Dichloroethane mg/kg ND 0.0050 07/28/16 14:47 1,2-Dichloropropane mg/kg ND 0.0050 07/28/16 14:47 1,3,5-Trimethylbenzene mg/kg ND 0.0050 07/28/16 14:47 1,3-Dichlorobenzene mg/kg ND 0.0050 07/28/16 14:47 1,3-Dichloropropane mg/kg ND 0.0050 07/28/16 14:47 1,4-Dichlorobenzene mg/kg ND 0.0050 07/28/16 14:47 2,2-Dichloropropane mg/kg ND 0.0050 07/28/16 14:47 2-Butanone (MEK)mg/kg ND 0.025 07/28/16 14:47 2-Chlorotoluene mg/kg ND 0.0050 07/28/16 14:47 2-Hexanone mg/kg ND 0.10 07/28/16 14:47 4-Chlorotoluene mg/kg ND 0.0050 07/28/16 14:47 4-Methyl-2-pentanone (MIBK)mg/kg ND 0.025 07/28/16 14:47 Acetone mg/kg ND 0.10 07/28/16 14:47 Acrolein mg/kg ND 0.10 07/28/16 14:47 Acrylonitrile mg/kg ND 0.10 07/28/16 14:47 Benzene mg/kg ND 0.0050 07/28/16 14:47 Bromobenzene mg/kg ND 0.0050 07/28/16 14:47 Bromochloromethane mg/kg ND 0.0050 07/28/16 14:47 Bromodichloromethane mg/kg ND 0.0050 07/28/16 14:47 Bromoform mg/kg ND 0.0050 07/28/16 14:47 Bromomethane mg/kg ND 0.0050 07/28/16 14:47 Carbon disulfide mg/kg ND 0.010 07/28/16 14:47 Carbon tetrachloride mg/kg ND 0.0050 07/28/16 14:47 Chlorobenzene mg/kg ND 0.0050 07/28/16 14:47 Chloroethane mg/kg ND 0.0050 07/28/16 14:47 Chloroform mg/kg ND 0.0050 07/28/16 14:47 Chloromethane mg/kg ND 0.0050 07/28/16 14:47 cis-1,2-Dichloroethene mg/kg ND 0.0050 07/28/16 14:47 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 27 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1593658 Associated Lab Samples:50149912001, 50149912003, 50149912004 Matrix:Solid Analyzed cis-1,3-Dichloropropene mg/kg ND 0.0050 07/28/16 14:47 Dibromochloromethane mg/kg ND 0.0050 07/28/16 14:47 Dibromomethane mg/kg ND 0.0050 07/28/16 14:47 Dichlorodifluoromethane mg/kg ND 0.0050 07/28/16 14:47 Ethyl methacrylate mg/kg ND 0.10 07/28/16 14:47 Ethylbenzene mg/kg ND 0.0050 07/28/16 14:47 Hexachloro-1,3-butadiene mg/kg ND 0.0050 07/28/16 14:47 Iodomethane mg/kg ND 0.10 07/28/16 14:47 Isopropylbenzene (Cumene)mg/kg ND 0.0050 07/28/16 14:47 Methyl-tert-butyl ether mg/kg ND 0.0050 07/28/16 14:47 Methylene Chloride mg/kg ND 0.020 07/28/16 14:47 n-Butylbenzene mg/kg ND 0.0050 07/28/16 14:47 n-Hexane mg/kg ND 0.0050 07/28/16 14:47 n-Propylbenzene mg/kg ND 0.0050 07/28/16 14:47 Naphthalene mg/kg ND 0.0050 07/28/16 14:47 p-Isopropyltoluene mg/kg ND 0.0050 07/28/16 14:47 sec-Butylbenzene mg/kg ND 0.0050 07/28/16 14:47 Styrene mg/kg ND 0.0050 07/28/16 14:47 tert-Butylbenzene mg/kg ND 0.0050 07/28/16 14:47 Tetrachloroethene mg/kg ND 0.0050 07/28/16 14:47 Toluene mg/kg ND 0.0050 07/28/16 14:47 trans-1,2-Dichloroethene mg/kg ND 0.0050 07/28/16 14:47 trans-1,3-Dichloropropene mg/kg ND 0.0050 07/28/16 14:47 trans-1,4-Dichloro-2-butene mg/kg ND 0.10 07/28/16 14:47 Trichloroethene mg/kg ND 0.0050 07/28/16 14:47 Trichlorofluoromethane mg/kg ND 0.0050 07/28/16 14:47 Vinyl acetate mg/kg ND 0.10 07/28/16 14:47 Vinyl chloride mg/kg ND 0.0050 07/28/16 14:47 Xylene (Total)mg/kg ND 0.010 07/28/16 14:47 4-Bromofluorobenzene (S)%.99 65-127 07/28/16 14:47 Dibromofluoromethane (S)%.104 70-128 07/28/16 14:47 Toluene-d8 (S)%.96 72-139 07/28/16 14:47 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1593659LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1-Trichloroethane mg/kg 0.054.05 109 67-123 1,1,2,2-Tetrachloroethane mg/kg 0.050.05 100 67-129 1,1-Dichloroethene mg/kg 0.058.05 116 64-133 1,2,4-Trimethylbenzene mg/kg 0.048.05 95 66-118 1,2-Dichloropropane mg/kg 0.049.05 98 74-119 Benzene mg/kg 0.052.05 104 72-120 Chlorobenzene mg/kg 0.048.05 96 72-115 Chloroform mg/kg 0.050.05 100 66-116 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 28 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1593659LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene mg/kg 0.053.05 107 74-115 Ethylbenzene mg/kg 0.048.05 96 70-121 Isopropylbenzene (Cumene)mg/kg 0.048.05 95 78-130 Methyl-tert-butyl ether mg/kg 0.053.05 106 68-123 Naphthalene mg/kg 0.045.05 91 63-125 Tetrachloroethene mg/kg 0.048.05 95 66-118 Toluene mg/kg 0.048.05 95 68-121 trans-1,2-Dichloroethene mg/kg 0.054.05 107 71-120 Trichloroethene mg/kg 0.053.05 106 73-120 Vinyl chloride mg/kg 0.059.05 118 54-155 Xylene (Total)mg/kg 0.14.15 94 69-122 4-Bromofluorobenzene (S)%.100 65-127 Dibromofluoromethane (S)%.106 70-128 Toluene-d8 (S)%.103 72-139 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 29 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344431 EPA 8260 EPA 8260 8260 MSV 5035A Volatile Organics Associated Lab Samples:50149912002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1594760 Associated Lab Samples:50149912002 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 07/29/16 14:35 1,1,1-Trichloroethane mg/kg ND 0.0050 07/29/16 14:35 1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 07/29/16 14:35 1,1,2-Trichloroethane mg/kg ND 0.0050 07/29/16 14:35 1,1-Dichloroethane mg/kg ND 0.0050 07/29/16 14:35 1,1-Dichloroethene mg/kg ND 0.0050 07/29/16 14:35 1,1-Dichloropropene mg/kg ND 0.0050 07/29/16 14:35 1,2,3-Trichlorobenzene mg/kg ND 0.0050 07/29/16 14:35 1,2,3-Trichloropropane mg/kg ND 0.0050 07/29/16 14:35 1,2,4-Trichlorobenzene mg/kg ND 0.0050 07/29/16 14:35 1,2,4-Trimethylbenzene mg/kg ND 0.0050 07/29/16 14:35 1,2-Dibromoethane (EDB)mg/kg ND 0.0050 07/29/16 14:35 1,2-Dichlorobenzene mg/kg ND 0.0050 07/29/16 14:35 1,2-Dichloroethane mg/kg ND 0.0050 07/29/16 14:35 1,2-Dichloropropane mg/kg ND 0.0050 07/29/16 14:35 1,3,5-Trimethylbenzene mg/kg ND 0.0050 07/29/16 14:35 1,3-Dichlorobenzene mg/kg ND 0.0050 07/29/16 14:35 1,3-Dichloropropane mg/kg ND 0.0050 07/29/16 14:35 1,4-Dichlorobenzene mg/kg ND 0.0050 07/29/16 14:35 2,2-Dichloropropane mg/kg ND 0.0050 07/29/16 14:35 2-Butanone (MEK)mg/kg ND 0.025 07/29/16 14:35 2-Chlorotoluene mg/kg ND 0.0050 07/29/16 14:35 2-Hexanone mg/kg ND 0.10 07/29/16 14:35 4-Chlorotoluene mg/kg ND 0.0050 07/29/16 14:35 4-Methyl-2-pentanone (MIBK)mg/kg ND 0.025 07/29/16 14:35 Acetone mg/kg ND 0.10 07/29/16 14:35 Acrolein mg/kg ND 0.10 07/29/16 14:35 Acrylonitrile mg/kg ND 0.10 07/29/16 14:35 Benzene mg/kg ND 0.0050 07/29/16 14:35 Bromobenzene mg/kg ND 0.0050 07/29/16 14:35 Bromochloromethane mg/kg ND 0.0050 07/29/16 14:35 Bromodichloromethane mg/kg ND 0.0050 07/29/16 14:35 Bromoform mg/kg ND 0.0050 07/29/16 14:35 Bromomethane mg/kg ND 0.0050 07/29/16 14:35 Carbon disulfide mg/kg ND 0.010 07/29/16 14:35 Carbon tetrachloride mg/kg ND 0.0050 07/29/16 14:35 Chlorobenzene mg/kg ND 0.0050 07/29/16 14:35 Chloroethane mg/kg ND 0.0050 07/29/16 14:35 Chloroform mg/kg ND 0.0050 07/29/16 14:35 Chloromethane mg/kg ND 0.0050 07/29/16 14:35 cis-1,2-Dichloroethene mg/kg ND 0.0050 07/29/16 14:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 30 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1594760 Associated Lab Samples:50149912002 Matrix:Solid Analyzed cis-1,3-Dichloropropene mg/kg ND 0.0050 07/29/16 14:35 Dibromochloromethane mg/kg ND 0.0050 07/29/16 14:35 Dibromomethane mg/kg ND 0.0050 07/29/16 14:35 Dichlorodifluoromethane mg/kg ND 0.0050 07/29/16 14:35 Ethyl methacrylate mg/kg ND 0.10 07/29/16 14:35 Ethylbenzene mg/kg ND 0.0050 07/29/16 14:35 Hexachloro-1,3-butadiene mg/kg ND 0.0050 07/29/16 14:35 Iodomethane mg/kg ND 0.10 07/29/16 14:35 Isopropylbenzene (Cumene)mg/kg ND 0.0050 07/29/16 14:35 Methyl-tert-butyl ether mg/kg ND 0.0050 07/29/16 14:35 Methylene Chloride mg/kg ND 0.020 07/29/16 14:35 n-Butylbenzene mg/kg ND 0.0050 07/29/16 14:35 n-Hexane mg/kg ND 0.0050 07/29/16 14:35 n-Propylbenzene mg/kg ND 0.0050 07/29/16 14:35 Naphthalene mg/kg ND 0.0050 07/29/16 14:35 p-Isopropyltoluene mg/kg ND 0.0050 07/29/16 14:35 sec-Butylbenzene mg/kg ND 0.0050 07/29/16 14:35 Styrene mg/kg ND 0.0050 07/29/16 14:35 tert-Butylbenzene mg/kg ND 0.0050 07/29/16 14:35 Tetrachloroethene mg/kg ND 0.0050 07/29/16 14:35 Toluene mg/kg ND 0.0050 07/29/16 14:35 trans-1,2-Dichloroethene mg/kg ND 0.0050 07/29/16 14:35 trans-1,3-Dichloropropene mg/kg ND 0.0050 07/29/16 14:35 trans-1,4-Dichloro-2-butene mg/kg ND 0.10 07/29/16 14:35 Trichloroethene mg/kg ND 0.0050 07/29/16 14:35 Trichlorofluoromethane mg/kg ND 0.0050 07/29/16 14:35 Vinyl acetate mg/kg ND 0.10 07/29/16 14:35 Vinyl chloride mg/kg ND 0.0050 07/29/16 14:35 Xylene (Total)mg/kg ND 0.010 07/29/16 14:35 4-Bromofluorobenzene (S)%.96 65-127 07/29/16 14:35 Dibromofluoromethane (S)%.103 70-128 07/29/16 14:35 Toluene-d8 (S)%.100 72-139 07/29/16 14:35 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1594761LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1-Trichloroethane mg/kg 0.052.05 104 67-123 1,1,2,2-Tetrachloroethane mg/kg 0.050.05 100 67-129 1,1-Dichloroethene mg/kg 0.053.05 107 64-133 1,2,4-Trimethylbenzene mg/kg 0.048.05 96 66-118 1,2-Dichloropropane mg/kg 0.049.05 97 74-119 Benzene mg/kg 0.048.05 96 72-120 Chlorobenzene mg/kg 0.047.05 94 72-115 Chloroform mg/kg 0.047.05 94 66-116 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 31 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1594761LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene mg/kg 0.050.05 100 74-115 Ethylbenzene mg/kg 0.049.05 98 70-121 Isopropylbenzene (Cumene)mg/kg 0.046.05 91 78-130 Methyl-tert-butyl ether mg/kg 0.052.05 103 68-123 Naphthalene mg/kg 0.047.05 95 63-125 Tetrachloroethene mg/kg 0.047.05 94 66-118 Toluene mg/kg 0.045.05 90 68-121 trans-1,2-Dichloroethene mg/kg 0.053.05 106 71-120 Trichloroethene mg/kg 0.051.05 103 73-120 Vinyl chloride mg/kg 0.048.05 96 54-155 Xylene (Total)mg/kg 0.14.15 92 69-122 4-Bromofluorobenzene (S)%.100 65-127 Dibromofluoromethane (S)%.102 70-128 Toluene-d8 (S)%.101 72-139 Parameter Units MS Result % Rec Limits Qual% RecConc. 1594762MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50149912002 1594763 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1-Trichloroethane mg/kg .057 102 37-144103 11 20.051ND 0.059 0.053 1,1,2,2-Tetrachloroethane mg/kg .057 106 12-174105 13 20.051ND 0.061 0.054 1,1-Dichloroethene mg/kg .057 106 36-162109 9 20.051ND 0.061 0.056 1,2,4-Trimethylbenzene mg/kg .057 105 10-157102 15 20.051ND 0.061 0.052 1,2-Dichloropropane mg/kg .057 97 43-13894 15 20.051ND 0.056 0.048 Benzene mg/kg .057 94 36-14492 14 20.051ND 0.054 0.047 Chlorobenzene mg/kg .057 96 16-14099 9 20.051ND 0.055 0.051 Chloroform mg/kg .057 93 39-13691 14 20.051ND 0.054 0.047 cis-1,2-Dichloroethene mg/kg .057 104 34-14399 17 20.051ND 0.060 0.051 Ethylbenzene mg/kg .057 99 15-14799 12 20.051ND 0.057 0.051 Isopropylbenzene (Cumene)mg/kg .057 97 10-16394 15 20.051ND 0.056 0.048 Methyl-tert-butyl ether mg/kg .057 99 48-14595 15 20.051ND 0.057 0.049 Naphthalene mg/kg .057 72 10-13274 10 20.051ND 0.042 0.038 Tetrachloroethene mg/kg .057 105 14-156103 13 20.051ND 0.061 0.053 Toluene mg/kg .057 94 24-15193 13 20.051ND 0.055 0.048 trans-1,2-Dichloroethene mg/kg .057 104 33-147106 11 20.051ND 0.060 0.054 Trichloroethene mg/kg .057 100 21-16497 16 20.051ND 0.058 0.050 Vinyl chloride mg/kg .057 98 32-17797 13 20.051ND 0.057 0.050 Xylene (Total)mg/kg .17 95 12-14896 12 20.16ND 0.17 0.15 4-Bromofluorobenzene (S)%.95 65-12792 Dibromofluoromethane (S)%.98 70-12899 Toluene-d8 (S)%.104 72-139103 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 32 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343229 EPA 3546 EPA 8270 by SIM 8270 MSSV PAH by SIM Associated Lab Samples:50149912001, 50149912002, 50149912003, 50149912004 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1589764 Associated Lab Samples:50149912001, 50149912002, 50149912003, 50149912004 Matrix:Solid Analyzed 1-Methylnaphthalene mg/kg ND 0.0050 N207/25/16 15:15 2-Methylnaphthalene mg/kg ND 0.0050 07/25/16 15:15 Acenaphthene mg/kg ND 0.0050 07/25/16 15:15 Acenaphthylene mg/kg ND 0.0050 07/25/16 15:15 Anthracene mg/kg ND 0.0050 07/25/16 15:15 Benzo(a)anthracene mg/kg ND 0.0050 07/25/16 15:15 Benzo(a)pyrene mg/kg ND 0.0050 07/25/16 15:15 Benzo(b)fluoranthene mg/kg ND 0.0050 07/25/16 15:15 Benzo(g,h,i)perylene mg/kg ND 0.0050 07/25/16 15:15 Benzo(k)fluoranthene mg/kg ND 0.0050 07/25/16 15:15 Chrysene mg/kg ND 0.0050 07/25/16 15:15 Dibenz(a,h)anthracene mg/kg ND 0.0050 07/25/16 15:15 Fluoranthene mg/kg ND 0.0050 07/25/16 15:15 Fluorene mg/kg ND 0.0050 07/25/16 15:15 Indeno(1,2,3-cd)pyrene mg/kg ND 0.0050 07/25/16 15:15 Naphthalene mg/kg ND 0.0050 07/25/16 15:15 Phenanthrene mg/kg ND 0.0050 07/25/16 15:15 Pyrene mg/kg ND 0.0050 07/25/16 15:15 2-Fluorobiphenyl (S)%.84 25-121 07/25/16 15:15 p-Terphenyl-d14 (S)%.101 27-124 07/25/16 15:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589765LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene mg/kg 0.25 N2.33 77 41-109 2-Methylnaphthalene mg/kg 0.25.33 76 39-109 Acenaphthene mg/kg 0.28.33 84 44-127 Acenaphthylene mg/kg 0.27.33 80 43-128 Anthracene mg/kg 0.29.33 88 49-131 Benzo(a)anthracene mg/kg 0.32.33 95 52-128 Benzo(a)pyrene mg/kg 0.26.33 77 54-141 Benzo(b)fluoranthene mg/kg 0.25.33 75 50-146 Benzo(g,h,i)perylene mg/kg 0.26.33 77 51-141 Benzo(k)fluoranthene mg/kg 0.27.33 81 55-139 Chrysene mg/kg 0.32.33 97 56-131 Dibenz(a,h)anthracene mg/kg 0.25.33 74 53-142 Fluoranthene mg/kg 0.30.33 89 51-139 Fluorene mg/kg 0.28.33 85 45-131 Indeno(1,2,3-cd)pyrene mg/kg 0.25.33 74 51-141 Naphthalene mg/kg 0.25.33 76 43-112 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 33 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589765LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene mg/kg 0.30.33 91 47-132 Pyrene mg/kg 0.33.33 99 55-130 2-Fluorobiphenyl (S)%.76 25-121 p-Terphenyl-d14 (S)%.87 27-124 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589766MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50149912002 1589767 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene mg/kg N2.4 72 17-11875 4 20.4ND 0.29 0.30 2-Methylnaphthalene mg/kg .4 70 15-11872 3 20.4ND 0.28 0.29 Acenaphthene mg/kg .4 78 21-12578 1 20.4ND 0.32 0.32 Acenaphthylene mg/kg .4 77 21-12679 2 20.4ND 0.31 0.32 Anthracene mg/kg .4 83 15-13476 9 20.4ND 0.33 0.31 Benzo(a)anthracene mg/kg .4 93 14-12986 8 20.4ND 0.38 0.35 Benzo(a)pyrene mg/kg .4 67 10-14663 8 20.4ND 0.27 0.25 Benzo(b)fluoranthene mg/kg .4 71 10-14662 14 20.4ND 0.29 0.25 Benzo(g,h,i)perylene mg/kg .4 68 10-14263 7 20.4ND 0.28 0.26 Benzo(k)fluoranthene mg/kg .4 70 10-14771 1 20.4ND 0.28 0.29 Chrysene mg/kg .4 84 11-14080 5 20.4ND 0.34 0.32 Dibenz(a,h)anthracene mg/kg .4 67 16-13665 4 20.4ND 0.27 0.26 Fluoranthene mg/kg .4 86 10-14680 7 20.4ND 0.35 0.33 Fluorene mg/kg .4 81 20-13182 1 20.4ND 0.33 0.33 Indeno(1,2,3-cd)pyrene mg/kg .4 67 10-14662 8 20.4ND 0.27 0.25 Naphthalene mg/kg .4 73 15-12674 0 20.4ND 0.30 0.30 Phenanthrene mg/kg .4 83 10-14880 4 20.4ND 0.34 0.32 Pyrene mg/kg .4 84 14-13679 6 20.4ND 0.34 0.32 2-Fluorobiphenyl (S)%.70 25-12177 p-Terphenyl-d14 (S)%.74 27-12475 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589768MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150209023 1589769 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene mg/kg N2.4 100 17-118110 8 20.466.0 ug/kg 0.47 0.51 2-Methylnaphthalene mg/kg .4 103 15-118113 9 20.482.9 ug/kg 0.50 0.54 Acenaphthene mg/kg .4 85 21-12588 3 20.4ND 0.34 0.36 Acenaphthylene mg/kg .4 80 21-12678 2 20.4ND 0.32 0.32 Anthracene mg/kg .4 89 15-13489 1 20.4ND 0.36 0.36 Benzo(a)anthracene mg/kg .4 93 14-129101 9 20.423.2 ug/kg 0.40 0.43 Benzo(a)pyrene mg/kg .4 70 10-14678 11 20.4ND 0.28 0.32 Benzo(b)fluoranthene mg/kg .4 68 10-14681 18 20.4ND 0.27 0.33 Benzo(g,h,i)perylene mg/kg .4 71 10-14273 3 20.4ND 0.29 0.30 Benzo(k)fluoranthene mg/kg .4 77 10-14772 7 20.4ND 0.31 0.29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 34 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1589768MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150209023 1589769 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chrysene mg/kg .4 86 11-14093 8 20.420.7 ug/kg 0.37 0.40 Dibenz(a,h)anthracene mg/kg .4 69 16-13667 3 20.4ND 0.28 0.27 Fluoranthene mg/kg .4 84 10-14696 13 20.427.1 ug/kg 0.37 0.42 Fluorene mg/kg .4 89 20-13197 9 20.4ND 0.36 0.39 Indeno(1,2,3-cd)pyrene mg/kg .4 68 10-14669 2 20.4ND 0.28 0.28 Naphthalene mg/kg .4 76 15-12678 3 20.436.9 ug/kg 0.34 0.35 Phenanthrene mg/kg .4 91 10-148100 9 20.438.8 ug/kg 0.41 0.44 Pyrene mg/kg .4 95 14-136107 11 20.428.8 ug/kg 0.41 0.46 2-Fluorobiphenyl (S)%.78 25-12175 p-Terphenyl-d14 (S)%.88 27-12481 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 35 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343778 SM 2540G SM 2540G Dry Weight/Percent Moisture Associated Lab Samples:50149912001, 50149912002, 50149912003 Parameter Units Dup Result Max RPD QualifiersRPDResult 50149903002 1591989SAMPLE DUPLICATE: Percent Moisture %5.3 R1755.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 50149912002 1591990SAMPLE DUPLICATE: Percent Moisture %17.6 2 518.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 36 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149912 LAKEVILLE Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343967 SM 2540G SM 2540G Dry Weight/Percent Moisture Associated Lab Samples:50149912004 Parameter Units Dup Result Max RPD QualifiersRPDResult 50149912004 1592520SAMPLE DUPLICATE: Percent Moisture %14.8 0 514.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 50150523001 1592521SAMPLE DUPLICATE: Percent Moisture %12.9 R16512.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 37 of 42 #=QL# QUALIFIERS Pace Project No.: Project: 50149912 LAKEVILLE DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - IndianapolisPASI-I ANALYTE QUALIFIERS Sample was diluted due to the presence of high levels of target analytes.D4 Analyte detected below reporting limit, therefore result is an estimate.J Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0 Matrix spike recovery was outside laboratory control limits due to matrix interferences.M3 The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 38 of 42 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 50149912 LAKEVILLE Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 50149912001 342639 343679LV-SB-1(012014)EPA 3050 EPA 6010 50149912002 342639 343679LV-SB-2(010012)EPA 3050 EPA 6010 50149912003 342639 343679LV-SB-3(010012)EPA 3050 EPA 6010 50149912004 342639 343679LV-FD-1 EPA 3050 EPA 6010 50149912001 343229 343387LV-SB-1(012014)EPA 3546 EPA 8270 by SIM 50149912002 343229 343387LV-SB-2(010012)EPA 3546 EPA 8270 by SIM 50149912003 343229 343387LV-SB-3(010012)EPA 3546 EPA 8270 by SIM 50149912004 343229 343387LV-FD-1 EPA 3546 EPA 8270 by SIM 50149912005 343833TRIP BLANK EPA 8260 50149912001 344221LV-SB-1(012014)EPA 8260 50149912002 344431LV-SB-2(010012)EPA 8260 50149912003 344221LV-SB-3(010012)EPA 8260 50149912004 344221LV-FD-1 EPA 8260 50149912001 343778LV-SB-1(012014)SM 2540G 50149912002 343778LV-SB-2(010012)SM 2540G 50149912003 343778LV-SB-3(010012)SM 2540G 50149912004 343967LV-FD-1 SM 2540G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/02/2016 01:12 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 39 of 42 Page 40 of 42 Page 41 of 42 Page 42 of 42 #=CL# August 04, 2016 LIMS USE: FR - NIVAS VIJAY LIMS OBJECT ID: 50150125 50150125 Project: Pace Project No.: RE: Nivas Vijay Heartland 3410 Mishawaka Ave. South Bend, IN 46615 214 W. Patterson St. Lakeville Dear Nivas Vijay: Enclosed are the analytical results for sample(s) received by the laboratory on July 21, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Mick Mayse mick.mayse@pacelabs.com Project Manager Enclosures cc:Nivas Vijay, Heartland Environmental REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 1 of 42 #=CP# CERTIFICATIONS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Indiana Certification IDs 7726 Moller Road, Indianapolis, IN 46268 Illinois Certification #: 200074 Indiana Certification #: C-49-06 Kansas/NELAP Certification #:E-10177 Kentucky UST Certification #: 0042 Kentucky WW Certification #:98019 Ohio VAP Certification #: CL-0065 Oklahoma Certification #: 2014-148 Texas Certification #: T104704355-15-9 West Virginia Certification #: 330 Wisconsin Certification #: 999788130 USDA Soil Permit #: P330-10-00128 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 2 of 42 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Lab ID Sample ID Matrix Date Collected Date Received 50150125001 LV-GW-SB-1 Water 07/20/16 11:55 07/21/16 08:35 50150125002 LV-GW-SB-2 Water 07/20/16 10:05 07/21/16 08:35 50150125003 LV-GW-SB-3 Water 07/20/16 11:25 07/21/16 08:35 50150125004 LV-GW-FD-1 Water 07/20/16 10:50 07/21/16 08:35 50150125005 LV-GW-ERB Water 07/20/16 12:35 07/21/16 08:35 50150125006 Trip Blank Water 07/20/16 08:00 07/21/16 08:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 3 of 42 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 50150125001 LV-GW-SB-1 EPA 6010 1 PASI-IMJC EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 75 PASI-IALA 50150125002 LV-GW-SB-2 EPA 6010 1 PASI-IMJC EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 75 PASI-IALA 50150125003 LV-GW-SB-3 EPA 6010 1 PASI-IMJC EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 75 PASI-IALA 50150125004 LV-GW-FD-1 EPA 6010 1 PASI-IMJC EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 75 PASI-IALA 50150125005 LV-GW-ERB EPA 6010 1 PASI-IMJC EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 75 PASI-IALA 50150125006 Trip Blank EPA 6010 1 PASI-IMJC EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 75 PASI-IALA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 4 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-SB-1 Lab ID:50150125001 Collected:07/20/16 11:55 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 2730 ug/L 07/27/16 09:47 7439-92-107/26/16 07:0850.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/22/16 16:56 83-32-907/21/16 20:351.0 1 Acenaphthylene ND ug/L 07/22/16 16:56 208-96-807/21/16 20:351.0 1 Anthracene 0.19 ug/L 07/22/16 16:56 120-12-707/21/16 20:350.10 1 Benzo(a)anthracene ND ug/L 07/22/16 16:56 56-55-307/21/16 20:350.10 1 Benzo(a)pyrene ND ug/L 07/22/16 16:56 50-32-807/21/16 20:350.10 1 Benzo(b)fluoranthene ND ug/L 07/22/16 16:56 205-99-207/21/16 20:350.10 1 Benzo(g,h,i)perylene ND ug/L 07/22/16 16:56 191-24-207/21/16 20:350.10 1 Benzo(k)fluoranthene ND ug/L 07/22/16 16:56 207-08-907/21/16 20:350.10 1 Chrysene ND ug/L 07/22/16 16:56 218-01-907/21/16 20:350.50 1 Dibenz(a,h)anthracene ND ug/L 07/22/16 16:56 53-70-307/21/16 20:350.10 1 Fluoranthene ND ug/L 07/22/16 16:56 206-44-007/21/16 20:351.0 1 Fluorene ND ug/L 07/22/16 16:56 86-73-707/21/16 20:351.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/22/16 16:56 193-39-507/21/16 20:350.10 1 1-Methylnaphthalene 30.1 ug/L 07/22/16 16:56 90-12-0 N207/21/16 20:351.0 1 2-Methylnaphthalene 48.7 ug/L 07/22/16 16:56 91-57-607/21/16 20:351.0 1 Naphthalene 69.9 ug/L 07/26/16 07:58 91-20-307/21/16 20:355.0 5 Phenanthrene 1.6 ug/L 07/22/16 16:56 85-01-807/21/16 20:351.0 1 Pyrene ND ug/L 07/22/16 16:56 129-00-007/21/16 20:351.0 1 Surrogates 2-Fluorobiphenyl (S)42 %.07/22/16 16:56 321-60-807/21/16 20:3518-117 1 p-Terphenyl-d14 (S)54 %.07/22/16 16:56 1718-51-007/21/16 20:3510-112 1 Analytical Method: EPA 82608260 MSV Indiana Acetone ND ug/L 08/02/16 14:30 67-64-15005 Acrolein ND ug/L 08/02/16 14:30 107-02-82505 Acrylonitrile ND ug/L 08/02/16 14:30 107-13-15005 Benzene 118 ug/L 08/02/16 14:30 71-43-225.0 5 Bromobenzene ND ug/L 08/02/16 14:30 108-86-125.0 5 Bromochloromethane ND ug/L 08/02/16 14:30 74-97-525.0 5 Bromodichloromethane ND ug/L 08/02/16 14:30 75-27-425.0 5 Bromoform ND ug/L 08/02/16 14:30 75-25-225.0 5 Bromomethane ND ug/L 08/02/16 14:30 74-83-925.0 5 2-Butanone (MEK)ND ug/L 08/02/16 14:30 78-93-31255 n-Butylbenzene ND ug/L 08/02/16 14:30 104-51-825.0 5 sec-Butylbenzene ND ug/L 08/02/16 14:30 135-98-825.0 5 tert-Butylbenzene ND ug/L 08/02/16 14:30 98-06-625.0 5 Carbon disulfide ND ug/L 08/02/16 14:30 75-15-050.0 5 Carbon tetrachloride ND ug/L 08/02/16 14:30 56-23-525.0 5 Chlorobenzene ND ug/L 08/02/16 14:30 108-90-725.0 5 Chloroethane ND ug/L 08/02/16 14:30 75-00-325.0 5 Chloroform ND ug/L 08/02/16 14:30 67-66-325.0 5 Chloromethane ND ug/L 08/02/16 14:30 74-87-325.0 5 2-Chlorotoluene ND ug/L 08/02/16 14:30 95-49-825.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 5 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-SB-1 Lab ID:50150125001 Collected:07/20/16 11:55 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 4-Chlorotoluene ND ug/L 08/02/16 14:30 106-43-425.0 5 Dibromochloromethane ND ug/L 08/02/16 14:30 124-48-125.0 5 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 14:30 106-93-425.0 5 Dibromomethane ND ug/L 08/02/16 14:30 74-95-325.0 5 1,2-Dichlorobenzene ND ug/L 08/02/16 14:30 95-50-125.0 5 1,3-Dichlorobenzene ND ug/L 08/02/16 14:30 541-73-125.0 5 1,4-Dichlorobenzene ND ug/L 08/02/16 14:30 106-46-725.0 5 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 14:30 110-57-65005 Dichlorodifluoromethane ND ug/L 08/02/16 14:30 75-71-825.0 5 1,1-Dichloroethane ND ug/L 08/02/16 14:30 75-34-325.0 5 1,2-Dichloroethane ND ug/L 08/02/16 14:30 107-06-225.0 5 1,1-Dichloroethene ND ug/L 08/02/16 14:30 75-35-425.0 5 cis-1,2-Dichloroethene ND ug/L 08/02/16 14:30 156-59-225.0 5 trans-1,2-Dichloroethene ND ug/L 08/02/16 14:30 156-60-525.0 5 1,2-Dichloropropane ND ug/L 08/02/16 14:30 78-87-525.0 5 1,3-Dichloropropane ND ug/L 08/02/16 14:30 142-28-925.0 5 2,2-Dichloropropane ND ug/L 08/02/16 14:30 594-20-725.0 5 1,1-Dichloropropene ND ug/L 08/02/16 14:30 563-58-625.0 5 cis-1,3-Dichloropropene ND ug/L 08/02/16 14:30 10061-01-525.0 5 trans-1,3-Dichloropropene ND ug/L 08/02/16 14:30 10061-02-625.0 5 Ethylbenzene 769 ug/L 08/02/16 14:30 100-41-425.0 5 Ethyl methacrylate ND ug/L 08/02/16 14:30 97-63-25005 Hexachloro-1,3-butadiene ND ug/L 08/02/16 14:30 87-68-325.0 5 n-Hexane 138 ug/L 08/02/16 14:30 110-54-325.0 5 2-Hexanone ND ug/L 08/02/16 14:30 591-78-61255 Iodomethane ND ug/L 08/02/16 14:30 74-88-450.0 5 Isopropylbenzene (Cumene)49.8 ug/L 08/02/16 14:30 98-82-825.0 5 p-Isopropyltoluene ND ug/L 08/02/16 14:30 99-87-625.0 5 Methylene Chloride ND ug/L 08/02/16 14:30 75-09-225.0 5 1-Methylnaphthalene 132 ug/L 08/02/16 14:30 90-12-0 N225.0 5 2-Methylnaphthalene 219 ug/L 08/02/16 14:30 91-57-650.0 5 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 14:30 108-10-11255 Methyl-tert-butyl ether ND ug/L 08/02/16 14:30 1634-04-420.0 5 Naphthalene 327 ug/L 08/02/16 14:30 91-20-38.5 5 n-Propylbenzene 145 ug/L 08/02/16 14:30 103-65-125.0 5 Styrene ND ug/L 08/02/16 14:30 100-42-525.0 5 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 14:30 630-20-625.0 5 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 14:30 79-34-525.0 5 Tetrachloroethene ND ug/L 08/02/16 14:30 127-18-425.0 5 Toluene ND ug/L 08/02/16 14:30 108-88-325.0 5 1,2,3-Trichlorobenzene ND ug/L 08/02/16 14:30 87-61-625.0 5 1,2,4-Trichlorobenzene ND ug/L 08/02/16 14:30 120-82-125.0 5 1,1,1-Trichloroethane ND ug/L 08/02/16 14:30 71-55-625.0 5 1,1,2-Trichloroethane ND ug/L 08/02/16 14:30 79-00-525.0 5 Trichloroethene ND ug/L 08/02/16 14:30 79-01-625.0 5 Trichlorofluoromethane ND ug/L 08/02/16 14:30 75-69-425.0 5 1,2,3-Trichloropropane ND ug/L 08/02/16 14:30 96-18-425.0 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 6 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-SB-1 Lab ID:50150125001 Collected:07/20/16 11:55 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 1,2,4-Trimethylbenzene 1050 ug/L 08/02/16 14:30 95-63-625.0 5 1,3,5-Trimethylbenzene 338 ug/L 08/02/16 14:30 108-67-825.0 5 Vinyl acetate ND ug/L 08/02/16 14:30 108-05-42505 Vinyl chloride ND ug/L 08/02/16 14:30 75-01-410.0 5 Xylene (Total)1920 ug/L 08/02/16 14:30 1330-20-750.0 5 Surrogates Dibromofluoromethane (S)101 %.08/02/16 14:30 1868-53-7 D484-118 5 4-Bromofluorobenzene (S)99 %.08/02/16 14:30 460-00-479-116 5 Toluene-d8 (S)99 %.08/02/16 14:30 2037-26-586-110 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 7 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-SB-2 Lab ID:50150125002 Collected:07/20/16 10:05 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 217 ug/L 07/27/16 09:49 7439-92-107/26/16 07:0810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/22/16 17:09 83-32-907/21/16 20:351.0 1 Acenaphthylene ND ug/L 07/22/16 17:09 208-96-807/21/16 20:351.0 1 Anthracene ND ug/L 07/22/16 17:09 120-12-707/21/16 20:350.10 1 Benzo(a)anthracene ND ug/L 07/22/16 17:09 56-55-307/21/16 20:350.10 1 Benzo(a)pyrene ND ug/L 07/22/16 17:09 50-32-807/21/16 20:350.10 1 Benzo(b)fluoranthene ND ug/L 07/22/16 17:09 205-99-207/21/16 20:350.10 1 Benzo(g,h,i)perylene ND ug/L 07/22/16 17:09 191-24-207/21/16 20:350.10 1 Benzo(k)fluoranthene ND ug/L 07/22/16 17:09 207-08-907/21/16 20:350.10 1 Chrysene ND ug/L 07/22/16 17:09 218-01-907/21/16 20:350.50 1 Dibenz(a,h)anthracene ND ug/L 07/22/16 17:09 53-70-307/21/16 20:350.10 1 Fluoranthene ND ug/L 07/22/16 17:09 206-44-007/21/16 20:351.0 1 Fluorene ND ug/L 07/22/16 17:09 86-73-707/21/16 20:351.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/22/16 17:09 193-39-507/21/16 20:350.10 1 1-Methylnaphthalene ND ug/L 07/22/16 17:09 90-12-0 N207/21/16 20:351.0 1 2-Methylnaphthalene ND ug/L 07/22/16 17:09 91-57-607/21/16 20:351.0 1 Naphthalene ND ug/L 07/22/16 17:09 91-20-307/21/16 20:351.0 1 Phenanthrene ND ug/L 07/22/16 17:09 85-01-807/21/16 20:351.0 1 Pyrene ND ug/L 07/22/16 17:09 129-00-007/21/16 20:351.0 1 Surrogates 2-Fluorobiphenyl (S)47 %.07/22/16 17:09 321-60-807/21/16 20:3518-117 1 p-Terphenyl-d14 (S)46 %.07/22/16 17:09 1718-51-007/21/16 20:3510-112 1 Analytical Method: EPA 82608260 MSV Indiana Acetone ND ug/L 08/01/16 22:44 67-64-11001 Acrolein ND ug/L 08/01/16 22:44 107-02-850.0 1 Acrylonitrile ND ug/L 08/01/16 22:44 107-13-11001 Benzene ND ug/L 08/01/16 22:44 71-43-25.0 1 Bromobenzene ND ug/L 08/01/16 22:44 108-86-15.0 1 Bromochloromethane ND ug/L 08/01/16 22:44 74-97-55.0 1 Bromodichloromethane ND ug/L 08/01/16 22:44 75-27-45.0 1 Bromoform ND ug/L 08/01/16 22:44 75-25-25.0 1 Bromomethane ND ug/L 08/01/16 22:44 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/01/16 22:44 78-93-325.0 1 n-Butylbenzene ND ug/L 08/01/16 22:44 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/01/16 22:44 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/01/16 22:44 98-06-65.0 1 Carbon disulfide ND ug/L 08/01/16 22:44 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/01/16 22:44 56-23-55.0 1 Chlorobenzene ND ug/L 08/01/16 22:44 108-90-75.0 1 Chloroethane ND ug/L 08/01/16 22:44 75-00-35.0 1 Chloroform ND ug/L 08/01/16 22:44 67-66-35.0 1 Chloromethane ND ug/L 08/01/16 22:44 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/01/16 22:44 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 8 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-SB-2 Lab ID:50150125002 Collected:07/20/16 10:05 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 4-Chlorotoluene ND ug/L 08/01/16 22:44 106-43-45.0 1 Dibromochloromethane ND ug/L 08/01/16 22:44 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/01/16 22:44 106-93-45.0 1 Dibromomethane ND ug/L 08/01/16 22:44 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/01/16 22:44 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/01/16 22:44 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/01/16 22:44 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/01/16 22:44 110-57-61001 Dichlorodifluoromethane ND ug/L 08/01/16 22:44 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/01/16 22:44 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/01/16 22:44 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/01/16 22:44 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/01/16 22:44 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/01/16 22:44 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/01/16 22:44 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/01/16 22:44 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/01/16 22:44 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/01/16 22:44 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/01/16 22:44 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/01/16 22:44 10061-02-65.0 1 Ethylbenzene ND ug/L 08/01/16 22:44 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/01/16 22:44 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/01/16 22:44 87-68-35.0 1 n-Hexane ND ug/L 08/01/16 22:44 110-54-35.0 1 2-Hexanone ND ug/L 08/01/16 22:44 591-78-625.0 1 Iodomethane ND ug/L 08/01/16 22:44 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/01/16 22:44 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/01/16 22:44 99-87-65.0 1 Methylene Chloride ND ug/L 08/01/16 22:44 75-09-25.0 1 1-Methylnaphthalene ND ug/L 08/01/16 22:44 90-12-0 N25.0 1 2-Methylnaphthalene ND ug/L 08/01/16 22:44 91-57-610.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/01/16 22:44 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/01/16 22:44 1634-04-44.0 1 Naphthalene ND ug/L 08/01/16 22:44 91-20-31.7 1 n-Propylbenzene ND ug/L 08/01/16 22:44 103-65-15.0 1 Styrene ND ug/L 08/01/16 22:44 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/01/16 22:44 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/01/16 22:44 79-34-55.0 1 Tetrachloroethene ND ug/L 08/01/16 22:44 127-18-45.0 1 Toluene ND ug/L 08/01/16 22:44 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/01/16 22:44 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/01/16 22:44 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/01/16 22:44 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/01/16 22:44 79-00-55.0 1 Trichloroethene ND ug/L 08/01/16 22:44 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/01/16 22:44 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/01/16 22:44 96-18-45.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 9 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-SB-2 Lab ID:50150125002 Collected:07/20/16 10:05 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 1,2,4-Trimethylbenzene ND ug/L 08/01/16 22:44 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/01/16 22:44 108-67-85.0 1 Vinyl acetate ND ug/L 08/01/16 22:44 108-05-450.0 1 Vinyl chloride ND ug/L 08/01/16 22:44 75-01-42.0 1 Xylene (Total)ND ug/L 08/01/16 22:44 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)117 %.08/01/16 22:44 1868-53-784-118 1 4-Bromofluorobenzene (S)107 %.08/01/16 22:44 460-00-479-116 1 Toluene-d8 (S)92 %.08/01/16 22:44 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 10 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-SB-3 Lab ID:50150125003 Collected:07/20/16 11:25 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 2970 ug/L 07/27/16 09:51 7439-92-107/26/16 07:0850.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/22/16 17:23 83-32-907/21/16 20:351.0 1 Acenaphthylene ND ug/L 07/22/16 17:23 208-96-807/21/16 20:351.0 1 Anthracene ND ug/L 07/22/16 17:23 120-12-707/21/16 20:350.10 1 Benzo(a)anthracene ND ug/L 07/22/16 17:23 56-55-307/21/16 20:350.10 1 Benzo(a)pyrene ND ug/L 07/22/16 17:23 50-32-807/21/16 20:350.10 1 Benzo(b)fluoranthene ND ug/L 07/22/16 17:23 205-99-207/21/16 20:350.10 1 Benzo(g,h,i)perylene ND ug/L 07/22/16 17:23 191-24-207/21/16 20:350.10 1 Benzo(k)fluoranthene ND ug/L 07/22/16 17:23 207-08-907/21/16 20:350.10 1 Chrysene ND ug/L 07/22/16 17:23 218-01-907/21/16 20:350.50 1 Dibenz(a,h)anthracene ND ug/L 07/22/16 17:23 53-70-307/21/16 20:350.10 1 Fluoranthene ND ug/L 07/22/16 17:23 206-44-007/21/16 20:351.0 1 Fluorene ND ug/L 07/22/16 17:23 86-73-707/21/16 20:351.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/22/16 17:23 193-39-507/21/16 20:350.10 1 1-Methylnaphthalene ND ug/L 07/22/16 17:23 90-12-0 N207/21/16 20:351.0 1 2-Methylnaphthalene ND ug/L 07/22/16 17:23 91-57-607/21/16 20:351.0 1 Naphthalene ND ug/L 07/22/16 17:23 91-20-307/21/16 20:351.0 1 Phenanthrene ND ug/L 07/22/16 17:23 85-01-807/21/16 20:351.0 1 Pyrene ND ug/L 07/22/16 17:23 129-00-007/21/16 20:351.0 1 Surrogates 2-Fluorobiphenyl (S)48 %.07/22/16 17:23 321-60-807/21/16 20:3518-117 1 p-Terphenyl-d14 (S)48 %.07/22/16 17:23 1718-51-007/21/16 20:3510-112 1 Analytical Method: EPA 82608260 MSV Indiana Acetone ND ug/L 08/02/16 15:45 67-64-11001 Acrolein ND ug/L 08/02/16 15:45 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 15:45 107-13-11001 Benzene ND ug/L 08/02/16 15:45 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 15:45 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 15:45 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 15:45 75-27-45.0 1 Bromoform ND ug/L 08/02/16 15:45 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 15:45 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 15:45 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 15:45 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 15:45 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 15:45 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 15:45 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 15:45 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 15:45 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 15:45 75-00-35.0 1 Chloroform ND ug/L 08/02/16 15:45 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 15:45 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 15:45 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 11 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-SB-3 Lab ID:50150125003 Collected:07/20/16 11:25 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 4-Chlorotoluene ND ug/L 08/02/16 15:45 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 15:45 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 15:45 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 15:45 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 15:45 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 15:45 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 15:45 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 15:45 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 15:45 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 15:45 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 15:45 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 15:45 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 15:45 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 15:45 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 15:45 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 15:45 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 15:45 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 15:45 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 15:45 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 15:45 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 15:45 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 15:45 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 15:45 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 15:45 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 15:45 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 15:45 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 15:45 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 15:45 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 15:45 75-09-25.0 1 1-Methylnaphthalene ND ug/L 08/02/16 15:45 90-12-0 N25.0 1 2-Methylnaphthalene ND ug/L 08/02/16 15:45 91-57-610.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 15:45 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 15:45 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 15:45 91-20-31.7 1 n-Propylbenzene ND ug/L 08/02/16 15:45 103-65-15.0 1 Styrene ND ug/L 08/02/16 15:45 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 15:45 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 15:45 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 15:45 127-18-45.0 1 Toluene ND ug/L 08/02/16 15:45 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 15:45 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 15:45 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 15:45 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 15:45 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 15:45 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 15:45 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 15:45 96-18-45.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 12 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-SB-3 Lab ID:50150125003 Collected:07/20/16 11:25 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 1,2,4-Trimethylbenzene ND ug/L 08/02/16 15:45 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 15:45 108-67-85.0 1 Vinyl acetate ND ug/L 08/02/16 15:45 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 15:45 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 15:45 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)104 %.08/02/16 15:45 1868-53-784-118 1 4-Bromofluorobenzene (S)101 %.08/02/16 15:45 460-00-479-116 1 Toluene-d8 (S)97 %.08/02/16 15:45 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 13 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-FD-1 Lab ID:50150125004 Collected:07/20/16 10:50 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 15.6 ug/L 07/27/16 09:54 7439-92-107/26/16 07:0810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/22/16 17:36 83-32-907/21/16 20:351.0 1 Acenaphthylene ND ug/L 07/22/16 17:36 208-96-807/21/16 20:351.0 1 Anthracene ND ug/L 07/22/16 17:36 120-12-707/21/16 20:350.10 1 Benzo(a)anthracene ND ug/L 07/22/16 17:36 56-55-307/21/16 20:350.10 1 Benzo(a)pyrene ND ug/L 07/22/16 17:36 50-32-807/21/16 20:350.10 1 Benzo(b)fluoranthene ND ug/L 07/22/16 17:36 205-99-207/21/16 20:350.10 1 Benzo(g,h,i)perylene ND ug/L 07/22/16 17:36 191-24-207/21/16 20:350.10 1 Benzo(k)fluoranthene ND ug/L 07/22/16 17:36 207-08-907/21/16 20:350.10 1 Chrysene ND ug/L 07/22/16 17:36 218-01-907/21/16 20:350.50 1 Dibenz(a,h)anthracene ND ug/L 07/22/16 17:36 53-70-307/21/16 20:350.10 1 Fluoranthene ND ug/L 07/22/16 17:36 206-44-007/21/16 20:351.0 1 Fluorene ND ug/L 07/22/16 17:36 86-73-707/21/16 20:351.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/22/16 17:36 193-39-507/21/16 20:350.10 1 1-Methylnaphthalene ND ug/L 07/22/16 17:36 90-12-0 N207/21/16 20:351.0 1 2-Methylnaphthalene ND ug/L 07/22/16 17:36 91-57-607/21/16 20:351.0 1 Naphthalene ND ug/L 07/22/16 17:36 91-20-307/21/16 20:351.0 1 Phenanthrene ND ug/L 07/22/16 17:36 85-01-807/21/16 20:351.0 1 Pyrene ND ug/L 07/22/16 17:36 129-00-007/21/16 20:351.0 1 Surrogates 2-Fluorobiphenyl (S)31 %.07/22/16 17:36 321-60-807/21/16 20:3518-117 1 p-Terphenyl-d14 (S)28 %.07/22/16 17:36 1718-51-007/21/16 20:3510-112 1 Analytical Method: EPA 82608260 MSV Indiana Acetone ND ug/L 08/02/16 16:23 67-64-11001 Acrolein ND ug/L 08/02/16 16:23 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 16:23 107-13-1 R11001 Benzene ND ug/L 08/02/16 16:23 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 16:23 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 16:23 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 16:23 75-27-45.0 1 Bromoform ND ug/L 08/02/16 16:23 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 16:23 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 16:23 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 16:23 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 16:23 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 16:23 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 16:23 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 16:23 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 16:23 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 16:23 75-00-35.0 1 Chloroform ND ug/L 08/02/16 16:23 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 16:23 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 16:23 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 14 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-FD-1 Lab ID:50150125004 Collected:07/20/16 10:50 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 4-Chlorotoluene ND ug/L 08/02/16 16:23 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 16:23 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 16:23 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 16:23 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 16:23 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 16:23 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 16:23 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 16:23 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 16:23 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 16:23 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 16:23 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 16:23 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 16:23 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 16:23 156-60-5 R15.0 1 1,2-Dichloropropane ND ug/L 08/02/16 16:23 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 16:23 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 16:23 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 16:23 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 16:23 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 16:23 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 16:23 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 16:23 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 16:23 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 16:23 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 16:23 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 16:23 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 16:23 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 16:23 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 16:23 75-09-25.0 1 1-Methylnaphthalene ND ug/L 08/02/16 16:23 90-12-0 N25.0 1 2-Methylnaphthalene ND ug/L 08/02/16 16:23 91-57-610.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 16:23 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 16:23 1634-04-4 R14.0 1 Naphthalene ND ug/L 08/02/16 16:23 91-20-31.7 1 n-Propylbenzene ND ug/L 08/02/16 16:23 103-65-15.0 1 Styrene ND ug/L 08/02/16 16:23 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 16:23 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 16:23 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 16:23 127-18-45.0 1 Toluene ND ug/L 08/02/16 16:23 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 16:23 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 16:23 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 16:23 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 16:23 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 16:23 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 16:23 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 16:23 96-18-45.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 15 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-FD-1 Lab ID:50150125004 Collected:07/20/16 10:50 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 1,2,4-Trimethylbenzene ND ug/L 08/02/16 16:23 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 16:23 108-67-85.0 1 Vinyl acetate ND ug/L 08/02/16 16:23 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 16:23 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 16:23 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)104 %.08/02/16 16:23 1868-53-784-118 1 4-Bromofluorobenzene (S)103 %.08/02/16 16:23 460-00-479-116 1 Toluene-d8 (S)95 %.08/02/16 16:23 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 16 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-ERB Lab ID:50150125005 Collected:07/20/16 12:35 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead ND ug/L 07/27/16 10:53 7439-92-107/26/16 07:0810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/22/16 18:16 83-32-907/21/16 20:351.0 1 Acenaphthylene ND ug/L 07/22/16 18:16 208-96-807/21/16 20:351.0 1 Anthracene ND ug/L 07/22/16 18:16 120-12-707/21/16 20:350.10 1 Benzo(a)anthracene ND ug/L 07/22/16 18:16 56-55-307/21/16 20:350.10 1 Benzo(a)pyrene ND ug/L 07/22/16 18:16 50-32-807/21/16 20:350.10 1 Benzo(b)fluoranthene ND ug/L 07/22/16 18:16 205-99-207/21/16 20:350.10 1 Benzo(g,h,i)perylene ND ug/L 07/22/16 18:16 191-24-207/21/16 20:350.10 1 Benzo(k)fluoranthene ND ug/L 07/22/16 18:16 207-08-907/21/16 20:350.10 1 Chrysene ND ug/L 07/22/16 18:16 218-01-907/21/16 20:350.50 1 Dibenz(a,h)anthracene ND ug/L 07/22/16 18:16 53-70-307/21/16 20:350.10 1 Fluoranthene ND ug/L 07/22/16 18:16 206-44-007/21/16 20:351.0 1 Fluorene ND ug/L 07/22/16 18:16 86-73-707/21/16 20:351.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/22/16 18:16 193-39-507/21/16 20:350.10 1 1-Methylnaphthalene ND ug/L 07/22/16 18:16 90-12-0 N207/21/16 20:351.0 1 2-Methylnaphthalene ND ug/L 07/22/16 18:16 91-57-607/21/16 20:351.0 1 Naphthalene ND ug/L 07/22/16 18:16 91-20-307/21/16 20:351.0 1 Phenanthrene ND ug/L 07/22/16 18:16 85-01-807/21/16 20:351.0 1 Pyrene ND ug/L 07/22/16 18:16 129-00-007/21/16 20:351.0 1 Surrogates 2-Fluorobiphenyl (S)39 %.07/22/16 18:16 321-60-807/21/16 20:3518-117 1 p-Terphenyl-d14 (S)41 %.07/22/16 18:16 1718-51-007/21/16 20:3510-112 1 Analytical Method: EPA 82608260 MSV Indiana Acetone ND ug/L 08/02/16 18:16 67-64-11001 Acrolein ND ug/L 08/02/16 18:16 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 18:16 107-13-11001 Benzene ND ug/L 08/02/16 18:16 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 18:16 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 18:16 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 18:16 75-27-45.0 1 Bromoform ND ug/L 08/02/16 18:16 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 18:16 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 18:16 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 18:16 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 18:16 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 18:16 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 18:16 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 18:16 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 18:16 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 18:16 75-00-35.0 1 Chloroform ND ug/L 08/02/16 18:16 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 18:16 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 18:16 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 17 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-ERB Lab ID:50150125005 Collected:07/20/16 12:35 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 4-Chlorotoluene ND ug/L 08/02/16 18:16 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 18:16 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 18:16 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 18:16 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 18:16 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 18:16 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 18:16 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 18:16 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 18:16 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 18:16 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 18:16 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 18:16 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 18:16 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 18:16 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 18:16 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 18:16 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 18:16 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 18:16 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 18:16 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 18:16 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 18:16 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 18:16 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 18:16 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 18:16 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 18:16 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 18:16 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 18:16 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 18:16 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 18:16 75-09-25.0 1 1-Methylnaphthalene ND ug/L 08/02/16 18:16 90-12-0 N25.0 1 2-Methylnaphthalene ND ug/L 08/02/16 18:16 91-57-610.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 18:16 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 18:16 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 18:16 91-20-31.7 1 n-Propylbenzene ND ug/L 08/02/16 18:16 103-65-15.0 1 Styrene ND ug/L 08/02/16 18:16 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 18:16 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 18:16 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 18:16 127-18-45.0 1 Toluene ND ug/L 08/02/16 18:16 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 18:16 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 18:16 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 18:16 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 18:16 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 18:16 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 18:16 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 18:16 96-18-45.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 18 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:LV-GW-ERB Lab ID:50150125005 Collected:07/20/16 12:35 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 1,2,4-Trimethylbenzene ND ug/L 08/02/16 18:16 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 18:16 108-67-85.0 1 Vinyl acetate ND ug/L 08/02/16 18:16 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 18:16 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 18:16 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)103 %.08/02/16 18:16 1868-53-784-118 1 4-Bromofluorobenzene (S)101 %.08/02/16 18:16 460-00-479-116 1 Toluene-d8 (S)96 %.08/02/16 18:16 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 19 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:Trip Blank Lab ID:50150125006 Collected:07/20/16 08:00 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead ND ug/L 07/27/16 10:55 7439-92-107/26/16 07:0810.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/22/16 18:29 83-32-907/21/16 20:351.0 1 Acenaphthylene ND ug/L 07/22/16 18:29 208-96-807/21/16 20:351.0 1 Anthracene ND ug/L 07/22/16 18:29 120-12-707/21/16 20:350.10 1 Benzo(a)anthracene ND ug/L 07/22/16 18:29 56-55-307/21/16 20:350.10 1 Benzo(a)pyrene ND ug/L 07/22/16 18:29 50-32-807/21/16 20:350.10 1 Benzo(b)fluoranthene ND ug/L 07/22/16 18:29 205-99-207/21/16 20:350.10 1 Benzo(g,h,i)perylene ND ug/L 07/22/16 18:29 191-24-207/21/16 20:350.10 1 Benzo(k)fluoranthene ND ug/L 07/22/16 18:29 207-08-907/21/16 20:350.10 1 Chrysene ND ug/L 07/22/16 18:29 218-01-907/21/16 20:350.50 1 Dibenz(a,h)anthracene ND ug/L 07/22/16 18:29 53-70-307/21/16 20:350.10 1 Fluoranthene ND ug/L 07/22/16 18:29 206-44-007/21/16 20:351.0 1 Fluorene ND ug/L 07/22/16 18:29 86-73-707/21/16 20:351.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/22/16 18:29 193-39-507/21/16 20:350.10 1 1-Methylnaphthalene ND ug/L 07/22/16 18:29 90-12-0 N207/21/16 20:351.0 1 2-Methylnaphthalene ND ug/L 07/22/16 18:29 91-57-607/21/16 20:351.0 1 Naphthalene ND ug/L 07/22/16 18:29 91-20-307/21/16 20:351.0 1 Phenanthrene ND ug/L 07/22/16 18:29 85-01-807/21/16 20:351.0 1 Pyrene ND ug/L 07/22/16 18:29 129-00-007/21/16 20:351.0 1 Surrogates 2-Fluorobiphenyl (S)40 %.07/22/16 18:29 321-60-807/21/16 20:3518-117 1 p-Terphenyl-d14 (S)42 %.07/22/16 18:29 1718-51-007/21/16 20:3510-112 1 Analytical Method: EPA 82608260 MSV Indiana Acetone ND ug/L 08/02/16 18:54 67-64-11001 Acrolein ND ug/L 08/02/16 18:54 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 18:54 107-13-11001 Benzene ND ug/L 08/02/16 18:54 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 18:54 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 18:54 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 18:54 75-27-45.0 1 Bromoform ND ug/L 08/02/16 18:54 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 18:54 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 18:54 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 18:54 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 18:54 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 18:54 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 18:54 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 18:54 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 18:54 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 18:54 75-00-35.0 1 Chloroform ND ug/L 08/02/16 18:54 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 18:54 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 18:54 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 20 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:Trip Blank Lab ID:50150125006 Collected:07/20/16 08:00 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 4-Chlorotoluene ND ug/L 08/02/16 18:54 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 18:54 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 18:54 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 18:54 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 18:54 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 18:54 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 18:54 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 18:54 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 18:54 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 18:54 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 18:54 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 18:54 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 18:54 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 18:54 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 18:54 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 18:54 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 18:54 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 18:54 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 18:54 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 18:54 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 18:54 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 18:54 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 18:54 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 18:54 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 18:54 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 18:54 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 18:54 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 18:54 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 18:54 75-09-25.0 1 1-Methylnaphthalene ND ug/L 08/02/16 18:54 90-12-0 N25.0 1 2-Methylnaphthalene ND ug/L 08/02/16 18:54 91-57-610.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 18:54 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 18:54 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 18:54 91-20-31.7 1 n-Propylbenzene ND ug/L 08/02/16 18:54 103-65-15.0 1 Styrene ND ug/L 08/02/16 18:54 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 18:54 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 18:54 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 18:54 127-18-45.0 1 Toluene ND ug/L 08/02/16 18:54 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 18:54 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 18:54 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 18:54 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 18:54 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 18:54 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 18:54 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 18:54 96-18-45.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 21 of 42 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Sample:Trip Blank Lab ID:50150125006 Collected:07/20/16 08:00 Received:07/21/16 08:35 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana 1,2,4-Trimethylbenzene ND ug/L 08/02/16 18:54 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 18:54 108-67-85.0 1 Vinyl acetate ND ug/L 08/02/16 18:54 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 18:54 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 18:54 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)105 %.08/02/16 18:54 1868-53-784-118 1 4-Bromofluorobenzene (S)103 %.08/02/16 18:54 460-00-479-116 1 Toluene-d8 (S)95 %.08/02/16 18:54 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 22 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343306 EPA 3010 EPA 6010 6010 MET Associated Lab Samples:50150125001, 50150125002, 50150125003, 50150125004, 50150125005, 50150125006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1590238 Associated Lab Samples:50150125001, 50150125002, 50150125003, 50150125004, 50150125005, 50150125006 Matrix:Water Analyzed Lead ug/L ND 10.0 07/27/16 10:48 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1590239LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 10401000 104 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1590240MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150125004 1590241 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead ug/L 1000 95 75-12596 0 20100015.6 968 972 Parameter Units MS Result % Rec Limits Qual% RecConc. 1590242MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50149955027 1590243 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead ug/L 1000 96 75-12597 0 20100010.7 973 977 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 23 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344708 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50150125002 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595813 Associated Lab Samples:50150125002 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/01/16 12:29 1,1,1-Trichloroethane ug/L ND 5.0 08/01/16 12:29 1,1,2,2-Tetrachloroethane ug/L ND 5.0 08/01/16 12:29 1,1,2-Trichloroethane ug/L ND 5.0 08/01/16 12:29 1,1-Dichloroethane ug/L ND 5.0 08/01/16 12:29 1,1-Dichloroethene ug/L ND 5.0 08/01/16 12:29 1,1-Dichloropropene ug/L ND 5.0 08/01/16 12:29 1,2,3-Trichlorobenzene ug/L ND 5.0 08/01/16 12:29 1,2,3-Trichloropropane ug/L ND 5.0 08/01/16 12:29 1,2,4-Trichlorobenzene ug/L ND 5.0 08/01/16 12:29 1,2,4-Trimethylbenzene ug/L ND 5.0 08/01/16 12:29 1,2-Dibromoethane (EDB)ug/L ND 5.0 08/01/16 12:29 1,2-Dichlorobenzene ug/L ND 5.0 08/01/16 12:29 1,2-Dichloroethane ug/L ND 5.0 08/01/16 12:29 1,2-Dichloropropane ug/L ND 5.0 08/01/16 12:29 1,3,5-Trimethylbenzene ug/L ND 5.0 08/01/16 12:29 1,3-Dichlorobenzene ug/L ND 5.0 08/01/16 12:29 1,3-Dichloropropane ug/L ND 5.0 08/01/16 12:29 1,4-Dichlorobenzene ug/L ND 5.0 08/01/16 12:29 1-Methylnaphthalene ug/L ND 5.0 N208/01/16 12:29 2,2-Dichloropropane ug/L ND 5.0 08/01/16 12:29 2-Butanone (MEK)ug/L ND 25.0 08/01/16 12:29 2-Chlorotoluene ug/L ND 5.0 08/01/16 12:29 2-Hexanone ug/L ND 25.0 08/01/16 12:29 2-Methylnaphthalene ug/L ND 10.0 08/01/16 12:29 4-Chlorotoluene ug/L ND 5.0 08/01/16 12:29 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 08/01/16 12:29 Acetone ug/L ND 100 08/01/16 12:29 Acrolein ug/L ND 50.0 08/01/16 12:29 Acrylonitrile ug/L ND 100 08/01/16 12:29 Benzene ug/L ND 5.0 08/01/16 12:29 Bromobenzene ug/L ND 5.0 08/01/16 12:29 Bromochloromethane ug/L ND 5.0 08/01/16 12:29 Bromodichloromethane ug/L ND 5.0 08/01/16 12:29 Bromoform ug/L ND 5.0 08/01/16 12:29 Bromomethane ug/L ND 5.0 08/01/16 12:29 Carbon disulfide ug/L ND 10.0 08/01/16 12:29 Carbon tetrachloride ug/L ND 5.0 08/01/16 12:29 Chlorobenzene ug/L ND 5.0 08/01/16 12:29 Chloroethane ug/L ND 5.0 08/01/16 12:29 Chloroform ug/L ND 5.0 08/01/16 12:29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 24 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1595813 Associated Lab Samples:50150125002 Matrix:Water Analyzed Chloromethane ug/L ND 5.0 08/01/16 12:29 cis-1,2-Dichloroethene ug/L ND 5.0 08/01/16 12:29 cis-1,3-Dichloropropene ug/L ND 5.0 08/01/16 12:29 Dibromochloromethane ug/L ND 5.0 08/01/16 12:29 Dibromomethane ug/L ND 5.0 08/01/16 12:29 Dichlorodifluoromethane ug/L ND 5.0 08/01/16 12:29 Ethyl methacrylate ug/L ND 100 08/01/16 12:29 Ethylbenzene ug/L ND 5.0 08/01/16 12:29 Hexachloro-1,3-butadiene ug/L ND 5.0 08/01/16 12:29 Iodomethane ug/L ND 10.0 08/01/16 12:29 Isopropylbenzene (Cumene)ug/L ND 5.0 08/01/16 12:29 Methyl-tert-butyl ether ug/L ND 4.0 08/01/16 12:29 Methylene Chloride ug/L ND 5.0 08/01/16 12:29 n-Butylbenzene ug/L ND 5.0 08/01/16 12:29 n-Hexane ug/L ND 5.0 08/01/16 12:29 n-Propylbenzene ug/L ND 5.0 08/01/16 12:29 Naphthalene ug/L ND 1.7 08/01/16 12:29 p-Isopropyltoluene ug/L ND 5.0 08/01/16 12:29 sec-Butylbenzene ug/L ND 5.0 08/01/16 12:29 Styrene ug/L ND 5.0 08/01/16 12:29 tert-Butylbenzene ug/L ND 5.0 08/01/16 12:29 Tetrachloroethene ug/L ND 5.0 08/01/16 12:29 Toluene ug/L ND 5.0 08/01/16 12:29 trans-1,2-Dichloroethene ug/L ND 5.0 08/01/16 12:29 trans-1,3-Dichloropropene ug/L ND 5.0 08/01/16 12:29 trans-1,4-Dichloro-2-butene ug/L ND 100 08/01/16 12:29 Trichloroethene ug/L ND 5.0 08/01/16 12:29 Trichlorofluoromethane ug/L ND 5.0 08/01/16 12:29 Vinyl acetate ug/L ND 50.0 08/01/16 12:29 Vinyl chloride ug/L ND 2.0 08/01/16 12:29 Xylene (Total)ug/L ND 10.0 08/01/16 12:29 4-Bromofluorobenzene (S)%.107 79-116 08/01/16 12:29 Dibromofluoromethane (S)%.114 84-118 08/01/16 12:29 Toluene-d8 (S)%.92 86-110 08/01/16 12:29 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595814LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 57.050 114 74-130 1,1,1-Trichloroethane ug/L 51.050 102 72-123 1,1,2,2-Tetrachloroethane ug/L 55.450 111 72-124 1,1,2-Trichloroethane ug/L 57.050 114 75-125 1,1-Dichloroethane ug/L 48.250 96 70-120 1,1-Dichloroethene ug/L 53.850 108 69-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 25 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595814LABORATORY CONTROL SAMPLE: LCSSpike 1,1-Dichloropropene ug/L 53.350 107 81-129 1,2,3-Trichlorobenzene ug/L 52.450 105 71-130 1,2,3-Trichloropropane ug/L 58.850 118 77-127 1,2,4-Trichlorobenzene ug/L 54.550 109 66-126 1,2,4-Trimethylbenzene ug/L 53.550 107 73-125 1,2-Dibromoethane (EDB)ug/L 59.650 119 76-125 1,2-Dichlorobenzene ug/L 50.950 102 77-122 1,2-Dichloroethane ug/L 50.850 102 70-123 1,2-Dichloropropane ug/L 52.450 105 77-124 1,3,5-Trimethylbenzene ug/L 53.250 106 75-124 1,3-Dichlorobenzene ug/L 52.750 105 76-124 1,3-Dichloropropane ug/L 55.250 110 77-123 1,4-Dichlorobenzene ug/L 53.050 106 75-117 1-Methylnaphthalene ug/L 59.1 N25011855-151 2,2-Dichloropropane ug/L 51.250 102 44-147 2-Butanone (MEK)ug/L 324250 130 60-135 2-Chlorotoluene ug/L 49.250 98 75-124 2-Hexanone ug/L 304250 122 65-139 2-Methylnaphthalene ug/L 50.650 101 58-148 4-Chlorotoluene ug/L 54.450 109 75-124 4-Methyl-2-pentanone (MIBK)ug/L 306250 122 66-134 Acetone ug/L 363 L025014547-144 Acrolein ug/L 14201000 142 31-200 Acrylonitrile ug/L 215200 107 64-133 Benzene ug/L 52.750 105 76-122 Bromobenzene ug/L 50.050 100 75-117 Bromochloromethane ug/L 47.950 96 74-134 Bromodichloromethane ug/L 51.050 102 71-124 Bromoform ug/L 47.250 94 60-125 Bromomethane ug/L 74.850 150 23-194 Carbon disulfide ug/L 47.150 94 63-130 Carbon tetrachloride ug/L 52.250 104 73-133 Chlorobenzene ug/L 52.850 106 76-118 Chloroethane ug/L 40.550 81 50-147 Chloroform ug/L 45.350 91 70-119 Chloromethane ug/L 51.150 102 52-136 cis-1,2-Dichloroethene ug/L 50.450 101 74-120 cis-1,3-Dichloropropene ug/L 57.050 114 71-134 Dibromochloromethane ug/L 55.950 112 73-127 Dibromomethane ug/L 52.150 104 75-124 Dichlorodifluoromethane ug/L 52.950 106 39-166 Ethyl methacrylate ug/L 232200 116 73-136 Ethylbenzene ug/L 51.850 104 75-123 Hexachloro-1,3-butadiene ug/L 53.550 107 70-125 Iodomethane ug/L 155 L010015556-142 Isopropylbenzene (Cumene)ug/L 52.550 105 84-134 Methyl-tert-butyl ether ug/L 62.450 125 65-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 26 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1595814LABORATORY CONTROL SAMPLE: LCSSpike Methylene Chloride ug/L 44.450 89 66-130 n-Butylbenzene ug/L 54.450 109 70-127 n-Hexane ug/L 53.350 107 64-131 n-Propylbenzene ug/L 53.950 108 78-131 Naphthalene ug/L 54.350 109 65-134 p-Isopropyltoluene ug/L 53.850 108 75-124 sec-Butylbenzene ug/L 54.150 108 83-135 Styrene ug/L 52.650 105 78-128 tert-Butylbenzene ug/L 40.650 81 62-114 Tetrachloroethene ug/L 54.250 108 69-119 Toluene ug/L 51.150 102 74-122 trans-1,2-Dichloroethene ug/L 53.550 107 72-122 trans-1,3-Dichloropropene ug/L 49.550 99 66-135 trans-1,4-Dichloro-2-butene ug/L 221200 111 39-153 Trichloroethene ug/L 53.050 106 75-123 Trichlorofluoromethane ug/L 44.550 89 58-148 Vinyl acetate ug/L 233200 117 67-154 Vinyl chloride ug/L 50.550 101 61-147 Xylene (Total)ug/L 155150 103 75-127 4-Bromofluorobenzene (S)%.96 79-116 Dibromofluoromethane (S)%.91 84-118 Toluene-d8 (S)%.101 86-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1595815MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150210005 1595816 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 50 119 44-142123 4 2050ND59.3 61.5 1,1,1-Trichloroethane ug/L 50 106 51-140107 1 2050ND53.2 53.7 1,1,2,2-Tetrachloroethane ug/L 50 113 49-138121 7 2050ND56.4 60.4 1,1,2-Trichloroethane ug/L 50 117 51-138122 4 2050ND58.7 61.2 1,1-Dichloroethane ug/L 50 102 48-137103 0 2050ND51.2 51.3 1,1-Dichloroethene ug/L 50 109 51-144110 1 2050ND54.6 55.2 1,1-Dichloropropene ug/L 50 111 54-150112 1 2050ND55.4 56.1 1,2,3-Trichlorobenzene ug/L 50 105 32-140111 6 2050ND52.6 55.6 1,2,3-Trichloropropane ug/L 50 117 51-139124 6 2050ND58.4 62.1 1,2,4-Trichlorobenzene ug/L 50 105 27-134111 5 2050ND52.6 55.6 1,2,4-Trimethylbenzene ug/L 50 109 32-143111 2 2050ND54.3 55.6 1,2-Dibromoethane (EDB)ug/L 50 123 52-134127 3 2050ND61.3 63.4 1,2-Dichlorobenzene ug/L 50 107 38-138108 2 2050ND53.3 54.2 1,2-Dichloroethane ug/L 50 106 44-144109 3 2050ND52.9 54.3 1,2-Dichloropropane ug/L 50 111 56-138112 1 2050ND55.5 55.9 1,3,5-Trimethylbenzene ug/L 50 108 28-146108 0 2050ND54.1 54.1 1,3-Dichlorobenzene ug/L 50 108 36-139111 3 2050ND54.1 55.6 1,3-Dichloropropane ug/L 50 114 54-137119 4 2050ND57.1 59.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 27 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1595815MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150210005 1595816 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,4-Dichlorobenzene ug/L 50 106 34-134110 3 2050ND53.2 55.0 1-Methylnaphthalene ug/L N25011232-150126 11 2050ND56.2 62.9 2,2-Dichloropropane ug/L 50 108 20-142109 1 2050ND54.1 54.4 2-Butanone (MEK)ug/L 250 103 44-142113 9 20250ND258281 2-Chlorotoluene ug/L 50 102 36-143106 4 2050ND51.2 53.1 2-Hexanone ug/L 250 108 43-150120 10 20250ND271299 2-Methylnaphthalene ug/L 50 93 27-148106 13 2050ND46.5 53.0 4-Chlorotoluene ug/L 50 110 34-143112 2 2050ND55.0 56.2 4-Methyl-2-pentanone (MIBK)ug/L 250 115 46-143125 9 20250ND287313 Acetone ug/L 250 112 33-150115 3 2025021.4J 301 310 Acrolein ug/L 1000 122 32-200128 5 201000ND12301280 Acrylonitrile ug/L 200 100 47-143108 8 20200ND200217 Benzene ug/L 50 110 51-140113 2 20501.1J 56.2 57.4 Bromobenzene ug/L 50 103 41-134107 3 2050ND51.5 53.3 Bromochloromethane ug/L 50 102 53-148102 1 2050ND50.9 51.2 Bromodichloromethane ug/L 50 112 46-137113 0 2050ND56.1 56.3 Bromoform ug/L 50 96 36-12799 3 2050ND48.2 49.7 Bromomethane ug/L 50 152 10-188153 1 2050ND75.9 76.6 Carbon disulfide ug/L 50 95 35-14896 1 2050ND47.5 48.0 Carbon tetrachloride ug/L 50 106 45-151106 0 2050ND53.0 53.1 Chlorobenzene ug/L 50 109 45-138114 5 2050ND54.3 56.9 Chloroethane ug/L 50 82 33-16483 1 2050ND40.9 41.5 Chloroform ug/L 50 95 50-13595 0 20502.4J 49.7 50.0 Chloromethane ug/L 50 95 38-146102 7 2050ND47.4 50.9 cis-1,2-Dichloroethene ug/L 50 106 43-144108 1 2050ND53.1 53.8 cis-1,3-Dichloropropene ug/L 50 118 42-136121 2 2050ND59.2 60.5 Dibromochloromethane ug/L 50 116 45-136120 4 20501.8J 59.7 61.9 Dibromomethane ug/L 50 109 51-139110 0 2050ND54.6 54.8 Dichlorodifluoromethane ug/L 50 104 29-174109 5 2050ND52.2 54.6 Ethyl methacrylate ug/L 200 114 44-150124 9 20200ND228248 Ethylbenzene ug/L 50 106 36-146113 6 2050ND53.4 56.6 Hexachloro-1,3-butadiene ug/L 50 105 14-150106 1 2050ND52.3 53.0 Iodomethane ug/L M010016028-153155 3 20100ND160155 Isopropylbenzene (Cumene)ug/L 50 105 43-159108 3 2050ND52.5 54.2 Methyl-tert-butyl ether ug/L 50 129 43-146135 5 2050ND64.3 67.4 Methylene Chloride ug/L 50 104 48-140106 1 2050ND52.1 52.8 n-Butylbenzene ug/L 50 106 16-152110 4 2050ND53.1 55.1 n-Hexane ug/L 50 111 40-144108 3 2050ND55.3 53.9 n-Propylbenzene ug/L 50 111 28-157112 2 2050ND55.3 56.1 Naphthalene ug/L 50 108 38-141114 6 2050ND54.0 57.2 p-Isopropyltoluene ug/L 50 107 21-151110 2 2050ND53.6 54.8 sec-Butylbenzene ug/L 50 109 27-165112 2 2050ND54.7 56.0 Styrene ug/L 50 106 31-148110 3 2050ND52.9 54.8 tert-Butylbenzene ug/L 50 83 24-13183 0 2050ND41.4 41.6 Tetrachloroethene ug/L 50 109 38-139114 5 2050ND54.4 57.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 28 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1595815MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150210005 1595816 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Toluene ug/L 50 62 44-14062 0 2050203234234 trans-1,2-Dichloroethene ug/L 50 109 50-139113 4 2050ND54.7 56.7 trans-1,3-Dichloropropene ug/L 50 102 37-138105 3 2050ND51.0 52.6 trans-1,4-Dichloro-2-butene ug/L 200 115 10-157119 3 20200ND230238 Trichloroethene ug/L 50 111 44-146112 0 20500.61J 56.3 56.5 Trichlorofluoromethane ug/L 50 85 41-16487 2 2050ND42.4 43.4 Vinyl acetate ug/L 200 104 15-146107 3 20200ND207213 Vinyl chloride ug/L 50 102 43-166102 1 2050ND50.8 51.2 Xylene (Total)ug/L 150 105 35-146110 4 20150ND158165 4-Bromofluorobenzene (S)%.95 79-11696 Dibromofluoromethane (S)%.92 84-11890 Toluene-d8 (S)%.100 86-110101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 29 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344905 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50150125001, 50150125003, 50150125004, 50150125005, 50150125006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596544 Associated Lab Samples:50150125001, 50150125003, 50150125004, 50150125005, 50150125006 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/02/16 13:53 1,1,1-Trichloroethane ug/L ND 5.0 08/02/16 13:53 1,1,2,2-Tetrachloroethane ug/L ND 5.0 08/02/16 13:53 1,1,2-Trichloroethane ug/L ND 5.0 08/02/16 13:53 1,1-Dichloroethane ug/L ND 5.0 08/02/16 13:53 1,1-Dichloroethene ug/L ND 5.0 08/02/16 13:53 1,1-Dichloropropene ug/L ND 5.0 08/02/16 13:53 1,2,3-Trichlorobenzene ug/L ND 5.0 08/02/16 13:53 1,2,3-Trichloropropane ug/L ND 5.0 08/02/16 13:53 1,2,4-Trichlorobenzene ug/L ND 5.0 08/02/16 13:53 1,2,4-Trimethylbenzene ug/L ND 5.0 08/02/16 13:53 1,2-Dibromoethane (EDB)ug/L ND 5.0 08/02/16 13:53 1,2-Dichlorobenzene ug/L ND 5.0 08/02/16 13:53 1,2-Dichloroethane ug/L ND 5.0 08/02/16 13:53 1,2-Dichloropropane ug/L ND 5.0 08/02/16 13:53 1,3,5-Trimethylbenzene ug/L ND 5.0 08/02/16 13:53 1,3-Dichlorobenzene ug/L ND 5.0 08/02/16 13:53 1,3-Dichloropropane ug/L ND 5.0 08/02/16 13:53 1,4-Dichlorobenzene ug/L ND 5.0 08/02/16 13:53 1-Methylnaphthalene ug/L ND 5.0 N208/02/16 13:53 2,2-Dichloropropane ug/L ND 5.0 08/02/16 13:53 2-Butanone (MEK)ug/L ND 25.0 08/02/16 13:53 2-Chlorotoluene ug/L ND 5.0 08/02/16 13:53 2-Hexanone ug/L ND 25.0 08/02/16 13:53 2-Methylnaphthalene ug/L ND 10.0 08/02/16 13:53 4-Chlorotoluene ug/L ND 5.0 08/02/16 13:53 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 08/02/16 13:53 Acetone ug/L ND 100 08/02/16 13:53 Acrolein ug/L ND 50.0 08/02/16 13:53 Acrylonitrile ug/L ND 100 08/02/16 13:53 Benzene ug/L ND 5.0 08/02/16 13:53 Bromobenzene ug/L ND 5.0 08/02/16 13:53 Bromochloromethane ug/L ND 5.0 08/02/16 13:53 Bromodichloromethane ug/L ND 5.0 08/02/16 13:53 Bromoform ug/L ND 5.0 08/02/16 13:53 Bromomethane ug/L ND 5.0 08/02/16 13:53 Carbon disulfide ug/L ND 10.0 08/02/16 13:53 Carbon tetrachloride ug/L ND 5.0 08/02/16 13:53 Chlorobenzene ug/L ND 5.0 08/02/16 13:53 Chloroethane ug/L ND 5.0 08/02/16 13:53 Chloroform ug/L ND 5.0 08/02/16 13:53 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 30 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596544 Associated Lab Samples:50150125001, 50150125003, 50150125004, 50150125005, 50150125006 Matrix:Water Analyzed Chloromethane ug/L ND 5.0 08/02/16 13:53 cis-1,2-Dichloroethene ug/L ND 5.0 08/02/16 13:53 cis-1,3-Dichloropropene ug/L ND 5.0 08/02/16 13:53 Dibromochloromethane ug/L ND 5.0 08/02/16 13:53 Dibromomethane ug/L ND 5.0 08/02/16 13:53 Dichlorodifluoromethane ug/L ND 5.0 08/02/16 13:53 Ethyl methacrylate ug/L ND 100 08/02/16 13:53 Ethylbenzene ug/L ND 5.0 08/02/16 13:53 Hexachloro-1,3-butadiene ug/L ND 5.0 08/02/16 13:53 Iodomethane ug/L ND 10.0 08/02/16 13:53 Isopropylbenzene (Cumene)ug/L ND 5.0 08/02/16 13:53 Methyl-tert-butyl ether ug/L ND 4.0 08/02/16 13:53 Methylene Chloride ug/L ND 5.0 08/02/16 13:53 n-Butylbenzene ug/L ND 5.0 08/02/16 13:53 n-Hexane ug/L ND 5.0 08/02/16 13:53 n-Propylbenzene ug/L ND 5.0 08/02/16 13:53 Naphthalene ug/L ND 1.7 08/02/16 13:53 p-Isopropyltoluene ug/L ND 5.0 08/02/16 13:53 sec-Butylbenzene ug/L ND 5.0 08/02/16 13:53 Styrene ug/L ND 5.0 08/02/16 13:53 tert-Butylbenzene ug/L ND 5.0 08/02/16 13:53 Tetrachloroethene ug/L ND 5.0 08/02/16 13:53 Toluene ug/L ND 5.0 08/02/16 13:53 trans-1,2-Dichloroethene ug/L ND 5.0 08/02/16 13:53 trans-1,3-Dichloropropene ug/L ND 5.0 08/02/16 13:53 trans-1,4-Dichloro-2-butene ug/L ND 100 08/02/16 13:53 Trichloroethene ug/L ND 5.0 08/02/16 13:53 Trichlorofluoromethane ug/L ND 5.0 08/02/16 13:53 Vinyl acetate ug/L ND 50.0 08/02/16 13:53 Vinyl chloride ug/L ND 2.0 08/02/16 13:53 Xylene (Total)ug/L ND 10.0 08/02/16 13:53 4-Bromofluorobenzene (S)%.103 79-116 08/02/16 13:53 Dibromofluoromethane (S)%.104 84-118 08/02/16 13:53 Toluene-d8 (S)%.96 86-110 08/02/16 13:53 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596545LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 54.550 109 74-130 1,1,1-Trichloroethane ug/L 57.150 114 72-123 1,1,2,2-Tetrachloroethane ug/L 53.750 107 72-124 1,1,2-Trichloroethane ug/L 55.950 112 75-125 1,1-Dichloroethane ug/L 54.750 109 70-120 1,1-Dichloroethene ug/L 60.250 120 69-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 31 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596545LABORATORY CONTROL SAMPLE: LCSSpike 1,1-Dichloropropene ug/L 57.350 115 81-129 1,2,3-Trichlorobenzene ug/L 55.650 111 71-130 1,2,3-Trichloropropane ug/L 56.550 113 77-127 1,2,4-Trichlorobenzene ug/L 56.750 113 66-126 1,2,4-Trimethylbenzene ug/L 52.650 105 73-125 1,2-Dibromoethane (EDB)ug/L 54.750 109 76-125 1,2-Dichlorobenzene ug/L 52.650 105 77-122 1,2-Dichloroethane ug/L 56.350 113 70-123 1,2-Dichloropropane ug/L 56.250 112 77-124 1,3,5-Trimethylbenzene ug/L 54.750 109 75-124 1,3-Dichlorobenzene ug/L 55.250 110 76-124 1,3-Dichloropropane ug/L 54.750 109 77-123 1,4-Dichlorobenzene ug/L 54.850 110 75-117 1-Methylnaphthalene ug/L 58.9 N25011855-151 2,2-Dichloropropane ug/L 57.050 114 44-147 2-Butanone (MEK)ug/L 263250 105 60-135 2-Chlorotoluene ug/L 54.950 110 75-124 2-Hexanone ug/L 278250 111 65-139 2-Methylnaphthalene ug/L 49.250 98 58-148 4-Chlorotoluene ug/L 56.750 113 75-124 4-Methyl-2-pentanone (MIBK)ug/L 274250 109 66-134 Acetone ug/L 297250 119 47-144 Acrolein ug/L 13701000 137 31-200 Acrylonitrile ug/L 228200 114 64-133 Benzene ug/L 57.250 114 76-122 Bromobenzene ug/L 54.550 109 75-117 Bromochloromethane ug/L 57.250 114 74-134 Bromodichloromethane ug/L 55.050 110 71-124 Bromoform ug/L 51.850 104 60-125 Bromomethane ug/L 59.350 119 23-194 Carbon disulfide ug/L 55.150 110 63-130 Carbon tetrachloride ug/L 59.650 119 73-133 Chlorobenzene ug/L 55.850 112 76-118 Chloroethane ug/L 45.150 90 50-147 Chloroform ug/L 50.450 101 70-119 Chloromethane ug/L 46.050 92 52-136 cis-1,2-Dichloroethene ug/L 58.450 117 74-120 cis-1,3-Dichloropropene ug/L 56.350 113 71-134 Dibromochloromethane ug/L 54.450 109 73-127 Dibromomethane ug/L 56.750 113 75-124 Dichlorodifluoromethane ug/L 45.150 90 39-166 Ethyl methacrylate ug/L 220200 110 73-136 Ethylbenzene ug/L 55.450 111 75-123 Hexachloro-1,3-butadiene ug/L 56.550 113 70-125 Iodomethane ug/L 108100 108 56-142 Isopropylbenzene (Cumene)ug/L 56.150 112 84-134 Methyl-tert-butyl ether ug/L 57.550 115 65-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 32 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596545LABORATORY CONTROL SAMPLE: LCSSpike Methylene Chloride ug/L 47.650 95 66-130 n-Butylbenzene ug/L 56.750 113 70-127 n-Hexane ug/L 58.350 117 64-131 n-Propylbenzene ug/L 56.550 113 78-131 Naphthalene ug/L 55.550 111 65-134 p-Isopropyltoluene ug/L 56.350 113 75-124 sec-Butylbenzene ug/L 57.250 114 83-135 Styrene ug/L 55.750 111 78-128 tert-Butylbenzene ug/L 40.550 81 62-114 Tetrachloroethene ug/L 52.850 106 69-119 Toluene ug/L 50.050 100 74-122 trans-1,2-Dichloroethene ug/L 60.850 122 72-122 trans-1,3-Dichloropropene ug/L 56.350 113 66-135 trans-1,4-Dichloro-2-butene ug/L 226200 113 39-153 Trichloroethene ug/L 54.350 109 75-123 Trichlorofluoromethane ug/L 52.650 105 58-148 Vinyl acetate ug/L 220200 110 67-154 Vinyl chloride ug/L 51.950 104 61-147 Xylene (Total)ug/L 168150 112 75-127 4-Bromofluorobenzene (S)%.99 79-116 Dibromofluoromethane (S)%.101 84-118 Toluene-d8 (S)%.99 86-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1596546MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150125004 1596547 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 50 125 44-142111 12 2050ND62.6 55.7 1,1,1-Trichloroethane ug/L 50 126 51-140115 9 2050ND63.1 57.7 1,1,2,2-Tetrachloroethane ug/L 50 123 49-138110 11 2050ND61.5 55.1 1,1,2-Trichloroethane ug/L 50 126 51-138114 10 2050ND63.0 56.9 1,1-Dichloroethane ug/L 50 124 48-137114 9 2050ND62.2 56.8 1,1-Dichloroethene ug/L 50 125 51-144121 4 2050ND62.7 60.4 1,1-Dichloropropene ug/L 50 127 54-150116 9 2050ND63.7 58.1 1,2,3-Trichlorobenzene ug/L 50 120 32-140112 7 2050ND60.1 55.9 1,2,3-Trichloropropane ug/L 50 128 51-139113 12 2050ND63.8 56.7 1,2,4-Trichlorobenzene ug/L 50 121 27-134114 6 2050ND60.6 56.9 1,2,4-Trimethylbenzene ug/L 50 115 32-143105 9 2050ND59.2 54.0 1,2-Dibromoethane (EDB)ug/L 50 125 52-134109 14 2050ND62.6 54.7 1,2-Dichlorobenzene ug/L 50 118 38-138109 8 2050ND58.8 54.6 1,2-Dichloroethane ug/L 50 129 44-144117 10 2050ND64.4 58.3 1,2-Dichloropropane ug/L 50 124 56-138115 8 2050ND62.1 57.3 1,3,5-Trimethylbenzene ug/L 50 117 28-146111 6 2050ND59.2 55.9 1,3-Dichlorobenzene ug/L 50 121 36-139112 7 2050ND60.3 56.1 1,3-Dichloropropane ug/L 50 126 54-137112 12 2050ND63.1 56.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 33 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596546MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150125004 1596547 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,4-Dichlorobenzene ug/L 50 121 34-134111 8 2050ND60.4 55.6 1-Methylnaphthalene ug/L N25013132-150118 10 2050ND65.8 59.7 2,2-Dichloropropane ug/L 50 128 20-142117 9 2050ND64.0 58.6 2-Butanone (MEK)ug/L 250 113 44-14292 20 20250ND282230 2-Chlorotoluene ug/L 50 120 36-143112 6 2050ND59.9 56.1 2-Hexanone ug/L 250 125 43-150104 18 20250ND312260 2-Methylnaphthalene ug/L 50 108 27-14899 8 2050ND54.7 50.3 4-Chlorotoluene ug/L 50 125 34-143115 8 2050ND62.3 57.5 4-Methyl-2-pentanone (MIBK)ug/L 250 127 46-143106 18 20250ND319266 Acetone ug/L 250 118 33-150101 16 20250ND296252 Acrolein ug/L 1000 145 32-200118 20 201000ND14501180 Acrylonitrile ug/L R120013247-14397 30 20200ND264195 Benzene ug/L 50 128 51-140118 8 2050ND63.9 58.9 Bromobenzene ug/L 50 123 41-134111 10 2050ND61.3 55.4 Bromochloromethane ug/L 50 134 53-148120 10 2050ND66.8 60.2 Bromodichloromethane ug/L 50 125 46-137114 9 2050ND62.4 57.0 Bromoform ug/L 50 118 36-127106 11 2050ND59.2 52.8 Bromomethane ug/L 50 135 10-188135 1 2050ND67.3 67.7 Carbon disulfide ug/L 50 118 35-148108 9 2050ND59.1 54.0 Carbon tetrachloride ug/L 50 133 45-151121 9 2050ND66.4 60.7 Chlorobenzene ug/L 50 125 45-138112 11 2050ND62.6 56.0 Chloroethane ug/L 50 99 33-16493 6 2050ND49.5 46.6 Chloroform ug/L 50 114 50-135105 8 2050ND56.9 52.3 Chloromethane ug/L 50 103 38-146103 0 2050ND51.3 51.5 cis-1,2-Dichloroethene ug/L 50 134 43-144121 10 2050ND66.9 60.6 cis-1,3-Dichloropropene ug/L 50 126 42-136112 12 2050ND63.0 55.9 Dibromochloromethane ug/L 50 124 45-136110 12 2050ND61.8 54.9 Dibromomethane ug/L 50 129 51-139116 10 2050ND64.5 58.1 Dichlorodifluoromethane ug/L 50 100 29-17493 8 2050ND50.2 46.5 Ethyl methacrylate ug/L 200 126 44-150111 13 20200ND252221 Ethylbenzene ug/L 50 124 36-146112 10 2050ND62.2 56.2 Hexachloro-1,3-butadiene ug/L 50 122 14-150113 7 2050ND60.8 56.7 Iodomethane ug/L 100 106 28-153108 2 20100ND106108 Isopropylbenzene (Cumene)ug/L 50 124 43-159111 11 2050ND62.3 56.0 Methyl-tert-butyl ether ug/L R15013343-146101 27 2050ND66.3 50.6 Methylene Chloride ug/L 50 99 48-14091 8 2050ND53.1 48.8 n-Butylbenzene ug/L 50 122 16-152112 8 2050ND60.8 56.2 n-Hexane ug/L 50 126 40-144119 6 2050ND63.1 59.4 n-Propylbenzene ug/L 50 122 28-157115 6 2050ND61.2 57.7 Naphthalene ug/L 50 126 38-141115 9 2050ND63.7 58.2 p-Isopropyltoluene ug/L 50 122 21-151113 8 2050ND60.9 56.3 sec-Butylbenzene ug/L 50 123 27-165115 7 2050ND62.8 58.7 Styrene ug/L 50 125 31-148110 13 2050ND62.6 55.2 tert-Butylbenzene ug/L 50 89 24-13183 7 2050ND44.4 41.4 Tetrachloroethene ug/L 50 117 38-139105 11 2050ND58.4 52.3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 34 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596546MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150125004 1596547 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Toluene ug/L 50 110 44-140100 10 2050ND55.6 50.5 trans-1,2-Dichloroethene ug/L R15013850-139104 28 2050ND69.0 52.2 trans-1,3-Dichloropropene ug/L 50 127 37-138112 12 2050ND63.3 56.2 trans-1,4-Dichloro-2-butene ug/L 200 130 10-157111 15 20200ND259222 Trichloroethene ug/L 50 121 44-146109 11 2050ND60.6 54.5 Trichlorofluoromethane ug/L 50 111 41-164105 6 2050ND55.7 52.4 Vinyl acetate ug/L 200 116 15-146103 12 20200ND233206 Vinyl chloride ug/L 50 114 43-166105 8 2050ND56.9 52.7 Xylene (Total)ug/L 150 125 35-146113 10 20150ND187169 4-Bromofluorobenzene (S)%.100 79-11699 Dibromofluoromethane (S)%.102 84-118101 Toluene-d8 (S)%.100 86-11099 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 35 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343183 EPA 3510 EPA 8270 by SIM LVE 8270 Water PAH LV by SIM MSSV Associated Lab Samples:50150125001, 50150125002, 50150125003, 50150125004, 50150125005, 50150125006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1589579 Associated Lab Samples:50150125001, 50150125002, 50150125003, 50150125004, 50150125005, 50150125006 Matrix:Water Analyzed 1-Methylnaphthalene ug/L ND 1.0 N207/22/16 13:36 2-Methylnaphthalene ug/L ND 1.0 07/22/16 13:36 Acenaphthene ug/L ND 1.0 07/22/16 13:36 Acenaphthylene ug/L ND 1.0 07/22/16 13:36 Anthracene ug/L ND 0.10 07/22/16 13:36 Benzo(a)anthracene ug/L ND 0.10 07/22/16 13:36 Benzo(a)pyrene ug/L ND 0.10 07/22/16 13:36 Benzo(b)fluoranthene ug/L ND 0.10 07/22/16 13:36 Benzo(g,h,i)perylene ug/L ND 0.10 07/22/16 13:36 Benzo(k)fluoranthene ug/L ND 0.10 07/22/16 13:36 Chrysene ug/L ND 0.50 07/22/16 13:36 Dibenz(a,h)anthracene ug/L ND 0.10 07/22/16 13:36 Fluoranthene ug/L ND 1.0 07/22/16 13:36 Fluorene ug/L ND 1.0 07/22/16 13:36 Indeno(1,2,3-cd)pyrene ug/L ND 0.10 07/22/16 13:36 Naphthalene ug/L ND 1.0 07/22/16 13:36 Phenanthrene ug/L ND 1.0 07/22/16 13:36 Pyrene ug/L ND 1.0 07/22/16 13:36 2-Fluorobiphenyl (S)%.58 18-117 07/22/16 13:36 p-Terphenyl-d14 (S)%.66 10-112 07/22/16 13:36 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589580LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene ug/L 3.8 N2103835-115 2-Methylnaphthalene ug/L 3.610 36 25-120 Acenaphthene ug/L 4.610 46 37-129 Acenaphthylene ug/L 5.110 51 36-139 Anthracene ug/L 5.910 59 43-147 Benzo(a)anthracene ug/L 7.010 70 49-149 Benzo(a)pyrene ug/L 6.510 65 28-150 Benzo(b)fluoranthene ug/L 5.610 56 35-147 Benzo(g,h,i)perylene ug/L 6.310 63 15-133 Benzo(k)fluoranthene ug/L 6.910 69 24-149 Chrysene ug/L 7.010 70 45-139 Dibenz(a,h)anthracene ug/L 6.010 60 14-139 Fluoranthene ug/L 6.710 67 46-166 Fluorene ug/L 4.910 49 38-138 Indeno(1,2,3-cd)pyrene ug/L 6.110 61 17-139 Naphthalene ug/L 4.310 43 29-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 36 of 42 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589580LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene ug/L 6.010 60 48-145 Pyrene ug/L 6.910 69 48-152 2-Fluorobiphenyl (S)%.37 18-117 p-Terphenyl-d14 (S)%.48 10-112 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589581MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150125004 1589582 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2103016-12127 8 2010ND3.0 2.8 2-Methylnaphthalene ug/L 10 28 11-12226 7 2010ND2.9 2.7 Acenaphthene ug/L 10 38 14-13737 3 2010ND3.8 3.7 Acenaphthylene ug/L 10 46 17-14144 4 2010ND4.6 4.4 Anthracene ug/L 10 56 22-14555 2 2010ND5.6 5.5 Benzo(a)anthracene ug/L 10 56 16-12858 3 2010ND5.6 5.8 Benzo(a)pyrene ug/L 10 49 10-9750 2 2010ND4.9 5.0 Benzo(b)fluoranthene ug/L 10 39 10-10343 9 2010ND3.9 4.3 Benzo(g,h,i)perylene ug/L 10 41 10-7044 8 2010ND4.1 4.4 Benzo(k)fluoranthene ug/L 10 50 10-9548 5 2010ND5.0 4.8 Chrysene ug/L 10 52 15-11856 7 2010ND5.2 5.6 Dibenz(a,h)anthracene ug/L 10 42 10-7346 9 2010ND4.2 4.6 Fluoranthene ug/L 10 59 24-15957 3 2010ND5.9 5.7 Fluorene ug/L 10 48 19-14046 3 2010ND4.8 4.6 Indeno(1,2,3-cd)pyrene ug/L 10 42 10-7446 8 2010ND4.2 4.6 Naphthalene ug/L 10 33 10-13234 1 2010ND3.5 3.6 Phenanthrene ug/L 10 55 31-14154 2 2010ND5.5 5.4 Pyrene ug/L 10 57 29-14458 1 2010ND5.7 5.8 2-Fluorobiphenyl (S)%.38 18-11737 p-Terphenyl-d14 (S)%.33 10-11232 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 37 of 42 #=QL# QUALIFIERS Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - IndianapolisPASI-I ANALYTE QUALIFIERS Sample was diluted due to the presence of high levels of target analytes.D4 Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0 Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.M0 The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 38 of 42 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 50150125 214 W. Patterson St. Lakeville Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 50150125001 343306 343907LV-GW-SB-1 EPA 3010 EPA 6010 50150125002 343306 343907LV-GW-SB-2 EPA 3010 EPA 6010 50150125003 343306 343907LV-GW-SB-3 EPA 3010 EPA 6010 50150125004 343306 343907LV-GW-FD-1 EPA 3010 EPA 6010 50150125005 343306 343907LV-GW-ERB EPA 3010 EPA 6010 50150125006 343306 343907Trip Blank EPA 3010 EPA 6010 50150125001 343183 343222LV-GW-SB-1 EPA 3510 EPA 8270 by SIM LVE 50150125002 343183 343222LV-GW-SB-2 EPA 3510 EPA 8270 by SIM LVE 50150125003 343183 343222LV-GW-SB-3 EPA 3510 EPA 8270 by SIM LVE 50150125004 343183 343222LV-GW-FD-1 EPA 3510 EPA 8270 by SIM LVE 50150125005 343183 343222LV-GW-ERB EPA 3510 EPA 8270 by SIM LVE 50150125006 343183 343222Trip Blank EPA 3510 EPA 8270 by SIM LVE 50150125001 344905LV-GW-SB-1 EPA 8260 50150125002 344708LV-GW-SB-2 EPA 8260 50150125003 344905LV-GW-SB-3 EPA 8260 50150125004 344905LV-GW-FD-1 EPA 8260 50150125005 344905LV-GW-ERB EPA 8260 50150125006 344905Trip Blank EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 04:34 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 39 of 42 Page 40 of 42 Page 41 of 42 Page 42 of 42