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HomeMy WebLinkAboutFormer K-Mart Phase II Prepared for: City of South Bend Brownfields Coalition 227 West Jefferson Boulevard, 13th Floor South Bend, Indiana 46601 Phase II Environmental Site Assessment Former K-Mart Shopping Center 4850 West Western Avenue South Bend, Indiana 46619 Symbiont Project No. W150460 HEA Project No. 5200-16-08 August 24, 2016 Prepared for: City of South Bend Brownfields Coalition 227 West Jefferson Boulevard, 13th Floor South Bend, Indiana 46601 Phase II Environmental Site Assessment Former K-Mart Shopping Center 4850 West Western Avenue South Bend, Indiana 46619 Symbiont Project No. W150460 HEA Project No. 5200-16-08 August 24, 2016 Ryan Eckdale-Dudley, GISP Project Manager Symbiont Nivas R. Vijay, CHMM Project Manager Heartland Environmental Associates, Inc. P:\R1-H1-W150460-521 Former K-Mart Phase II Symbiont TABLE OF CONTENTS Section Page EXECUTIVE SUMMARY ..................................................................................... i 1.0 INTRODUCTION ................................................................................................ 1 2.0 BACKGROUND INFORMATION ........................................................................ 2 2.1 Site Description/Background ................................................................... 2 2.2 Physical Setting ...................................................................................... 2 2.3 Recognized Environmental Conditions .................................................... 2 2.4 Objective and Scope of Work .................................................................. 3 3.0 METHODS OF INVESTIGATION ....................................................................... 5 3.1 Soil Assessment ..................................................................................... 5 3.2 Groundwater Assessment ....................................................................... 6 3.3 Ground Penetrating Radar Survey .......................................................... 7 4.0 PHASE II ENVIRONMENTAL SITE ASSESSMENT RESULTS .......................... 8 4.1 Soil Conditions ........................................................................................ 8 4.1.1 Field Observations....................................................................... 8 4.1.2 Laboratory Analytical Results ...................................................... 8 4.2 Groundwater Conditions ......................................................................... 9 4.2.1 Site Hydrogeology ....................................................................... 9 4.2.2 Laboratory Analytical Results ...................................................... 9 4.3 Ground Penetrating Radar Results ......................................................... 9 5.0 CONCLUSIONS AND RECOMMENDATIONS ................................................. 10 5.1 Conclusions .......................................................................................... 10 5.2 Recommendations ................................................................................ 10 6.0 LIMITATIONS .................................................................................................. 12 7.0 REFERENCES ................................................................................................. 13 TABLES 1 Lead in Soil, Former K-Mart Shopping Center, South Bend, Indiana 2 Lead in Groundwater, Former K-Mart Shopping Center, South Bend, Indiana 3 Groundwater Elevation Data, Former K-Mart Shopping Center, South Bend, Indiana P:\R1-H1-W150460-521 Former K-Mart Phase II Symbiont TABLE OF CONTENTS (CONTINUED) FIGURES 1 Site Location Map 2 Soil Boring Location Map APPENDICES A Soil Boring Logs B Laboratory Reports P:\R1-H1-W150460-521 Former K-Mart Phase II Symbiont ACRONYMS AND ABBREVIATIONS amsl Above Mean Sea Level bgs Below Ground Surface Coalition City of South Bend Brownfields Coalition ESA Environmental Site Assessment EPA United States Environmental Protection Agency GPR Ground Penetrating Radar HEA Heartland Environmental Associates, Inc IDEM Indiana Department of Environmental Management LUST Leaking Underground Storage Tank mg/kg Milligrams per Kilogram MS Matrix Spike MSD Matrix Spike Duplicate PAH Polycyclic Aromatic Hydrocarbon PBC Polychlorinated Biphenyls PID Photoionization Detector ppm Parts Per Million Pace Pace Analytical, Indianapolis, IN PVC Polyvinyl Chloride QAPP Quality Assurance Project Plan QA/QC Quality Assurance/Quality Control RCG Remediation Closure Guide REC Recognized Environmental Condition RMGSL Residential Migration to Groundwater SAG Site Assessment Grant SAP Sampling and Analysis Plan Site Former K-Mart Shopping Center, 4850 West Western Ave, South Bend, IN Symbiont Symbiont Science, Engineering and Construction µg/kg Micrograms per Kilogram µg/l Micrograms per Liter UST Underground Storage Tank VOC Volatile Organic Compound P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont i EXECUTIVE SUMMARY This Phase II Environmental Site Assessment (ESA) Report summarizes the results of an environmental investigation of the former K-Mart Shopping Center located at 4850 West Western Avenue, South Bend, Indiana (referred to as the “Site” or the “property”) (Figure 1). The Phase II ESA was conducted in accordance with a site-specific Sampling and Analysis Plan prepared by Symbiont and Heartland Environmental Associates, Inc. (Heartland, Symbiont, 2016) and approved by the United States Environmental Protection Agency (EPA). The Phase II ESA was completed under the City of South Bend Brownfields Coalition’s EPA Community- Wide Brownfield Site Assessment Grant. The purpose of the Phase II ESA was to evaluate recognized environmental conditions (RECs) and other environmental concerns identified in the Phase I Environmental Site Assessment (Heartland, 2016). CONCLUSIONS The following conclusions regarding Site conditions are based on the results of the Phase II Environmental Site Assessment. Soil  Volatile organic compounds (VOCs), polycyclic aromatic hydrocarbons (PAHs), and polychlorinated biphenyls (PCB) were not detected in any of the soil samples collected at the Site. Based on these results, there does not appear to petroleum product impacts to Site soil in the vicinity of the soil sample locations.  Lead was detected in all soil samples collected at the Site as part of the Phase II ESA. Lead was detected in site soil samples at concentrations ranging from 1.6 to 4.7 micrograms per kilogram (mg/kg). These detected concentrations of lead did not exceed the Indiana Department of Environmental Management (IDEM), Remediation Closure Guide (RCG) Residential Migration to Groundwater Screening Levels (RMGSLs). The presence of low concentrations of lead are presumed to be naturally occurring (http://sustainableindiana2016.org/lead-in-indianas-soil/) and not likely associated with a petroleum release. Groundwater  VOCs and PAHs were not detected in any of the groundwater samples collected at the site. Based on these results, there appears to be no petroleum product impacts to site groundwater in the vicinity of the groundwater sample locations.  Lead was detected in all groundwater samples collected at the Site as part of the Phase II ESA. Lead was detected in groundwater samples at concentrations ranging from 16.0 to 76.2 micrograms per liter (ug/l). The detected concentrations of lead exceed the IDEM RCG Residential Screening Level (RSL) of 15 ug/l. It is likely, due to the low P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont ii concentrations of lead encountered and the limited lead impacts encountered in soil, that lead impacts in groundwater are a result of elevated turbidity in groundwater samples collected from temporary groundwater piezometers and are not a result of impacts due to historic site usage. Underground Storage Tanks  No subsurface anomalies indicative of underground storage tanks (USTs) were identified during the ground penetrating radar survey. RECOMMENDATIONS Based on the results of field observations, and soil and groundwater analytical data, there appears to be no impacts to soil and groundwater associated with the RECs and environmental concerns identified in Phase I ESA. Additional soil and/or groundwater investigations do not appear to be warranted at the Site at this time based on the results of this Phase II ESA. Interested parties may wish to retain legal counsel in this matter as Symbiont and Heartland are not qualified to provide legal advice. P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 1 Section 1.0 INTRODUCTION This Phase II Environmental Site Assessment (ESA) Report summarizes the results of an environmental investigation of the former K-Mart property located at 4850 West Western Avenue, South Bend, Indiana (herein referred to as the “Site” or “property”). The ESA was completed in accordance with a site-specific Sampling and Analysis Plan (SAP) prepared by Symbiont (Symbiont, 2016) and approved by the United States Environmental Protection Agency (EPA). The Phase II ESA was completed as part of an EPA Community-Wide Brownfield Site Assessment Grant awarded to the City of South Bend Brownfields Coalition (Coalition) in September 2014 under Cooperative Agreement BF-00E01371. The Site location map is provided as Figure 1. The purpose of the Phase II ESA was to evaluate recognized environmental conditions (RECs) and other environmental concerns identified in the Phase I ESA (Heartland, 2016). Specifically, the purpose of the assessment was to determine if there is evidence of underground storage tanks (USTs) at the Site and to confirm the presence of petroleum products and/or hazardous substances at the Site in conditions that constitute disposal or a release, or provide sufficient information to render a professional opinion that there is no reasonable basis to suspect the presence of hazardous substances or petroleum products at the Site. Supporting documentation is presented in the following appendices:  Appendix A – Soil Boring Logs  Appendix B – Laboratory Reports P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 2 Section 2.0 BACKGROUND INFORMATION 2.1 SITE DESCRIPTION/BACKGROUND The site is located on approximately 9.75-acres situated on one parcel (Parcel # 018-4129- 50324). The site was developed in 1976 as a K-Mart Shopping Center. The site operated as a K-Mart retail store from 1976 through 2005, when the site was vacated. The eastern portion of the site was subsequently segmented and began operation as a Family Dollar retail store in 2007. Three additional retail vendors have also operated in the eastern portion of the site since 2007, with the vendors including a restaurant, an insurance sales office and a cellular phone retailer. Prior to development as K-Mart the site was undeveloped. The remainder of the Site currently consists of the partially vacant commercial shopping center plaza with an associated parking lot and landscaped areas. The site is currently owned by 4850 Western, LLC. A site location map is provided as Figure 1. 2.2 PHYSICAL SETTING The Site elevation is approximately 720 feet above mean sea level. The Site is generally flat and gently slopes to the southwest. 2.3 RECOGNIZED ENVIRONMENTAL CONDITIONS A Phase I ESA conducted in April 2016 (Heartland, 2016), identified the following RECs and potential environmental concerns at the Site. Historical Presence of an Underground Storage Tank As part of operations as K-Mart, the Site historically operated an automobile repair center, located in the westernmost portion of the Site building. The Site operated at least one UST containing waste oil. This UST was removed in October 1993. Soil samples collected in 1993 during UST removal activities indicated the presence of total petroleum hydrocarbon impacts at concentrations exceeding Indiana Department of Environmental Management (IDEM) cleanup objectives. The site was issued a low priority leaking underground storage tank (LUST) incident number (LUST Incident #199301523) in 1994 for this release. After further review from IDEM, this LUST incident was issued a No Further Action (NFA) status in December 1999 based on the low levels of TPH encountered during the UST removal. Groundwater samples were not collected as part of the UST closure confirmation sampling. Potential Existing Underground Storage Tank During the 2016 Phase I Site inspection, evidence of an additional UST, in the form of a vent pipe and access panel, was observed directly west of the Site building, near the location of the previously removed UST. The potential exists that a replacement waste oil UST was installed P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 3 after removal of the previous waste oil UST. Documentation pertaining to the installation or registration of a new UST was located during records search of the Site. Historical Property Use as an Automobile Service Garage As stated above, a portion of the Site operated as an automobile service garage from at least 1976 through 2005. The service garage operated at least four hydraulic lifts. These hydraulics lifts appeared to still be present during the time of the Phase I ESA Site inspection. It was determined that a Phase II ESA should be conducted to evaluate for the presence of petroleum impacts to soil and/or groundwater based on historic usage of the Site. This SAP has been prepared to outline the scope of work for the recommended Phase II ESA. 2.4 OBJECTIVE AND SCOPE OF WORK The objective of this Phase II ESA is to evaluate RECs identified in the Phase I ESA. Specifically, the purpose of the assessment is to determine if there is an existing UST on Site. Additionally, the purpose of the assessment is to determine if there were petroleum product releases associated with historic usage of the Site. Field investigation activities and laboratory analyses were conducted in accordance with the site specific Sampling and Analysis Plan (SAP) (Symbiont and Heartland 2016) and the Quality Assurance Project Plan (QAPP) (Heartland, 2016). The scope of work for investigation of potential Site soil impacts included:  Sample collection and descriptive logging of soil at seven boring locations within the vicinity of the former UST and existing hydraulic lifts. Four borings were installed with the vicinity of the former UST and three soil boring were installed in the vicinity of the existing hydraulic lifts.  Field screening of soil samples in each boring using a photoionization detector (PID) for the presence of volatile organic compounds (VOCs).  Soil samples collected in the vicinity of the former UST were submitted to an analytical laboratory for lead, polycyclic aromatic hydrocarbons (PAHs), and VOC analysis.  Soil samples collected in the vicinity of the existing hydraulic lifts were submitted to an analytical laboratory for analysis of polychlorinated biphenyls (PCBs) in addition to lead, VOCs, and PAHs.  Field duplicate, trip blank, matrix-spike (MS) and matrix-spike duplicate (MSD) samples were collected and also analyzed in accordance with the SAP and QAPP.  Surveying of boring locations. The scope of work for investigation of potential Site groundwater impacts included: P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 4  Completion of all seven soil borings as temporary one-inch diameter polyvinyl chloride (PVC) groundwater monitoring wells.  Measurement of water levels and confirmation of the presence/absences of light non- aqueous phase liquids (LNAPL), and development and sampling of temporary wells.  Laboratory analysis of groundwater samples for dissolved lead, PAHs and VOCs. Field duplicate, trip blank, MS and MSD samples were collected and submitted to the laboratory for analysis in accordance with the SAP and QAPP.  Surveying temporary and permanent monitoring wells. The scope of work for confirming the presence of a possible UST on Site included:  Performing a ground penetrating radar (GPR) survey in the vicinity of the former USTs to identify existing an existing tank and/or tank excavation pits. P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 5 Section 3.0 METHODS OF INVESTIGATION This section summarizes the methods of investigation used to perform the field and laboratory portions of the Phase II ESA. 3.1 SOIL ASSESSMENT Soil Boring Installation Seven soil borings were installed using Geoprobe® Dual-Tube direct-push drilling techniques. The soil types and observations were described and recorded by an onsite geologist. Soil boring logs are provided in Appendix A. The locations of boreholes are shown in Figure 2. All probe drilling rods and soil sampling equipment were decontaminated prior to arrival onsite and between soil boring locations. Sampling equipment was decontaminated with an Alconox equivalent wash followed by clean tap water or distilled water rinses. Field Screening Soil samples from approximately every one to two-foot interval of subsurface were field screened for the presence of VOCs using a PID. The results were recorded in parts per million (ppm) and are reported on the soil boring logs (Appendix A). Sampling and Laboratory Analysis One soil sample was collected from each soil boring for laboratory analysis. Soil samples for laboratory analyses were collected from immediately above the water table, which was estimated at approximately 8 feet below ground surface (bgs). Soil samples for laboratory analysis were placed directly into laboratory-supplied containers, preserved as appropriate, and immediately placed in a cooler on ice for shipping to Pace Analytical – Indianapolis, Indiana (Pace) under a chain of custody for analysis. Soil samples were analyzed for lead using EPA Method 6020B, PAHs using EPA Method 8270 SIM, VOCs using EPA Method 8260. Soil samples collect from soil borings SB-5 through SB-7 were analyzed for PCBs using EPA Method 8082 in addition to lead, VOCs, and PAHs. Field duplicate samples were submitted for lead, PAHs, VOCs, and PCB analysis. Trip blanks were submitted to the laboratory for VOC analysis. In order to ensure that the laboratory’s data precision and accuracy were maintained, soil MS and MSD samples were submitted to the laboratory for analysis. Laboratory reports are provided in Appendix B. Evaluation Criteria Potential environmental impacts to soil were evaluated by comparing the concentrations of the detected constituents with their respective IDEM Remediation Closure Guide (RCG) Residential P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 6 Migration to Groundwater Screening Levels (RMGSLs) and Residential Direct Contact Screening Levels, as issued March 2012 and amended March 2016. 3.2 GROUNDWATER ASSESSMENT Temporary Monitoring Well Installation Temporary monitoring wells constructed of 1-inch diameter schedule 40 polyvinyl chloride blank well casing and 0.010-inch slotted well screens were installed at each of the seven soil boring locations. Quartz filter sand was placed in the annular space between the borehole wall and the outside of each screen. The annular space above the filter pack was filled to the ground surface with granular bentonite to serve as a seal to prevent infiltration of surface water runoff into the borings. The locations of the temporary wells provided in Figure 2. Water Level Measurements After the wells were developed and given time to recharge, static groundwater level measurements were collected. The water level recorded at each monitoring well was used to determine the surface elevation of the water table at each well. Measurements were recorded using a Solinist™ water level indicator which was decontaminated between each well. The approximate depth to the water table is presented in Table 3. An oil/water interface probe was used to determine the presence or absence of LNAPL in each of the temporary monitoring wells. LNAPL was not detected in any of the temporary monitoring wells. Sampling and Laboratory Analysis Temporary groundwater monitoring wells were allowed to stabilize following well installation for at least 24-hours prior to sampling. Groundwater samples were collected from each temporary well utilizing dedicated disposable bailers after allowing for the 24-hour stabilization period. Groundwater samples collected for dissolved lead were collected with a disposable bailer and placed into a non-preserved container and filtered by the laboratory prior to analysis. Groundwater samples collected for PAH analysis were collected with a disposable bailer and samples were placed directly into laboratory supplied non-preserved amber glass jars. Groundwater samples collected for VOC analysis were collected with a disposable bailer and samples were placed directly into laboratory-supplied sample jars containing a hydrochloric acid preservative. Samples were then labeled and placed in a cooler on ice for shipping to Pace under a chain of custody for analysis. Groundwater sample analyses included dissolved lead, PAHs and VOCs. Field sampling precision and data quality was evaluated through the use of sample duplicates and trip blanks. Field duplicate samples were submitted for lead PAHs and VOCs analysis. Trip blanks were submitted to the laboratory for VOC analysis. Groundwater MS and MSD samples were also submitted to the laboratory for analysis. Laboratory reports are provided in Appendix B. Evaluation Criteria P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 7 Potential environmental impacts to groundwater were evaluated by comparing the concentrations of the detected constituents with their respective IDEM RCG Residential Screening Levels (RSLs), as issued March 2012 and amended March 2016. 3.3 GROUND PENETRATING RADAR SURVEY GPR is a non-destructive geophysical method that uses the reflection of microwave radiation to image the subsurface. Pulsed high frequency radio waves in the microwave band of the radio spectrum (radar) are directed into the ground and the reflected signals are detected, processed, and displayed to give a visual image of the subsurface structure. The GPR detects differences in physical properties such as conductivity and density; metallic objects are most clearly visible, but it can also detect PVC, concrete, and often old excavations if the backfill is different from native soil. As each scan progresses, the GPR presents a sub-surface image in real time, allowing USTs, utilities, foundations, and other significant anomalies to be marked out directly in the field. A GPR survey was conducted in the areas where suspected underground storage tanks could be present based on findings of the Phase I ESA. Additionally, a GPR survey was conducted at all boring locations to clear the drilling areas of underground utilities prior to conducting subsurface work. P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 8 Section 4.0 PHASE II ENVIRONMENTAL SITE ASSESSMENT RESULTS The soil and groundwater sample locations are depicted on Figure 2. Laboratory reports for soil and groundwater are provided in Appendix B and summarized in Tables 1 and 2. Water level measurements are summarized in Table 3. 4.1 SOIL CONDITIONS The following paragraphs describe the results of the Phase II ESA soil investigation. 4.1.1 Field Observations Six borings (SB-2 through SB-7) were completed to a depth of 12 feet bgs and one soil boring (SB-1) was completed to a depth of approximately 28 feet bgs. The exterior of the site at boring locations SB-1 through SB-4 is capped with approximately 3-inches of asphalt. Interior borings SB-4 through SB-7 is capped with approximately 6-inches of concrete. The Site is generally underlain by discontinuous hard clays, fine sands, coarse sands and occasional cobbles. The water table is generally encountered in a coarse grained sand that occurs at approximately 6 to 8 feet bgs (Appendix A). VOC were not detected at concentrations exceeding 1.0 ppm in soil samples screened using a PID. 4.1.2 Laboratory Analytical Results Laboratory analytical results for soil samples are summarized in Table 1. Sample results are discussed in the following paragraphs. Lead in Soil Lead was detected in all soil samples collected from each of the soil borings drilled and sampled on Site. Concentrations of lead ranged from 1.7 milligrams per kilogram (mg/kg) in a soil sample collected from 8 to 9 feet bgs from soil boring SB-2 to 4.7 mg/kg in a soil sample collected from 26 to 28 feet bgs from soil boring SB-1 (Table 1). Other Constituents All soil samples collected as part of the Phase II ESA were analyzed for VOCs and PAHs. VOCs and PAHs were not detected above laboratory detection limits in any of the soil samples. PCBs were analyzed for soil samples collected from soil borings SB-5, SB-6 and SB-7. PCBs were not detected above laboratory detection limits in the soil samples collected from these borings (Appendix B). P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 9 4.2 GROUNDWATER CONDITIONS The following paragraphs describe the results of the groundwater investigation. 4.2.1 Site Hydrogeology Depth to groundwater was measured in Site temporary monitoring wells on July 22, 2016. Groundwater elevation at the Site ranged from 89.84 feet above mean sea level (amsl) at SB-7 to 90.30 feet amsl at SB-1. The apparent flow direction of groundwater across the Site is primarily to the east (Table 3). 4.2.2 Laboratory Analytical Results Laboratory analytical results for groundwater samples are summarized in Table 2. Sample results are discussed in detail in the following paragraphs. Lead in Groundwater Lead was detected in all groundwater samples collected from each of the temporary groundwater monitoring wells installed and sampled at the Site. Concentrations of lead in groundwater ranged from 16.0 ug/l in a groundwater sample collected from SB-6 to 76.2 ug/l in a groundwater sample collected from SB-4 (Table 2). Other Constituents All groundwater samples collected as part of the Phase II ESA were analyzed for VOCs and PAHs. VOCs and PAHs were not detected above laboratory detection limits in any of the groundwater samples (Appendix B). 4.3 GROUND PENETRATING RADAR RESULTS The GPR survey did not identify any sub surface structures and/or anomalies that were interpreted as a potential UST. P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 10 Section 5.0 CONCLUSIONS AND RECOMMENDATIONS The following paragraphs summarize the conclusions and recommendations of this Phase II ESA. 5.1 CONCLUSIONS Soil  VOCs, PAHs and PCB were not detected in any of the soil samples collected at the Site and analyzed for these constituents. Based on these results, there does not appear to petroleum product impacts to Site soil in the vicinity of the soil boring and sampling locations.  Lead was detected in all soil samples collected at the Site as part of the Phase II ESA. Lead was not detected at concentrations exceeding it respective IDEM RCG RMGSLs . The presence of low concentrations of lead are presumed to be naturally occurring (http://sustainableindiana2016.org/lead-in-indianas-soil/) and not likely associated with a petroleum release. Groundwater  VOCs and PAHs were not detected in any of the groundwater samples collected at the Site. Based on these results, there appear to be no petroleum product impacts to site groundwater in the vicinity of the groundwater sample locations.  Lead was detected in all groundwater samples collected at the Site as part of the Phase II ESA. Lead was detected in groundwater samples at concentrations ranging from 16.0 to 76.2 ug/l. The detected concentrations of lead exceed the IDEM RCG RSL for residential tap of 15 ug/l. It is likely, due to the low concentrations of lead encountered and the limited lead impacts encountered in soil, that lead impacts in groundwater are a result of elevated turbidity in groundwater samples collected from temporary groundwater piezometers and are not a result of impacts due to historic Site usage. Underground Storage Tanks  No subsurface anomalies indicative of underground storage tanks were identified during the GPR survey conducted as part of the Phase II ESA. 5.2 RECOMMENDATIONS Based on the results of field observations, and soil and groundwater analytical data, there appears to be no impacts to soil and groundwater associated with the RECs and environmental concerns identified in Phase I ESA. Additional soil and/or groundwater investigations related to P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 11 the RECs do not appear to be warranted at the Site at this time based on the results of this Phase II ESA. Interested parties may wish to retain legal counsel in this matter as Symbiont and Heartland are not qualified to provide legal advice. P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 12 Section 6.0 LIMITATIONS The Phase II ESA was performed in accordance with generally accepted practices for the environmental consulting profession, undertaking similar studies at the same time and in the same geographical area as the work conducted by Symbiont and Heartland. Symbiont and Heartland observed the degree of care and skill that are generally exercised by the profession under similar circumstances and conditions. No other warranty is expressed or implied. Symbiont and Heartland’s observations, findings, and opinions should not be considered as scientific certainties, but only as opinion based upon our professional judgment concerning the significance of the data gathered during the course of this investigation. Specifically, Symbiont and Heartland cannot represent that the Property contains hazardous or toxic materials or other latent conditions beyond that observed by Symbiont and Heartland during the course of the investigation. Additionally, due to limitations of the investigation process and the necessary use of data furnished by others, Symbiont, Heartland, and its subcontractors cannot assume liability if actual conditions differ from the information presented in this report. P:\R1-H1-W150460-521 Former K-Mart Phase II.doc Symbiont 13 Section 7.0 REFERENCES Heartland, 2015, Quality Assurance Project Plan, City of South Bend Brownfields Coalition, Community-Wide Brownfields Assessment Project, prepared for The City of South Bend and Coalition Partners, The City of Mishiwaka, and Saint Joseph County, Indiana, February 2015. Heartland, 2016, Phase I Environmental Site Assessment, Former K-Mart Shopping Center, 4850 West Western Avenue, South Bend, Indiana, April 12, 2016. Symbiont, 2016, Sampling and Analysis Plan for Phase II Environmental Site Assessment, Former K-Mart Shopping Center, 4850 West Western Avenue, South Bend, Indiana 46619, May 6, 2016. TABLES TABLE 1 LEAD IN SOILFORMER K-MART SHOPPING CENTER, SOUTH BEND, INDIANA GROUNDWATERRESIDENTIAL(mg/kg)COMMERCIAL/ INDUSTRIAL(mg/kg)EXCAVATION(mg/kg)SOIL MTG RESIDENTIAL(mg/kg)SB-1 26 - 28 7/18/16 4.7SB-2 8 - 9 7/21/16 1.7SB-3 8 - 9 7/21/16 2.2SB-4 7 - 8 7/21/16 2.1SB-5 8 - 9 7/21/16 3.8SB-6 8 - 9 7/21/16 1.9SB-7 8 - 9 7/21/16 2.9 IDEM RCG = Indiana Department of Environmental Management, Remediation Closure Guidebgs = below ground surfacemg/kg = milligrams per kilogramMTG = migration to groundwater NOTE: IDEM RCG DEFAULTING SCREENING LEVELS, MARCH 2016BORING IDENTIFIER SAMPLE DEPTH(feet bgs)SAMPLE DATE RESULT (mg/kg) Volatile organic compounds, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls were analyzed for but not detected in soil samples. Refer to Appendix B for laboratory reports. 400 800 1000 270 SOIL EXPOSURE, DIRECT CONTACT Former Kmart Table 1 Soil Analytical 1 of 1 TABLE 2 LEAD IN GROUNDWATERFORMER K-MART SHOPPING CENTER, SOUTH BEND, INDIANA IDEM RCG DEFAULTING SCREENING LEVELS, MARCH 2016GROUNDWATERRESIDENTIAL TAP (ug/l)SB-1 7/22/16 24.3SB-2 7/22/16 28.7SB-3 7/22/16 18.0SB-4 7/22/16 76.2SB-5 7/22/16 40.4SB-6 7/22/16 16.0SB-7 7/22/16 28.1 IDEM RCG = Indiana Department of Environmental Management, Remediation Closure Guidebgs = below ground surfaceug/l = micrograms per liter NOTE:Volatile organic compounds and polycyclic aromatic hydrocarbons were analyzed for but not detected in groundwater samples. Refer to Appendix B for laboratory reports. BORING/TEMPORARY WELL IDENTIFIER SAMPLE DATE RESULT (ug/l) 15 Former Kmart Table 2 GW Analytical 1 of 1 TABLE 3 GROUNDWATER ELEVATION DATAFORMER K-MART SHOPPING CENTERSOUTH BEND, INDIANA TEMPORARY WELL IDENTIFIER MEASURING POINT ELEVATION(feet amsl)TOTAL DEPTH OF WELL (feet below MPE)DEPTH TO WATER(feet below MPE)WATER LEVEL ELEVATION(feet amsl)SB-1 97.35 11.85 7.05 90.30SB-2 97.32 11.94 7.23 90.09SB-3 98.12 11.75 8.00 90.12SB-4 98.17 11.96 8.13 90.04SB-5 101.20 14.70 11.29 89.91SB-6 101.37 14.75 11.50 89.87SB-7 101.41 14.75 11.57 89.84 amsl = above mean sea levelMPE = measuring point elevation Former Kmart Table 3 GW Elevation Data 1 of 1 FIGURES APPENDIX A SOIL BORING LOGS Asphalt Topsoil Fine to medium sand, light yellow brown, 10YR 6/4, friable, low moisture Medium sand, light yelow brown, 10YR 6/4, hard, moderate moisture Clay Medium sand, light yellow brown, 10YR 6/4, some pebbles, wet at base Clay, brown, 10YR 5/3, hard, some pebbles, medium moisture Clay, gray brown, 10YR 5/2, hard, some pebbles Clay, gray brown, 10YR 5/2, hard, some pebbles, sl moist Clay, gray, 10YR 5/1, slightly moist, some pebbles Total depth 28-ft 5 10 15 20 25 3.0 3.1 4.0 3.0 2.0 4.0 4.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 0.3 0.2 0.3 0.3 0.0 0.0 0.0 SB-1 Former K-Mart Shopping Center Drilling Contractor 5200-16-08 Geologist John Barnhart Date Drilled 7/18/2016 Boring Diameter Inches Feet Geoprobe Static Water Level South Bend, IN4850 West Western Avenue Ark Engineering Services Total Depth of borehole 28 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\4850 Western Avenue, South Bend, IN\Phase II\KMART.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 97.27DrillerChris Chambers 2067 Drill Rig Asphalt Fine sand, white Fine sand to cobbles Find sand to cobbles, clayey Fine sand to cobbles Fine sand, moist Coarse sand, wet Clay Total Depth 12-ft 5 10 15 0.0 0.0 0.0 0.0 0.2 0.1 0.0 SB-2 Former K-Mart Shopping Center Drilling Contractor 5200-16-08 Geologist John Sill Date Drilled 7/21/2016 Boring Diameter Inches Feet Geoprobe Static Water Level South Bend, IN4850 West Western Avenue Ark Engineering Services Total Depth of borehole 12 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\4850 Western Avenue, South Bend, IN\Phase II\KMART.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 97.26DrillerChris Chambers 2067 Drill Rig Asphalt Clay black, coarse sand, yellow, fine sand, white, moist Fine sand, white, wet, clay seam @ 8-ft Coarse sand, wet Clay Total Depth 12-ft 5 10 15 0.0 0.2 0.3 0.3 0.0 0.0 0.0 SB-3 Former K-Mart Shopping Center Drilling Contractor 5200-16-08 Geologist John Sill Date Drilled 7/21/2016 Boring Diameter Inches Feet Geoprobe Static Water Level South Bend, IN4850 West Western Avenue Ark Engineering Services Total Depth of borehole 12 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\4850 Western Avenue, South Bend, IN\Phase II\KMART.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.02DrillerChris Chambers 2067 Drill Rig Asphalt Fine sand, brown, moist Fine sand, white, clay seam at 3.5-ft Fine sand, cobbles & clay at 6-ft, moist Coarse sand, cobbles Fine sand, wet, rocky seam at 10.5-ft Clay, tight Total Depth 12-ft 5 10 15 0.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 SB-4 Former K-Mart Shopping Center Drilling Contractor 5200-16-08 Geologist John Sill Date Drilled 7/21/2016 Boring Diameter Inches Feet Geoprobe Static Water Level South Bend, IN4850 West Western Avenue Ark Engineering Services Total Depth of borehole 12 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\4850 Western Avenue, South Bend, IN\Phase II\KMART.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.12DrillerChris Chambers 2067 Drill Rig Concrete Fine sand, moist Fine sand, tan, dry Fine sand, cobbles, yellow brown Fine sand, gray, wet, some odor Coarse sand, wet Clay, hard Total depth 12-ft 5 10 15 0.0 0.0 0.0 0.7 0.5 0.0 0.0 SB-5 Former K-Mart Shopping Center Drilling Contractor 5200-16-08 Geologist John Sill Date Drilled 7/21/2016 Boring Diameter Inches Feet Geoprobe Static Water Level South Bend, IN4850 West Western Avenue Ark Engineering Services Total Depth of borehole 12 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\4850 Western Avenue, South Bend, IN\Phase II\KMART.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.54DrillerChris Chambers 2067 Drill Rig Concrete Fine sand, yellow brown Sand, tan, dry Sand, Clay at 7-ft, cobbles, at 7.5-8-ft Coarse sand, brown, wet Fine sand Clay, brown, very tight Total depth 12-ft 5 10 15 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SB-6 Former K-Mart Shopping Center Drilling Contractor 5200-16-08 Geologist John Sill Date Drilled 7/21/2016 Boring Diameter Inches Feet Geoprobe Static Water Level South Bend, IN4850 West Western Avenue Ark Engineering Services Total Depth of borehole 12 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\4850 Western Avenue, South Bend, IN\Phase II\KMART.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.56DrillerChris Chambers 2067 Drill Rig Concrete Fine sand, yellow brown, clay seams @ 2-ft Fine sand, white, dry Sand, tan, cobbles, at 7-ft Coarse sand, brown, wet at 8.5-ft Fine sand, wet Fine sand, rocky seam at 10.5-ft Clay, brown, very tight Total depth 12-ft 5 10 15 0.0 0.0 0.0 0.0 0.2 0.0 0.0 0.0 SB-7 Former K-Mart Shopping Center Drilling Contractor 5200-16-08 Geologist John Sill Date Drilled 7/21/2016 Boring Diameter Inches Feet Geoprobe Static Water Level South Bend, IN4850 West Western Avenue Ark Engineering Services Total Depth of borehole 12 Feet Boring Method Direct Push Page 1 Heartland Environmental Associates, Inc.Graphic LogDescription DepthSampleRecovery (ft)P:\Symbiont - City of South Bend USEPA Projects\4850 Western Avenue, South Bend, IN\Phase II\KMART.wl2License Blow CountPID (ppm)Completion3410 Mishawaka Avenue South Bend, Indiana 46615 Ground Elevation 98.52DrillerChris Chambers 2067 Drill Rig APPENDIX B LABORATORY REPORTS #=CL# August 01, 2016 LIMS USE: FR - GREG WAGGLE LIMS OBJECT ID: 50149910 50149910 Project: Pace Project No.: RE: Mr. Nivas VijayHeartland Environmental Assoc., Inc.3410 Mishawaka Avenue Southbend, IN 46610 KMART Dear Mr. Vijay: Enclosed are the analytical results for sample(s) received by the laboratory on July 19, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Mick Mayse mick.mayse@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 1 of 21 #=CP# CERTIFICATIONS Pace Project No.: Project: 50149910 KMART Indiana Certification IDs 7726 Moller Road, Indianapolis, IN 46268 Illinois Certification #: 200074 Indiana Certification #: C-49-06 Kansas/NELAP Certification #:E-10177 Kentucky UST Certification #: 0042 Kentucky WW Certification #:98019 Ohio VAP Certification #: CL-0065 Oklahoma Certification #: 2014-148 Texas Certification #: T104704355-15-9 West Virginia Certification #: 330 Wisconsin Certification #: 999788130 USDA Soil Permit #: P330-10-00128 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 2 of 21 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 50149910 KMART Lab ID Sample ID Matrix Date Collected Date Received 50149910001 KM-SB-1(026028)Solid 07/18/16 10:30 07/19/16 09:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 3 of 21 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 50149910 KMART Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 50149910001 KM-SB-1(026028)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-ITMW SM 2540G 1 PASI-ISKK REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 4 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149910 KMART Sample:KM-SB-1(026028)Lab ID:50149910001 Collected:07/18/16 10:30 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 4.7 mg/kg 07/26/16 01:07 7439-92-107/22/16 07:120.98 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/26/16 17:02 83-32-907/22/16 10:390.0054 1 Acenaphthylene ND mg/kg 07/26/16 17:02 208-96-807/22/16 10:390.0054 1 Anthracene ND mg/kg 07/26/16 17:02 120-12-707/22/16 10:390.0054 1 Benzo(a)anthracene ND mg/kg 07/26/16 17:02 56-55-307/22/16 10:390.0054 1 Benzo(a)pyrene ND mg/kg 07/26/16 17:02 50-32-807/22/16 10:390.0054 1 Benzo(b)fluoranthene ND mg/kg 07/26/16 17:02 205-99-207/22/16 10:390.0054 1 Benzo(g,h,i)perylene ND mg/kg 07/26/16 17:02 191-24-207/22/16 10:390.0054 1 Benzo(k)fluoranthene ND mg/kg 07/26/16 17:02 207-08-907/22/16 10:390.0054 1 Chrysene ND mg/kg 07/26/16 17:02 218-01-907/22/16 10:390.0054 1 Dibenz(a,h)anthracene ND mg/kg 07/26/16 17:02 53-70-307/22/16 10:390.0054 1 Fluoranthene ND mg/kg 07/26/16 17:02 206-44-007/22/16 10:390.0054 1 Fluorene ND mg/kg 07/26/16 17:02 86-73-707/22/16 10:390.0054 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/26/16 17:02 193-39-507/22/16 10:390.0054 1 1-Methylnaphthalene ND mg/kg 07/26/16 17:02 90-12-0 N207/22/16 10:390.0054 1 2-Methylnaphthalene ND mg/kg 07/26/16 17:02 91-57-607/22/16 10:390.0054 1 Naphthalene ND mg/kg 07/26/16 17:02 91-20-307/22/16 10:390.0054 1 Phenanthrene ND mg/kg 07/26/16 17:02 85-01-807/22/16 10:390.0054 1 Pyrene ND mg/kg 07/26/16 17:02 129-00-007/22/16 10:390.0054 1 Surrogates 2-Fluorobiphenyl (S)74 %.07/26/16 17:02 321-60-807/22/16 10:3925-121 1 p-Terphenyl-d14 (S)79 %.07/26/16 17:02 1718-51-007/22/16 10:3927-124 1 Analytical Method: EPA 8270 Acenaphthene ND ug/kg 07/20/16 19:51 83-32-93561 Acenaphthylene ND ug/kg 07/20/16 19:51 208-96-83561 Anthracene ND ug/kg 07/20/16 19:51 120-12-73561 Benzo(a)anthracene ND ug/kg 07/20/16 19:51 56-55-33561 Benzo(a)pyrene ND ug/kg 07/20/16 19:51 50-32-83561 Benzo(b)fluoranthene ND ug/kg 07/20/16 19:51 205-99-23561 Benzo(g,h,i)perylene ND ug/kg 07/20/16 19:51 191-24-23561 Benzo(k)fluoranthene ND ug/kg 07/20/16 19:51 207-08-93561 Benzyl alcohol ND ug/kg 07/20/16 19:51 100-51-67121 4-Bromophenylphenyl ether ND ug/kg 07/20/16 19:51 101-55-33561 Butylbenzylphthalate ND ug/kg 07/20/16 19:51 85-68-73561 4-Chloro-3-methylphenol ND ug/kg 07/20/16 19:51 59-50-77121 4-Chloroaniline ND ug/kg 07/20/16 19:51 106-47-87121 bis(2-Chloroethoxy)methane ND ug/kg 07/20/16 19:51 111-91-13561 bis(2-Chloroethyl) ether ND ug/kg 07/20/16 19:51 111-44-43561 bis(2chloro1methylethyl) ether ND ug/kg 07/20/16 19:51 108-60-13561 2-Chloronaphthalene ND ug/kg 07/20/16 19:51 91-58-73561 2-Chlorophenol ND ug/kg 07/20/16 19:51 95-57-83561 4-Chlorophenylphenyl ether ND ug/kg 07/20/16 19:51 7005-72-33561 Chrysene ND ug/kg 07/20/16 19:51 218-01-93561 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 5 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149910 KMART Sample:KM-SB-1(026028)Lab ID:50149910001 Collected:07/18/16 10:30 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8270 Dibenz(a,h)anthracene ND ug/kg 07/20/16 19:51 53-70-33561 Dibenzofuran ND ug/kg 07/20/16 19:51 132-64-93561 3,3'-Dichlorobenzidine ND ug/kg 07/20/16 19:51 91-94-17121 2,4-Dichlorophenol ND ug/kg 07/20/16 19:51 120-83-23561 Diethylphthalate ND ug/kg 07/20/16 19:51 84-66-23561 2,4-Dimethylphenol ND ug/kg 07/20/16 19:51 105-67-93561 Dimethylphthalate ND ug/kg 07/20/16 19:51 131-11-33561 Di-n-butylphthalate ND ug/kg 07/20/16 19:51 84-74-23561 4,6-Dinitro-2-methylphenol ND ug/kg 07/20/16 19:51 534-52-117301 2,4-Dinitrophenol ND ug/kg 07/20/16 19:51 51-28-517301 2,4-Dinitrotoluene ND ug/kg 07/20/16 19:51 121-14-23561 2,6-Dinitrotoluene ND ug/kg 07/20/16 19:51 606-20-23561 Di-n-octylphthalate ND ug/kg 07/20/16 19:51 117-84-03561 bis(2-Ethylhexyl)phthalate ND ug/kg 07/20/16 19:51 117-81-73561 Fluoranthene ND ug/kg 07/20/16 19:51 206-44-03561 Fluorene ND ug/kg 07/20/16 19:51 86-73-73561 Hexachloro-1,3-butadiene ND ug/kg 07/20/16 19:51 87-68-33561 Hexachlorobenzene ND ug/kg 07/20/16 19:51 118-74-13561 Hexachlorocyclopentadiene ND ug/kg 07/20/16 19:51 77-47-43561 Hexachloroethane ND ug/kg 07/20/16 19:51 67-72-13561 Indeno(1,2,3-cd)pyrene ND ug/kg 07/20/16 19:51 193-39-53561 Isophorone ND ug/kg 07/20/16 19:51 78-59-13561 1-Methylnaphthalene ND ug/kg 07/20/16 19:51 90-12-0 N23561 2-Methylnaphthalene ND ug/kg 07/20/16 19:51 91-57-63561 2-Methylphenol(o-Cresol)ND ug/kg 07/20/16 19:51 95-48-73561 3&4-Methylphenol(m&p Cresol)ND ug/kg 07/20/16 19:517121 Naphthalene ND ug/kg 07/20/16 19:51 91-20-33561 2-Nitroaniline ND ug/kg 07/20/16 19:51 88-74-417301 3-Nitroaniline ND ug/kg 07/20/16 19:51 99-09-217301 4-Nitroaniline ND ug/kg 07/20/16 19:51 100-01-617301 Nitrobenzene ND ug/kg 07/20/16 19:51 98-95-33561 2-Nitrophenol ND ug/kg 07/20/16 19:51 88-75-53561 4-Nitrophenol ND ug/kg 07/20/16 19:51 100-02-717301 N-Nitroso-di-n-propylamine ND ug/kg 07/20/16 19:51 621-64-73561 N-Nitrosodiphenylamine ND ug/kg 07/20/16 19:51 86-30-63561 Pentachlorophenol ND ug/kg 07/20/16 19:51 87-86-517301 Phenanthrene ND ug/kg 07/20/16 19:51 85-01-83561 Phenol ND ug/kg 07/20/16 19:51 108-95-23561 Pyrene ND ug/kg 07/20/16 19:51 129-00-03561 2,4,5-Trichlorophenol ND ug/kg 07/20/16 19:51 95-95-43561 2,4,6-Trichlorophenol ND ug/kg 07/20/16 19:51 88-06-23561 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 07/28/16 06:18 67-64-10.080 1 Acrolein ND mg/kg 07/28/16 06:18 107-02-80.080 1 Acrylonitrile ND mg/kg 07/28/16 06:18 107-13-10.080 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 6 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149910 KMART Sample:KM-SB-1(026028)Lab ID:50149910001 Collected:07/18/16 10:30 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA Benzene ND mg/kg 07/28/16 06:18 71-43-20.0040 1 Bromobenzene ND mg/kg 07/28/16 06:18 108-86-10.0040 1 Bromochloromethane ND mg/kg 07/28/16 06:18 74-97-50.0040 1 Bromodichloromethane ND mg/kg 07/28/16 06:18 75-27-40.0040 1 Bromoform ND mg/kg 07/28/16 06:18 75-25-20.0040 1 Bromomethane ND mg/kg 07/28/16 06:18 74-83-90.0040 1 2-Butanone (MEK)ND mg/kg 07/28/16 06:18 78-93-30.020 1 n-Butylbenzene ND mg/kg 07/28/16 06:18 104-51-80.0040 1 sec-Butylbenzene ND mg/kg 07/28/16 06:18 135-98-80.0040 1 tert-Butylbenzene ND mg/kg 07/28/16 06:18 98-06-60.0040 1 Carbon disulfide ND mg/kg 07/28/16 06:18 75-15-00.0080 1 Carbon tetrachloride ND mg/kg 07/28/16 06:18 56-23-50.0040 1 Chlorobenzene ND mg/kg 07/28/16 06:18 108-90-70.0040 1 Chloroethane ND mg/kg 07/28/16 06:18 75-00-30.0040 1 Chloroform ND mg/kg 07/28/16 06:18 67-66-30.0040 1 Chloromethane ND mg/kg 07/28/16 06:18 74-87-30.0040 1 2-Chlorotoluene ND mg/kg 07/28/16 06:18 95-49-80.0040 1 4-Chlorotoluene ND mg/kg 07/28/16 06:18 106-43-40.0040 1 Dibromochloromethane ND mg/kg 07/28/16 06:18 124-48-10.0040 1 1,2-Dibromoethane (EDB)ND mg/kg 07/28/16 06:18 106-93-40.0040 1 Dibromomethane ND mg/kg 07/28/16 06:18 74-95-30.0040 1 1,2-Dichlorobenzene ND mg/kg 07/28/16 06:18 95-50-10.0040 1 1,3-Dichlorobenzene ND mg/kg 07/28/16 06:18 541-73-10.0040 1 1,4-Dichlorobenzene ND mg/kg 07/28/16 06:18 106-46-70.0040 1 trans-1,4-Dichloro-2-butene ND mg/kg 07/28/16 06:18 110-57-60.080 1 Dichlorodifluoromethane ND mg/kg 07/28/16 06:18 75-71-80.0040 1 1,1-Dichloroethane ND mg/kg 07/28/16 06:18 75-34-30.0040 1 1,2-Dichloroethane ND mg/kg 07/28/16 06:18 107-06-20.0040 1 1,1-Dichloroethene ND mg/kg 07/28/16 06:18 75-35-40.0040 1 cis-1,2-Dichloroethene ND mg/kg 07/28/16 06:18 156-59-20.0040 1 trans-1,2-Dichloroethene ND mg/kg 07/28/16 06:18 156-60-50.0040 1 1,2-Dichloropropane ND mg/kg 07/28/16 06:18 78-87-50.0040 1 1,3-Dichloropropane ND mg/kg 07/28/16 06:18 142-28-90.0040 1 2,2-Dichloropropane ND mg/kg 07/28/16 06:18 594-20-70.0040 1 1,1-Dichloropropene ND mg/kg 07/28/16 06:18 563-58-60.0040 1 cis-1,3-Dichloropropene ND mg/kg 07/28/16 06:18 10061-01-50.0040 1 trans-1,3-Dichloropropene ND mg/kg 07/28/16 06:18 10061-02-60.0040 1 Ethylbenzene ND mg/kg 07/28/16 06:18 100-41-40.0040 1 Ethyl methacrylate ND mg/kg 07/28/16 06:18 97-63-20.080 1 Hexachloro-1,3-butadiene ND mg/kg 07/28/16 06:18 87-68-30.0040 1 n-Hexane ND mg/kg 07/28/16 06:18 110-54-30.0040 1 2-Hexanone ND mg/kg 07/28/16 06:18 591-78-60.080 1 Iodomethane ND mg/kg 07/28/16 06:18 74-88-40.080 1 Isopropylbenzene (Cumene)ND mg/kg 07/28/16 06:18 98-82-80.0040 1 p-Isopropyltoluene ND mg/kg 07/28/16 06:18 99-87-60.0040 1 Methylene Chloride ND mg/kg 07/28/16 06:18 75-09-20.016 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 7 of 21 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50149910 KMART Sample:KM-SB-1(026028)Lab ID:50149910001 Collected:07/18/16 10:30 Received:07/19/16 09:30 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Methyl-2-pentanone (MIBK)ND mg/kg 07/28/16 06:18 108-10-10.020 1 Methyl-tert-butyl ether ND mg/kg 07/28/16 06:18 1634-04-40.0040 1 Naphthalene ND mg/kg 07/28/16 06:18 91-20-30.0040 1 n-Propylbenzene ND mg/kg 07/28/16 06:18 103-65-10.0040 1 Styrene ND mg/kg 07/28/16 06:18 100-42-50.0040 1 1,1,1,2-Tetrachloroethane ND mg/kg 07/28/16 06:18 630-20-60.0040 1 1,1,2,2-Tetrachloroethane ND mg/kg 07/28/16 06:18 79-34-50.0040 1 Tetrachloroethene ND mg/kg 07/28/16 06:18 127-18-40.0040 1 Toluene ND mg/kg 07/28/16 06:18 108-88-30.0040 1 1,2,3-Trichlorobenzene ND mg/kg 07/28/16 06:18 87-61-60.0040 1 1,2,4-Trichlorobenzene ND mg/kg 07/28/16 06:18 120-82-10.0040 1 1,1,1-Trichloroethane ND mg/kg 07/28/16 06:18 71-55-60.0040 1 1,1,2-Trichloroethane ND mg/kg 07/28/16 06:18 79-00-50.0040 1 Trichloroethene ND mg/kg 07/28/16 06:18 79-01-60.0040 1 Trichlorofluoromethane ND mg/kg 07/28/16 06:18 75-69-40.0040 1 1,2,3-Trichloropropane ND mg/kg 07/28/16 06:18 96-18-40.0040 1 1,2,4-Trimethylbenzene ND mg/kg 07/28/16 06:18 95-63-60.0040 1 1,3,5-Trimethylbenzene ND mg/kg 07/28/16 06:18 108-67-80.0040 1 Vinyl acetate ND mg/kg 07/28/16 06:18 108-05-40.080 1 Vinyl chloride ND mg/kg 07/28/16 06:18 75-01-40.0040 1 Xylene (Total)ND mg/kg 07/28/16 06:18 1330-20-70.0080 1 Surrogates Dibromofluoromethane (S)109 %.07/28/16 06:18 1868-53-770-128 1 Toluene-d8 (S)113 %.07/28/16 06:18 2037-26-572-139 1 4-Bromofluorobenzene (S)77 %.07/28/16 06:18 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 7.3 %07/26/16 16:250.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 8 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149910 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 342981 EPA 3050 EPA 6010 6010 MET Associated Lab Samples:50149910001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1588483 Associated Lab Samples:50149910001 Matrix:Solid Analyzed Lead mg/kg ND 1.0 07/26/16 01:00 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1588484LABORATORY CONTROL SAMPLE: LCSSpike Lead mg/kg 48.950 98 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1588485MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50149993003 1588486 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead mg/kg 64.6 93 75-12584 11 2063.810.1 70.5 63.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 9 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149910 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344036 EPA 8260 EPA 8260 8260 MSV 5035A Volatile Organics Associated Lab Samples:50149910001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1592881 Associated Lab Samples:50149910001 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 07/28/16 01:54 1,1,1-Trichloroethane mg/kg ND 0.0050 07/28/16 01:54 1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 07/28/16 01:54 1,1,2-Trichloroethane mg/kg ND 0.0050 07/28/16 01:54 1,1-Dichloroethane mg/kg ND 0.0050 07/28/16 01:54 1,1-Dichloroethene mg/kg ND 0.0050 07/28/16 01:54 1,1-Dichloropropene mg/kg ND 0.0050 07/28/16 01:54 1,2,3-Trichlorobenzene mg/kg ND 0.0050 07/28/16 01:54 1,2,3-Trichloropropane mg/kg ND 0.0050 07/28/16 01:54 1,2,4-Trichlorobenzene mg/kg ND 0.0050 07/28/16 01:54 1,2,4-Trimethylbenzene mg/kg ND 0.0050 07/28/16 01:54 1,2-Dibromoethane (EDB)mg/kg ND 0.0050 07/28/16 01:54 1,2-Dichlorobenzene mg/kg ND 0.0050 07/28/16 01:54 1,2-Dichloroethane mg/kg ND 0.0050 07/28/16 01:54 1,2-Dichloropropane mg/kg ND 0.0050 07/28/16 01:54 1,3,5-Trimethylbenzene mg/kg ND 0.0050 07/28/16 01:54 1,3-Dichlorobenzene mg/kg ND 0.0050 07/28/16 01:54 1,3-Dichloropropane mg/kg ND 0.0050 07/28/16 01:54 1,4-Dichlorobenzene mg/kg ND 0.0050 07/28/16 01:54 2,2-Dichloropropane mg/kg ND 0.0050 07/28/16 01:54 2-Butanone (MEK)mg/kg ND 0.025 07/28/16 01:54 2-Chlorotoluene mg/kg ND 0.0050 07/28/16 01:54 2-Hexanone mg/kg ND 0.10 07/28/16 01:54 4-Chlorotoluene mg/kg ND 0.0050 07/28/16 01:54 4-Methyl-2-pentanone (MIBK)mg/kg ND 0.025 07/28/16 01:54 Acetone mg/kg ND 0.10 07/28/16 01:54 Acrolein mg/kg ND 0.10 07/28/16 01:54 Acrylonitrile mg/kg ND 0.10 07/28/16 01:54 Benzene mg/kg ND 0.0050 07/28/16 01:54 Bromobenzene mg/kg ND 0.0050 07/28/16 01:54 Bromochloromethane mg/kg ND 0.0050 07/28/16 01:54 Bromodichloromethane mg/kg ND 0.0050 07/28/16 01:54 Bromoform mg/kg ND 0.0050 07/28/16 01:54 Bromomethane mg/kg ND 0.0050 07/28/16 01:54 Carbon disulfide mg/kg ND 0.010 07/28/16 01:54 Carbon tetrachloride mg/kg ND 0.0050 07/28/16 01:54 Chlorobenzene mg/kg ND 0.0050 07/28/16 01:54 Chloroethane mg/kg ND 0.0050 07/28/16 01:54 Chloroform mg/kg ND 0.0050 07/28/16 01:54 Chloromethane mg/kg ND 0.0050 07/28/16 01:54 cis-1,2-Dichloroethene mg/kg ND 0.0050 07/28/16 01:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 10 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149910 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1592881 Associated Lab Samples:50149910001 Matrix:Solid Analyzed cis-1,3-Dichloropropene mg/kg ND 0.0050 07/28/16 01:54 Dibromochloromethane mg/kg ND 0.0050 07/28/16 01:54 Dibromomethane mg/kg ND 0.0050 07/28/16 01:54 Dichlorodifluoromethane mg/kg ND 0.0050 07/28/16 01:54 Ethyl methacrylate mg/kg ND 0.10 07/28/16 01:54 Ethylbenzene mg/kg ND 0.0050 07/28/16 01:54 Hexachloro-1,3-butadiene mg/kg ND 0.0050 07/28/16 01:54 Iodomethane mg/kg ND 0.10 07/28/16 01:54 Isopropylbenzene (Cumene)mg/kg ND 0.0050 07/28/16 01:54 Methyl-tert-butyl ether mg/kg ND 0.0050 07/28/16 01:54 Methylene Chloride mg/kg ND 0.020 07/28/16 01:54 n-Butylbenzene mg/kg ND 0.0050 07/28/16 01:54 n-Hexane mg/kg ND 0.0050 07/28/16 01:54 n-Propylbenzene mg/kg ND 0.0050 07/28/16 01:54 Naphthalene mg/kg ND 0.0050 07/28/16 01:54 p-Isopropyltoluene mg/kg ND 0.0050 07/28/16 01:54 sec-Butylbenzene mg/kg ND 0.0050 07/28/16 01:54 Styrene mg/kg ND 0.0050 07/28/16 01:54 tert-Butylbenzene mg/kg ND 0.0050 07/28/16 01:54 Tetrachloroethene mg/kg ND 0.0050 07/28/16 01:54 Toluene mg/kg ND 0.0050 07/28/16 01:54 trans-1,2-Dichloroethene mg/kg ND 0.0050 07/28/16 01:54 trans-1,3-Dichloropropene mg/kg ND 0.0050 07/28/16 01:54 trans-1,4-Dichloro-2-butene mg/kg ND 0.10 07/28/16 01:54 Trichloroethene mg/kg ND 0.0050 07/28/16 01:54 Trichlorofluoromethane mg/kg ND 0.0050 07/28/16 01:54 Vinyl acetate mg/kg ND 0.10 07/28/16 01:54 Vinyl chloride mg/kg ND 0.0050 07/28/16 01:54 Xylene (Total)mg/kg ND 0.010 07/28/16 01:54 4-Bromofluorobenzene (S)%.99 65-127 07/28/16 01:54 Dibromofluoromethane (S)%.109 70-128 07/28/16 01:54 Toluene-d8 (S)%.98 72-139 07/28/16 01:54 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1592882LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1-Trichloroethane mg/kg 0.046.05 92 67-123 1,1,2,2-Tetrachloroethane mg/kg 0.049.05 98 67-129 1,1-Dichloroethene mg/kg 0.050.05 100 64-133 1,2,4-Trimethylbenzene mg/kg 0.044.05 89 66-118 1,2-Dichloropropane mg/kg 0.046.05 92 74-119 Benzene mg/kg 0.044.05 89 72-120 Chlorobenzene mg/kg 0.046.05 93 72-115 Chloroform mg/kg 0.043.05 86 66-116 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 11 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149910 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1592882LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene mg/kg 0.048.05 97 74-115 Ethylbenzene mg/kg 0.048.05 95 70-121 Isopropylbenzene (Cumene)mg/kg 0.045.05 89 78-130 Methyl-tert-butyl ether mg/kg 0.049.05 97 68-123 Naphthalene mg/kg 0.042.05 85 63-125 Tetrachloroethene mg/kg 0.043.05 86 66-118 Toluene mg/kg 0.046.05 92 68-121 trans-1,2-Dichloroethene mg/kg 0.048.05 96 71-120 Trichloroethene mg/kg 0.047.05 94 73-120 Vinyl chloride mg/kg 0.051.05 103 54-155 Xylene (Total)mg/kg 0.14.15 91 69-122 4-Bromofluorobenzene (S)%.101 65-127 Dibromofluoromethane (S)%.95 70-128 Toluene-d8 (S)%.108 72-139 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 12 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149910 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343229 EPA 3546 EPA 8270 by SIM 8270 MSSV PAH by SIM Associated Lab Samples:50149910001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1589764 Associated Lab Samples:50149910001 Matrix:Solid Analyzed 1-Methylnaphthalene mg/kg ND 0.0050 N207/25/16 15:15 2-Methylnaphthalene mg/kg ND 0.0050 07/25/16 15:15 Acenaphthene mg/kg ND 0.0050 07/25/16 15:15 Acenaphthylene mg/kg ND 0.0050 07/25/16 15:15 Anthracene mg/kg ND 0.0050 07/25/16 15:15 Benzo(a)anthracene mg/kg ND 0.0050 07/25/16 15:15 Benzo(a)pyrene mg/kg ND 0.0050 07/25/16 15:15 Benzo(b)fluoranthene mg/kg ND 0.0050 07/25/16 15:15 Benzo(g,h,i)perylene mg/kg ND 0.0050 07/25/16 15:15 Benzo(k)fluoranthene mg/kg ND 0.0050 07/25/16 15:15 Chrysene mg/kg ND 0.0050 07/25/16 15:15 Dibenz(a,h)anthracene mg/kg ND 0.0050 07/25/16 15:15 Fluoranthene mg/kg ND 0.0050 07/25/16 15:15 Fluorene mg/kg ND 0.0050 07/25/16 15:15 Indeno(1,2,3-cd)pyrene mg/kg ND 0.0050 07/25/16 15:15 Naphthalene mg/kg ND 0.0050 07/25/16 15:15 Phenanthrene mg/kg ND 0.0050 07/25/16 15:15 Pyrene mg/kg ND 0.0050 07/25/16 15:15 2-Fluorobiphenyl (S)%.84 25-121 07/25/16 15:15 p-Terphenyl-d14 (S)%.101 27-124 07/25/16 15:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589765LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene mg/kg 0.25 N2.33 77 41-109 2-Methylnaphthalene mg/kg 0.25.33 76 39-109 Acenaphthene mg/kg 0.28.33 84 44-127 Acenaphthylene mg/kg 0.27.33 80 43-128 Anthracene mg/kg 0.29.33 88 49-131 Benzo(a)anthracene mg/kg 0.32.33 95 52-128 Benzo(a)pyrene mg/kg 0.26.33 77 54-141 Benzo(b)fluoranthene mg/kg 0.25.33 75 50-146 Benzo(g,h,i)perylene mg/kg 0.26.33 77 51-141 Benzo(k)fluoranthene mg/kg 0.27.33 81 55-139 Chrysene mg/kg 0.32.33 97 56-131 Dibenz(a,h)anthracene mg/kg 0.25.33 74 53-142 Fluoranthene mg/kg 0.30.33 89 51-139 Fluorene mg/kg 0.28.33 85 45-131 Indeno(1,2,3-cd)pyrene mg/kg 0.25.33 74 51-141 Naphthalene mg/kg 0.25.33 76 43-112 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 13 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149910 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1589765LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene mg/kg 0.30.33 91 47-132 Pyrene mg/kg 0.33.33 99 55-130 2-Fluorobiphenyl (S)%.76 25-121 p-Terphenyl-d14 (S)%.87 27-124 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589766MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50149912002 1589767 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene mg/kg N2.4 72 17-11875 4 20.4ND 0.29 0.30 2-Methylnaphthalene mg/kg .4 70 15-11872 3 20.4ND 0.28 0.29 Acenaphthene mg/kg .4 78 21-12578 1 20.4ND 0.32 0.32 Acenaphthylene mg/kg .4 77 21-12679 2 20.4ND 0.31 0.32 Anthracene mg/kg .4 83 15-13476 9 20.4ND 0.33 0.31 Benzo(a)anthracene mg/kg .4 93 14-12986 8 20.4ND 0.38 0.35 Benzo(a)pyrene mg/kg .4 67 10-14663 8 20.4ND 0.27 0.25 Benzo(b)fluoranthene mg/kg .4 71 10-14662 14 20.4ND 0.29 0.25 Benzo(g,h,i)perylene mg/kg .4 68 10-14263 7 20.4ND 0.28 0.26 Benzo(k)fluoranthene mg/kg .4 70 10-14771 1 20.4ND 0.28 0.29 Chrysene mg/kg .4 84 11-14080 5 20.4ND 0.34 0.32 Dibenz(a,h)anthracene mg/kg .4 67 16-13665 4 20.4ND 0.27 0.26 Fluoranthene mg/kg .4 86 10-14680 7 20.4ND 0.35 0.33 Fluorene mg/kg .4 81 20-13182 1 20.4ND 0.33 0.33 Indeno(1,2,3-cd)pyrene mg/kg .4 67 10-14662 8 20.4ND 0.27 0.25 Naphthalene mg/kg .4 73 15-12674 0 20.4ND 0.30 0.30 Phenanthrene mg/kg .4 83 10-14880 4 20.4ND 0.34 0.32 Pyrene mg/kg .4 84 14-13679 6 20.4ND 0.34 0.32 2-Fluorobiphenyl (S)%.70 25-12177 p-Terphenyl-d14 (S)%.74 27-12475 Parameter Units MS Result % Rec Limits Qual% RecConc. 1589768MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150209023 1589769 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene mg/kg N2.4 100 17-118110 8 20.466.0 ug/kg 0.47 0.51 2-Methylnaphthalene mg/kg .4 103 15-118113 9 20.482.9 ug/kg 0.50 0.54 Acenaphthene mg/kg .4 85 21-12588 3 20.4ND 0.34 0.36 Acenaphthylene mg/kg .4 80 21-12678 2 20.4ND 0.32 0.32 Anthracene mg/kg .4 89 15-13489 1 20.4ND 0.36 0.36 Benzo(a)anthracene mg/kg .4 93 14-129101 9 20.423.2 ug/kg 0.40 0.43 Benzo(a)pyrene mg/kg .4 70 10-14678 11 20.4ND 0.28 0.32 Benzo(b)fluoranthene mg/kg .4 68 10-14681 18 20.4ND 0.27 0.33 Benzo(g,h,i)perylene mg/kg .4 71 10-14273 3 20.4ND 0.29 0.30 Benzo(k)fluoranthene mg/kg .4 77 10-14772 7 20.4ND 0.31 0.29 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 14 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149910 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1589768MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150209023 1589769 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chrysene mg/kg .4 86 11-14093 8 20.420.7 ug/kg 0.37 0.40 Dibenz(a,h)anthracene mg/kg .4 69 16-13667 3 20.4ND 0.28 0.27 Fluoranthene mg/kg .4 84 10-14696 13 20.427.1 ug/kg 0.37 0.42 Fluorene mg/kg .4 89 20-13197 9 20.4ND 0.36 0.39 Indeno(1,2,3-cd)pyrene mg/kg .4 68 10-14669 2 20.4ND 0.28 0.28 Naphthalene mg/kg .4 76 15-12678 3 20.436.9 ug/kg 0.34 0.35 Phenanthrene mg/kg .4 91 10-148100 9 20.438.8 ug/kg 0.41 0.44 Pyrene mg/kg .4 95 14-136107 11 20.428.8 ug/kg 0.41 0.46 2-Fluorobiphenyl (S)%.78 25-12175 p-Terphenyl-d14 (S)%.88 27-12481 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 15 of 21 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50149910 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343778 SM 2540G SM 2540G Dry Weight/Percent Moisture Associated Lab Samples:50149910001 Parameter Units Dup Result Max RPD QualifiersRPDResult 50149903002 1591989SAMPLE DUPLICATE: Percent Moisture %5.3 R1755.7 Parameter Units Dup Result Max RPD QualifiersRPDResult 50149912002 1591990SAMPLE DUPLICATE: Percent Moisture %17.6 2 518.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 16 of 21 #=QL# QUALIFIERS Pace Project No.: Project: 50149910 KMART DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - IndianapolisPASI-I ANALYTE QUALIFIERS The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 17 of 21 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 50149910 KMART Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 50149910001 342981 343672KM-SB-1(026028)EPA 3050 EPA 6010 50149910001 343229 343387KM-SB-1(026028)EPA 3546 EPA 8270 by SIM 50149910001 344036KM-SB-1(026028)EPA 8260 50149910001 343778KM-SB-1(026028)SM 2540G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/01/2016 01:59 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 18 of 21 Page 19 of 21 Page 20 of 21 Page 21 of 21 #=CL# August 04, 2016 LIMS USE: FR - GREG WAGGLE LIMS OBJECT ID: 50150303 50150303 Project: Pace Project No.: RE: Mr. Greg Waggle Symbiont 6737 W. Washington St. Suite 3440 Milwaukee, WI 53214 KMART Dear Mr. Waggle: Enclosed are the analytical results for sample(s) received by the laboratory on July 22, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Mick Mayse mick.mayse@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 1 of 58 #=CP# CERTIFICATIONS Pace Project No.: Project: 50150303 KMART Indiana Certification IDs 7726 Moller Road, Indianapolis, IN 46268 Illinois Certification #: 200074 Indiana Certification #: C-49-06 Kansas/NELAP Certification #:E-10177 Kentucky UST Certification #: 0042 Kentucky WW Certification #:98019 Ohio VAP Certification #: CL-0065 Oklahoma Certification #: 2014-148 Texas Certification #: T104704355-15-9 West Virginia Certification #: 330 Wisconsin Certification #: 999788130 USDA Soil Permit #: P330-10-00128 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 2 of 58 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 50150303 KMART Lab ID Sample ID Matrix Date Collected Date Received 50150303001 KM-SB-SB-2 (008-009)Solid 07/21/16 12:43 07/22/16 08:20 50150303002 KM-SB-SB-3 (008-009)Solid 07/21/16 13:23 07/22/16 08:20 50150303003 KM-SB-SB-4 (007-008)Solid 07/21/16 12:25 07/22/16 08:20 50150303004 KM-SB-SB-5 (008-009)Solid 07/21/16 11:27 07/22/16 08:20 50150303005 KM-SB-SB-6 (008-009)Solid 07/21/16 11:39 07/22/16 08:20 50150303006 KM-SB-SB-7 (008-009)Solid 07/21/16 12:00 07/22/16 08:20 50150303007 KM-SB-FD-1 Solid 07/21/16 12:25 07/22/16 08:20 50150303009 TRIP BLANK Water 07/21/16 08:00 07/22/16 08:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 3 of 58 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 50150303 KMART Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 50150303001 KM-SB-SB-2 (008-009)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-IJCM EPA 8260 73 PASI-IJLZ SM 2540G 1 PASI-IESC 50150303002 KM-SB-SB-3 (008-009)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-IJLZ SM 2540G 1 PASI-ISKK 50150303003 KM-SB-SB-4 (007-008)EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-IJLZ SM 2540G 1 PASI-ISKK 50150303004 KM-SB-SB-5 (008-009)EPA 8082 8 PASI-INPW EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-IJLZ SM 2540G 1 PASI-ISKK 50150303005 KM-SB-SB-6 (008-009)EPA 8082 8 PASI-INPW EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-IJLZ SM 2540G 1 PASI-ISKK 50150303006 KM-SB-SB-7 (008-009)EPA 8082 8 PASI-INPW EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-IJLZ SM 2540G 1 PASI-ISKK 50150303007 KM-SB-FD-1 EPA 6010 1 PASI-IJPK EPA 8270 by SIM 20 PASI-ITBP EPA 8260 73 PASI-IJLZ SM 2540G 1 PASI-ISKK 50150303009 TRIP BLANK EPA 8260 75 PASI-IJLZ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 4 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-2 (008-009)Lab ID:50150303001 Collected:07/21/16 12:43 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 1.7 mg/kg 08/02/16 02:11 7439-92-107/29/16 07:301.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/27/16 05:17 83-32-907/25/16 11:300.0056 1 Acenaphthylene ND mg/kg 07/27/16 05:17 208-96-807/25/16 11:300.0056 1 Anthracene ND mg/kg 07/27/16 05:17 120-12-707/25/16 11:300.0056 1 Benzo(a)anthracene ND mg/kg 07/27/16 05:17 56-55-307/25/16 11:300.0056 1 Benzo(a)pyrene ND mg/kg 07/27/16 05:17 50-32-807/25/16 11:300.0056 1 Benzo(b)fluoranthene ND mg/kg 07/27/16 05:17 205-99-207/25/16 11:300.0056 1 Benzo(g,h,i)perylene ND mg/kg 07/27/16 05:17 191-24-207/25/16 11:300.0056 1 Benzo(k)fluoranthene ND mg/kg 07/27/16 05:17 207-08-907/25/16 11:300.0056 1 Chrysene ND mg/kg 07/27/16 05:17 218-01-907/25/16 11:300.0056 1 Dibenz(a,h)anthracene ND mg/kg 07/27/16 05:17 53-70-307/25/16 11:300.0056 1 Fluoranthene ND mg/kg 07/27/16 05:17 206-44-007/25/16 11:300.0056 1 Fluorene ND mg/kg 07/27/16 05:17 86-73-707/25/16 11:300.0056 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/27/16 05:17 193-39-507/25/16 11:300.0056 1 1-Methylnaphthalene ND mg/kg 07/27/16 05:17 90-12-0 N207/25/16 11:300.0056 1 2-Methylnaphthalene ND mg/kg 07/27/16 05:17 91-57-607/25/16 11:300.0056 1 Naphthalene ND mg/kg 07/27/16 05:17 91-20-307/25/16 11:300.0056 1 Phenanthrene ND mg/kg 07/27/16 05:17 85-01-807/25/16 11:300.0056 1 Pyrene ND mg/kg 07/27/16 05:17 129-00-007/25/16 11:300.0056 1 Surrogates 2-Fluorobiphenyl (S)68 %.07/27/16 05:17 321-60-807/25/16 11:3025-121 1 p-Terphenyl-d14 (S)75 %.07/27/16 05:17 1718-51-007/25/16 11:3027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 08/02/16 18:03 67-64-10.096 1 Acrolein ND mg/kg 08/02/16 18:03 107-02-80.096 1 Acrylonitrile ND mg/kg 08/02/16 18:03 107-13-10.096 1 Benzene ND mg/kg 08/02/16 18:03 71-43-20.0048 1 Bromobenzene ND mg/kg 08/02/16 18:03 108-86-10.0048 1 Bromochloromethane ND mg/kg 08/02/16 18:03 74-97-50.0048 1 Bromodichloromethane ND mg/kg 08/02/16 18:03 75-27-40.0048 1 Bromoform ND mg/kg 08/02/16 18:03 75-25-20.0048 1 Bromomethane ND mg/kg 08/02/16 18:03 74-83-90.0048 1 2-Butanone (MEK)ND mg/kg 08/02/16 18:03 78-93-30.024 1 n-Butylbenzene ND mg/kg 08/02/16 18:03 104-51-80.0048 1 sec-Butylbenzene ND mg/kg 08/02/16 18:03 135-98-80.0048 1 tert-Butylbenzene ND mg/kg 08/02/16 18:03 98-06-60.0048 1 Carbon disulfide ND mg/kg 08/02/16 18:03 75-15-00.0096 1 Carbon tetrachloride ND mg/kg 08/02/16 18:03 56-23-50.0048 1 Chlorobenzene ND mg/kg 08/02/16 18:03 108-90-70.0048 1 Chloroethane ND mg/kg 08/02/16 18:03 75-00-30.0048 1 Chloroform ND mg/kg 08/02/16 18:03 67-66-30.0048 1 Chloromethane ND mg/kg 08/02/16 18:03 74-87-30.0048 1 2-Chlorotoluene ND mg/kg 08/02/16 18:03 95-49-80.0048 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 5 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-2 (008-009)Lab ID:50150303001 Collected:07/21/16 12:43 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 08/02/16 18:03 106-43-40.0048 1 Dibromochloromethane ND mg/kg 08/02/16 18:03 124-48-10.0048 1 1,2-Dibromoethane (EDB)ND mg/kg 08/02/16 18:03 106-93-4 L30.0048 1 Dibromomethane ND mg/kg 08/02/16 18:03 74-95-30.0048 1 1,2-Dichlorobenzene ND mg/kg 08/02/16 18:03 95-50-10.0048 1 1,3-Dichlorobenzene ND mg/kg 08/02/16 18:03 541-73-10.0048 1 1,4-Dichlorobenzene ND mg/kg 08/02/16 18:03 106-46-70.0048 1 trans-1,4-Dichloro-2-butene ND mg/kg 08/02/16 18:03 110-57-60.096 1 Dichlorodifluoromethane ND mg/kg 08/02/16 18:03 75-71-80.0048 1 1,1-Dichloroethane ND mg/kg 08/02/16 18:03 75-34-30.0048 1 1,2-Dichloroethane ND mg/kg 08/02/16 18:03 107-06-20.0048 1 1,1-Dichloroethene ND mg/kg 08/02/16 18:03 75-35-40.0048 1 cis-1,2-Dichloroethene ND mg/kg 08/02/16 18:03 156-59-20.0048 1 trans-1,2-Dichloroethene ND mg/kg 08/02/16 18:03 156-60-50.0048 1 1,2-Dichloropropane ND mg/kg 08/02/16 18:03 78-87-50.0048 1 1,3-Dichloropropane ND mg/kg 08/02/16 18:03 142-28-90.0048 1 2,2-Dichloropropane ND mg/kg 08/02/16 18:03 594-20-70.0048 1 1,1-Dichloropropene ND mg/kg 08/02/16 18:03 563-58-60.0048 1 cis-1,3-Dichloropropene ND mg/kg 08/02/16 18:03 10061-01-50.0048 1 trans-1,3-Dichloropropene ND mg/kg 08/02/16 18:03 10061-02-60.0048 1 Ethylbenzene ND mg/kg 08/02/16 18:03 100-41-40.0048 1 Ethyl methacrylate ND mg/kg 08/02/16 18:03 97-63-20.096 1 Hexachloro-1,3-butadiene ND mg/kg 08/02/16 18:03 87-68-30.0048 1 n-Hexane ND mg/kg 08/02/16 18:03 110-54-30.0048 1 2-Hexanone ND mg/kg 08/02/16 18:03 591-78-60.096 1 Iodomethane ND mg/kg 08/02/16 18:03 74-88-40.096 1 Isopropylbenzene (Cumene)ND mg/kg 08/02/16 18:03 98-82-80.0048 1 p-Isopropyltoluene ND mg/kg 08/02/16 18:03 99-87-60.0048 1 Methylene Chloride ND mg/kg 08/02/16 18:03 75-09-20.019 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/02/16 18:03 108-10-10.024 1 Methyl-tert-butyl ether ND mg/kg 08/02/16 18:03 1634-04-40.0048 1 Naphthalene ND mg/kg 08/02/16 18:03 91-20-30.0048 1 n-Propylbenzene ND mg/kg 08/02/16 18:03 103-65-10.0048 1 Styrene ND mg/kg 08/02/16 18:03 100-42-50.0048 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/02/16 18:03 630-20-60.0048 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/02/16 18:03 79-34-50.0048 1 Tetrachloroethene ND mg/kg 08/02/16 18:03 127-18-40.0048 1 Toluene ND mg/kg 08/02/16 18:03 108-88-30.0048 1 1,2,3-Trichlorobenzene ND mg/kg 08/02/16 18:03 87-61-60.0048 1 1,2,4-Trichlorobenzene ND mg/kg 08/02/16 18:03 120-82-10.0048 1 1,1,1-Trichloroethane ND mg/kg 08/02/16 18:03 71-55-60.0048 1 1,1,2-Trichloroethane ND mg/kg 08/02/16 18:03 79-00-50.0048 1 Trichloroethene ND mg/kg 08/02/16 18:03 79-01-60.0048 1 Trichlorofluoromethane ND mg/kg 08/02/16 18:03 75-69-40.0048 1 1,2,3-Trichloropropane ND mg/kg 08/02/16 18:03 96-18-40.0048 1 1,2,4-Trimethylbenzene ND mg/kg 08/02/16 18:03 95-63-60.0048 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 6 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-2 (008-009)Lab ID:50150303001 Collected:07/21/16 12:43 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 08/02/16 18:03 108-67-80.0048 1 Vinyl acetate ND mg/kg 08/02/16 18:03 108-05-40.096 1 Vinyl chloride ND mg/kg 08/02/16 18:03 75-01-40.0048 1 Xylene (Total)ND mg/kg 08/02/16 18:03 1330-20-70.0096 1 Surrogates Dibromofluoromethane (S)93 %.08/02/16 18:03 1868-53-770-128 1 Toluene-d8 (S)96 %.08/02/16 18:03 2037-26-572-139 1 4-Bromofluorobenzene (S)92 %.08/02/16 18:03 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 10.4 %08/02/16 11:590.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 7 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-3 (008-009)Lab ID:50150303002 Collected:07/21/16 13:23 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 2.2 mg/kg 08/02/16 02:21 7439-92-107/29/16 07:301.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/27/16 05:49 83-32-907/25/16 11:000.0058 1 Acenaphthylene ND mg/kg 07/27/16 05:49 208-96-807/25/16 11:000.0058 1 Anthracene ND mg/kg 07/27/16 05:49 120-12-707/25/16 11:000.0058 1 Benzo(a)anthracene ND mg/kg 07/27/16 05:49 56-55-307/25/16 11:000.0058 1 Benzo(a)pyrene ND mg/kg 07/27/16 05:49 50-32-807/25/16 11:000.0058 1 Benzo(b)fluoranthene ND mg/kg 07/27/16 05:49 205-99-207/25/16 11:000.0058 1 Benzo(g,h,i)perylene ND mg/kg 07/27/16 05:49 191-24-207/25/16 11:000.0058 1 Benzo(k)fluoranthene ND mg/kg 07/27/16 05:49 207-08-907/25/16 11:000.0058 1 Chrysene ND mg/kg 07/27/16 05:49 218-01-907/25/16 11:000.0058 1 Dibenz(a,h)anthracene ND mg/kg 07/27/16 05:49 53-70-307/25/16 11:000.0058 1 Fluoranthene ND mg/kg 07/27/16 05:49 206-44-007/25/16 11:000.0058 1 Fluorene ND mg/kg 07/27/16 05:49 86-73-707/25/16 11:000.0058 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/27/16 05:49 193-39-507/25/16 11:000.0058 1 1-Methylnaphthalene ND mg/kg 07/27/16 05:49 90-12-0 N207/25/16 11:000.0058 1 2-Methylnaphthalene ND mg/kg 07/27/16 05:49 91-57-607/25/16 11:000.0058 1 Naphthalene ND mg/kg 07/27/16 05:49 91-20-307/25/16 11:000.0058 1 Phenanthrene ND mg/kg 07/27/16 05:49 85-01-807/25/16 11:000.0058 1 Pyrene ND mg/kg 07/27/16 05:49 129-00-007/25/16 11:000.0058 1 Surrogates 2-Fluorobiphenyl (S)64 %.07/27/16 05:49 321-60-807/25/16 11:0025-121 1 p-Terphenyl-d14 (S)66 %.07/27/16 05:49 1718-51-007/25/16 11:0027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 08/02/16 19:39 67-64-10.10 1 Acrolein ND mg/kg 08/02/16 19:39 107-02-80.10 1 Acrylonitrile ND mg/kg 08/02/16 19:39 107-13-10.10 1 Benzene ND mg/kg 08/02/16 19:39 71-43-20.0052 1 Bromobenzene ND mg/kg 08/02/16 19:39 108-86-10.0052 1 Bromochloromethane ND mg/kg 08/02/16 19:39 74-97-50.0052 1 Bromodichloromethane ND mg/kg 08/02/16 19:39 75-27-40.0052 1 Bromoform ND mg/kg 08/02/16 19:39 75-25-20.0052 1 Bromomethane ND mg/kg 08/02/16 19:39 74-83-90.0052 1 2-Butanone (MEK)ND mg/kg 08/02/16 19:39 78-93-30.026 1 n-Butylbenzene ND mg/kg 08/02/16 19:39 104-51-80.0052 1 sec-Butylbenzene ND mg/kg 08/02/16 19:39 135-98-80.0052 1 tert-Butylbenzene ND mg/kg 08/02/16 19:39 98-06-60.0052 1 Carbon disulfide ND mg/kg 08/02/16 19:39 75-15-00.010 1 Carbon tetrachloride ND mg/kg 08/02/16 19:39 56-23-50.0052 1 Chlorobenzene ND mg/kg 08/02/16 19:39 108-90-70.0052 1 Chloroethane ND mg/kg 08/02/16 19:39 75-00-30.0052 1 Chloroform ND mg/kg 08/02/16 19:39 67-66-30.0052 1 Chloromethane ND mg/kg 08/02/16 19:39 74-87-30.0052 1 2-Chlorotoluene ND mg/kg 08/02/16 19:39 95-49-80.0052 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 8 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-3 (008-009)Lab ID:50150303002 Collected:07/21/16 13:23 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 08/02/16 19:39 106-43-40.0052 1 Dibromochloromethane ND mg/kg 08/02/16 19:39 124-48-10.0052 1 1,2-Dibromoethane (EDB)ND mg/kg 08/02/16 19:39 106-93-40.0052 1 Dibromomethane ND mg/kg 08/02/16 19:39 74-95-30.0052 1 1,2-Dichlorobenzene ND mg/kg 08/02/16 19:39 95-50-10.0052 1 1,3-Dichlorobenzene ND mg/kg 08/02/16 19:39 541-73-10.0052 1 1,4-Dichlorobenzene ND mg/kg 08/02/16 19:39 106-46-70.0052 1 trans-1,4-Dichloro-2-butene ND mg/kg 08/02/16 19:39 110-57-60.10 1 Dichlorodifluoromethane ND mg/kg 08/02/16 19:39 75-71-80.0052 1 1,1-Dichloroethane ND mg/kg 08/02/16 19:39 75-34-30.0052 1 1,2-Dichloroethane ND mg/kg 08/02/16 19:39 107-06-20.0052 1 1,1-Dichloroethene ND mg/kg 08/02/16 19:39 75-35-40.0052 1 cis-1,2-Dichloroethene ND mg/kg 08/02/16 19:39 156-59-20.0052 1 trans-1,2-Dichloroethene ND mg/kg 08/02/16 19:39 156-60-50.0052 1 1,2-Dichloropropane ND mg/kg 08/02/16 19:39 78-87-50.0052 1 1,3-Dichloropropane ND mg/kg 08/02/16 19:39 142-28-90.0052 1 2,2-Dichloropropane ND mg/kg 08/02/16 19:39 594-20-70.0052 1 1,1-Dichloropropene ND mg/kg 08/02/16 19:39 563-58-60.0052 1 cis-1,3-Dichloropropene ND mg/kg 08/02/16 19:39 10061-01-50.0052 1 trans-1,3-Dichloropropene ND mg/kg 08/02/16 19:39 10061-02-60.0052 1 Ethylbenzene ND mg/kg 08/02/16 19:39 100-41-40.0052 1 Ethyl methacrylate ND mg/kg 08/02/16 19:39 97-63-20.10 1 Hexachloro-1,3-butadiene ND mg/kg 08/02/16 19:39 87-68-30.0052 1 n-Hexane ND mg/kg 08/02/16 19:39 110-54-30.0052 1 2-Hexanone ND mg/kg 08/02/16 19:39 591-78-60.10 1 Iodomethane ND mg/kg 08/02/16 19:39 74-88-40.10 1 Isopropylbenzene (Cumene)ND mg/kg 08/02/16 19:39 98-82-80.0052 1 p-Isopropyltoluene ND mg/kg 08/02/16 19:39 99-87-60.0052 1 Methylene Chloride ND mg/kg 08/02/16 19:39 75-09-20.021 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/02/16 19:39 108-10-10.026 1 Methyl-tert-butyl ether ND mg/kg 08/02/16 19:39 1634-04-40.0052 1 Naphthalene ND mg/kg 08/02/16 19:39 91-20-30.0052 1 n-Propylbenzene ND mg/kg 08/02/16 19:39 103-65-10.0052 1 Styrene ND mg/kg 08/02/16 19:39 100-42-50.0052 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/02/16 19:39 630-20-60.0052 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/02/16 19:39 79-34-50.0052 1 Tetrachloroethene ND mg/kg 08/02/16 19:39 127-18-40.0052 1 Toluene ND mg/kg 08/02/16 19:39 108-88-30.0052 1 1,2,3-Trichlorobenzene ND mg/kg 08/02/16 19:39 87-61-60.0052 1 1,2,4-Trichlorobenzene ND mg/kg 08/02/16 19:39 120-82-10.0052 1 1,1,1-Trichloroethane ND mg/kg 08/02/16 19:39 71-55-60.0052 1 1,1,2-Trichloroethane ND mg/kg 08/02/16 19:39 79-00-50.0052 1 Trichloroethene ND mg/kg 08/02/16 19:39 79-01-60.0052 1 Trichlorofluoromethane ND mg/kg 08/02/16 19:39 75-69-40.0052 1 1,2,3-Trichloropropane ND mg/kg 08/02/16 19:39 96-18-40.0052 1 1,2,4-Trimethylbenzene ND mg/kg 08/02/16 19:39 95-63-60.0052 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 9 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-3 (008-009)Lab ID:50150303002 Collected:07/21/16 13:23 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 08/02/16 19:39 108-67-80.0052 1 Vinyl acetate ND mg/kg 08/02/16 19:39 108-05-40.10 1 Vinyl chloride ND mg/kg 08/02/16 19:39 75-01-40.0052 1 Xylene (Total)ND mg/kg 08/02/16 19:39 1330-20-70.010 1 Surrogates Dibromofluoromethane (S)96 %.08/02/16 19:39 1868-53-770-128 1 Toluene-d8 (S)96 %.08/02/16 19:39 2037-26-572-139 1 4-Bromofluorobenzene (S)95 %.08/02/16 19:39 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 14.2 %08/01/16 15:460.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 10 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-4 (007-008)Lab ID:50150303003 Collected:07/21/16 12:25 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 2.1 mg/kg 08/02/16 02:27 7439-92-107/29/16 07:301.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/27/16 06:07 83-32-907/25/16 11:000.0056 1 Acenaphthylene ND mg/kg 07/27/16 06:07 208-96-807/25/16 11:000.0056 1 Anthracene ND mg/kg 07/27/16 06:07 120-12-707/25/16 11:000.0056 1 Benzo(a)anthracene ND mg/kg 07/27/16 06:07 56-55-307/25/16 11:000.0056 1 Benzo(a)pyrene ND mg/kg 07/27/16 06:07 50-32-807/25/16 11:000.0056 1 Benzo(b)fluoranthene ND mg/kg 07/27/16 06:07 205-99-207/25/16 11:000.0056 1 Benzo(g,h,i)perylene ND mg/kg 07/27/16 06:07 191-24-207/25/16 11:000.0056 1 Benzo(k)fluoranthene ND mg/kg 07/27/16 06:07 207-08-907/25/16 11:000.0056 1 Chrysene ND mg/kg 07/27/16 06:07 218-01-907/25/16 11:000.0056 1 Dibenz(a,h)anthracene ND mg/kg 07/27/16 06:07 53-70-307/25/16 11:000.0056 1 Fluoranthene ND mg/kg 07/27/16 06:07 206-44-007/25/16 11:000.0056 1 Fluorene ND mg/kg 07/27/16 06:07 86-73-707/25/16 11:000.0056 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/27/16 06:07 193-39-507/25/16 11:000.0056 1 1-Methylnaphthalene ND mg/kg 07/27/16 06:07 90-12-0 N207/25/16 11:000.0056 1 2-Methylnaphthalene ND mg/kg 07/27/16 06:07 91-57-607/25/16 11:000.0056 1 Naphthalene ND mg/kg 07/27/16 06:07 91-20-307/25/16 11:000.0056 1 Phenanthrene ND mg/kg 07/27/16 06:07 85-01-807/25/16 11:000.0056 1 Pyrene ND mg/kg 07/27/16 06:07 129-00-007/25/16 11:000.0056 1 Surrogates 2-Fluorobiphenyl (S)66 %.07/27/16 06:07 321-60-807/25/16 11:0025-121 1 p-Terphenyl-d14 (S)66 %.07/27/16 06:07 1718-51-007/25/16 11:0027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 08/02/16 20:11 67-64-10.10 1 Acrolein ND mg/kg 08/02/16 20:11 107-02-80.10 1 Acrylonitrile ND mg/kg 08/02/16 20:11 107-13-10.10 1 Benzene ND mg/kg 08/02/16 20:11 71-43-20.0051 1 Bromobenzene ND mg/kg 08/02/16 20:11 108-86-10.0051 1 Bromochloromethane ND mg/kg 08/02/16 20:11 74-97-50.0051 1 Bromodichloromethane ND mg/kg 08/02/16 20:11 75-27-40.0051 1 Bromoform ND mg/kg 08/02/16 20:11 75-25-20.0051 1 Bromomethane ND mg/kg 08/02/16 20:11 74-83-90.0051 1 2-Butanone (MEK)ND mg/kg 08/02/16 20:11 78-93-30.026 1 n-Butylbenzene ND mg/kg 08/02/16 20:11 104-51-80.0051 1 sec-Butylbenzene ND mg/kg 08/02/16 20:11 135-98-80.0051 1 tert-Butylbenzene ND mg/kg 08/02/16 20:11 98-06-60.0051 1 Carbon disulfide ND mg/kg 08/02/16 20:11 75-15-00.010 1 Carbon tetrachloride ND mg/kg 08/02/16 20:11 56-23-50.0051 1 Chlorobenzene ND mg/kg 08/02/16 20:11 108-90-70.0051 1 Chloroethane ND mg/kg 08/02/16 20:11 75-00-30.0051 1 Chloroform ND mg/kg 08/02/16 20:11 67-66-30.0051 1 Chloromethane ND mg/kg 08/02/16 20:11 74-87-30.0051 1 2-Chlorotoluene ND mg/kg 08/02/16 20:11 95-49-80.0051 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 11 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-4 (007-008)Lab ID:50150303003 Collected:07/21/16 12:25 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 08/02/16 20:11 106-43-40.0051 1 Dibromochloromethane ND mg/kg 08/02/16 20:11 124-48-10.0051 1 1,2-Dibromoethane (EDB)ND mg/kg 08/02/16 20:11 106-93-40.0051 1 Dibromomethane ND mg/kg 08/02/16 20:11 74-95-30.0051 1 1,2-Dichlorobenzene ND mg/kg 08/02/16 20:11 95-50-10.0051 1 1,3-Dichlorobenzene ND mg/kg 08/02/16 20:11 541-73-10.0051 1 1,4-Dichlorobenzene ND mg/kg 08/02/16 20:11 106-46-70.0051 1 trans-1,4-Dichloro-2-butene ND mg/kg 08/02/16 20:11 110-57-60.10 1 Dichlorodifluoromethane ND mg/kg 08/02/16 20:11 75-71-80.0051 1 1,1-Dichloroethane ND mg/kg 08/02/16 20:11 75-34-30.0051 1 1,2-Dichloroethane ND mg/kg 08/02/16 20:11 107-06-20.0051 1 1,1-Dichloroethene ND mg/kg 08/02/16 20:11 75-35-40.0051 1 cis-1,2-Dichloroethene ND mg/kg 08/02/16 20:11 156-59-20.0051 1 trans-1,2-Dichloroethene ND mg/kg 08/02/16 20:11 156-60-50.0051 1 1,2-Dichloropropane ND mg/kg 08/02/16 20:11 78-87-50.0051 1 1,3-Dichloropropane ND mg/kg 08/02/16 20:11 142-28-90.0051 1 2,2-Dichloropropane ND mg/kg 08/02/16 20:11 594-20-70.0051 1 1,1-Dichloropropene ND mg/kg 08/02/16 20:11 563-58-60.0051 1 cis-1,3-Dichloropropene ND mg/kg 08/02/16 20:11 10061-01-50.0051 1 trans-1,3-Dichloropropene ND mg/kg 08/02/16 20:11 10061-02-60.0051 1 Ethylbenzene ND mg/kg 08/02/16 20:11 100-41-40.0051 1 Ethyl methacrylate ND mg/kg 08/02/16 20:11 97-63-20.10 1 Hexachloro-1,3-butadiene ND mg/kg 08/02/16 20:11 87-68-30.0051 1 n-Hexane ND mg/kg 08/02/16 20:11 110-54-30.0051 1 2-Hexanone ND mg/kg 08/02/16 20:11 591-78-60.10 1 Iodomethane ND mg/kg 08/02/16 20:11 74-88-40.10 1 Isopropylbenzene (Cumene)ND mg/kg 08/02/16 20:11 98-82-80.0051 1 p-Isopropyltoluene ND mg/kg 08/02/16 20:11 99-87-60.0051 1 Methylene Chloride ND mg/kg 08/02/16 20:11 75-09-20.020 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/02/16 20:11 108-10-10.026 1 Methyl-tert-butyl ether ND mg/kg 08/02/16 20:11 1634-04-40.0051 1 Naphthalene ND mg/kg 08/02/16 20:11 91-20-30.0051 1 n-Propylbenzene ND mg/kg 08/02/16 20:11 103-65-10.0051 1 Styrene ND mg/kg 08/02/16 20:11 100-42-50.0051 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/02/16 20:11 630-20-60.0051 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/02/16 20:11 79-34-50.0051 1 Tetrachloroethene ND mg/kg 08/02/16 20:11 127-18-40.0051 1 Toluene ND mg/kg 08/02/16 20:11 108-88-30.0051 1 1,2,3-Trichlorobenzene ND mg/kg 08/02/16 20:11 87-61-60.0051 1 1,2,4-Trichlorobenzene ND mg/kg 08/02/16 20:11 120-82-10.0051 1 1,1,1-Trichloroethane ND mg/kg 08/02/16 20:11 71-55-60.0051 1 1,1,2-Trichloroethane ND mg/kg 08/02/16 20:11 79-00-50.0051 1 Trichloroethene ND mg/kg 08/02/16 20:11 79-01-60.0051 1 Trichlorofluoromethane ND mg/kg 08/02/16 20:11 75-69-40.0051 1 1,2,3-Trichloropropane ND mg/kg 08/02/16 20:11 96-18-40.0051 1 1,2,4-Trimethylbenzene ND mg/kg 08/02/16 20:11 95-63-60.0051 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 12 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-4 (007-008)Lab ID:50150303003 Collected:07/21/16 12:25 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 08/02/16 20:11 108-67-80.0051 1 Vinyl acetate ND mg/kg 08/02/16 20:11 108-05-40.10 1 Vinyl chloride ND mg/kg 08/02/16 20:11 75-01-40.0051 1 Xylene (Total)ND mg/kg 08/02/16 20:11 1330-20-70.010 1 Surrogates Dibromofluoromethane (S)95 %.08/02/16 20:11 1868-53-770-128 1 Toluene-d8 (S)97 %.08/02/16 20:11 2037-26-572-139 1 4-Bromofluorobenzene (S)93 %.08/02/16 20:11 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 10.3 %08/01/16 15:460.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 13 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-5 (008-009)Lab ID:50150303004 Collected:07/21/16 11:27 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8082 Preparation Method: EPA 35468082 GCS PCB Solids PCB-1016 (Aroclor 1016)ND ug/kg 07/26/16 14:42 12674-11-207/25/16 11:451151 PCB-1221 (Aroclor 1221)ND ug/kg 07/26/16 14:42 11104-28-207/25/16 11:451151 PCB-1232 (Aroclor 1232)ND ug/kg 07/26/16 14:42 11141-16-507/25/16 11:451151 PCB-1242 (Aroclor 1242)ND ug/kg 07/26/16 14:42 53469-21-907/25/16 11:451151 PCB-1248 (Aroclor 1248)ND ug/kg 07/26/16 14:42 12672-29-607/25/16 11:451151 PCB-1254 (Aroclor 1254)ND ug/kg 07/26/16 14:42 11097-69-107/25/16 11:451151 PCB-1260 (Aroclor 1260)ND ug/kg 07/26/16 14:42 11096-82-507/25/16 11:451151 Surrogates Tetrachloro-m-xylene (S)62 %.07/26/16 14:42 877-09-807/25/16 11:4524-99 1 Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 3.8 mg/kg 08/02/16 02:29 7439-92-107/29/16 07:301.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/27/16 06:24 83-32-907/25/16 11:000.0057 1 Acenaphthylene ND mg/kg 07/27/16 06:24 208-96-807/25/16 11:000.0057 1 Anthracene ND mg/kg 07/27/16 06:24 120-12-707/25/16 11:000.0057 1 Benzo(a)anthracene ND mg/kg 07/27/16 06:24 56-55-307/25/16 11:000.0057 1 Benzo(a)pyrene ND mg/kg 07/27/16 06:24 50-32-807/25/16 11:000.0057 1 Benzo(b)fluoranthene ND mg/kg 07/27/16 06:24 205-99-207/25/16 11:000.0057 1 Benzo(g,h,i)perylene ND mg/kg 07/27/16 06:24 191-24-207/25/16 11:000.0057 1 Benzo(k)fluoranthene ND mg/kg 07/27/16 06:24 207-08-907/25/16 11:000.0057 1 Chrysene ND mg/kg 07/27/16 06:24 218-01-907/25/16 11:000.0057 1 Dibenz(a,h)anthracene ND mg/kg 07/27/16 06:24 53-70-307/25/16 11:000.0057 1 Fluoranthene ND mg/kg 07/27/16 06:24 206-44-007/25/16 11:000.0057 1 Fluorene ND mg/kg 07/27/16 06:24 86-73-707/25/16 11:000.0057 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/27/16 06:24 193-39-507/25/16 11:000.0057 1 1-Methylnaphthalene ND mg/kg 07/27/16 06:24 90-12-0 N207/25/16 11:000.0057 1 2-Methylnaphthalene ND mg/kg 07/27/16 06:24 91-57-607/25/16 11:000.0057 1 Naphthalene ND mg/kg 07/27/16 06:24 91-20-307/25/16 11:000.0057 1 Phenanthrene ND mg/kg 07/27/16 06:24 85-01-807/25/16 11:000.0057 1 Pyrene ND mg/kg 07/27/16 06:24 129-00-007/25/16 11:000.0057 1 Surrogates 2-Fluorobiphenyl (S)53 %.07/27/16 06:24 321-60-807/25/16 11:0025-121 1 p-Terphenyl-d14 (S)52 %.07/27/16 06:24 1718-51-007/25/16 11:0027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 08/02/16 20:43 67-64-10.096 1 Acrolein ND mg/kg 08/02/16 20:43 107-02-80.096 1 Acrylonitrile ND mg/kg 08/02/16 20:43 107-13-10.096 1 Benzene ND mg/kg 08/02/16 20:43 71-43-20.0048 1 Bromobenzene ND mg/kg 08/02/16 20:43 108-86-10.0048 1 Bromochloromethane ND mg/kg 08/02/16 20:43 74-97-50.0048 1 Bromodichloromethane ND mg/kg 08/02/16 20:43 75-27-40.0048 1 Bromoform ND mg/kg 08/02/16 20:43 75-25-20.0048 1 Bromomethane ND mg/kg 08/02/16 20:43 74-83-90.0048 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 14 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-5 (008-009)Lab ID:50150303004 Collected:07/21/16 11:27 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 2-Butanone (MEK)ND mg/kg 08/02/16 20:43 78-93-30.024 1 n-Butylbenzene ND mg/kg 08/02/16 20:43 104-51-80.0048 1 sec-Butylbenzene ND mg/kg 08/02/16 20:43 135-98-80.0048 1 tert-Butylbenzene ND mg/kg 08/02/16 20:43 98-06-60.0048 1 Carbon disulfide ND mg/kg 08/02/16 20:43 75-15-00.0096 1 Carbon tetrachloride ND mg/kg 08/02/16 20:43 56-23-50.0048 1 Chlorobenzene ND mg/kg 08/02/16 20:43 108-90-70.0048 1 Chloroethane ND mg/kg 08/02/16 20:43 75-00-30.0048 1 Chloroform ND mg/kg 08/02/16 20:43 67-66-30.0048 1 Chloromethane ND mg/kg 08/02/16 20:43 74-87-30.0048 1 2-Chlorotoluene ND mg/kg 08/02/16 20:43 95-49-80.0048 1 4-Chlorotoluene ND mg/kg 08/02/16 20:43 106-43-40.0048 1 Dibromochloromethane ND mg/kg 08/02/16 20:43 124-48-10.0048 1 1,2-Dibromoethane (EDB)ND mg/kg 08/02/16 20:43 106-93-4 L30.0048 1 Dibromomethane ND mg/kg 08/02/16 20:43 74-95-30.0048 1 1,2-Dichlorobenzene ND mg/kg 08/02/16 20:43 95-50-10.0048 1 1,3-Dichlorobenzene ND mg/kg 08/02/16 20:43 541-73-10.0048 1 1,4-Dichlorobenzene ND mg/kg 08/02/16 20:43 106-46-70.0048 1 trans-1,4-Dichloro-2-butene ND mg/kg 08/02/16 20:43 110-57-60.096 1 Dichlorodifluoromethane ND mg/kg 08/02/16 20:43 75-71-80.0048 1 1,1-Dichloroethane ND mg/kg 08/02/16 20:43 75-34-30.0048 1 1,2-Dichloroethane ND mg/kg 08/02/16 20:43 107-06-20.0048 1 1,1-Dichloroethene ND mg/kg 08/02/16 20:43 75-35-40.0048 1 cis-1,2-Dichloroethene ND mg/kg 08/02/16 20:43 156-59-20.0048 1 trans-1,2-Dichloroethene ND mg/kg 08/02/16 20:43 156-60-50.0048 1 1,2-Dichloropropane ND mg/kg 08/02/16 20:43 78-87-50.0048 1 1,3-Dichloropropane ND mg/kg 08/02/16 20:43 142-28-90.0048 1 2,2-Dichloropropane ND mg/kg 08/02/16 20:43 594-20-70.0048 1 1,1-Dichloropropene ND mg/kg 08/02/16 20:43 563-58-60.0048 1 cis-1,3-Dichloropropene ND mg/kg 08/02/16 20:43 10061-01-50.0048 1 trans-1,3-Dichloropropene ND mg/kg 08/02/16 20:43 10061-02-60.0048 1 Ethylbenzene ND mg/kg 08/02/16 20:43 100-41-40.0048 1 Ethyl methacrylate ND mg/kg 08/02/16 20:43 97-63-20.096 1 Hexachloro-1,3-butadiene ND mg/kg 08/02/16 20:43 87-68-30.0048 1 n-Hexane ND mg/kg 08/02/16 20:43 110-54-30.0048 1 2-Hexanone ND mg/kg 08/02/16 20:43 591-78-60.096 1 Iodomethane ND mg/kg 08/02/16 20:43 74-88-40.096 1 Isopropylbenzene (Cumene)ND mg/kg 08/02/16 20:43 98-82-80.0048 1 p-Isopropyltoluene ND mg/kg 08/02/16 20:43 99-87-60.0048 1 Methylene Chloride ND mg/kg 08/02/16 20:43 75-09-20.019 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/02/16 20:43 108-10-10.024 1 Methyl-tert-butyl ether ND mg/kg 08/02/16 20:43 1634-04-40.0048 1 Naphthalene ND mg/kg 08/02/16 20:43 91-20-30.0048 1 n-Propylbenzene ND mg/kg 08/02/16 20:43 103-65-10.0048 1 Styrene ND mg/kg 08/02/16 20:43 100-42-50.0048 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/02/16 20:43 630-20-60.0048 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 15 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-5 (008-009)Lab ID:50150303004 Collected:07/21/16 11:27 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,1,2,2-Tetrachloroethane ND mg/kg 08/02/16 20:43 79-34-50.0048 1 Tetrachloroethene ND mg/kg 08/02/16 20:43 127-18-40.0048 1 Toluene ND mg/kg 08/02/16 20:43 108-88-30.0048 1 1,2,3-Trichlorobenzene ND mg/kg 08/02/16 20:43 87-61-60.0048 1 1,2,4-Trichlorobenzene ND mg/kg 08/02/16 20:43 120-82-10.0048 1 1,1,1-Trichloroethane ND mg/kg 08/02/16 20:43 71-55-60.0048 1 1,1,2-Trichloroethane ND mg/kg 08/02/16 20:43 79-00-50.0048 1 Trichloroethene ND mg/kg 08/02/16 20:43 79-01-60.0048 1 Trichlorofluoromethane ND mg/kg 08/02/16 20:43 75-69-40.0048 1 1,2,3-Trichloropropane ND mg/kg 08/02/16 20:43 96-18-40.0048 1 1,2,4-Trimethylbenzene ND mg/kg 08/02/16 20:43 95-63-60.0048 1 1,3,5-Trimethylbenzene ND mg/kg 08/02/16 20:43 108-67-80.0048 1 Vinyl acetate ND mg/kg 08/02/16 20:43 108-05-40.096 1 Vinyl chloride ND mg/kg 08/02/16 20:43 75-01-40.0048 1 Xylene (Total)ND mg/kg 08/02/16 20:43 1330-20-70.0096 1 Surrogates Dibromofluoromethane (S)104 %.08/02/16 20:43 1868-53-770-128 1 Toluene-d8 (S)102 %.08/02/16 20:43 2037-26-572-139 1 4-Bromofluorobenzene (S)83 %.08/02/16 20:43 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 13.5 %08/01/16 15:460.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 16 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-6 (008-009)Lab ID:50150303005 Collected:07/21/16 11:39 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8082 Preparation Method: EPA 35468082 GCS PCB Solids PCB-1016 (Aroclor 1016)ND ug/kg 07/26/16 15:06 12674-11-207/25/16 11:451151 PCB-1221 (Aroclor 1221)ND ug/kg 07/26/16 15:06 11104-28-207/25/16 11:451151 PCB-1232 (Aroclor 1232)ND ug/kg 07/26/16 15:06 11141-16-507/25/16 11:451151 PCB-1242 (Aroclor 1242)ND ug/kg 07/26/16 15:06 53469-21-907/25/16 11:451151 PCB-1248 (Aroclor 1248)ND ug/kg 07/26/16 15:06 12672-29-607/25/16 11:451151 PCB-1254 (Aroclor 1254)ND ug/kg 07/26/16 15:06 11097-69-107/25/16 11:451151 PCB-1260 (Aroclor 1260)ND ug/kg 07/26/16 15:06 11096-82-507/25/16 11:451151 Surrogates Tetrachloro-m-xylene (S)75 %.07/26/16 15:06 877-09-807/25/16 11:4524-99 1 Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 1.9 mg/kg 08/02/16 02:31 7439-92-107/29/16 07:301.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/27/16 06:42 83-32-907/25/16 11:000.0057 1 Acenaphthylene ND mg/kg 07/27/16 06:42 208-96-807/25/16 11:000.0057 1 Anthracene ND mg/kg 07/27/16 06:42 120-12-707/25/16 11:000.0057 1 Benzo(a)anthracene ND mg/kg 07/27/16 06:42 56-55-307/25/16 11:000.0057 1 Benzo(a)pyrene ND mg/kg 07/27/16 06:42 50-32-807/25/16 11:000.0057 1 Benzo(b)fluoranthene ND mg/kg 07/27/16 06:42 205-99-207/25/16 11:000.0057 1 Benzo(g,h,i)perylene ND mg/kg 07/27/16 06:42 191-24-207/25/16 11:000.0057 1 Benzo(k)fluoranthene ND mg/kg 07/27/16 06:42 207-08-907/25/16 11:000.0057 1 Chrysene ND mg/kg 07/27/16 06:42 218-01-907/25/16 11:000.0057 1 Dibenz(a,h)anthracene ND mg/kg 07/27/16 06:42 53-70-307/25/16 11:000.0057 1 Fluoranthene ND mg/kg 07/27/16 06:42 206-44-007/25/16 11:000.0057 1 Fluorene ND mg/kg 07/27/16 06:42 86-73-707/25/16 11:000.0057 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/27/16 06:42 193-39-507/25/16 11:000.0057 1 1-Methylnaphthalene ND mg/kg 07/27/16 06:42 90-12-0 N207/25/16 11:000.0057 1 2-Methylnaphthalene ND mg/kg 07/27/16 06:42 91-57-607/25/16 11:000.0057 1 Naphthalene ND mg/kg 07/27/16 06:42 91-20-307/25/16 11:000.0057 1 Phenanthrene ND mg/kg 07/27/16 06:42 85-01-807/25/16 11:000.0057 1 Pyrene ND mg/kg 07/27/16 06:42 129-00-007/25/16 11:000.0057 1 Surrogates 2-Fluorobiphenyl (S)73 %.07/27/16 06:42 321-60-807/25/16 11:0025-121 1 p-Terphenyl-d14 (S)81 %.07/27/16 06:42 1718-51-007/25/16 11:0027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 08/03/16 12:14 67-64-10.11 1 Acrolein ND mg/kg 08/03/16 12:14 107-02-80.11 1 Acrylonitrile ND mg/kg 08/03/16 12:14 107-13-10.11 1 Benzene ND mg/kg 08/03/16 12:14 71-43-20.0053 1 Bromobenzene ND mg/kg 08/03/16 12:14 108-86-10.0053 1 Bromochloromethane ND mg/kg 08/03/16 12:14 74-97-50.0053 1 Bromodichloromethane ND mg/kg 08/03/16 12:14 75-27-40.0053 1 Bromoform ND mg/kg 08/03/16 12:14 75-25-20.0053 1 Bromomethane ND mg/kg 08/03/16 12:14 74-83-90.0053 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 17 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-6 (008-009)Lab ID:50150303005 Collected:07/21/16 11:39 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 2-Butanone (MEK)ND mg/kg 08/03/16 12:14 78-93-30.026 1 n-Butylbenzene ND mg/kg 08/03/16 12:14 104-51-80.0053 1 sec-Butylbenzene ND mg/kg 08/03/16 12:14 135-98-80.0053 1 tert-Butylbenzene ND mg/kg 08/03/16 12:14 98-06-60.0053 1 Carbon disulfide ND mg/kg 08/03/16 12:14 75-15-00.011 1 Carbon tetrachloride ND mg/kg 08/03/16 12:14 56-23-50.0053 1 Chlorobenzene ND mg/kg 08/03/16 12:14 108-90-70.0053 1 Chloroethane ND mg/kg 08/03/16 12:14 75-00-30.0053 1 Chloroform ND mg/kg 08/03/16 12:14 67-66-30.0053 1 Chloromethane ND mg/kg 08/03/16 12:14 74-87-30.0053 1 2-Chlorotoluene ND mg/kg 08/03/16 12:14 95-49-80.0053 1 4-Chlorotoluene ND mg/kg 08/03/16 12:14 106-43-40.0053 1 Dibromochloromethane ND mg/kg 08/03/16 12:14 124-48-10.0053 1 1,2-Dibromoethane (EDB)ND mg/kg 08/03/16 12:14 106-93-40.0053 1 Dibromomethane ND mg/kg 08/03/16 12:14 74-95-30.0053 1 1,2-Dichlorobenzene ND mg/kg 08/03/16 12:14 95-50-10.0053 1 1,3-Dichlorobenzene ND mg/kg 08/03/16 12:14 541-73-10.0053 1 1,4-Dichlorobenzene ND mg/kg 08/03/16 12:14 106-46-70.0053 1 trans-1,4-Dichloro-2-butene ND mg/kg 08/03/16 12:14 110-57-60.11 1 Dichlorodifluoromethane ND mg/kg 08/03/16 12:14 75-71-80.0053 1 1,1-Dichloroethane ND mg/kg 08/03/16 12:14 75-34-30.0053 1 1,2-Dichloroethane ND mg/kg 08/03/16 12:14 107-06-20.0053 1 1,1-Dichloroethene ND mg/kg 08/03/16 12:14 75-35-40.0053 1 cis-1,2-Dichloroethene ND mg/kg 08/03/16 12:14 156-59-20.0053 1 trans-1,2-Dichloroethene ND mg/kg 08/03/16 12:14 156-60-50.0053 1 1,2-Dichloropropane ND mg/kg 08/03/16 12:14 78-87-50.0053 1 1,3-Dichloropropane ND mg/kg 08/03/16 12:14 142-28-90.0053 1 2,2-Dichloropropane ND mg/kg 08/03/16 12:14 594-20-70.0053 1 1,1-Dichloropropene ND mg/kg 08/03/16 12:14 563-58-60.0053 1 cis-1,3-Dichloropropene ND mg/kg 08/03/16 12:14 10061-01-50.0053 1 trans-1,3-Dichloropropene ND mg/kg 08/03/16 12:14 10061-02-60.0053 1 Ethylbenzene ND mg/kg 08/03/16 12:14 100-41-40.0053 1 Ethyl methacrylate ND mg/kg 08/03/16 12:14 97-63-20.11 1 Hexachloro-1,3-butadiene ND mg/kg 08/03/16 12:14 87-68-30.0053 1 n-Hexane ND mg/kg 08/03/16 12:14 110-54-30.0053 1 2-Hexanone ND mg/kg 08/03/16 12:14 591-78-60.11 1 Iodomethane ND mg/kg 08/03/16 12:14 74-88-40.11 1 Isopropylbenzene (Cumene)ND mg/kg 08/03/16 12:14 98-82-80.0053 1 p-Isopropyltoluene ND mg/kg 08/03/16 12:14 99-87-60.0053 1 Methylene Chloride ND mg/kg 08/03/16 12:14 75-09-20.021 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/03/16 12:14 108-10-10.026 1 Methyl-tert-butyl ether ND mg/kg 08/03/16 12:14 1634-04-40.0053 1 Naphthalene ND mg/kg 08/03/16 12:14 91-20-30.0053 1 n-Propylbenzene ND mg/kg 08/03/16 12:14 103-65-10.0053 1 Styrene ND mg/kg 08/03/16 12:14 100-42-50.0053 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/03/16 12:14 630-20-60.0053 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 18 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-6 (008-009)Lab ID:50150303005 Collected:07/21/16 11:39 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,1,2,2-Tetrachloroethane ND mg/kg 08/03/16 12:14 79-34-50.0053 1 Tetrachloroethene ND mg/kg 08/03/16 12:14 127-18-40.0053 1 Toluene ND mg/kg 08/03/16 12:14 108-88-30.0053 1 1,2,3-Trichlorobenzene ND mg/kg 08/03/16 12:14 87-61-60.0053 1 1,2,4-Trichlorobenzene ND mg/kg 08/03/16 12:14 120-82-10.0053 1 1,1,1-Trichloroethane ND mg/kg 08/03/16 12:14 71-55-60.0053 1 1,1,2-Trichloroethane ND mg/kg 08/03/16 12:14 79-00-50.0053 1 Trichloroethene ND mg/kg 08/03/16 12:14 79-01-60.0053 1 Trichlorofluoromethane ND mg/kg 08/03/16 12:14 75-69-40.0053 1 1,2,3-Trichloropropane ND mg/kg 08/03/16 12:14 96-18-40.0053 1 1,2,4-Trimethylbenzene ND mg/kg 08/03/16 12:14 95-63-60.0053 1 1,3,5-Trimethylbenzene ND mg/kg 08/03/16 12:14 108-67-80.0053 1 Vinyl acetate ND mg/kg 08/03/16 12:14 108-05-40.11 1 Vinyl chloride ND mg/kg 08/03/16 12:14 75-01-40.0053 1 Xylene (Total)ND mg/kg 08/03/16 12:14 1330-20-70.011 1 Surrogates Dibromofluoromethane (S)97 %.08/03/16 12:14 1868-53-770-128 1 Toluene-d8 (S)97 %.08/03/16 12:14 2037-26-572-139 1 4-Bromofluorobenzene (S)93 %.08/03/16 12:14 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 13.1 %08/01/16 15:460.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 19 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-7 (008-009)Lab ID:50150303006 Collected:07/21/16 12:00 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 8082 Preparation Method: EPA 35468082 GCS PCB Solids PCB-1016 (Aroclor 1016)ND ug/kg 07/26/16 15:31 12674-11-207/25/16 11:451091 PCB-1221 (Aroclor 1221)ND ug/kg 07/26/16 15:31 11104-28-207/25/16 11:451091 PCB-1232 (Aroclor 1232)ND ug/kg 07/26/16 15:31 11141-16-507/25/16 11:451091 PCB-1242 (Aroclor 1242)ND ug/kg 07/26/16 15:31 53469-21-907/25/16 11:451091 PCB-1248 (Aroclor 1248)ND ug/kg 07/26/16 15:31 12672-29-607/25/16 11:451091 PCB-1254 (Aroclor 1254)ND ug/kg 07/26/16 15:31 11097-69-107/25/16 11:451091 PCB-1260 (Aroclor 1260)ND ug/kg 07/26/16 15:31 11096-82-507/25/16 11:451091 Surrogates Tetrachloro-m-xylene (S)53 %.07/26/16 15:31 877-09-807/25/16 11:4524-99 1 Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 2.9 mg/kg 08/02/16 02:33 7439-92-107/29/16 07:301.0 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/27/16 07:34 83-32-907/25/16 11:000.0054 1 Acenaphthylene ND mg/kg 07/27/16 07:34 208-96-807/25/16 11:000.0054 1 Anthracene ND mg/kg 07/27/16 07:34 120-12-707/25/16 11:000.0054 1 Benzo(a)anthracene ND mg/kg 07/27/16 07:34 56-55-307/25/16 11:000.0054 1 Benzo(a)pyrene ND mg/kg 07/27/16 07:34 50-32-807/25/16 11:000.0054 1 Benzo(b)fluoranthene ND mg/kg 07/27/16 07:34 205-99-207/25/16 11:000.0054 1 Benzo(g,h,i)perylene ND mg/kg 07/27/16 07:34 191-24-207/25/16 11:000.0054 1 Benzo(k)fluoranthene ND mg/kg 07/27/16 07:34 207-08-907/25/16 11:000.0054 1 Chrysene ND mg/kg 07/27/16 07:34 218-01-907/25/16 11:000.0054 1 Dibenz(a,h)anthracene ND mg/kg 07/27/16 07:34 53-70-307/25/16 11:000.0054 1 Fluoranthene ND mg/kg 07/27/16 07:34 206-44-007/25/16 11:000.0054 1 Fluorene ND mg/kg 07/27/16 07:34 86-73-707/25/16 11:000.0054 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/27/16 07:34 193-39-507/25/16 11:000.0054 1 1-Methylnaphthalene ND mg/kg 07/27/16 07:34 90-12-0 N207/25/16 11:000.0054 1 2-Methylnaphthalene ND mg/kg 07/27/16 07:34 91-57-607/25/16 11:000.0054 1 Naphthalene ND mg/kg 07/27/16 07:34 91-20-307/25/16 11:000.0054 1 Phenanthrene ND mg/kg 07/27/16 07:34 85-01-807/25/16 11:000.0054 1 Pyrene ND mg/kg 07/27/16 07:34 129-00-007/25/16 11:000.0054 1 Surrogates 2-Fluorobiphenyl (S)70 %.07/27/16 07:34 321-60-807/25/16 11:0025-121 1 p-Terphenyl-d14 (S)73 %.07/27/16 07:34 1718-51-007/25/16 11:0027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 08/02/16 21:47 67-64-10.099 1 Acrolein ND mg/kg 08/02/16 21:47 107-02-80.099 1 Acrylonitrile ND mg/kg 08/02/16 21:47 107-13-10.099 1 Benzene ND mg/kg 08/02/16 21:47 71-43-20.0049 1 Bromobenzene ND mg/kg 08/02/16 21:47 108-86-10.0049 1 Bromochloromethane ND mg/kg 08/02/16 21:47 74-97-50.0049 1 Bromodichloromethane ND mg/kg 08/02/16 21:47 75-27-40.0049 1 Bromoform ND mg/kg 08/02/16 21:47 75-25-20.0049 1 Bromomethane ND mg/kg 08/02/16 21:47 74-83-90.0049 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 20 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-7 (008-009)Lab ID:50150303006 Collected:07/21/16 12:00 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 2-Butanone (MEK)ND mg/kg 08/02/16 21:47 78-93-30.025 1 n-Butylbenzene ND mg/kg 08/02/16 21:47 104-51-80.0049 1 sec-Butylbenzene ND mg/kg 08/02/16 21:47 135-98-80.0049 1 tert-Butylbenzene ND mg/kg 08/02/16 21:47 98-06-60.0049 1 Carbon disulfide ND mg/kg 08/02/16 21:47 75-15-00.0099 1 Carbon tetrachloride ND mg/kg 08/02/16 21:47 56-23-50.0049 1 Chlorobenzene ND mg/kg 08/02/16 21:47 108-90-70.0049 1 Chloroethane ND mg/kg 08/02/16 21:47 75-00-30.0049 1 Chloroform ND mg/kg 08/02/16 21:47 67-66-30.0049 1 Chloromethane ND mg/kg 08/02/16 21:47 74-87-30.0049 1 2-Chlorotoluene ND mg/kg 08/02/16 21:47 95-49-80.0049 1 4-Chlorotoluene ND mg/kg 08/02/16 21:47 106-43-40.0049 1 Dibromochloromethane ND mg/kg 08/02/16 21:47 124-48-10.0049 1 1,2-Dibromoethane (EDB)ND mg/kg 08/02/16 21:47 106-93-4 L30.0049 1 Dibromomethane ND mg/kg 08/02/16 21:47 74-95-30.0049 1 1,2-Dichlorobenzene ND mg/kg 08/02/16 21:47 95-50-10.0049 1 1,3-Dichlorobenzene ND mg/kg 08/02/16 21:47 541-73-10.0049 1 1,4-Dichlorobenzene ND mg/kg 08/02/16 21:47 106-46-70.0049 1 trans-1,4-Dichloro-2-butene ND mg/kg 08/02/16 21:47 110-57-60.099 1 Dichlorodifluoromethane ND mg/kg 08/02/16 21:47 75-71-80.0049 1 1,1-Dichloroethane ND mg/kg 08/02/16 21:47 75-34-30.0049 1 1,2-Dichloroethane ND mg/kg 08/02/16 21:47 107-06-20.0049 1 1,1-Dichloroethene ND mg/kg 08/02/16 21:47 75-35-40.0049 1 cis-1,2-Dichloroethene ND mg/kg 08/02/16 21:47 156-59-20.0049 1 trans-1,2-Dichloroethene ND mg/kg 08/02/16 21:47 156-60-50.0049 1 1,2-Dichloropropane ND mg/kg 08/02/16 21:47 78-87-50.0049 1 1,3-Dichloropropane ND mg/kg 08/02/16 21:47 142-28-90.0049 1 2,2-Dichloropropane ND mg/kg 08/02/16 21:47 594-20-70.0049 1 1,1-Dichloropropene ND mg/kg 08/02/16 21:47 563-58-60.0049 1 cis-1,3-Dichloropropene ND mg/kg 08/02/16 21:47 10061-01-50.0049 1 trans-1,3-Dichloropropene ND mg/kg 08/02/16 21:47 10061-02-60.0049 1 Ethylbenzene ND mg/kg 08/02/16 21:47 100-41-40.0049 1 Ethyl methacrylate ND mg/kg 08/02/16 21:47 97-63-20.099 1 Hexachloro-1,3-butadiene ND mg/kg 08/02/16 21:47 87-68-30.0049 1 n-Hexane ND mg/kg 08/02/16 21:47 110-54-30.0049 1 2-Hexanone ND mg/kg 08/02/16 21:47 591-78-60.099 1 Iodomethane ND mg/kg 08/02/16 21:47 74-88-40.099 1 Isopropylbenzene (Cumene)ND mg/kg 08/02/16 21:47 98-82-80.0049 1 p-Isopropyltoluene ND mg/kg 08/02/16 21:47 99-87-60.0049 1 Methylene Chloride ND mg/kg 08/02/16 21:47 75-09-20.020 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/02/16 21:47 108-10-10.025 1 Methyl-tert-butyl ether ND mg/kg 08/02/16 21:47 1634-04-40.0049 1 Naphthalene ND mg/kg 08/02/16 21:47 91-20-30.0049 1 n-Propylbenzene ND mg/kg 08/02/16 21:47 103-65-10.0049 1 Styrene ND mg/kg 08/02/16 21:47 100-42-50.0049 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/02/16 21:47 630-20-60.0049 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 21 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-SB-7 (008-009)Lab ID:50150303006 Collected:07/21/16 12:00 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,1,2,2-Tetrachloroethane ND mg/kg 08/02/16 21:47 79-34-50.0049 1 Tetrachloroethene ND mg/kg 08/02/16 21:47 127-18-40.0049 1 Toluene ND mg/kg 08/02/16 21:47 108-88-30.0049 1 1,2,3-Trichlorobenzene ND mg/kg 08/02/16 21:47 87-61-60.0049 1 1,2,4-Trichlorobenzene ND mg/kg 08/02/16 21:47 120-82-10.0049 1 1,1,1-Trichloroethane ND mg/kg 08/02/16 21:47 71-55-60.0049 1 1,1,2-Trichloroethane ND mg/kg 08/02/16 21:47 79-00-50.0049 1 Trichloroethene ND mg/kg 08/02/16 21:47 79-01-60.0049 1 Trichlorofluoromethane ND mg/kg 08/02/16 21:47 75-69-40.0049 1 1,2,3-Trichloropropane ND mg/kg 08/02/16 21:47 96-18-40.0049 1 1,2,4-Trimethylbenzene ND mg/kg 08/02/16 21:47 95-63-60.0049 1 1,3,5-Trimethylbenzene ND mg/kg 08/02/16 21:47 108-67-80.0049 1 Vinyl acetate ND mg/kg 08/02/16 21:47 108-05-40.099 1 Vinyl chloride ND mg/kg 08/02/16 21:47 75-01-40.0049 1 Xylene (Total)ND mg/kg 08/02/16 21:47 1330-20-70.0099 1 Surrogates Dibromofluoromethane (S)98 %.08/02/16 21:47 1868-53-770-128 1 Toluene-d8 (S)100 %.08/02/16 21:47 2037-26-572-139 1 4-Bromofluorobenzene (S)87 %.08/02/16 21:47 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 8.8 %08/01/16 15:460.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 22 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-FD-1 Lab ID:50150303007 Collected:07/21/16 12:25 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30506010 MET ICP Lead 1.6 mg/kg 08/02/16 02:35 7439-92-107/29/16 07:301.1 1 Analytical Method: EPA 8270 by SIM Preparation Method: EPA 35468270 MSSV PAH by SIM Acenaphthene ND mg/kg 07/27/16 07:51 83-32-907/25/16 11:000.0060 1 Acenaphthylene ND mg/kg 07/27/16 07:51 208-96-807/25/16 11:000.0060 1 Anthracene ND mg/kg 07/27/16 07:51 120-12-707/25/16 11:000.0060 1 Benzo(a)anthracene ND mg/kg 07/27/16 07:51 56-55-307/25/16 11:000.0060 1 Benzo(a)pyrene ND mg/kg 07/27/16 07:51 50-32-807/25/16 11:000.0060 1 Benzo(b)fluoranthene ND mg/kg 07/27/16 07:51 205-99-207/25/16 11:000.0060 1 Benzo(g,h,i)perylene ND mg/kg 07/27/16 07:51 191-24-207/25/16 11:000.0060 1 Benzo(k)fluoranthene ND mg/kg 07/27/16 07:51 207-08-907/25/16 11:000.0060 1 Chrysene ND mg/kg 07/27/16 07:51 218-01-907/25/16 11:000.0060 1 Dibenz(a,h)anthracene ND mg/kg 07/27/16 07:51 53-70-307/25/16 11:000.0060 1 Fluoranthene ND mg/kg 07/27/16 07:51 206-44-007/25/16 11:000.0060 1 Fluorene ND mg/kg 07/27/16 07:51 86-73-707/25/16 11:000.0060 1 Indeno(1,2,3-cd)pyrene ND mg/kg 07/27/16 07:51 193-39-507/25/16 11:000.0060 1 1-Methylnaphthalene ND mg/kg 07/27/16 07:51 90-12-0 N207/25/16 11:000.0060 1 2-Methylnaphthalene ND mg/kg 07/27/16 07:51 91-57-607/25/16 11:000.0060 1 Naphthalene ND mg/kg 07/27/16 07:51 91-20-307/25/16 11:000.0060 1 Phenanthrene ND mg/kg 07/27/16 07:51 85-01-807/25/16 11:000.0060 1 Pyrene ND mg/kg 07/27/16 07:51 129-00-007/25/16 11:000.0060 1 Surrogates 2-Fluorobiphenyl (S)46 %.07/27/16 07:51 321-60-807/25/16 11:0025-121 1 p-Terphenyl-d14 (S)53 %.07/27/16 07:51 1718-51-007/25/16 11:0027-124 1 Analytical Method: EPA 82608260 MSV 5035A VOA Acetone ND mg/kg 08/02/16 22:19 67-64-10.099 1 Acrolein ND mg/kg 08/02/16 22:19 107-02-80.099 1 Acrylonitrile ND mg/kg 08/02/16 22:19 107-13-10.099 1 Benzene ND mg/kg 08/02/16 22:19 71-43-20.0049 1 Bromobenzene ND mg/kg 08/02/16 22:19 108-86-10.0049 1 Bromochloromethane ND mg/kg 08/02/16 22:19 74-97-50.0049 1 Bromodichloromethane ND mg/kg 08/02/16 22:19 75-27-40.0049 1 Bromoform ND mg/kg 08/02/16 22:19 75-25-20.0049 1 Bromomethane ND mg/kg 08/02/16 22:19 74-83-90.0049 1 2-Butanone (MEK)ND mg/kg 08/02/16 22:19 78-93-30.025 1 n-Butylbenzene ND mg/kg 08/02/16 22:19 104-51-80.0049 1 sec-Butylbenzene ND mg/kg 08/02/16 22:19 135-98-80.0049 1 tert-Butylbenzene ND mg/kg 08/02/16 22:19 98-06-60.0049 1 Carbon disulfide ND mg/kg 08/02/16 22:19 75-15-00.0099 1 Carbon tetrachloride ND mg/kg 08/02/16 22:19 56-23-50.0049 1 Chlorobenzene ND mg/kg 08/02/16 22:19 108-90-70.0049 1 Chloroethane ND mg/kg 08/02/16 22:19 75-00-30.0049 1 Chloroform ND mg/kg 08/02/16 22:19 67-66-30.0049 1 Chloromethane ND mg/kg 08/02/16 22:19 74-87-30.0049 1 2-Chlorotoluene ND mg/kg 08/02/16 22:19 95-49-80.0049 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 23 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-FD-1 Lab ID:50150303007 Collected:07/21/16 12:25 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 4-Chlorotoluene ND mg/kg 08/02/16 22:19 106-43-40.0049 1 Dibromochloromethane ND mg/kg 08/02/16 22:19 124-48-10.0049 1 1,2-Dibromoethane (EDB)ND mg/kg 08/02/16 22:19 106-93-4 L30.0049 1 Dibromomethane ND mg/kg 08/02/16 22:19 74-95-30.0049 1 1,2-Dichlorobenzene ND mg/kg 08/02/16 22:19 95-50-10.0049 1 1,3-Dichlorobenzene ND mg/kg 08/02/16 22:19 541-73-10.0049 1 1,4-Dichlorobenzene ND mg/kg 08/02/16 22:19 106-46-70.0049 1 trans-1,4-Dichloro-2-butene ND mg/kg 08/02/16 22:19 110-57-60.099 1 Dichlorodifluoromethane ND mg/kg 08/02/16 22:19 75-71-80.0049 1 1,1-Dichloroethane ND mg/kg 08/02/16 22:19 75-34-30.0049 1 1,2-Dichloroethane ND mg/kg 08/02/16 22:19 107-06-20.0049 1 1,1-Dichloroethene ND mg/kg 08/02/16 22:19 75-35-40.0049 1 cis-1,2-Dichloroethene ND mg/kg 08/02/16 22:19 156-59-20.0049 1 trans-1,2-Dichloroethene ND mg/kg 08/02/16 22:19 156-60-50.0049 1 1,2-Dichloropropane ND mg/kg 08/02/16 22:19 78-87-50.0049 1 1,3-Dichloropropane ND mg/kg 08/02/16 22:19 142-28-90.0049 1 2,2-Dichloropropane ND mg/kg 08/02/16 22:19 594-20-70.0049 1 1,1-Dichloropropene ND mg/kg 08/02/16 22:19 563-58-60.0049 1 cis-1,3-Dichloropropene ND mg/kg 08/02/16 22:19 10061-01-50.0049 1 trans-1,3-Dichloropropene ND mg/kg 08/02/16 22:19 10061-02-60.0049 1 Ethylbenzene ND mg/kg 08/02/16 22:19 100-41-40.0049 1 Ethyl methacrylate ND mg/kg 08/02/16 22:19 97-63-20.099 1 Hexachloro-1,3-butadiene ND mg/kg 08/02/16 22:19 87-68-30.0049 1 n-Hexane ND mg/kg 08/02/16 22:19 110-54-30.0049 1 2-Hexanone ND mg/kg 08/02/16 22:19 591-78-60.099 1 Iodomethane ND mg/kg 08/02/16 22:19 74-88-40.099 1 Isopropylbenzene (Cumene)ND mg/kg 08/02/16 22:19 98-82-80.0049 1 p-Isopropyltoluene ND mg/kg 08/02/16 22:19 99-87-60.0049 1 Methylene Chloride ND mg/kg 08/02/16 22:19 75-09-20.020 1 4-Methyl-2-pentanone (MIBK)ND mg/kg 08/02/16 22:19 108-10-10.025 1 Methyl-tert-butyl ether ND mg/kg 08/02/16 22:19 1634-04-40.0049 1 Naphthalene ND mg/kg 08/02/16 22:19 91-20-30.0049 1 n-Propylbenzene ND mg/kg 08/02/16 22:19 103-65-10.0049 1 Styrene ND mg/kg 08/02/16 22:19 100-42-50.0049 1 1,1,1,2-Tetrachloroethane ND mg/kg 08/02/16 22:19 630-20-60.0049 1 1,1,2,2-Tetrachloroethane ND mg/kg 08/02/16 22:19 79-34-50.0049 1 Tetrachloroethene ND mg/kg 08/02/16 22:19 127-18-40.0049 1 Toluene ND mg/kg 08/02/16 22:19 108-88-30.0049 1 1,2,3-Trichlorobenzene ND mg/kg 08/02/16 22:19 87-61-60.0049 1 1,2,4-Trichlorobenzene ND mg/kg 08/02/16 22:19 120-82-10.0049 1 1,1,1-Trichloroethane ND mg/kg 08/02/16 22:19 71-55-60.0049 1 1,1,2-Trichloroethane ND mg/kg 08/02/16 22:19 79-00-50.0049 1 Trichloroethene ND mg/kg 08/02/16 22:19 79-01-60.0049 1 Trichlorofluoromethane ND mg/kg 08/02/16 22:19 75-69-40.0049 1 1,2,3-Trichloropropane ND mg/kg 08/02/16 22:19 96-18-40.0049 1 1,2,4-Trimethylbenzene ND mg/kg 08/02/16 22:19 95-63-60.0049 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 24 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:KM-SB-FD-1 Lab ID:50150303007 Collected:07/21/16 12:25 Received:07/22/16 08:20 Matrix:Solid Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions. Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 5035A VOA 1,3,5-Trimethylbenzene ND mg/kg 08/02/16 22:19 108-67-80.0049 1 Vinyl acetate ND mg/kg 08/02/16 22:19 108-05-40.099 1 Vinyl chloride ND mg/kg 08/02/16 22:19 75-01-40.0049 1 Xylene (Total)ND mg/kg 08/02/16 22:19 1330-20-70.0099 1 Surrogates Dibromofluoromethane (S)96 %.08/02/16 22:19 1868-53-770-128 1 Toluene-d8 (S)96 %.08/02/16 22:19 2037-26-572-139 1 4-Bromofluorobenzene (S)94 %.08/02/16 22:19 460-00-465-127 1 Analytical Method: SM 2540GPercent Moisture Percent Moisture 17.5 %08/01/16 15:460.10 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 25 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:TRIP BLANK Lab ID:50150303009 Collected:07/21/16 08:00 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana Acetone ND ug/L 08/02/16 22:03 67-64-11001 Acrolein ND ug/L 08/02/16 22:03 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 22:03 107-13-11001 Benzene ND ug/L 08/02/16 22:03 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 22:03 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 22:03 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 22:03 75-27-45.0 1 Bromoform ND ug/L 08/02/16 22:03 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 22:03 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 22:03 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 22:03 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 22:03 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 22:03 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 22:03 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 22:03 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 22:03 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 22:03 75-00-35.0 1 Chloroform ND ug/L 08/02/16 22:03 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 22:03 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 22:03 95-49-85.0 1 4-Chlorotoluene ND ug/L 08/02/16 22:03 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 22:03 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 22:03 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 22:03 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 22:03 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 22:03 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 22:03 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 22:03 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 22:03 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 22:03 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 22:03 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 22:03 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 22:03 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 22:03 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 22:03 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 22:03 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 22:03 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 22:03 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 22:03 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 22:03 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 22:03 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 22:03 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 22:03 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 22:03 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 22:03 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 22:03 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 22:03 98-82-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 26 of 58 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150303 KMART Sample:TRIP BLANK Lab ID:50150303009 Collected:07/21/16 08:00 Received:07/22/16 08:20 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Indiana p-Isopropyltoluene ND ug/L 08/02/16 22:03 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 22:03 75-09-25.0 1 1-Methylnaphthalene ND ug/L 08/02/16 22:03 90-12-0 N25.0 1 2-Methylnaphthalene ND ug/L 08/02/16 22:03 91-57-610.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 22:03 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 22:03 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 22:03 91-20-31.7 1 n-Propylbenzene ND ug/L 08/02/16 22:03 103-65-15.0 1 Styrene ND ug/L 08/02/16 22:03 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 22:03 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 22:03 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 22:03 127-18-45.0 1 Toluene ND ug/L 08/02/16 22:03 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 22:03 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 22:03 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 22:03 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 22:03 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 22:03 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 22:03 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 22:03 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 22:03 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 22:03 108-67-85.0 1 Vinyl acetate ND ug/L 08/02/16 22:03 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 22:03 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 22:03 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)93 %.08/02/16 22:03 1868-53-784-118 1 4-Bromofluorobenzene (S)98 %.08/02/16 22:03 460-00-479-116 1 Toluene-d8 (S)95 %.08/02/16 22:03 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 27 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343473 EPA 3050 EPA 6010 6010 MET Associated Lab Samples:50150303001, 50150303002, 50150303003, 50150303004, 50150303005, 50150303006, 50150303007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1591009 Associated Lab Samples:50150303001, 50150303002, 50150303003, 50150303004, 50150303005, 50150303006, 50150303007 Matrix:Solid Analyzed Lead mg/kg ND 1.0 08/02/16 02:07 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591010LABORATORY CONTROL SAMPLE: LCSSpike Lead mg/kg 50.650 101 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591011MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150303001 1591012 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead mg/kg 54.5 91 75-12589 1 20551.7 51.1 50.8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 28 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344873 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50150303009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596457 Associated Lab Samples:50150303009 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/02/16 15:38 1,1,1-Trichloroethane ug/L ND 5.0 08/02/16 15:38 1,1,2,2-Tetrachloroethane ug/L ND 5.0 08/02/16 15:38 1,1,2-Trichloroethane ug/L ND 5.0 08/02/16 15:38 1,1-Dichloroethane ug/L ND 5.0 08/02/16 15:38 1,1-Dichloroethene ug/L ND 5.0 08/02/16 15:38 1,1-Dichloropropene ug/L ND 5.0 08/02/16 15:38 1,2,3-Trichlorobenzene ug/L ND 5.0 08/02/16 15:38 1,2,3-Trichloropropane ug/L ND 5.0 08/02/16 15:38 1,2,4-Trichlorobenzene ug/L ND 5.0 08/02/16 15:38 1,2,4-Trimethylbenzene ug/L ND 5.0 08/02/16 15:38 1,2-Dibromoethane (EDB)ug/L ND 5.0 08/02/16 15:38 1,2-Dichlorobenzene ug/L ND 5.0 08/02/16 15:38 1,2-Dichloroethane ug/L ND 5.0 08/02/16 15:38 1,2-Dichloropropane ug/L ND 5.0 08/02/16 15:38 1,3,5-Trimethylbenzene ug/L ND 5.0 08/02/16 15:38 1,3-Dichlorobenzene ug/L ND 5.0 08/02/16 15:38 1,3-Dichloropropane ug/L ND 5.0 08/02/16 15:38 1,4-Dichlorobenzene ug/L ND 5.0 08/02/16 15:38 1-Methylnaphthalene ug/L ND 5.0 N208/02/16 15:38 2,2-Dichloropropane ug/L ND 5.0 08/02/16 15:38 2-Butanone (MEK)ug/L ND 25.0 08/02/16 15:38 2-Chlorotoluene ug/L ND 5.0 08/02/16 15:38 2-Hexanone ug/L ND 25.0 08/02/16 15:38 2-Methylnaphthalene ug/L ND 10.0 08/02/16 15:38 4-Chlorotoluene ug/L ND 5.0 08/02/16 15:38 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 08/02/16 15:38 Acetone ug/L ND 100 08/02/16 15:38 Acrolein ug/L ND 50.0 08/02/16 15:38 Acrylonitrile ug/L ND 100 08/02/16 15:38 Benzene ug/L ND 5.0 08/02/16 15:38 Bromobenzene ug/L ND 5.0 08/02/16 15:38 Bromochloromethane ug/L ND 5.0 08/02/16 15:38 Bromodichloromethane ug/L ND 5.0 08/02/16 15:38 Bromoform ug/L ND 5.0 08/02/16 15:38 Bromomethane ug/L ND 5.0 08/02/16 15:38 Carbon disulfide ug/L ND 10.0 08/02/16 15:38 Carbon tetrachloride ug/L ND 5.0 08/02/16 15:38 Chlorobenzene ug/L ND 5.0 08/02/16 15:38 Chloroethane ug/L ND 5.0 08/02/16 15:38 Chloroform ug/L ND 5.0 08/02/16 15:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 29 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596457 Associated Lab Samples:50150303009 Matrix:Water Analyzed Chloromethane ug/L ND 5.0 08/02/16 15:38 cis-1,2-Dichloroethene ug/L ND 5.0 08/02/16 15:38 cis-1,3-Dichloropropene ug/L ND 5.0 08/02/16 15:38 Dibromochloromethane ug/L ND 5.0 08/02/16 15:38 Dibromomethane ug/L ND 5.0 08/02/16 15:38 Dichlorodifluoromethane ug/L ND 5.0 08/02/16 15:38 Ethyl methacrylate ug/L ND 100 08/02/16 15:38 Ethylbenzene ug/L ND 5.0 08/02/16 15:38 Hexachloro-1,3-butadiene ug/L ND 5.0 08/02/16 15:38 Iodomethane ug/L ND 10.0 08/02/16 15:38 Isopropylbenzene (Cumene)ug/L ND 5.0 08/02/16 15:38 Methyl-tert-butyl ether ug/L ND 4.0 08/02/16 15:38 Methylene Chloride ug/L ND 5.0 08/02/16 15:38 n-Butylbenzene ug/L ND 5.0 08/02/16 15:38 n-Hexane ug/L ND 5.0 08/02/16 15:38 n-Propylbenzene ug/L ND 5.0 08/02/16 15:38 Naphthalene ug/L ND 1.7 08/02/16 15:38 p-Isopropyltoluene ug/L ND 5.0 08/02/16 15:38 sec-Butylbenzene ug/L ND 5.0 08/02/16 15:38 Styrene ug/L ND 5.0 08/02/16 15:38 tert-Butylbenzene ug/L ND 5.0 08/02/16 15:38 Tetrachloroethene ug/L ND 5.0 08/02/16 15:38 Toluene ug/L ND 5.0 08/02/16 15:38 trans-1,2-Dichloroethene ug/L ND 5.0 08/02/16 15:38 trans-1,3-Dichloropropene ug/L ND 5.0 08/02/16 15:38 trans-1,4-Dichloro-2-butene ug/L ND 100 08/02/16 15:38 Trichloroethene ug/L ND 5.0 08/02/16 15:38 Trichlorofluoromethane ug/L ND 5.0 08/02/16 15:38 Vinyl acetate ug/L ND 50.0 08/02/16 15:38 Vinyl chloride ug/L ND 2.0 08/02/16 15:38 Xylene (Total)ug/L ND 10.0 08/02/16 15:38 4-Bromofluorobenzene (S)%.96 79-116 08/02/16 15:38 Dibromofluoromethane (S)%.90 84-118 08/02/16 15:38 Toluene-d8 (S)%.97 86-110 08/02/16 15:38 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596458LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 51.850 104 74-130 1,1,1-Trichloroethane ug/L 45.850 92 72-123 1,1,2,2-Tetrachloroethane ug/L 52.050 104 72-124 1,1,2-Trichloroethane ug/L 49.850 100 75-125 1,1-Dichloroethane ug/L 47.650 95 70-120 1,1-Dichloroethene ug/L 44.250 88 69-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 30 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596458LABORATORY CONTROL SAMPLE: LCSSpike 1,1-Dichloropropene ug/L 48.150 96 81-129 1,2,3-Trichlorobenzene ug/L 51.850 104 71-130 1,2,3-Trichloropropane ug/L 49.750 99 77-127 1,2,4-Trichlorobenzene ug/L 51.950 104 66-126 1,2,4-Trimethylbenzene ug/L 53.050 106 73-125 1,2-Dibromoethane (EDB)ug/L 53.150 106 76-125 1,2-Dichlorobenzene ug/L 48.450 97 77-122 1,2-Dichloroethane ug/L 40.950 82 70-123 1,2-Dichloropropane ug/L 50.350 101 77-124 1,3,5-Trimethylbenzene ug/L 52.350 105 75-124 1,3-Dichlorobenzene ug/L 51.450 103 76-124 1,3-Dichloropropane ug/L 50.450 101 77-123 1,4-Dichlorobenzene ug/L 50.550 101 75-117 1-Methylnaphthalene ug/L 52.0 N25010455-151 2,2-Dichloropropane ug/L 47.250 94 44-147 2-Butanone (MEK)ug/L 228250 91 60-135 2-Chlorotoluene ug/L 51.250 102 75-124 2-Hexanone ug/L 207250 83 65-139 2-Methylnaphthalene ug/L 46.150 92 58-148 4-Chlorotoluene ug/L 51.250 102 75-124 4-Methyl-2-pentanone (MIBK)ug/L 207250 83 66-134 Acetone ug/L 154250 62 47-144 Acrolein ug/L 10401000 104 31-200 Acrylonitrile ug/L 175200 87 64-133 Benzene ug/L 52.150 104 76-122 Bromobenzene ug/L 49.750 99 75-117 Bromochloromethane ug/L 42.750 85 74-134 Bromodichloromethane ug/L 47.150 94 71-124 Bromoform ug/L 42.650 85 60-125 Bromomethane ug/L 41.350 83 23-194 Carbon disulfide ug/L 44.050 88 63-130 Carbon tetrachloride ug/L 45.350 91 73-133 Chlorobenzene ug/L 53.250 106 76-118 Chloroethane ug/L 40.150 80 50-147 Chloroform ug/L 44.750 89 70-119 Chloromethane ug/L 28.950 58 52-136 cis-1,2-Dichloroethene ug/L 54.050 108 74-120 cis-1,3-Dichloropropene ug/L 52.350 105 71-134 Dibromochloromethane ug/L 47.550 95 73-127 Dibromomethane ug/L 49.950 100 75-124 Dichlorodifluoromethane ug/L 53.850 108 39-166 Ethyl methacrylate ug/L 215200 107 73-136 Ethylbenzene ug/L 55.150 110 75-123 Hexachloro-1,3-butadiene ug/L 55.550 111 70-125 Iodomethane ug/L 94.5100 95 56-142 Isopropylbenzene (Cumene)ug/L 55.650 111 84-134 Methyl-tert-butyl ether ug/L 45.050 90 65-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 31 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596458LABORATORY CONTROL SAMPLE: LCSSpike Methylene Chloride ug/L 47.750 95 66-130 n-Butylbenzene ug/L 51.050 102 70-127 n-Hexane ug/L 49.050 98 64-131 n-Propylbenzene ug/L 52.950 106 78-131 Naphthalene ug/L 51.950 104 65-134 p-Isopropyltoluene ug/L 53.950 108 75-124 sec-Butylbenzene ug/L 54.750 109 83-135 Styrene ug/L 55.050 110 78-128 tert-Butylbenzene ug/L 43.350 87 62-114 Tetrachloroethene ug/L 51.450 103 69-119 Toluene ug/L 48.950 98 74-122 trans-1,2-Dichloroethene ug/L 52.650 105 72-122 trans-1,3-Dichloropropene ug/L 50.350 101 66-135 trans-1,4-Dichloro-2-butene ug/L 184200 92 39-153 Trichloroethene ug/L 50.950 102 75-123 Trichlorofluoromethane ug/L 46.750 93 58-148 Vinyl acetate ug/L 205200 102 67-154 Vinyl chloride ug/L 43.450 87 61-147 Xylene (Total)ug/L 163150 109 75-127 4-Bromofluorobenzene (S)%.97 79-116 Dibromofluoromethane (S)%.90 84-118 Toluene-d8 (S)%.100 86-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1595784MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150409006 1595785 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 50 62 44-14268 10 2050ND30.9 34.2 1,1,1-Trichloroethane ug/L 50 71 51-14076 7 2050ND35.7 38.2 1,1,2,2-Tetrachloroethane ug/L 50 92 49-13897 6 2050ND46.0 48.7 1,1,2-Trichloroethane ug/L 50 83 51-13888 6 2050ND41.5 44.2 1,1-Dichloroethane ug/L 50 79 48-13787 10 2050ND39.5 43.6 1,1-Dichloroethene ug/L 50 70 51-14475 6 2050ND35.2 37.3 1,1-Dichloropropene ug/L 50 60 54-15065 7 2050ND30.2 32.4 1,2,3-Trichlorobenzene ug/L 50 36 32-14035 4 2050ND18.2 17.4 1,2,3-Trichloropropane ug/L 50 87 51-139103 17 2050ND43.3 51.6 1,2,4-Trichlorobenzene ug/L 50 28 27-13427 2 2050ND13.8 13.5 1,2,4-Trimethylbenzene ug/L M1502232-14321 7 2050ND11.4 10.6 1,2-Dibromoethane (EDB)ug/L 50 83 52-13496 14 2050ND41.6 47.8 1,2-Dichlorobenzene ug/L M1503538-13834 4 2050ND17.4 16.8 1,2-Dichloroethane ug/L 50 70 44-14477 9 2050ND35.1 38.5 1,2-Dichloropropane ug/L 50 79 56-13886 9 2050ND39.5 43.2 1,3,5-Trimethylbenzene ug/L M1502228-14621 5 2050ND11.0 10.4 1,3-Dichlorobenzene ug/L M1502636-13925 5 2050ND13.1 12.5 1,3-Dichloropropane ug/L 50 82 54-13790 10 2050ND40.8 45.1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 32 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1595784MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150409006 1595785 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,4-Dichlorobenzene ug/L M1502734-13425 6 2050ND13.3 12.6 1-Methylnaphthalene ug/L N2506332-15069 9 2050ND32.6 35.7 2,2-Dichloropropane ug/L 50 67 20-14270 3 2050ND33.7 34.8 2-Butanone (MEK)ug/L 250 105 44-142117 11 20250ND262292 2-Chlorotoluene ug/L M1502736-14326 4 2050ND13.4 13.0 2-Hexanone ug/L 250 89 43-150103 15 20250ND221256 2-Methylnaphthalene ug/L 50 50 27-14852 4 2050ND26.0 27.2 4-Chlorotoluene ug/L M1502534-14323 9 2050ND12.4 11.3 4-Methyl-2-pentanone (MIBK)ug/L 250 88 46-143100 13 20250ND219249 Acetone ug/L 250 70 33-15078 12 20250ND174195 Acrolein ug/L 1000 76 32-20089 15 201000ND765891 Acrylonitrile ug/L 200 94 47-143104 9 20200ND189207 Benzene ug/L 50 75 51-14080 6 2050ND37.5 39.9 Bromobenzene ug/L 50 41 41-13442 3 2050ND20.4 21.0 Bromochloromethane ug/L 50 78 53-14884 6 2050ND39.1 41.8 Bromodichloromethane ug/L 50 75 46-13783 11 2050ND37.3 41.7 Bromoform ug/L 50 74 36-12782 10 2050ND37.2 41.2 Bromomethane ug/L R1503810-18850 28 2050ND19.0 25.2 Carbon disulfide ug/L 50 63 35-14868 7 2050ND31.5 33.8 Carbon tetrachloride ug/L 50 67 45-15173 8 2050ND33.6 36.4 Chlorobenzene ug/L M1504445-13847 6 2050ND21.9 23.4 Chloroethane ug/L 50 82 33-16472 13 2050ND41.1 35.9 Chloroform ug/L 50 75 50-13582 9 2050ND37.6 41.2 Chloromethane ug/L 50 48 38-14653 11 2050ND23.9 26.6 cis-1,2-Dichloroethene ug/L 50 83 43-14489 6 2050ND41.6 44.3 cis-1,3-Dichloropropene ug/L 50 68 42-13675 11 2050ND33.9 37.7 Dibromochloromethane ug/L 50 77 45-13686 11 2050ND38.7 43.2 Dibromomethane ug/L 50 83 51-13996 15 2050ND41.6 48.2 Dichlorodifluoromethane ug/L 50 92 29-17498 6 2050ND45.9 49.0 Ethyl methacrylate ug/L 200 94 44-150107 13 20200ND188215 Ethylbenzene ug/L 50 36 36-14637 5 2050ND17.8 18.7 Hexachloro-1,3-butadiene ug/L M150714-1507 2050ND3.6J 3.3J Iodomethane ug/L R11003528-15356 46 20100ND35.4 56.3 Isopropylbenzene (Cumene)ug/L M1502843-15928 1 2050ND14.2 14.1 Methyl-tert-butyl ether ug/L 50 93 43-146105 12 2050ND46.6 52.4 Methylene Chloride ug/L 50 92 48-14096 5 2050ND46.0 48.1 n-Butylbenzene ug/L M1501016-1529 2050ND4.9J 4.4J n-Hexane ug/L 50 71 40-14473 4 2050ND35.3 36.6 n-Propylbenzene ug/L M1501928-15718 4 2050ND9.6 9.1 Naphthalene ug/L 50 61 38-14164 5 2050ND31.1 32.7 p-Isopropyltoluene ug/L M1501521-15113 14 2050ND7.3 6.3 sec-Butylbenzene ug/L M1501727-16515 10 2050ND8.4 7.6 Styrene ug/L 50 43 31-14843 0 2050ND21.5 21.5 tert-Butylbenzene ug/L M1501824-13117 11 2050ND9.2 8.3 Tetrachloroethene ug/L M1503738-13937 1 2050ND18.4 18.6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 33 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1595784MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150409006 1595785 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Toluene ug/L 50 47 44-14050 6 2050ND23.8 25.3 trans-1,2-Dichloroethene ug/L 50 74 50-13980 8 2050ND37.0 40.2 trans-1,3-Dichloropropene ug/L 50 66 37-13874 11 2050ND33.1 36.8 trans-1,4-Dichloro-2-butene ug/L 200 62 10-15773 16 20200ND125146 Trichloroethene ug/L 50 56 44-14661 8 2050ND28.2 30.5 Trichlorofluoromethane ug/L 50 83 41-16486 4 2050ND41.5 43.0 Vinyl acetate ug/L 200 51 15-14657 10 20200ND103114 Vinyl chloride ug/L 50 70 43-16674 6 2050ND35.0 37.0 Xylene (Total)ug/L MS1503535-14636 1 20150ND53.0 53.6 4-Bromofluorobenzene (S)%.98 79-11699 Dibromofluoromethane (S)%.94 84-11896 Toluene-d8 (S)%.96 86-11095 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 34 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344926 EPA 8260 EPA 8260 8260 MSV 5035A Volatile Organics Associated Lab Samples:50150303001, 50150303002, 50150303003, 50150303004, 50150303006, 50150303007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596641 Associated Lab Samples:50150303001, 50150303002, 50150303003, 50150303004, 50150303006, 50150303007 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 08/02/16 13:46 1,1,1-Trichloroethane mg/kg ND 0.0050 08/02/16 13:46 1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 08/02/16 13:46 1,1,2-Trichloroethane mg/kg ND 0.0050 08/02/16 13:46 1,1-Dichloroethane mg/kg ND 0.0050 08/02/16 13:46 1,1-Dichloroethene mg/kg ND 0.0050 08/02/16 13:46 1,1-Dichloropropene mg/kg ND 0.0050 08/02/16 13:46 1,2,3-Trichlorobenzene mg/kg ND 0.0050 08/02/16 13:46 1,2,3-Trichloropropane mg/kg ND 0.0050 08/02/16 13:46 1,2,4-Trichlorobenzene mg/kg ND 0.0050 08/02/16 13:46 1,2,4-Trimethylbenzene mg/kg ND 0.0050 08/02/16 13:46 1,2-Dibromoethane (EDB)mg/kg ND 0.0050 08/02/16 13:46 1,2-Dichlorobenzene mg/kg ND 0.0050 08/02/16 13:46 1,2-Dichloroethane mg/kg ND 0.0050 08/02/16 13:46 1,2-Dichloropropane mg/kg ND 0.0050 08/02/16 13:46 1,3,5-Trimethylbenzene mg/kg ND 0.0050 08/02/16 13:46 1,3-Dichlorobenzene mg/kg ND 0.0050 08/02/16 13:46 1,3-Dichloropropane mg/kg ND 0.0050 08/02/16 13:46 1,4-Dichlorobenzene mg/kg ND 0.0050 08/02/16 13:46 2,2-Dichloropropane mg/kg ND 0.0050 08/02/16 13:46 2-Butanone (MEK)mg/kg ND 0.025 08/02/16 13:46 2-Chlorotoluene mg/kg ND 0.0050 08/02/16 13:46 2-Hexanone mg/kg ND 0.10 08/02/16 13:46 4-Chlorotoluene mg/kg ND 0.0050 08/02/16 13:46 4-Methyl-2-pentanone (MIBK)mg/kg ND 0.025 08/02/16 13:46 Acetone mg/kg ND 0.10 08/02/16 13:46 Acrolein mg/kg ND 0.10 08/02/16 13:46 Acrylonitrile mg/kg ND 0.10 08/02/16 13:46 Benzene mg/kg ND 0.0050 08/02/16 13:46 Bromobenzene mg/kg ND 0.0050 08/02/16 13:46 Bromochloromethane mg/kg ND 0.0050 08/02/16 13:46 Bromodichloromethane mg/kg ND 0.0050 08/02/16 13:46 Bromoform mg/kg ND 0.0050 08/02/16 13:46 Bromomethane mg/kg ND 0.0050 08/02/16 13:46 Carbon disulfide mg/kg ND 0.010 08/02/16 13:46 Carbon tetrachloride mg/kg ND 0.0050 08/02/16 13:46 Chlorobenzene mg/kg ND 0.0050 08/02/16 13:46 Chloroethane mg/kg ND 0.0050 08/02/16 13:46 Chloroform mg/kg ND 0.0050 08/02/16 13:46 Chloromethane mg/kg ND 0.0050 08/02/16 13:46 cis-1,2-Dichloroethene mg/kg ND 0.0050 08/02/16 13:46 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 35 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596641 Associated Lab Samples:50150303001, 50150303002, 50150303003, 50150303004, 50150303006, 50150303007 Matrix:Solid Analyzed cis-1,3-Dichloropropene mg/kg ND 0.0050 08/02/16 13:46 Dibromochloromethane mg/kg ND 0.0050 08/02/16 13:46 Dibromomethane mg/kg ND 0.0050 08/02/16 13:46 Dichlorodifluoromethane mg/kg ND 0.0050 08/02/16 13:46 Ethyl methacrylate mg/kg ND 0.10 08/02/16 13:46 Ethylbenzene mg/kg ND 0.0050 08/02/16 13:46 Hexachloro-1,3-butadiene mg/kg ND 0.0050 08/02/16 13:46 Iodomethane mg/kg ND 0.10 08/02/16 13:46 Isopropylbenzene (Cumene)mg/kg ND 0.0050 08/02/16 13:46 Methyl-tert-butyl ether mg/kg ND 0.0050 08/02/16 13:46 Methylene Chloride mg/kg ND 0.020 08/02/16 13:46 n-Butylbenzene mg/kg ND 0.0050 08/02/16 13:46 n-Hexane mg/kg ND 0.0050 08/02/16 13:46 n-Propylbenzene mg/kg ND 0.0050 08/02/16 13:46 Naphthalene mg/kg ND 0.0050 08/02/16 13:46 p-Isopropyltoluene mg/kg ND 0.0050 08/02/16 13:46 sec-Butylbenzene mg/kg ND 0.0050 08/02/16 13:46 Styrene mg/kg ND 0.0050 08/02/16 13:46 tert-Butylbenzene mg/kg ND 0.0050 08/02/16 13:46 Tetrachloroethene mg/kg ND 0.0050 08/02/16 13:46 Toluene mg/kg ND 0.0050 08/02/16 13:46 trans-1,2-Dichloroethene mg/kg ND 0.0050 08/02/16 13:46 trans-1,3-Dichloropropene mg/kg ND 0.0050 08/02/16 13:46 trans-1,4-Dichloro-2-butene mg/kg ND 0.10 08/02/16 13:46 Trichloroethene mg/kg ND 0.0050 08/02/16 13:46 Trichlorofluoromethane mg/kg ND 0.0050 08/02/16 13:46 Vinyl acetate mg/kg ND 0.10 08/02/16 13:46 Vinyl chloride mg/kg ND 0.0050 08/02/16 13:46 Xylene (Total)mg/kg ND 0.010 08/02/16 13:46 4-Bromofluorobenzene (S)%.93 65-127 08/02/16 13:46 Dibromofluoromethane (S)%.93 70-128 08/02/16 13:46 Toluene-d8 (S)%.95 72-139 08/02/16 13:46 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596642LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane mg/kg 0.054.05 107 71-125 1,1,1-Trichloroethane mg/kg 0.049.05 97 67-123 1,1,2,2-Tetrachloroethane mg/kg 0.057.05 115 67-129 1,1,2-Trichloroethane mg/kg 0.054.05 107 74-125 1,1-Dichloroethane mg/kg 0.051.05 101 69-115 1,1-Dichloroethene mg/kg 0.056.05 113 64-133 1,1-Dichloropropene mg/kg 0.052.05 103 79-127 1,2,3-Trichlorobenzene mg/kg 0.055.05 110 63-122 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 36 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596642LABORATORY CONTROL SAMPLE: LCSSpike 1,2,3-Trichloropropane mg/kg 0.055.05 109 79-130 1,2,4-Trichlorobenzene mg/kg 0.056.05 112 55-120 1,2,4-Trimethylbenzene mg/kg 0.052.05 104 66-118 1,2-Dibromoethane (EDB)mg/kg 0.059 L0.05 118 79-117 1,2-Dichlorobenzene mg/kg 0.053.05 105 71-115 1,2-Dichloroethane mg/kg 0.045.05 91 71-121 1,2-Dichloropropane mg/kg 0.053.05 107 74-119 1,3,5-Trimethylbenzene mg/kg 0.053.05 106 67-118 1,3-Dichlorobenzene mg/kg 0.054.05 108 68-117 1,3-Dichloropropane mg/kg 0.054.05 108 75-121 1,4-Dichlorobenzene mg/kg 0.053.05 106 66-112 2,2-Dichloropropane mg/kg 0.051.05 102 63-126 2-Butanone (MEK)mg/kg 0.28.25 112 61-129 2-Chlorotoluene mg/kg 0.052.05 103 66-121 2-Hexanone mg/kg 0.26.25 104 68-136 4-Chlorotoluene mg/kg 0.052.05 104 67-118 4-Methyl-2-pentanone (MIBK)mg/kg 0.24.25 97 70-129 Acetone mg/kg 0.23.25 92 37-158 Acrolein mg/kg 1.21 123 46-200 Acrylonitrile mg/kg 0.20.2 101 70-120 Benzene mg/kg 0.056.05 112 72-120 Bromobenzene mg/kg 0.052.05 104 67-114 Bromochloromethane mg/kg 0.048.05 96 73-123 Bromodichloromethane mg/kg 0.050.05 100 72-114 Bromoform mg/kg 0.051.05 102 56-125 Bromomethane mg/kg 0.046.05 91 41-175 Carbon disulfide mg/kg 0.047.05 93 58-130 Carbon tetrachloride mg/kg 0.048.05 96 73-129 Chlorobenzene mg/kg 0.054.05 108 72-115 Chloroethane mg/kg 0.042.05 83 52-154 Chloroform mg/kg 0.043.05 87 66-116 Chloromethane mg/kg 0.037.05 74 49-139 cis-1,2-Dichloroethene mg/kg 0.054.05 109 74-115 cis-1,3-Dichloropropene mg/kg 0.056.05 112 74-122 Dibromochloromethane mg/kg 0.053.05 107 72-123 Dibromomethane mg/kg 0.052.05 104 78-118 Dichlorodifluoromethane mg/kg 0.054.05 109 31-182 Ethyl methacrylate mg/kg 0.24.2 118 73-136 Ethylbenzene mg/kg 0.055.05 110 70-121 Hexachloro-1,3-butadiene mg/kg 0.056.05 112 62-121 Iodomethane mg/kg 0.12.1 121 55-152 Isopropylbenzene (Cumene)mg/kg 0.056.05 111 78-130 Methyl-tert-butyl ether mg/kg 0.053.05 106 68-123 Methylene Chloride mg/kg 0.054.05 107 57-126 n-Butylbenzene mg/kg 0.054.05 108 61-121 n-Hexane mg/kg 0.050.05 99 64-124 n-Propylbenzene mg/kg 0.054.05 107 68-126 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 37 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596642LABORATORY CONTROL SAMPLE: LCSSpike Naphthalene mg/kg 0.059.05 119 63-125 p-Isopropyltoluene mg/kg 0.054.05 108 68-118 sec-Butylbenzene mg/kg 0.055.05 110 75-131 Styrene mg/kg 0.057.05 114 71-121 tert-Butylbenzene mg/kg 0.044.05 87 61-117 Tetrachloroethene mg/kg 0.054.05 108 66-118 Toluene mg/kg 0.047.05 94 68-121 trans-1,2-Dichloroethene mg/kg 0.058.05 116 71-120 trans-1,3-Dichloropropene mg/kg 0.054.05 107 72-127 trans-1,4-Dichloro-2-butene mg/kg 0.20.2 100 55-150 Trichloroethene mg/kg 0.053.05 107 73-120 Trichlorofluoromethane mg/kg 0.048.05 96 61-158 Vinyl acetate mg/kg 0.19.2 97 76-150 Vinyl chloride mg/kg 0.050.05 99 54-155 Xylene (Total)mg/kg 0.17.15 112 69-122 4-Bromofluorobenzene (S)%.98 65-127 Dibromofluoromethane (S)%.93 70-128 Toluene-d8 (S)%.96 72-139 Parameter Units MS Result % Rec Limits Qual% RecConc. 1596643MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150303001 1596644 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane mg/kg .049 103 24-143115 3 20.045ND 0.050 0.052 1,1,1-Trichloroethane mg/kg .049 91 37-144102 4 20.045ND 0.044 0.046 1,1,2,2-Tetrachloroethane mg/kg .049 111 12-174129 8 20.045ND 0.054 0.058 1,1,2-Trichloroethane mg/kg .049 98 34-153115 8 20.045ND 0.048 0.052 1,1-Dichloroethane mg/kg .049 91 39-139102 4 20.045ND 0.044 0.046 1,1-Dichloroethene mg/kg .049 102 36-162110 1 20.045ND 0.050 0.050 1,1-Dichloropropene mg/kg .049 96 36-152105 1 20.045ND 0.047 0.047 1,2,3-Trichlorobenzene mg/kg .049 86 10-11888 6 20.045ND 0.042 0.039 1,2,3-Trichloropropane mg/kg .049 105 25-186120 6 20.045ND 0.051 0.054 1,2,4-Trichlorobenzene mg/kg .049 88 10-11495 0 20.045ND 0.043 0.043 1,2,4-Trimethylbenzene mg/kg .049 101 10-157117 6 20.045ND 0.051 0.054 1,2-Dibromoethane (EDB)mg/kg .049 111 27-142122 2 20.045ND 0.054 0.055 1,2-Dichlorobenzene mg/kg .049 97 10-133110 4 20.045ND 0.047 0.049 1,2-Dichloroethane mg/kg .049 82 40-13891 2 20.045ND 0.040 0.041 1,2-Dichloropropane mg/kg .049 100 43-138114 5 20.045ND 0.049 0.051 1,3,5-Trimethylbenzene mg/kg .049 104 10-168118 4 20.045ND 0.051 0.053 1,3-Dichlorobenzene mg/kg .049 101 10-138115 6 20.045ND 0.049 0.052 1,3-Dichloropropane mg/kg .049 100 37-142115 5 20.045ND 0.049 0.052 1,4-Dichlorobenzene mg/kg .049 98 10-130112 5 20.045ND 0.048 0.050 2,2-Dichloropropane mg/kg .049 98 33-144108 2 20.045ND 0.048 0.049 2-Butanone (MEK)mg/kg .25 111 21-183119 0 20.22ND 0.27 0.27 2-Chlorotoluene mg/kg .049 104 10-165117 4 20.045ND 0.051 0.053 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 38 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596643MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150303001 1596644 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 2-Hexanone mg/kg .25 101 16-187118 7 20.22ND 0.25 0.27 4-Chlorotoluene mg/kg .049 102 10-150115 4 20.045ND 0.050 0.052 4-Methyl-2-pentanone (MIBK)mg/kg .25 90 33-169100 3 20.22ND 0.22 0.23 Acetone mg/kg .25 92 10-200103 3 20.22ND 0.22 0.23 Acrolein mg/kg .97 102 10-189113 3 20.9ND 1.0 1.0 Acrylonitrile mg/kg .19 92 18-163101 2 20.18ND 0.18 0.18 Benzene mg/kg .049 103 36-144116 4 20.045ND 0.050 0.052 Bromobenzene mg/kg .049 93 10-135102 2 20.045ND 0.045 0.046 Bromochloromethane mg/kg .049 89 41-147101 5 20.045ND 0.043 0.045 Bromodichloromethane mg/kg .049 95 23-137106 3 20.045ND 0.046 0.048 Bromoform mg/kg .049 104 10-147120 7 20.045ND 0.050 0.054 Bromomethane mg/kg .049 80 10-19689 3 20.045ND 0.039 0.040 Carbon disulfide mg/kg .049 84 22-15095 4 20.045ND 0.041 0.043 Carbon tetrachloride mg/kg .049 91 29-152103 5 20.045ND 0.044 0.046 Chlorobenzene mg/kg .049 101 16-140113 4 20.045ND 0.049 0.051 Chloroethane mg/kg .049 73 19-18279 0 20.045ND 0.035 0.036 Chloroform mg/kg .049 81 39-13691 4 20.045ND 0.039 0.041 Chloromethane mg/kg .049 52 21-16758 2 20.045ND 0.025 0.026 cis-1,2-Dichloroethene mg/kg .049 103 34-143114 2 20.045ND 0.050 0.051 cis-1,3-Dichloropropene mg/kg .049 106 19-145121 5 20.045ND 0.052 0.055 Dibromochloromethane mg/kg .049 102 18-142115 5 20.045ND 0.050 0.052 Dibromomethane mg/kg .049 98 35-140108 1 20.045ND 0.048 0.049 Dichlorodifluoromethane mg/kg .049 103 10-200107 4 20.045ND 0.050 0.048 Ethyl methacrylate mg/kg .19 108 10-164124 6 20.18ND 0.21 0.22 Ethylbenzene mg/kg .049 106 15-147116 2 20.045ND 0.052 0.053 Hexachloro-1,3-butadiene mg/kg .049 110 10-146124 4 20.045ND 0.054 0.056 Iodomethane mg/kg .097 117 16-166132 4 20.09ND 0.11 0.12 Isopropylbenzene (Cumene)mg/kg .049 107 10-163118 2 20.045ND 0.052 0.053 Methyl-tert-butyl ether mg/kg .049 97 48-145108 3 20.045ND 0.047 0.049 Methylene Chloride mg/kg .049 98 35-142113 7 20.045ND 0.051 0.054 n-Butylbenzene mg/kg .049 104 10-159120 7 20.045ND 0.051 0.054 n-Hexane mg/kg .049 94 17-158104 2 20.045ND 0.046 0.047 n-Propylbenzene mg/kg .049 108 10-176125 6 20.045ND 0.053 0.056 Naphthalene mg/kg .049 94 10-13297 4 20.045ND 0.049 0.047 p-Isopropyltoluene mg/kg .049 108 10-164123 5 20.045ND 0.053 0.056 sec-Butylbenzene mg/kg .049 113 10-189129 5 20.045ND 0.055 0.058 Styrene mg/kg .049 107 10-147120 4 20.045ND 0.052 0.054 tert-Butylbenzene mg/kg .049 88 10-168102 7 20.045ND 0.043 0.046 Tetrachloroethene mg/kg .049 104 14-156115 2 20.045ND 0.051 0.052 Toluene mg/kg .049 87 24-15198 3 20.045ND 0.043 0.044 trans-1,2-Dichloroethene mg/kg .049 104 33-147116 3 20.045ND 0.051 0.052 trans-1,3-Dichloropropene mg/kg .049 102 13-144114 3 20.045ND 0.050 0.052 trans-1,4-Dichloro-2-butene mg/kg .19 88 10-156100 4 20.18ND 0.17 0.18 Trichloroethene mg/kg .049 102 21-164113 2 20.045ND 0.050 0.051 Trichlorofluoromethane mg/kg .049 87 23-18793 2 20.045ND 0.042 0.042 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 39 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596643MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150303001 1596644 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Vinyl acetate mg/kg .19 68 10-15179 7 20.18ND 0.13 0.14 Vinyl chloride mg/kg .049 80 32-17789 3 20.045ND 0.039 0.040 Xylene (Total)mg/kg .15 105 12-148119 4 20.13ND 0.15 0.16 4-Bromofluorobenzene (S)%.95 65-12794 Dibromofluoromethane (S)%.91 70-12895 Toluene-d8 (S)%.97 72-13999 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 40 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344927 EPA 8260 EPA 8260 8260 MSV 5035A Volatile Organics Associated Lab Samples:50150303005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596645 Associated Lab Samples:50150303005 Matrix:Solid Analyzed 1,1,1,2-Tetrachloroethane mg/kg ND 0.0050 08/03/16 02:36 1,1,1-Trichloroethane mg/kg ND 0.0050 08/03/16 02:36 1,1,2,2-Tetrachloroethane mg/kg ND 0.0050 08/03/16 02:36 1,1,2-Trichloroethane mg/kg ND 0.0050 08/03/16 02:36 1,1-Dichloroethane mg/kg ND 0.0050 08/03/16 02:36 1,1-Dichloroethene mg/kg ND 0.0050 08/03/16 02:36 1,1-Dichloropropene mg/kg ND 0.0050 08/03/16 02:36 1,2,3-Trichlorobenzene mg/kg ND 0.0050 08/03/16 02:36 1,2,3-Trichloropropane mg/kg ND 0.0050 08/03/16 02:36 1,2,4-Trichlorobenzene mg/kg ND 0.0050 08/03/16 02:36 1,2,4-Trimethylbenzene mg/kg ND 0.0050 08/03/16 02:36 1,2-Dibromoethane (EDB)mg/kg ND 0.0050 08/03/16 02:36 1,2-Dichlorobenzene mg/kg ND 0.0050 08/03/16 02:36 1,2-Dichloroethane mg/kg ND 0.0050 08/03/16 02:36 1,2-Dichloropropane mg/kg ND 0.0050 08/03/16 02:36 1,3,5-Trimethylbenzene mg/kg ND 0.0050 08/03/16 02:36 1,3-Dichlorobenzene mg/kg ND 0.0050 08/03/16 02:36 1,3-Dichloropropane mg/kg ND 0.0050 08/03/16 02:36 1,4-Dichlorobenzene mg/kg ND 0.0050 08/03/16 02:36 2,2-Dichloropropane mg/kg ND 0.0050 08/03/16 02:36 2-Butanone (MEK)mg/kg ND 0.025 08/03/16 02:36 2-Chlorotoluene mg/kg ND 0.0050 08/03/16 02:36 2-Hexanone mg/kg ND 0.10 08/03/16 02:36 4-Chlorotoluene mg/kg ND 0.0050 08/03/16 02:36 4-Methyl-2-pentanone (MIBK)mg/kg ND 0.025 08/03/16 02:36 Acetone mg/kg ND 0.10 08/03/16 02:36 Acrolein mg/kg ND 0.10 08/03/16 02:36 Acrylonitrile mg/kg ND 0.10 08/03/16 02:36 Benzene mg/kg ND 0.0050 08/03/16 02:36 Bromobenzene mg/kg ND 0.0050 08/03/16 02:36 Bromochloromethane mg/kg ND 0.0050 08/03/16 02:36 Bromodichloromethane mg/kg ND 0.0050 08/03/16 02:36 Bromoform mg/kg ND 0.0050 08/03/16 02:36 Bromomethane mg/kg ND 0.0050 08/03/16 02:36 Carbon disulfide mg/kg ND 0.010 08/03/16 02:36 Carbon tetrachloride mg/kg ND 0.0050 08/03/16 02:36 Chlorobenzene mg/kg ND 0.0050 08/03/16 02:36 Chloroethane mg/kg ND 0.0050 08/03/16 02:36 Chloroform mg/kg ND 0.0050 08/03/16 02:36 Chloromethane mg/kg ND 0.0050 08/03/16 02:36 cis-1,2-Dichloroethene mg/kg ND 0.0050 08/03/16 02:36 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 41 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596645 Associated Lab Samples:50150303005 Matrix:Solid Analyzed cis-1,3-Dichloropropene mg/kg ND 0.0050 08/03/16 02:36 Dibromochloromethane mg/kg ND 0.0050 08/03/16 02:36 Dibromomethane mg/kg ND 0.0050 08/03/16 02:36 Dichlorodifluoromethane mg/kg ND 0.0050 08/03/16 02:36 Ethyl methacrylate mg/kg ND 0.10 08/03/16 02:36 Ethylbenzene mg/kg ND 0.0050 08/03/16 02:36 Hexachloro-1,3-butadiene mg/kg ND 0.0050 08/03/16 02:36 Iodomethane mg/kg ND 0.10 08/03/16 02:36 Isopropylbenzene (Cumene)mg/kg ND 0.0050 08/03/16 02:36 Methyl-tert-butyl ether mg/kg ND 0.0050 08/03/16 02:36 Methylene Chloride mg/kg ND 0.020 08/03/16 02:36 n-Butylbenzene mg/kg ND 0.0050 08/03/16 02:36 n-Hexane mg/kg ND 0.0050 08/03/16 02:36 n-Propylbenzene mg/kg ND 0.0050 08/03/16 02:36 Naphthalene mg/kg ND 0.0050 08/03/16 02:36 p-Isopropyltoluene mg/kg ND 0.0050 08/03/16 02:36 sec-Butylbenzene mg/kg ND 0.0050 08/03/16 02:36 Styrene mg/kg ND 0.0050 08/03/16 02:36 tert-Butylbenzene mg/kg ND 0.0050 08/03/16 02:36 Tetrachloroethene mg/kg ND 0.0050 08/03/16 02:36 Toluene mg/kg ND 0.0050 08/03/16 02:36 trans-1,2-Dichloroethene mg/kg ND 0.0050 08/03/16 02:36 trans-1,3-Dichloropropene mg/kg ND 0.0050 08/03/16 02:36 trans-1,4-Dichloro-2-butene mg/kg ND 0.10 08/03/16 02:36 Trichloroethene mg/kg ND 0.0050 08/03/16 02:36 Trichlorofluoromethane mg/kg ND 0.0050 08/03/16 02:36 Vinyl acetate mg/kg ND 0.10 08/03/16 02:36 Vinyl chloride mg/kg ND 0.0050 08/03/16 02:36 Xylene (Total)mg/kg ND 0.010 08/03/16 02:36 4-Bromofluorobenzene (S)%.93 65-127 08/03/16 02:36 Dibromofluoromethane (S)%.91 70-128 08/03/16 02:36 Toluene-d8 (S)%.95 72-139 08/03/16 02:36 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596646LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane mg/kg 0.055.05 109 71-125 1,1,1-Trichloroethane mg/kg 0.048.05 97 67-123 1,1,2,2-Tetrachloroethane mg/kg 0.053.05 105 67-129 1,1,2-Trichloroethane mg/kg 0.051.05 103 74-125 1,1-Dichloroethane mg/kg 0.048.05 95 69-115 1,1-Dichloroethene mg/kg 0.054.05 108 64-133 1,1-Dichloropropene mg/kg 0.049.05 97 79-127 1,2,3-Trichlorobenzene mg/kg 0.046.05 93 63-122 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 42 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596646LABORATORY CONTROL SAMPLE: LCSSpike 1,2,3-Trichloropropane mg/kg 0.049.05 97 79-130 1,2,4-Trichlorobenzene mg/kg 0.044.05 89 55-120 1,2,4-Trimethylbenzene mg/kg 0.048.05 96 66-118 1,2-Dibromoethane (EDB)mg/kg 0.055.05 110 79-117 1,2-Dichlorobenzene mg/kg 0.048.05 95 71-115 1,2-Dichloroethane mg/kg 0.042.05 84 71-121 1,2-Dichloropropane mg/kg 0.051.05 103 74-119 1,3,5-Trimethylbenzene mg/kg 0.049.05 98 67-118 1,3-Dichlorobenzene mg/kg 0.049.05 98 68-117 1,3-Dichloropropane mg/kg 0.052.05 103 75-121 1,4-Dichlorobenzene mg/kg 0.046.05 92 66-112 2,2-Dichloropropane mg/kg 0.044.05 89 63-126 2-Butanone (MEK)mg/kg 0.24.25 96 61-129 2-Chlorotoluene mg/kg 0.049.05 98 66-121 2-Hexanone mg/kg 0.23.25 91 68-136 4-Chlorotoluene mg/kg 0.047.05 95 67-118 4-Methyl-2-pentanone (MIBK)mg/kg 0.21.25 85 70-129 Acetone mg/kg 0.18.25 71 37-158 Acrolein mg/kg 1.11 113 46-200 Acrylonitrile mg/kg 0.18.2 89 70-120 Benzene mg/kg 0.052.05 105 72-120 Bromobenzene mg/kg 0.048.05 97 67-114 Bromochloromethane mg/kg 0.049.05 97 73-123 Bromodichloromethane mg/kg 0.050.05 99 72-114 Bromoform mg/kg 0.053.05 106 56-125 Bromomethane mg/kg 0.041.05 83 41-175 Carbon disulfide mg/kg 0.046.05 93 58-130 Carbon tetrachloride mg/kg 0.049.05 98 73-129 Chlorobenzene mg/kg 0.051.05 103 72-115 Chloroethane mg/kg 0.039.05 77 52-154 Chloroform mg/kg 0.042.05 84 66-116 Chloromethane mg/kg 0.029.05 58 49-139 cis-1,2-Dichloroethene mg/kg 0.051.05 101 74-115 cis-1,3-Dichloropropene mg/kg 0.053.05 106 74-122 Dibromochloromethane mg/kg 0.053.05 106 72-123 Dibromomethane mg/kg 0.050.05 101 78-118 Dichlorodifluoromethane mg/kg 0.053.05 106 31-182 Ethyl methacrylate mg/kg 0.22.2 110 73-136 Ethylbenzene mg/kg 0.052.05 105 70-121 Hexachloro-1,3-butadiene mg/kg 0.051.05 103 62-121 Iodomethane mg/kg 0.12.1 122 55-152 Isopropylbenzene (Cumene)mg/kg 0.053.05 106 78-130 Methyl-tert-butyl ether mg/kg 0.049.05 98 68-123 Methylene Chloride mg/kg 0.051.05 102 57-126 n-Butylbenzene mg/kg 0.048.05 96 61-121 n-Hexane mg/kg 0.046.05 92 64-124 n-Propylbenzene mg/kg 0.050.05 100 68-126 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 43 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596646LABORATORY CONTROL SAMPLE: LCSSpike Naphthalene mg/kg 0.052.05 104 63-125 p-Isopropyltoluene mg/kg 0.050.05 100 68-118 sec-Butylbenzene mg/kg 0.053.05 105 75-131 Styrene mg/kg 0.054.05 108 71-121 tert-Butylbenzene mg/kg 0.042.05 84 61-117 Tetrachloroethene mg/kg 0.050.05 101 66-118 Toluene mg/kg 0.044.05 88 68-121 trans-1,2-Dichloroethene mg/kg 0.055.05 110 71-120 trans-1,3-Dichloropropene mg/kg 0.049.05 98 72-127 trans-1,4-Dichloro-2-butene mg/kg 0.16.2 82 55-150 Trichloroethene mg/kg 0.051.05 101 73-120 Trichlorofluoromethane mg/kg 0.046.05 91 61-158 Vinyl acetate mg/kg 0.17.2 83 76-150 Vinyl chloride mg/kg 0.042.05 83 54-155 Xylene (Total)mg/kg 0.16.15 104 69-122 4-Bromofluorobenzene (S)%.97 65-127 Dibromofluoromethane (S)%.90 70-128 Toluene-d8 (S)%.98 72-139 Parameter Units MS Result % Rec Limits Qual% RecConc. 1596647MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150291006 1596648 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane mg/kg .047 103 24-143103 3 20.046ND 0.049 0.047 1,1,1-Trichloroethane mg/kg .047 106 37-144102 7 20.046ND 0.050 0.047 1,1,2,2-Tetrachloroethane mg/kg .047 106 12-174101 8 20.046ND 0.050 0.046 1,1,2-Trichloroethane mg/kg .047 99 34-15398 5 20.046ND 0.047 0.045 1,1-Dichloroethane mg/kg .047 104 39-139103 4 20.046ND 0.049 0.047 1,1-Dichloroethene mg/kg .047 116 36-162117 3 20.046ND 0.055 0.054 1,1-Dichloropropene mg/kg .047 104 36-152104 3 20.046ND 0.049 0.048 1,2,3-Trichlorobenzene mg/kg .047 47 10-11848 0 20.046ND 0.022 0.022 1,2,3-Trichloropropane mg/kg .047 113 25-186113 3 20.046ND 0.054 0.052 1,2,4-Trichlorobenzene mg/kg .047 55 10-11454 5 20.046ND 0.026 0.025 1,2,4-Trimethylbenzene mg/kg .047 100 10-15799 4 20.046ND 0.050 0.048 1,2-Dibromoethane (EDB)mg/kg .047 109 27-142112 0 20.046ND 0.051 0.051 1,2-Dichlorobenzene mg/kg .047 86 10-13384 5 20.046ND 0.041 0.039 1,2-Dichloroethane mg/kg .047 86 40-13887 2 20.046ND 0.041 0.040 1,2-Dichloropropane mg/kg .047 107 43-138108 3 20.046ND 0.051 0.049 1,3,5-Trimethylbenzene mg/kg .047 108 10-168103 9 20.046ND 0.052 0.048 1,3-Dichlorobenzene mg/kg .047 93 10-13892 5 20.046ND 0.044 0.042 1,3-Dichloropropane mg/kg .047 108 37-142110 2 20.046ND 0.051 0.050 1,4-Dichlorobenzene mg/kg .047 91 10-13086 9 20.046ND 0.043 0.039 2,2-Dichloropropane mg/kg .047 105 33-144105 3 20.046ND 0.050 0.048 2-Butanone (MEK)mg/kg .24 100 21-183102 1 20.23ND 0.24 0.23 2-Chlorotoluene mg/kg .047 107 10-165102 8 20.046ND 0.051 0.047 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 44 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596647MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150291006 1596648 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 2-Hexanone mg/kg .24 94 16-187100 2 20.23ND 0.22 0.23 4-Chlorotoluene mg/kg .047 106 10-150101 9 20.046ND 0.050 0.046 4-Methyl-2-pentanone (MIBK)mg/kg .24 87 33-16993 3 20.23ND 0.21 0.21 Acetone mg/kg .24 99 10-200103 1 20.23ND 0.23 0.24 Acrolein mg/kg .95 81 10-18984 0 20.92ND 0.77 0.77 Acrylonitrile mg/kg .19 99 18-16398 4 20.19ND 0.19 0.18 Benzene mg/kg .047 113 36-144111 5 20.046ND 0.057 0.054 Bromobenzene mg/kg .047 85 10-13585 4 20.046ND 0.041 0.039 Bromochloromethane mg/kg .047 101 41-14790 15 20.046ND 0.048 0.042 Bromodichloromethane mg/kg .047 96 23-13796 4 20.046ND 0.046 0.044 Bromoform mg/kg .047 106 10-147109 0 20.046ND 0.050 0.050 Bromomethane mg/kg .047 88 10-19693 3 20.046ND 0.042 0.043 Carbon disulfide mg/kg .047 96 22-15096 4 20.046ND 0.046 0.044 Carbon tetrachloride mg/kg .047 104 29-152104 3 20.046ND 0.049 0.048 Chlorobenzene mg/kg .047 101 16-14099 5 20.046ND 0.048 0.045 Chloroethane mg/kg .047 84 19-18286 1 20.046ND 0.040 0.039 Chloroform mg/kg .047 89 39-13689 4 20.046ND 0.042 0.041 Chloromethane mg/kg .047 72 21-16772 3 20.046ND 0.034 0.033 cis-1,2-Dichloroethene mg/kg .047 112 34-143110 5 20.046ND 0.053 0.051 cis-1,3-Dichloropropene mg/kg .047 110 19-145108 5 20.046ND 0.052 0.050 Dibromochloromethane mg/kg .047 110 18-142104 8 20.046ND 0.052 0.048 Dibromomethane mg/kg .047 100 35-140101 2 20.046ND 0.047 0.047 Dichlorodifluoromethane mg/kg .047 123 10-200120 6 20.046ND 0.058 0.055 Ethyl methacrylate mg/kg .19 79 10-16485 4 20.19ND 0.15 0.16 Ethylbenzene mg/kg .047 109 15-147105 7 20.046ND 0.054 0.050 Hexachloro-1,3-butadiene mg/kg .047 98 10-14699 3 20.046ND 0.047 0.045 Iodomethane mg/kg .095 136 16-166136 3 20.092ND 0.13 0.13 Isopropylbenzene (Cumene)mg/kg .047 108 10-163106 5 20.046ND 0.051 0.049 Methyl-tert-butyl ether mg/kg .047 102 48-145105 1 20.046ND 0.048 0.048 Methylene Chloride mg/kg .047 100 35-14298 5 20.046ND 0.054 0.051 n-Butylbenzene mg/kg .047 102 10-15997 9 20.046ND 0.049 0.044 n-Hexane mg/kg .047 122 17-158120 5 20.046ND 0.058 0.055 n-Propylbenzene mg/kg .047 120 10-176114 8 20.046ND 0.057 0.052 Naphthalene mg/kg .047 65 10-13269 3 20.046ND 0.032 0.033 p-Isopropyltoluene mg/kg .047 111 10-164107 7 20.046ND 0.052 0.049 sec-Butylbenzene mg/kg .047 126 10-189120 8 20.046ND 0.060 0.055 Styrene mg/kg .047 101 10-147101 4 20.046ND 0.048 0.046 tert-Butylbenzene mg/kg .047 101 10-16896 9 20.046ND 0.048 0.044 Tetrachloroethene mg/kg .047 111 14-156108 6 20.046ND 0.053 0.050 Toluene mg/kg .047 94 24-15191 5 20.0460.015 0.059 0.056 trans-1,2-Dichloroethene mg/kg .047 119 33-147115 6 20.046ND 0.056 0.053 trans-1,3-Dichloropropene mg/kg .047 99 13-144100 3 20.046ND 0.047 0.046 trans-1,4-Dichloro-2-butene mg/kg .19 76 10-15672 8 20.19ND 0.14 0.13 Trichloroethene mg/kg .047 110 21-164115 1 20.046ND 0.052 0.053 Trichlorofluoromethane mg/kg .047 106 23-187101 8 20.046ND 0.050 0.046 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 45 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596647MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150291006 1596648 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Vinyl acetate mg/kg .19 15 10-15114 20.19ND ND ND Vinyl chloride mg/kg .047 97 32-17797 3 20.046ND 0.046 0.045 Xylene (Total)mg/kg .15 107 12-148105 5 20.14ND 0.16 0.15 4-Bromofluorobenzene (S)%.91 65-12790 Dibromofluoromethane (S)%.93 70-12893 Toluene-d8 (S)%.100 72-139100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 46 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343508 EPA 3546 EPA 8082 8082 GCS PCB Associated Lab Samples:50150303004, 50150303005, 50150303006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1591086 Associated Lab Samples:50150303004, 50150303005, 50150303006 Matrix:Solid Analyzed PCB-1016 (Aroclor 1016)ug/kg ND 99.7 07/26/16 13:36 PCB-1221 (Aroclor 1221)ug/kg ND 99.7 07/26/16 13:36 PCB-1232 (Aroclor 1232)ug/kg ND 99.7 07/26/16 13:36 PCB-1242 (Aroclor 1242)ug/kg ND 99.7 07/26/16 13:36 PCB-1248 (Aroclor 1248)ug/kg ND 99.7 07/26/16 13:36 PCB-1254 (Aroclor 1254)ug/kg ND 99.7 07/26/16 13:36 PCB-1260 (Aroclor 1260)ug/kg ND 99.7 07/26/16 13:36 Tetrachloro-m-xylene (S)%.70 24-99 07/26/16 13:36 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591087LABORATORY CONTROL SAMPLE: LCSSpike PCB-1016 (Aroclor 1016)ug/kg 103166 62 40-107 PCB-1260 (Aroclor 1260)ug/kg 120166 72 41-110 Tetrachloro-m-xylene (S)%.73 24-99 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591088MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150303004 1591089 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. PCB-1016 (Aroclor 1016)ug/kg 191 39 10-14134 20193ND74.1J 65.7J PCB-1260 (Aroclor 1260)ug/kg 191 43 10-13142 20193ND82.2J 81.6J Tetrachloro-m-xylene (S)%.52 24-9955 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 47 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343497 EPA 3546 EPA 8270 by SIM 8270 MSSV PAH by SIM Associated Lab Samples:50150303002, 50150303003, 50150303004, 50150303005, 50150303006, 50150303007 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1591068 Associated Lab Samples:50150303002, 50150303003, 50150303004, 50150303005, 50150303006, 50150303007 Matrix:Solid Analyzed 1-Methylnaphthalene mg/kg ND 0.0050 N207/27/16 02:03 2-Methylnaphthalene mg/kg ND 0.0050 07/27/16 02:03 Acenaphthene mg/kg ND 0.0050 07/27/16 02:03 Acenaphthylene mg/kg ND 0.0050 07/27/16 02:03 Anthracene mg/kg ND 0.0050 07/27/16 02:03 Benzo(a)anthracene mg/kg ND 0.0050 07/27/16 02:03 Benzo(a)pyrene mg/kg ND 0.0050 07/27/16 02:03 Benzo(b)fluoranthene mg/kg ND 0.0050 07/27/16 02:03 Benzo(g,h,i)perylene mg/kg ND 0.0050 07/27/16 02:03 Benzo(k)fluoranthene mg/kg ND 0.0050 07/27/16 02:03 Chrysene mg/kg ND 0.0050 07/27/16 02:03 Dibenz(a,h)anthracene mg/kg ND 0.0050 07/27/16 02:03 Fluoranthene mg/kg ND 0.0050 07/27/16 02:03 Fluorene mg/kg ND 0.0050 07/27/16 02:03 Indeno(1,2,3-cd)pyrene mg/kg ND 0.0050 07/27/16 02:03 Naphthalene mg/kg ND 0.0050 07/27/16 02:03 Phenanthrene mg/kg ND 0.0050 07/27/16 02:03 Pyrene mg/kg ND 0.0050 07/27/16 02:03 2-Fluorobiphenyl (S)%.75 25-121 07/27/16 02:03 p-Terphenyl-d14 (S)%.85 27-124 07/27/16 02:03 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591069LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene mg/kg 0.25 N2.33 75 41-109 2-Methylnaphthalene mg/kg 0.24.33 73 39-109 Acenaphthene mg/kg 0.26.33 77 44-127 Acenaphthylene mg/kg 0.26.33 77 43-128 Anthracene mg/kg 0.27.33 82 49-131 Benzo(a)anthracene mg/kg 0.32.33 97 52-128 Benzo(a)pyrene mg/kg 0.23.33 68 54-141 Benzo(b)fluoranthene mg/kg 0.23.33 70 50-146 Benzo(g,h,i)perylene mg/kg 0.23.33 68 51-141 Benzo(k)fluoranthene mg/kg 0.23.33 68 55-139 Chrysene mg/kg 0.28.33 83 56-131 Dibenz(a,h)anthracene mg/kg 0.23.33 68 53-142 Fluoranthene mg/kg 0.29.33 86 51-139 Fluorene mg/kg 0.28.33 83 45-131 Indeno(1,2,3-cd)pyrene mg/kg 0.22.33 67 51-141 Naphthalene mg/kg 0.22.33 67 43-112 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 48 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591069LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene mg/kg 0.27.33 82 47-132 Pyrene mg/kg 0.28.33 85 55-130 2-Fluorobiphenyl (S)%.71 25-121 p-Terphenyl-d14 (S)%.76 27-124 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591070MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150291006 1591071 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene mg/kg N2.35 73 17-11875 3 20.35ND 0.25 0.26 2-Methylnaphthalene mg/kg .35 70 15-11872 3 20.35ND 0.24 0.25 Acenaphthene mg/kg .35 77 21-12579 4 20.35ND 0.26 0.27 Acenaphthylene mg/kg .35 77 21-12678 1 20.35ND 0.27 0.27 Anthracene mg/kg .35 79 15-13481 2 20.35ND 0.27 0.28 Benzo(a)anthracene mg/kg .35 90 14-12997 8 20.35ND 0.31 0.34 Benzo(a)pyrene mg/kg .35 66 10-14669 5 20.35ND 0.23 0.24 Benzo(b)fluoranthene mg/kg .35 67 10-14670 5 20.35ND 0.23 0.24 Benzo(g,h,i)perylene mg/kg .35 64 10-14266 2 20.35ND 0.22 0.23 Benzo(k)fluoranthene mg/kg .35 69 10-14771 2 20.35ND 0.24 0.24 Chrysene mg/kg .35 82 11-14084 2 20.35ND 0.28 0.29 Dibenz(a,h)anthracene mg/kg .35 62 16-13665 5 20.35ND 0.21 0.23 Fluoranthene mg/kg .35 84 10-14686 2 20.35ND 0.29 0.30 Fluorene mg/kg .35 81 20-13183 3 20.35ND 0.28 0.29 Indeno(1,2,3-cd)pyrene mg/kg .35 63 10-14665 4 20.35ND 0.22 0.23 Naphthalene mg/kg .35 69 15-12672 4 20.35ND 0.24 0.25 Phenanthrene mg/kg .35 82 10-14884 2 20.35ND 0.28 0.29 Pyrene mg/kg .35 83 14-13686 4 20.35ND 0.29 0.30 2-Fluorobiphenyl (S)%.73 25-12173 p-Terphenyl-d14 (S)%.76 27-12477 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 49 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343499 EPA 3546 EPA 8270 by SIM 8270 MSSV PAH by SIM Associated Lab Samples:50150303001 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1591072 Associated Lab Samples:50150303001 Matrix:Solid Analyzed 1-Methylnaphthalene mg/kg ND 0.0050 N207/27/16 18:15 2-Methylnaphthalene mg/kg ND 0.0050 07/27/16 18:15 Acenaphthene mg/kg ND 0.0050 07/27/16 18:15 Acenaphthylene mg/kg ND 0.0050 07/27/16 18:15 Anthracene mg/kg ND 0.0050 07/27/16 18:15 Benzo(a)anthracene mg/kg ND 0.0050 07/27/16 18:15 Benzo(a)pyrene mg/kg ND 0.0050 07/27/16 18:15 Benzo(b)fluoranthene mg/kg ND 0.0050 07/27/16 18:15 Benzo(g,h,i)perylene mg/kg ND 0.0050 07/27/16 18:15 Benzo(k)fluoranthene mg/kg ND 0.0050 07/27/16 18:15 Chrysene mg/kg ND 0.0050 07/27/16 18:15 Dibenz(a,h)anthracene mg/kg ND 0.0050 07/27/16 18:15 Fluoranthene mg/kg ND 0.0050 07/27/16 18:15 Fluorene mg/kg ND 0.0050 07/27/16 18:15 Indeno(1,2,3-cd)pyrene mg/kg ND 0.0050 07/27/16 18:15 Naphthalene mg/kg ND 0.0050 07/27/16 18:15 Phenanthrene mg/kg ND 0.0050 07/27/16 18:15 Pyrene mg/kg ND 0.0050 07/27/16 18:15 2-Fluorobiphenyl (S)%.49 25-121 07/27/16 18:15 p-Terphenyl-d14 (S)%.55 27-124 07/27/16 18:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591073LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene mg/kg 0.26 N2.33 79 41-109 2-Methylnaphthalene mg/kg 0.26.33 79 39-109 Acenaphthene mg/kg 0.28.33 86 44-127 Acenaphthylene mg/kg 0.27.33 84 43-128 Anthracene mg/kg 0.30.33 90 49-131 Benzo(a)anthracene mg/kg 0.32.33 98 52-128 Benzo(a)pyrene mg/kg 0.25.33 76 54-141 Benzo(b)fluoranthene mg/kg 0.24.33 74 50-146 Benzo(g,h,i)perylene mg/kg 0.25.33 75 51-141 Benzo(k)fluoranthene mg/kg 0.26.33 79 55-139 Chrysene mg/kg 0.32.33 98 56-131 Dibenz(a,h)anthracene mg/kg 0.24.33 73 53-142 Fluoranthene mg/kg 0.30.33 92 51-139 Fluorene mg/kg 0.29.33 87 45-131 Indeno(1,2,3-cd)pyrene mg/kg 0.24.33 73 51-141 Naphthalene mg/kg 0.25.33 77 43-112 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 50 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591073LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene mg/kg 0.30.33 93 47-132 Pyrene mg/kg 0.33.33 100 55-130 2-Fluorobiphenyl (S)%.74 25-121 p-Terphenyl-d14 (S)%.85 27-124 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591074MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150303001 1591075 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene mg/kg N2.37 65 17-11868 3 20.37ND 0.24 0.25 2-Methylnaphthalene mg/kg .37 65 15-11867 3 20.37ND 0.24 0.25 Acenaphthene mg/kg .37 71 21-12572 0 20.37ND 0.27 0.27 Acenaphthylene mg/kg .37 69 21-12671 1 20.37ND 0.26 0.26 Anthracene mg/kg .37 74 15-13473 1 20.37ND 0.27 0.27 Benzo(a)anthracene mg/kg .37 78 14-12976 3 20.37ND 0.29 0.28 Benzo(a)pyrene mg/kg .37 61 10-14659 5 20.37ND 0.23 0.22 Benzo(b)fluoranthene mg/kg .37 58 10-14656 4 20.37ND 0.22 0.21 Benzo(g,h,i)perylene mg/kg .37 61 10-14258 5 20.37ND 0.23 0.21 Benzo(k)fluoranthene mg/kg .37 66 10-14763 5 20.37ND 0.25 0.23 Chrysene mg/kg .37 80 11-14077 3 20.37ND 0.30 0.29 Dibenz(a,h)anthracene mg/kg .37 60 16-13656 6 20.37ND 0.22 0.21 Fluoranthene mg/kg .37 74 10-14673 2 20.37ND 0.28 0.27 Fluorene mg/kg .37 72 20-13172 0 20.37ND 0.27 0.27 Indeno(1,2,3-cd)pyrene mg/kg .37 59 10-14656 6 20.37ND 0.22 0.21 Naphthalene mg/kg .37 64 15-12666 4 20.37ND 0.24 0.25 Phenanthrene mg/kg .37 75 10-14874 1 20.37ND 0.28 0.28 Pyrene mg/kg .37 80 14-13678 2 20.37ND 0.30 0.29 2-Fluorobiphenyl (S)%.61 25-12163 p-Terphenyl-d14 (S)%.63 27-12464 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 51 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344625 SM 2540G SM 2540G Dry Weight/Percent Moisture Associated Lab Samples:50150303002, 50150303003, 50150303004, 50150303005, 50150303006, 50150303007 Parameter Units Dup Result Max RPD QualifiersRPDResult 50150580001 1595492SAMPLE DUPLICATE: Percent Moisture %72.1 R110565.4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 52 of 58 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150303 KMART Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344845 SM 2540G SM 2540G Dry Weight/Percent Moisture Associated Lab Samples:50150303001 Parameter Units Dup Result Max RPD QualifiersRPDResult 50150303001 1596342SAMPLE DUPLICATE: Percent Moisture %11.9 R114510.4 Parameter Units Dup Result Max RPD QualifiersRPDResult 50150364001 1596343SAMPLE DUPLICATE: Percent Moisture %15.5 R116513.2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 53 of 58 #=QL# QUALIFIERS Pace Project No.: Project: 50150303 KMART DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - IndianapolisPASI-I ANALYTE QUALIFIERS Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias.L3 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1 Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result.MS The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 54 of 58 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 50150303 KMART Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 50150303004 343508 343699KM-SB-SB-5 (008-009)EPA 3546 EPA 8082 50150303005 343508 343699KM-SB-SB-6 (008-009)EPA 3546 EPA 8082 50150303006 343508 343699KM-SB-SB-7 (008-009)EPA 3546 EPA 8082 50150303001 343473 344752KM-SB-SB-2 (008-009)EPA 3050 EPA 6010 50150303002 343473 344752KM-SB-SB-3 (008-009)EPA 3050 EPA 6010 50150303003 343473 344752KM-SB-SB-4 (007-008)EPA 3050 EPA 6010 50150303004 343473 344752KM-SB-SB-5 (008-009)EPA 3050 EPA 6010 50150303005 343473 344752KM-SB-SB-6 (008-009)EPA 3050 EPA 6010 50150303006 343473 344752KM-SB-SB-7 (008-009)EPA 3050 EPA 6010 50150303007 343473 344752KM-SB-FD-1 EPA 3050 EPA 6010 50150303001 343499 343841KM-SB-SB-2 (008-009)EPA 3546 EPA 8270 by SIM 50150303002 343497 343828KM-SB-SB-3 (008-009)EPA 3546 EPA 8270 by SIM 50150303003 343497 343828KM-SB-SB-4 (007-008)EPA 3546 EPA 8270 by SIM 50150303004 343497 343828KM-SB-SB-5 (008-009)EPA 3546 EPA 8270 by SIM 50150303005 343497 343828KM-SB-SB-6 (008-009)EPA 3546 EPA 8270 by SIM 50150303006 343497 343828KM-SB-SB-7 (008-009)EPA 3546 EPA 8270 by SIM 50150303007 343497 343828KM-SB-FD-1 EPA 3546 EPA 8270 by SIM 50150303009 344873TRIP BLANK EPA 8260 50150303001 344926KM-SB-SB-2 (008-009)EPA 8260 50150303002 344926KM-SB-SB-3 (008-009)EPA 8260 50150303003 344926KM-SB-SB-4 (007-008)EPA 8260 50150303004 344926KM-SB-SB-5 (008-009)EPA 8260 50150303005 344927KM-SB-SB-6 (008-009)EPA 8260 50150303006 344926KM-SB-SB-7 (008-009)EPA 8260 50150303007 344926KM-SB-FD-1 EPA 8260 50150303001 344845KM-SB-SB-2 (008-009)SM 2540G 50150303002 344625KM-SB-SB-3 (008-009)SM 2540G 50150303003 344625KM-SB-SB-4 (007-008)SM 2540G 50150303004 344625KM-SB-SB-5 (008-009)SM 2540G 50150303005 344625KM-SB-SB-6 (008-009)SM 2540G 50150303006 344625KM-SB-SB-7 (008-009)SM 2540G 50150303007 344625KM-SB-FD-1 SM 2540G REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/04/2016 06:04 PM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 55 of 58 Page 56 of 58 Page 57 of 58 Page 58 of 58 #=CL# August 05, 2016 LIMS USE: FR - GREG WAGGLE LIMS OBJECT ID: 50150369 50150369 Project: Pace Project No.: RE: Mr. Greg Waggle Symbiont 6737 W. Washington St. Suite 3440 Milwaukee, WI 53214 4850 W Western Ave South Bend Dear Mr. Waggle: Enclosed are the analytical results for sample(s) received by the laboratory on July 23, 2016. The results relate only to the samples included in this report. Results reported herein conform to the most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Mick Mayse mick.mayse@pacelabs.com Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 1 of 64 #=CP# CERTIFICATIONS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Indiana Certification IDs 7726 Moller Road, Indianapolis, IN 46268 Illinois Certification #: 200074 Indiana Certification #: C-49-06 Kansas/NELAP Certification #:E-10177 Kentucky UST Certification #: 0042 Kentucky WW Certification #:98019 Ohio VAP Certification #: CL-0065 Oklahoma Certification #: 2014-148 Texas Certification #: T104704355-15-9 West Virginia Certification #: 330 Wisconsin Certification #: 999788130 USDA Soil Permit #: P330-10-00128 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 2 of 64 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Lab ID Sample ID Matrix Date Collected Date Received 50150369001 KM-GW-SB-1 Water 07/22/16 09:35 07/23/16 08:50 50150369002 KM-GW-SB-2 Water 07/22/16 10:05 07/23/16 08:50 50150369003 KM-GW-SB-3 Water 07/22/16 11:45 07/23/16 08:50 50150369004 KM-GW-SB-4 Water 07/22/16 11:20 07/23/16 08:50 50150369005 KM-GW-SB-5 Water 07/22/16 11:05 07/23/16 08:50 50150369006 KM-GW-SB-6 Water 07/22/16 10:50 07/23/16 08:50 50150369007 KM-GW-SB-7 Water 07/22/16 10:25 07/23/16 08:50 50150369008 KM-GW-FD-1 Water 07/22/16 12:10 07/23/16 08:50 50150369009 KM-GW-ERB Water 07/22/16 12:25 07/23/16 08:50 50150369010 KM-GW-TB Water 07/22/16 08:00 07/23/16 08:50 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 3 of 64 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 50150369001 KM-GW-SB-1 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-IRSW 50150369002 KM-GW-SB-2 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-IRSW 50150369003 KM-GW-SB-3 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-IRSW 50150369004 KM-GW-SB-4 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-IRSW 50150369005 KM-GW-SB-5 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-IRSW 50150369006 KM-GW-SB-6 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-IRSW 50150369007 KM-GW-SB-7 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-IRSW 50150369008 KM-GW-FD-1 EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-IRSW 50150369009 KM-GW-ERB EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-IRSW 50150369010 KM-GW-TB EPA 6010 1 PASI-IJPK EPA 8270 by SIM LVE 20 PASI-ITBP EPA 8260 73 PASI-ICAP REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc.. Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 4 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-1 Lab ID:50150369001 Collected:07/22/16 09:35 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 24.3 ug/L 07/29/16 01:51 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/25/16 23:59 83-32-907/24/16 19:231.0 1 Acenaphthylene ND ug/L 07/25/16 23:59 208-96-807/24/16 19:231.0 1 Anthracene ND ug/L 07/25/16 23:59 120-12-707/24/16 19:230.10 1 Benzo(a)anthracene ND ug/L 07/25/16 23:59 56-55-307/24/16 19:230.10 1 Benzo(a)pyrene ND ug/L 07/25/16 23:59 50-32-807/24/16 19:230.10 1 Benzo(b)fluoranthene ND ug/L 07/25/16 23:59 205-99-207/24/16 19:230.10 1 Benzo(g,h,i)perylene ND ug/L 07/25/16 23:59 191-24-207/24/16 19:230.10 1 Benzo(k)fluoranthene ND ug/L 07/25/16 23:59 207-08-907/24/16 19:230.10 1 Chrysene ND ug/L 07/25/16 23:59 218-01-907/24/16 19:230.50 1 Dibenz(a,h)anthracene ND ug/L 07/25/16 23:59 53-70-307/24/16 19:230.10 1 Fluoranthene ND ug/L 07/25/16 23:59 206-44-007/24/16 19:231.0 1 Fluorene ND ug/L 07/25/16 23:59 86-73-707/24/16 19:231.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/25/16 23:59 193-39-507/24/16 19:230.10 1 1-Methylnaphthalene ND ug/L 07/25/16 23:59 90-12-0 N207/24/16 19:231.0 1 2-Methylnaphthalene ND ug/L 07/25/16 23:59 91-57-607/24/16 19:231.0 1 Naphthalene ND ug/L 07/25/16 23:59 91-20-307/24/16 19:231.0 1 Phenanthrene ND ug/L 07/25/16 23:59 85-01-807/24/16 19:231.0 1 Pyrene ND ug/L 07/25/16 23:59 129-00-007/24/16 19:231.0 1 Surrogates 2-Fluorobiphenyl (S)37 %.07/25/16 23:59 321-60-807/24/16 19:2318-117 1 p-Terphenyl-d14 (S)43 %.07/25/16 23:59 1718-51-007/24/16 19:2310-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 18:27 67-64-11001 Acrolein ND ug/L 08/02/16 18:27 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 18:27 107-13-11001 Benzene ND ug/L 08/02/16 18:27 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 18:27 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 18:27 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 18:27 75-27-45.0 1 Bromoform ND ug/L 08/02/16 18:27 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 18:27 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 18:27 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 18:27 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 18:27 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 18:27 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 18:27 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 18:27 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 18:27 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 18:27 75-00-35.0 1 Chloroform ND ug/L 08/02/16 18:27 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 18:27 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 18:27 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 5 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-1 Lab ID:50150369001 Collected:07/22/16 09:35 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 18:27 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 18:27 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 18:27 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 18:27 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 18:27 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 18:27 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 18:27 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 18:27 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 18:27 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 18:27 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 18:27 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 18:27 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 18:27 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 18:27 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 18:27 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 18:27 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 18:27 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 18:27 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 18:27 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 18:27 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 18:27 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 18:27 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 18:27 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 18:27 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 18:27 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 18:27 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 18:27 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 18:27 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 18:27 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 18:27 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 18:27 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 18:27 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 18:27 103-65-15.0 1 Styrene ND ug/L 08/02/16 18:27 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 18:27 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 18:27 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 18:27 127-18-45.0 1 Toluene ND ug/L 08/02/16 18:27 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 18:27 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 18:27 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 18:27 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 18:27 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 18:27 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 18:27 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 18:27 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 18:27 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 18:27 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 6 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-1 Lab ID:50150369001 Collected:07/22/16 09:35 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 18:27 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 18:27 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 18:27 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)99 %.08/02/16 18:27 1868-53-784-118 1 4-Bromofluorobenzene (S)97 %.08/02/16 18:27 460-00-479-116 1 Toluene-d8 (S)98 %.08/02/16 18:27 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 7 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-2 Lab ID:50150369002 Collected:07/22/16 10:05 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 28.7 ug/L 07/29/16 01:53 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 00:12 83-32-907/24/16 19:231.0 1 Acenaphthylene ND ug/L 07/26/16 00:12 208-96-807/24/16 19:231.0 1 Anthracene ND ug/L 07/26/16 00:12 120-12-707/24/16 19:230.10 1 Benzo(a)anthracene ND ug/L 07/26/16 00:12 56-55-307/24/16 19:230.10 1 Benzo(a)pyrene ND ug/L 07/26/16 00:12 50-32-807/24/16 19:230.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 00:12 205-99-207/24/16 19:230.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 00:12 191-24-207/24/16 19:230.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 00:12 207-08-907/24/16 19:230.10 1 Chrysene ND ug/L 07/26/16 00:12 218-01-907/24/16 19:230.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 00:12 53-70-307/24/16 19:230.10 1 Fluoranthene ND ug/L 07/26/16 00:12 206-44-007/24/16 19:231.0 1 Fluorene ND ug/L 07/26/16 00:12 86-73-707/24/16 19:231.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 00:12 193-39-507/24/16 19:230.10 1 1-Methylnaphthalene ND ug/L 07/26/16 00:12 90-12-0 N207/24/16 19:231.0 1 2-Methylnaphthalene ND ug/L 07/26/16 00:12 91-57-607/24/16 19:231.0 1 Naphthalene ND ug/L 07/26/16 00:12 91-20-307/24/16 19:231.0 1 Phenanthrene ND ug/L 07/26/16 00:12 85-01-807/24/16 19:231.0 1 Pyrene ND ug/L 07/26/16 00:12 129-00-007/24/16 19:231.0 1 Surrogates 2-Fluorobiphenyl (S)41 %.07/26/16 00:12 321-60-807/24/16 19:2318-117 1 p-Terphenyl-d14 (S)46 %.07/26/16 00:12 1718-51-007/24/16 19:2310-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 19:01 67-64-11001 Acrolein ND ug/L 08/02/16 19:01 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 19:01 107-13-11001 Benzene ND ug/L 08/02/16 19:01 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 19:01 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 19:01 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 19:01 75-27-45.0 1 Bromoform ND ug/L 08/02/16 19:01 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 19:01 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 19:01 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 19:01 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 19:01 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 19:01 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 19:01 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 19:01 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 19:01 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 19:01 75-00-35.0 1 Chloroform ND ug/L 08/02/16 19:01 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 19:01 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 19:01 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 8 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-2 Lab ID:50150369002 Collected:07/22/16 10:05 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 19:01 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 19:01 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 19:01 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 19:01 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 19:01 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 19:01 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 19:01 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 19:01 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 19:01 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 19:01 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 19:01 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 19:01 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 19:01 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 19:01 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 19:01 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 19:01 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 19:01 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 19:01 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 19:01 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 19:01 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 19:01 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 19:01 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 19:01 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 19:01 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 19:01 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 19:01 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 19:01 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 19:01 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 19:01 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 19:01 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 19:01 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 19:01 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 19:01 103-65-15.0 1 Styrene ND ug/L 08/02/16 19:01 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 19:01 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 19:01 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 19:01 127-18-45.0 1 Toluene ND ug/L 08/02/16 19:01 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 19:01 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 19:01 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 19:01 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 19:01 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 19:01 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 19:01 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 19:01 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 19:01 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 19:01 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 9 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-2 Lab ID:50150369002 Collected:07/22/16 10:05 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 19:01 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 19:01 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 19:01 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)102 %.08/02/16 19:01 1868-53-784-118 1 4-Bromofluorobenzene (S)98 %.08/02/16 19:01 460-00-479-116 1 Toluene-d8 (S)100 %.08/02/16 19:01 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 10 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-3 Lab ID:50150369003 Collected:07/22/16 11:45 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 18.0 ug/L 07/29/16 01:55 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 00:25 83-32-907/24/16 19:231.0 1 Acenaphthylene ND ug/L 07/26/16 00:25 208-96-807/24/16 19:231.0 1 Anthracene ND ug/L 07/26/16 00:25 120-12-707/24/16 19:230.10 1 Benzo(a)anthracene ND ug/L 07/26/16 00:25 56-55-307/24/16 19:230.10 1 Benzo(a)pyrene ND ug/L 07/26/16 00:25 50-32-807/24/16 19:230.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 00:25 205-99-207/24/16 19:230.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 00:25 191-24-207/24/16 19:230.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 00:25 207-08-907/24/16 19:230.10 1 Chrysene ND ug/L 07/26/16 00:25 218-01-907/24/16 19:230.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 00:25 53-70-307/24/16 19:230.10 1 Fluoranthene ND ug/L 07/26/16 00:25 206-44-007/24/16 19:231.0 1 Fluorene ND ug/L 07/26/16 00:25 86-73-707/24/16 19:231.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 00:25 193-39-507/24/16 19:230.10 1 1-Methylnaphthalene ND ug/L 07/26/16 00:25 90-12-0 N207/24/16 19:231.0 1 2-Methylnaphthalene ND ug/L 07/26/16 00:25 91-57-607/24/16 19:231.0 1 Naphthalene ND ug/L 07/26/16 00:25 91-20-307/24/16 19:231.0 1 Phenanthrene ND ug/L 07/26/16 00:25 85-01-807/24/16 19:231.0 1 Pyrene ND ug/L 07/26/16 00:25 129-00-007/24/16 19:231.0 1 Surrogates 2-Fluorobiphenyl (S)38 %.07/26/16 00:25 321-60-807/24/16 19:2318-117 1 p-Terphenyl-d14 (S)42 %.07/26/16 00:25 1718-51-007/24/16 19:2310-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 19:35 67-64-11001 Acrolein ND ug/L 08/02/16 19:35 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 19:35 107-13-11001 Benzene ND ug/L 08/02/16 19:35 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 19:35 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 19:35 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 19:35 75-27-45.0 1 Bromoform ND ug/L 08/02/16 19:35 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 19:35 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 19:35 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 19:35 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 19:35 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 19:35 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 19:35 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 19:35 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 19:35 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 19:35 75-00-35.0 1 Chloroform ND ug/L 08/02/16 19:35 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 19:35 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 19:35 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 11 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-3 Lab ID:50150369003 Collected:07/22/16 11:45 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 19:35 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 19:35 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 19:35 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 19:35 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 19:35 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 19:35 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 19:35 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 19:35 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 19:35 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 19:35 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 19:35 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 19:35 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 19:35 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 19:35 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 19:35 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 19:35 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 19:35 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 19:35 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 19:35 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 19:35 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 19:35 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 19:35 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 19:35 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 19:35 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 19:35 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 19:35 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 19:35 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 19:35 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 19:35 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 19:35 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 19:35 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 19:35 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 19:35 103-65-15.0 1 Styrene ND ug/L 08/02/16 19:35 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 19:35 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 19:35 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 19:35 127-18-45.0 1 Toluene ND ug/L 08/02/16 19:35 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 19:35 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 19:35 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 19:35 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 19:35 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 19:35 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 19:35 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 19:35 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 19:35 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 19:35 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 12 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-3 Lab ID:50150369003 Collected:07/22/16 11:45 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 19:35 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 19:35 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 19:35 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)99 %.08/02/16 19:35 1868-53-784-118 1 4-Bromofluorobenzene (S)96 %.08/02/16 19:35 460-00-479-116 1 Toluene-d8 (S)97 %.08/02/16 19:35 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 13 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-4 Lab ID:50150369004 Collected:07/22/16 11:20 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 76.2 ug/L 07/29/16 01:58 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 00:39 83-32-907/24/16 19:231.0 1 Acenaphthylene ND ug/L 07/26/16 00:39 208-96-807/24/16 19:231.0 1 Anthracene ND ug/L 07/26/16 00:39 120-12-707/24/16 19:230.10 1 Benzo(a)anthracene ND ug/L 07/26/16 00:39 56-55-307/24/16 19:230.10 1 Benzo(a)pyrene ND ug/L 07/26/16 00:39 50-32-807/24/16 19:230.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 00:39 205-99-207/24/16 19:230.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 00:39 191-24-207/24/16 19:230.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 00:39 207-08-907/24/16 19:230.10 1 Chrysene ND ug/L 07/26/16 00:39 218-01-907/24/16 19:230.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 00:39 53-70-307/24/16 19:230.10 1 Fluoranthene ND ug/L 07/26/16 00:39 206-44-007/24/16 19:231.0 1 Fluorene ND ug/L 07/26/16 00:39 86-73-707/24/16 19:231.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 00:39 193-39-507/24/16 19:230.10 1 1-Methylnaphthalene ND ug/L 07/26/16 00:39 90-12-0 N207/24/16 19:231.0 1 2-Methylnaphthalene ND ug/L 07/26/16 00:39 91-57-607/24/16 19:231.0 1 Naphthalene ND ug/L 07/26/16 00:39 91-20-307/24/16 19:231.0 1 Phenanthrene ND ug/L 07/26/16 00:39 85-01-807/24/16 19:231.0 1 Pyrene ND ug/L 07/26/16 00:39 129-00-007/24/16 19:231.0 1 Surrogates 2-Fluorobiphenyl (S)42 %.07/26/16 00:39 321-60-807/24/16 19:2318-117 1 p-Terphenyl-d14 (S)42 %.07/26/16 00:39 1718-51-007/24/16 19:2310-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 20:10 67-64-11001 Acrolein ND ug/L 08/02/16 20:10 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 20:10 107-13-11001 Benzene ND ug/L 08/02/16 20:10 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 20:10 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 20:10 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 20:10 75-27-45.0 1 Bromoform ND ug/L 08/02/16 20:10 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 20:10 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 20:10 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 20:10 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 20:10 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 20:10 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 20:10 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 20:10 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 20:10 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 20:10 75-00-35.0 1 Chloroform ND ug/L 08/02/16 20:10 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 20:10 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 20:10 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 14 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-4 Lab ID:50150369004 Collected:07/22/16 11:20 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 20:10 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 20:10 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 20:10 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 20:10 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 20:10 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 20:10 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 20:10 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 20:10 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 20:10 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 20:10 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 20:10 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 20:10 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 20:10 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 20:10 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 20:10 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 20:10 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 20:10 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 20:10 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 20:10 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 20:10 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 20:10 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 20:10 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 20:10 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 20:10 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 20:10 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 20:10 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 20:10 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 20:10 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 20:10 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 20:10 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 20:10 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 20:10 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 20:10 103-65-15.0 1 Styrene ND ug/L 08/02/16 20:10 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 20:10 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 20:10 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 20:10 127-18-45.0 1 Toluene ND ug/L 08/02/16 20:10 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 20:10 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 20:10 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 20:10 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 20:10 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 20:10 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 20:10 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 20:10 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 20:10 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 20:10 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 15 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-4 Lab ID:50150369004 Collected:07/22/16 11:20 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 20:10 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 20:10 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 20:10 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)103 %.08/02/16 20:10 1868-53-784-118 1 4-Bromofluorobenzene (S)101 %.08/02/16 20:10 460-00-479-116 1 Toluene-d8 (S)99 %.08/02/16 20:10 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 16 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-5 Lab ID:50150369005 Collected:07/22/16 11:05 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 40.4 ug/L 07/29/16 02:00 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 00:52 83-32-907/24/16 19:231.0 1 Acenaphthylene ND ug/L 07/26/16 00:52 208-96-807/24/16 19:231.0 1 Anthracene ND ug/L 07/26/16 00:52 120-12-707/24/16 19:230.10 1 Benzo(a)anthracene ND ug/L 07/26/16 00:52 56-55-307/24/16 19:230.10 1 Benzo(a)pyrene ND ug/L 07/26/16 00:52 50-32-807/24/16 19:230.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 00:52 205-99-207/24/16 19:230.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 00:52 191-24-207/24/16 19:230.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 00:52 207-08-907/24/16 19:230.10 1 Chrysene ND ug/L 07/26/16 00:52 218-01-907/24/16 19:230.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 00:52 53-70-307/24/16 19:230.10 1 Fluoranthene ND ug/L 07/26/16 00:52 206-44-007/24/16 19:231.0 1 Fluorene ND ug/L 07/26/16 00:52 86-73-707/24/16 19:231.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 00:52 193-39-507/24/16 19:230.10 1 1-Methylnaphthalene ND ug/L 07/26/16 00:52 90-12-0 N207/24/16 19:231.0 1 2-Methylnaphthalene ND ug/L 07/26/16 00:52 91-57-607/24/16 19:231.0 1 Naphthalene ND ug/L 07/26/16 00:52 91-20-307/24/16 19:231.0 1 Phenanthrene ND ug/L 07/26/16 00:52 85-01-807/24/16 19:231.0 1 Pyrene ND ug/L 07/26/16 00:52 129-00-007/24/16 19:231.0 1 Surrogates 2-Fluorobiphenyl (S)39 %.07/26/16 00:52 321-60-807/24/16 19:2318-117 1 p-Terphenyl-d14 (S)35 %.07/26/16 00:52 1718-51-007/24/16 19:2310-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 20:44 67-64-11001 Acrolein ND ug/L 08/02/16 20:44 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 20:44 107-13-11001 Benzene ND ug/L 08/02/16 20:44 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 20:44 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 20:44 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 20:44 75-27-45.0 1 Bromoform ND ug/L 08/02/16 20:44 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 20:44 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 20:44 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 20:44 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 20:44 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 20:44 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 20:44 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 20:44 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 20:44 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 20:44 75-00-35.0 1 Chloroform ND ug/L 08/02/16 20:44 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 20:44 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 20:44 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 17 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-5 Lab ID:50150369005 Collected:07/22/16 11:05 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 20:44 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 20:44 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 20:44 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 20:44 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 20:44 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 20:44 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 20:44 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 20:44 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 20:44 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 20:44 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 20:44 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 20:44 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 20:44 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 20:44 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 20:44 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 20:44 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 20:44 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 20:44 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 20:44 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 20:44 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 20:44 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 20:44 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 20:44 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 20:44 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 20:44 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 20:44 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 20:44 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 20:44 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 20:44 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 20:44 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 20:44 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 20:44 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 20:44 103-65-15.0 1 Styrene ND ug/L 08/02/16 20:44 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 20:44 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 20:44 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 20:44 127-18-45.0 1 Toluene ND ug/L 08/02/16 20:44 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 20:44 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 20:44 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 20:44 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 20:44 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 20:44 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 20:44 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 20:44 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 20:44 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 20:44 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 18 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-5 Lab ID:50150369005 Collected:07/22/16 11:05 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 20:44 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 20:44 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 20:44 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)100 %.08/02/16 20:44 1868-53-784-118 1 4-Bromofluorobenzene (S)99 %.08/02/16 20:44 460-00-479-116 1 Toluene-d8 (S)100 %.08/02/16 20:44 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 19 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-6 Lab ID:50150369006 Collected:07/22/16 10:50 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 16.0 ug/L 07/29/16 02:02 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 01:05 83-32-907/24/16 19:231.0 1 Acenaphthylene ND ug/L 07/26/16 01:05 208-96-807/24/16 19:231.0 1 Anthracene ND ug/L 07/26/16 01:05 120-12-707/24/16 19:230.10 1 Benzo(a)anthracene ND ug/L 07/26/16 01:05 56-55-307/24/16 19:230.10 1 Benzo(a)pyrene ND ug/L 07/26/16 01:05 50-32-807/24/16 19:230.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 01:05 205-99-207/24/16 19:230.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 01:05 191-24-207/24/16 19:230.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 01:05 207-08-907/24/16 19:230.10 1 Chrysene ND ug/L 07/26/16 01:05 218-01-907/24/16 19:230.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 01:05 53-70-307/24/16 19:230.10 1 Fluoranthene ND ug/L 07/26/16 01:05 206-44-007/24/16 19:231.0 1 Fluorene ND ug/L 07/26/16 01:05 86-73-707/24/16 19:231.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 01:05 193-39-507/24/16 19:230.10 1 1-Methylnaphthalene ND ug/L 07/26/16 01:05 90-12-0 N207/24/16 19:231.0 1 2-Methylnaphthalene ND ug/L 07/26/16 01:05 91-57-607/24/16 19:231.0 1 Naphthalene ND ug/L 07/26/16 01:05 91-20-307/24/16 19:231.0 1 Phenanthrene ND ug/L 07/26/16 01:05 85-01-807/24/16 19:231.0 1 Pyrene ND ug/L 07/26/16 01:05 129-00-007/24/16 19:231.0 1 Surrogates 2-Fluorobiphenyl (S)44 %.07/26/16 01:05 321-60-807/24/16 19:2318-117 1 p-Terphenyl-d14 (S)45 %.07/26/16 01:05 1718-51-007/24/16 19:2310-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 21:19 67-64-11001 Acrolein ND ug/L 08/02/16 21:19 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 21:19 107-13-11001 Benzene ND ug/L 08/02/16 21:19 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 21:19 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 21:19 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 21:19 75-27-45.0 1 Bromoform ND ug/L 08/02/16 21:19 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 21:19 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 21:19 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 21:19 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 21:19 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 21:19 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 21:19 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 21:19 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 21:19 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 21:19 75-00-35.0 1 Chloroform ND ug/L 08/02/16 21:19 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 21:19 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 21:19 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 20 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-6 Lab ID:50150369006 Collected:07/22/16 10:50 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 21:19 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 21:19 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 21:19 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 21:19 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 21:19 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 21:19 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 21:19 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 21:19 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 21:19 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 21:19 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 21:19 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 21:19 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 21:19 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 21:19 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 21:19 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 21:19 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 21:19 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 21:19 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 21:19 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 21:19 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 21:19 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 21:19 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 21:19 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 21:19 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 21:19 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 21:19 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 21:19 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 21:19 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 21:19 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 21:19 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 21:19 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 21:19 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 21:19 103-65-15.0 1 Styrene ND ug/L 08/02/16 21:19 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 21:19 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 21:19 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 21:19 127-18-45.0 1 Toluene ND ug/L 08/02/16 21:19 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 21:19 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 21:19 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 21:19 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 21:19 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 21:19 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 21:19 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 21:19 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 21:19 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 21:19 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 21 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-6 Lab ID:50150369006 Collected:07/22/16 10:50 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 21:19 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 21:19 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 21:19 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)103 %.08/02/16 21:19 1868-53-784-118 1 4-Bromofluorobenzene (S)98 %.08/02/16 21:19 460-00-479-116 1 Toluene-d8 (S)98 %.08/02/16 21:19 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 22 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-7 Lab ID:50150369007 Collected:07/22/16 10:25 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead 28.1 ug/L 07/29/16 02:04 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 09:58 83-32-907/24/16 18:181.0 1 Acenaphthylene ND ug/L 07/26/16 09:58 208-96-807/24/16 18:181.0 1 Anthracene ND ug/L 07/26/16 09:58 120-12-707/24/16 18:180.10 1 Benzo(a)anthracene ND ug/L 07/26/16 09:58 56-55-307/24/16 18:180.10 1 Benzo(a)pyrene ND ug/L 07/26/16 09:58 50-32-807/24/16 18:180.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 09:58 205-99-207/24/16 18:180.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 09:58 191-24-207/24/16 18:180.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 09:58 207-08-907/24/16 18:180.10 1 Chrysene ND ug/L 07/26/16 09:58 218-01-907/24/16 18:180.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 09:58 53-70-307/24/16 18:180.10 1 Fluoranthene ND ug/L 07/26/16 09:58 206-44-007/24/16 18:181.0 1 Fluorene ND ug/L 07/26/16 09:58 86-73-707/24/16 18:181.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 09:58 193-39-507/24/16 18:180.10 1 1-Methylnaphthalene ND ug/L 07/26/16 09:58 90-12-0 N207/24/16 18:181.0 1 2-Methylnaphthalene ND ug/L 07/26/16 09:58 91-57-607/24/16 18:181.0 1 Naphthalene ND ug/L 07/26/16 09:58 91-20-307/24/16 18:181.0 1 Phenanthrene ND ug/L 07/26/16 09:58 85-01-807/24/16 18:181.0 1 Pyrene ND ug/L 07/26/16 09:58 129-00-007/24/16 18:181.0 1 Surrogates 2-Fluorobiphenyl (S)37 %.07/26/16 09:58 321-60-807/24/16 18:1818-117 1 p-Terphenyl-d14 (S)49 %.07/26/16 09:58 1718-51-007/24/16 18:1810-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 21:53 67-64-11001 Acrolein ND ug/L 08/02/16 21:53 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 21:53 107-13-11001 Benzene ND ug/L 08/02/16 21:53 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 21:53 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 21:53 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 21:53 75-27-45.0 1 Bromoform ND ug/L 08/02/16 21:53 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 21:53 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 21:53 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 21:53 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 21:53 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 21:53 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 21:53 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 21:53 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 21:53 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 21:53 75-00-35.0 1 Chloroform ND ug/L 08/02/16 21:53 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 21:53 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 21:53 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 23 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-7 Lab ID:50150369007 Collected:07/22/16 10:25 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 21:53 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 21:53 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 21:53 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 21:53 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 21:53 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 21:53 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 21:53 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 21:53 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 21:53 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 21:53 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 21:53 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 21:53 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 21:53 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 21:53 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 21:53 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 21:53 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 21:53 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 21:53 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 21:53 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 21:53 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 21:53 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 21:53 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 21:53 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 21:53 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 21:53 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 21:53 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 21:53 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 21:53 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 21:53 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 21:53 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 21:53 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 21:53 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 21:53 103-65-15.0 1 Styrene ND ug/L 08/02/16 21:53 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 21:53 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 21:53 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 21:53 127-18-45.0 1 Toluene ND ug/L 08/02/16 21:53 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 21:53 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 21:53 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 21:53 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 21:53 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 21:53 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 21:53 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 21:53 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 21:53 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 21:53 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 24 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-SB-7 Lab ID:50150369007 Collected:07/22/16 10:25 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 21:53 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 21:53 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 21:53 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)101 %.08/02/16 21:53 1868-53-784-118 1 4-Bromofluorobenzene (S)97 %.08/02/16 21:53 460-00-479-116 1 Toluene-d8 (S)99 %.08/02/16 21:53 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 25 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-FD-1 Lab ID:50150369008 Collected:07/22/16 12:10 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead ND ug/L 07/29/16 02:09 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 10:11 83-32-907/24/16 18:181.0 1 Acenaphthylene ND ug/L 07/26/16 10:11 208-96-807/24/16 18:181.0 1 Anthracene ND ug/L 07/26/16 10:11 120-12-707/24/16 18:180.10 1 Benzo(a)anthracene ND ug/L 07/26/16 10:11 56-55-307/24/16 18:180.10 1 Benzo(a)pyrene ND ug/L 07/26/16 10:11 50-32-807/24/16 18:180.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 10:11 205-99-207/24/16 18:180.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 10:11 191-24-207/24/16 18:180.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 10:11 207-08-907/24/16 18:180.10 1 Chrysene ND ug/L 07/26/16 10:11 218-01-907/24/16 18:180.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 10:11 53-70-307/24/16 18:180.10 1 Fluoranthene ND ug/L 07/26/16 10:11 206-44-007/24/16 18:181.0 1 Fluorene ND ug/L 07/26/16 10:11 86-73-707/24/16 18:181.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 10:11 193-39-507/24/16 18:180.10 1 1-Methylnaphthalene ND ug/L 07/26/16 10:11 90-12-0 N207/24/16 18:181.0 1 2-Methylnaphthalene ND ug/L 07/26/16 10:11 91-57-607/24/16 18:181.0 1 Naphthalene ND ug/L 07/26/16 10:11 91-20-307/24/16 18:181.0 1 Phenanthrene ND ug/L 07/26/16 10:11 85-01-807/24/16 18:181.0 1 Pyrene ND ug/L 07/26/16 10:11 129-00-007/24/16 18:181.0 1 Surrogates 2-Fluorobiphenyl (S)36 %.07/26/16 10:11 321-60-807/24/16 18:1818-117 1 p-Terphenyl-d14 (S)45 %.07/26/16 10:11 1718-51-007/24/16 18:1810-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/02/16 22:27 67-64-11001 Acrolein ND ug/L 08/02/16 22:27 107-02-850.0 1 Acrylonitrile ND ug/L 08/02/16 22:27 107-13-11001 Benzene ND ug/L 08/02/16 22:27 71-43-25.0 1 Bromobenzene ND ug/L 08/02/16 22:27 108-86-15.0 1 Bromochloromethane ND ug/L 08/02/16 22:27 74-97-55.0 1 Bromodichloromethane ND ug/L 08/02/16 22:27 75-27-45.0 1 Bromoform ND ug/L 08/02/16 22:27 75-25-25.0 1 Bromomethane ND ug/L 08/02/16 22:27 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/02/16 22:27 78-93-325.0 1 n-Butylbenzene ND ug/L 08/02/16 22:27 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/02/16 22:27 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/02/16 22:27 98-06-65.0 1 Carbon disulfide ND ug/L 08/02/16 22:27 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/02/16 22:27 56-23-55.0 1 Chlorobenzene ND ug/L 08/02/16 22:27 108-90-75.0 1 Chloroethane ND ug/L 08/02/16 22:27 75-00-35.0 1 Chloroform ND ug/L 08/02/16 22:27 67-66-35.0 1 Chloromethane ND ug/L 08/02/16 22:27 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/02/16 22:27 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 26 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-FD-1 Lab ID:50150369008 Collected:07/22/16 12:10 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/02/16 22:27 106-43-45.0 1 Dibromochloromethane ND ug/L 08/02/16 22:27 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/02/16 22:27 106-93-45.0 1 Dibromomethane ND ug/L 08/02/16 22:27 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/02/16 22:27 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/02/16 22:27 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/02/16 22:27 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/02/16 22:27 110-57-61001 Dichlorodifluoromethane ND ug/L 08/02/16 22:27 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/02/16 22:27 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/02/16 22:27 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/02/16 22:27 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/02/16 22:27 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/02/16 22:27 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/02/16 22:27 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/02/16 22:27 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/02/16 22:27 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/02/16 22:27 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/02/16 22:27 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/02/16 22:27 10061-02-65.0 1 Ethylbenzene ND ug/L 08/02/16 22:27 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/02/16 22:27 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/02/16 22:27 87-68-35.0 1 n-Hexane ND ug/L 08/02/16 22:27 110-54-35.0 1 2-Hexanone ND ug/L 08/02/16 22:27 591-78-625.0 1 Iodomethane ND ug/L 08/02/16 22:27 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/02/16 22:27 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/02/16 22:27 99-87-65.0 1 Methylene Chloride ND ug/L 08/02/16 22:27 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/02/16 22:27 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/02/16 22:27 1634-04-44.0 1 Naphthalene ND ug/L 08/02/16 22:27 91-20-35.0 1 n-Propylbenzene ND ug/L 08/02/16 22:27 103-65-15.0 1 Styrene ND ug/L 08/02/16 22:27 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/02/16 22:27 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/02/16 22:27 79-34-55.0 1 Tetrachloroethene ND ug/L 08/02/16 22:27 127-18-45.0 1 Toluene ND ug/L 08/02/16 22:27 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/02/16 22:27 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/02/16 22:27 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/02/16 22:27 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/02/16 22:27 79-00-55.0 1 Trichloroethene ND ug/L 08/02/16 22:27 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/02/16 22:27 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/02/16 22:27 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/02/16 22:27 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/02/16 22:27 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 27 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-FD-1 Lab ID:50150369008 Collected:07/22/16 12:10 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/02/16 22:27 108-05-450.0 1 Vinyl chloride ND ug/L 08/02/16 22:27 75-01-42.0 1 Xylene (Total)ND ug/L 08/02/16 22:27 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)102 %.08/02/16 22:27 1868-53-784-118 1 4-Bromofluorobenzene (S)100 %.08/02/16 22:27 460-00-479-116 1 Toluene-d8 (S)99 %.08/02/16 22:27 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 28 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-ERB Lab ID:50150369009 Collected:07/22/16 12:25 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead ND ug/L 07/29/16 02:24 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 10:51 83-32-907/24/16 18:181.0 1 Acenaphthylene ND ug/L 07/26/16 10:51 208-96-807/24/16 18:181.0 1 Anthracene ND ug/L 07/26/16 10:51 120-12-707/24/16 18:180.10 1 Benzo(a)anthracene ND ug/L 07/26/16 10:51 56-55-307/24/16 18:180.10 1 Benzo(a)pyrene ND ug/L 07/26/16 10:51 50-32-807/24/16 18:180.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 10:51 205-99-207/24/16 18:180.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 10:51 191-24-207/24/16 18:180.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 10:51 207-08-907/24/16 18:180.10 1 Chrysene ND ug/L 07/26/16 10:51 218-01-907/24/16 18:180.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 10:51 53-70-307/24/16 18:180.10 1 Fluoranthene ND ug/L 07/26/16 10:51 206-44-007/24/16 18:181.0 1 Fluorene ND ug/L 07/26/16 10:51 86-73-707/24/16 18:181.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 10:51 193-39-507/24/16 18:180.10 1 1-Methylnaphthalene ND ug/L 07/26/16 10:51 90-12-0 N207/24/16 18:181.0 1 2-Methylnaphthalene ND ug/L 07/26/16 10:51 91-57-607/24/16 18:181.0 1 Naphthalene ND ug/L 07/26/16 10:51 91-20-307/24/16 18:181.0 1 Phenanthrene ND ug/L 07/26/16 10:51 85-01-807/24/16 18:181.0 1 Pyrene ND ug/L 07/26/16 10:51 129-00-007/24/16 18:181.0 1 Surrogates 2-Fluorobiphenyl (S)35 %.07/26/16 10:51 321-60-807/24/16 18:1818-117 1 p-Terphenyl-d14 (S)52 %.07/26/16 10:51 1718-51-007/24/16 18:1810-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/03/16 08:11 67-64-11001 Acrolein ND ug/L 08/03/16 08:11 107-02-850.0 1 Acrylonitrile ND ug/L 08/03/16 08:11 107-13-11001 Benzene ND ug/L 08/03/16 08:11 71-43-25.0 1 Bromobenzene ND ug/L 08/03/16 08:11 108-86-15.0 1 Bromochloromethane ND ug/L 08/03/16 08:11 74-97-55.0 1 Bromodichloromethane ND ug/L 08/03/16 08:11 75-27-45.0 1 Bromoform ND ug/L 08/03/16 08:11 75-25-25.0 1 Bromomethane ND ug/L 08/03/16 08:11 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/03/16 08:11 78-93-325.0 1 n-Butylbenzene ND ug/L 08/03/16 08:11 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/03/16 08:11 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/03/16 08:11 98-06-65.0 1 Carbon disulfide ND ug/L 08/03/16 08:11 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/03/16 08:11 56-23-55.0 1 Chlorobenzene ND ug/L 08/03/16 08:11 108-90-75.0 1 Chloroethane ND ug/L 08/03/16 08:11 75-00-35.0 1 Chloroform ND ug/L 08/03/16 08:11 67-66-35.0 1 Chloromethane ND ug/L 08/03/16 08:11 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/03/16 08:11 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 29 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-ERB Lab ID:50150369009 Collected:07/22/16 12:25 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/03/16 08:11 106-43-45.0 1 Dibromochloromethane ND ug/L 08/03/16 08:11 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/03/16 08:11 106-93-45.0 1 Dibromomethane ND ug/L 08/03/16 08:11 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/03/16 08:11 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/03/16 08:11 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/03/16 08:11 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/03/16 08:11 110-57-61001 Dichlorodifluoromethane ND ug/L 08/03/16 08:11 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/03/16 08:11 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/03/16 08:11 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/03/16 08:11 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/03/16 08:11 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/03/16 08:11 156-60-5 L35.0 1 1,2-Dichloropropane ND ug/L 08/03/16 08:11 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/03/16 08:11 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/03/16 08:11 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/03/16 08:11 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/03/16 08:11 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/03/16 08:11 10061-02-65.0 1 Ethylbenzene ND ug/L 08/03/16 08:11 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/03/16 08:11 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/03/16 08:11 87-68-35.0 1 n-Hexane ND ug/L 08/03/16 08:11 110-54-35.0 1 2-Hexanone ND ug/L 08/03/16 08:11 591-78-625.0 1 Iodomethane ND ug/L 08/03/16 08:11 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/03/16 08:11 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/03/16 08:11 99-87-65.0 1 Methylene Chloride ND ug/L 08/03/16 08:11 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/03/16 08:11 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/03/16 08:11 1634-04-44.0 1 Naphthalene ND ug/L 08/03/16 08:11 91-20-35.0 1 n-Propylbenzene ND ug/L 08/03/16 08:11 103-65-15.0 1 Styrene ND ug/L 08/03/16 08:11 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/03/16 08:11 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/03/16 08:11 79-34-55.0 1 Tetrachloroethene ND ug/L 08/03/16 08:11 127-18-45.0 1 Toluene ND ug/L 08/03/16 08:11 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/03/16 08:11 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/03/16 08:11 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/03/16 08:11 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/03/16 08:11 79-00-55.0 1 Trichloroethene ND ug/L 08/03/16 08:11 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/03/16 08:11 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/03/16 08:11 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/03/16 08:11 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/03/16 08:11 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 30 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-ERB Lab ID:50150369009 Collected:07/22/16 12:25 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/03/16 08:11 108-05-450.0 1 Vinyl chloride ND ug/L 08/03/16 08:11 75-01-42.0 1 Xylene (Total)ND ug/L 08/03/16 08:11 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)100 %.08/03/16 08:11 1868-53-784-118 1 4-Bromofluorobenzene (S)98 %.08/03/16 08:11 460-00-479-116 1 Toluene-d8 (S)97 %.08/03/16 08:11 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 31 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-TB Lab ID:50150369010 Collected:07/22/16 08:00 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 6010 Preparation Method: EPA 30106010 MET ICP Lead ND ug/L 07/29/16 02:26 7439-92-107/28/16 07:1910.0 1 Analytical Method: EPA 8270 by SIM LVE Preparation Method: EPA 35108270 MSSV PAHLV Acenaphthene ND ug/L 07/26/16 11:05 83-32-907/24/16 18:181.0 1 Acenaphthylene ND ug/L 07/26/16 11:05 208-96-807/24/16 18:181.0 1 Anthracene ND ug/L 07/26/16 11:05 120-12-707/24/16 18:180.10 1 Benzo(a)anthracene ND ug/L 07/26/16 11:05 56-55-307/24/16 18:180.10 1 Benzo(a)pyrene ND ug/L 07/26/16 11:05 50-32-807/24/16 18:180.10 1 Benzo(b)fluoranthene ND ug/L 07/26/16 11:05 205-99-207/24/16 18:180.10 1 Benzo(g,h,i)perylene ND ug/L 07/26/16 11:05 191-24-207/24/16 18:180.10 1 Benzo(k)fluoranthene ND ug/L 07/26/16 11:05 207-08-907/24/16 18:180.10 1 Chrysene ND ug/L 07/26/16 11:05 218-01-907/24/16 18:180.50 1 Dibenz(a,h)anthracene ND ug/L 07/26/16 11:05 53-70-307/24/16 18:180.10 1 Fluoranthene ND ug/L 07/26/16 11:05 206-44-007/24/16 18:181.0 1 Fluorene ND ug/L 07/26/16 11:05 86-73-707/24/16 18:181.0 1 Indeno(1,2,3-cd)pyrene ND ug/L 07/26/16 11:05 193-39-507/24/16 18:180.10 1 1-Methylnaphthalene ND ug/L 07/26/16 11:05 90-12-0 N207/24/16 18:181.0 1 2-Methylnaphthalene ND ug/L 07/26/16 11:05 91-57-607/24/16 18:181.0 1 Naphthalene ND ug/L 07/26/16 11:05 91-20-307/24/16 18:181.0 1 Phenanthrene ND ug/L 07/26/16 11:05 85-01-807/24/16 18:181.0 1 Pyrene ND ug/L 07/26/16 11:05 129-00-007/24/16 18:181.0 1 Surrogates 2-Fluorobiphenyl (S)36 %.07/26/16 11:05 321-60-807/24/16 18:1818-117 1 p-Terphenyl-d14 (S)51 %.07/26/16 11:05 1718-51-007/24/16 18:1810-112 1 Analytical Method: EPA 82608260 MSV Acetone ND ug/L 08/03/16 15:25 67-64-11001 Acrolein ND ug/L 08/03/16 15:25 107-02-850.0 1 Acrylonitrile ND ug/L 08/03/16 15:25 107-13-11001 Benzene ND ug/L 08/03/16 15:25 71-43-25.0 1 Bromobenzene ND ug/L 08/03/16 15:25 108-86-15.0 1 Bromochloromethane ND ug/L 08/03/16 15:25 74-97-55.0 1 Bromodichloromethane ND ug/L 08/03/16 15:25 75-27-45.0 1 Bromoform ND ug/L 08/03/16 15:25 75-25-25.0 1 Bromomethane ND ug/L 08/03/16 15:25 74-83-95.0 1 2-Butanone (MEK)ND ug/L 08/03/16 15:25 78-93-325.0 1 n-Butylbenzene ND ug/L 08/03/16 15:25 104-51-85.0 1 sec-Butylbenzene ND ug/L 08/03/16 15:25 135-98-85.0 1 tert-Butylbenzene ND ug/L 08/03/16 15:25 98-06-65.0 1 Carbon disulfide ND ug/L 08/03/16 15:25 75-15-010.0 1 Carbon tetrachloride ND ug/L 08/03/16 15:25 56-23-55.0 1 Chlorobenzene ND ug/L 08/03/16 15:25 108-90-75.0 1 Chloroethane ND ug/L 08/03/16 15:25 75-00-35.0 1 Chloroform ND ug/L 08/03/16 15:25 67-66-35.0 1 Chloromethane ND ug/L 08/03/16 15:25 74-87-35.0 1 2-Chlorotoluene ND ug/L 08/03/16 15:25 95-49-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 32 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-TB Lab ID:50150369010 Collected:07/22/16 08:00 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV 4-Chlorotoluene ND ug/L 08/03/16 15:25 106-43-45.0 1 Dibromochloromethane ND ug/L 08/03/16 15:25 124-48-15.0 1 1,2-Dibromoethane (EDB)ND ug/L 08/03/16 15:25 106-93-45.0 1 Dibromomethane ND ug/L 08/03/16 15:25 74-95-35.0 1 1,2-Dichlorobenzene ND ug/L 08/03/16 15:25 95-50-15.0 1 1,3-Dichlorobenzene ND ug/L 08/03/16 15:25 541-73-15.0 1 1,4-Dichlorobenzene ND ug/L 08/03/16 15:25 106-46-75.0 1 trans-1,4-Dichloro-2-butene ND ug/L 08/03/16 15:25 110-57-61001 Dichlorodifluoromethane ND ug/L 08/03/16 15:25 75-71-85.0 1 1,1-Dichloroethane ND ug/L 08/03/16 15:25 75-34-35.0 1 1,2-Dichloroethane ND ug/L 08/03/16 15:25 107-06-25.0 1 1,1-Dichloroethene ND ug/L 08/03/16 15:25 75-35-45.0 1 cis-1,2-Dichloroethene ND ug/L 08/03/16 15:25 156-59-25.0 1 trans-1,2-Dichloroethene ND ug/L 08/03/16 15:25 156-60-55.0 1 1,2-Dichloropropane ND ug/L 08/03/16 15:25 78-87-55.0 1 1,3-Dichloropropane ND ug/L 08/03/16 15:25 142-28-95.0 1 2,2-Dichloropropane ND ug/L 08/03/16 15:25 594-20-75.0 1 1,1-Dichloropropene ND ug/L 08/03/16 15:25 563-58-65.0 1 cis-1,3-Dichloropropene ND ug/L 08/03/16 15:25 10061-01-55.0 1 trans-1,3-Dichloropropene ND ug/L 08/03/16 15:25 10061-02-65.0 1 Ethylbenzene ND ug/L 08/03/16 15:25 100-41-45.0 1 Ethyl methacrylate ND ug/L 08/03/16 15:25 97-63-21001 Hexachloro-1,3-butadiene ND ug/L 08/03/16 15:25 87-68-35.0 1 n-Hexane ND ug/L 08/03/16 15:25 110-54-35.0 1 2-Hexanone ND ug/L 08/03/16 15:25 591-78-625.0 1 Iodomethane ND ug/L 08/03/16 15:25 74-88-410.0 1 Isopropylbenzene (Cumene)ND ug/L 08/03/16 15:25 98-82-85.0 1 p-Isopropyltoluene ND ug/L 08/03/16 15:25 99-87-65.0 1 Methylene Chloride ND ug/L 08/03/16 15:25 75-09-25.0 1 4-Methyl-2-pentanone (MIBK)ND ug/L 08/03/16 15:25 108-10-125.0 1 Methyl-tert-butyl ether ND ug/L 08/03/16 15:25 1634-04-44.0 1 Naphthalene ND ug/L 08/03/16 15:25 91-20-35.0 1 n-Propylbenzene ND ug/L 08/03/16 15:25 103-65-15.0 1 Styrene ND ug/L 08/03/16 15:25 100-42-55.0 1 1,1,1,2-Tetrachloroethane ND ug/L 08/03/16 15:25 630-20-65.0 1 1,1,2,2-Tetrachloroethane ND ug/L 08/03/16 15:25 79-34-55.0 1 Tetrachloroethene ND ug/L 08/03/16 15:25 127-18-45.0 1 Toluene ND ug/L 08/03/16 15:25 108-88-35.0 1 1,2,3-Trichlorobenzene ND ug/L 08/03/16 15:25 87-61-65.0 1 1,2,4-Trichlorobenzene ND ug/L 08/03/16 15:25 120-82-15.0 1 1,1,1-Trichloroethane ND ug/L 08/03/16 15:25 71-55-65.0 1 1,1,2-Trichloroethane ND ug/L 08/03/16 15:25 79-00-55.0 1 Trichloroethene ND ug/L 08/03/16 15:25 79-01-65.0 1 Trichlorofluoromethane ND ug/L 08/03/16 15:25 75-69-45.0 1 1,2,3-Trichloropropane ND ug/L 08/03/16 15:25 96-18-45.0 1 1,2,4-Trimethylbenzene ND ug/L 08/03/16 15:25 95-63-65.0 1 1,3,5-Trimethylbenzene ND ug/L 08/03/16 15:25 108-67-85.0 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 33 of 64 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Sample:KM-GW-TB Lab ID:50150369010 Collected:07/22/16 08:00 Received:07/23/16 08:50 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit Analytical Method: EPA 82608260 MSV Vinyl acetate ND ug/L 08/03/16 15:25 108-05-450.0 1 Vinyl chloride ND ug/L 08/03/16 15:25 75-01-42.0 1 Xylene (Total)ND ug/L 08/03/16 15:25 1330-20-710.0 1 Surrogates Dibromofluoromethane (S)100 %.08/03/16 15:25 1868-53-784-118 1 4-Bromofluorobenzene (S)97 %.08/03/16 15:25 460-00-479-116 1 Toluene-d8 (S)98 %.08/03/16 15:25 2037-26-586-110 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 34 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343795 EPA 3010 EPA 6010 6010 MET Associated Lab Samples:50150369001, 50150369002, 50150369003, 50150369004, 50150369005, 50150369006, 50150369007, 50150369008, 50150369009, 50150369010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1592054 Associated Lab Samples:50150369001, 50150369002, 50150369003, 50150369004, 50150369005, 50150369006, 50150369007, 50150369008, 50150369009, 50150369010 Matrix:Water Analyzed Lead ug/L ND 10.0 07/29/16 01:43 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1592055LABORATORY CONTROL SAMPLE: LCSSpike Lead ug/L 10001000 100 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1592056MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150369008 1592057 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Lead ug/L 1000 95 75-12593 2 201000ND951930 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 35 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344899 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50150369001, 50150369002, 50150369003, 50150369004, 50150369005, 50150369006, 50150369007, 50150369008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596531 Associated Lab Samples:50150369001, 50150369002, 50150369003, 50150369004, 50150369005, 50150369006, 50150369007, 50150369008 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/02/16 14:26 1,1,1-Trichloroethane ug/L ND 5.0 08/02/16 14:26 1,1,2,2-Tetrachloroethane ug/L ND 5.0 08/02/16 14:26 1,1,2-Trichloroethane ug/L ND 5.0 08/02/16 14:26 1,1-Dichloroethane ug/L ND 5.0 08/02/16 14:26 1,1-Dichloroethene ug/L ND 5.0 08/02/16 14:26 1,1-Dichloropropene ug/L ND 5.0 08/02/16 14:26 1,2,3-Trichlorobenzene ug/L ND 5.0 08/02/16 14:26 1,2,3-Trichloropropane ug/L ND 5.0 08/02/16 14:26 1,2,4-Trichlorobenzene ug/L ND 5.0 08/02/16 14:26 1,2,4-Trimethylbenzene ug/L ND 5.0 08/02/16 14:26 1,2-Dibromoethane (EDB)ug/L ND 5.0 08/02/16 14:26 1,2-Dichlorobenzene ug/L ND 5.0 08/02/16 14:26 1,2-Dichloroethane ug/L ND 5.0 08/02/16 14:26 1,2-Dichloropropane ug/L ND 5.0 08/02/16 14:26 1,3,5-Trimethylbenzene ug/L ND 5.0 08/02/16 14:26 1,3-Dichlorobenzene ug/L ND 5.0 08/02/16 14:26 1,3-Dichloropropane ug/L ND 5.0 08/02/16 14:26 1,4-Dichlorobenzene ug/L ND 5.0 08/02/16 14:26 2,2-Dichloropropane ug/L ND 5.0 08/02/16 14:26 2-Butanone (MEK)ug/L ND 25.0 08/02/16 14:26 2-Chlorotoluene ug/L ND 5.0 08/02/16 14:26 2-Hexanone ug/L ND 25.0 08/02/16 14:26 4-Chlorotoluene ug/L ND 5.0 08/02/16 14:26 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 08/02/16 14:26 Acetone ug/L ND 100 08/02/16 14:26 Acrolein ug/L ND 50.0 08/02/16 14:26 Acrylonitrile ug/L ND 100 08/02/16 14:26 Benzene ug/L ND 5.0 08/02/16 14:26 Bromobenzene ug/L ND 5.0 08/02/16 14:26 Bromochloromethane ug/L ND 5.0 08/02/16 14:26 Bromodichloromethane ug/L ND 5.0 08/02/16 14:26 Bromoform ug/L ND 5.0 08/02/16 14:26 Bromomethane ug/L ND 5.0 08/02/16 14:26 Carbon disulfide ug/L ND 10.0 08/02/16 14:26 Carbon tetrachloride ug/L ND 5.0 08/02/16 14:26 Chlorobenzene ug/L ND 5.0 08/02/16 14:26 Chloroethane ug/L ND 5.0 08/02/16 14:26 Chloroform ug/L ND 5.0 08/02/16 14:26 Chloromethane ug/L ND 5.0 08/02/16 14:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 36 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596531 Associated Lab Samples:50150369001, 50150369002, 50150369003, 50150369004, 50150369005, 50150369006, 50150369007, 50150369008 Matrix:Water Analyzed cis-1,2-Dichloroethene ug/L ND 5.0 08/02/16 14:26 cis-1,3-Dichloropropene ug/L ND 5.0 08/02/16 14:26 Dibromochloromethane ug/L ND 5.0 08/02/16 14:26 Dibromomethane ug/L ND 5.0 08/02/16 14:26 Dichlorodifluoromethane ug/L ND 5.0 08/02/16 14:26 Ethyl methacrylate ug/L ND 100 08/02/16 14:26 Ethylbenzene ug/L ND 5.0 08/02/16 14:26 Hexachloro-1,3-butadiene ug/L ND 5.0 08/02/16 14:26 Iodomethane ug/L ND 10.0 08/02/16 14:26 Isopropylbenzene (Cumene)ug/L ND 5.0 08/02/16 14:26 Methyl-tert-butyl ether ug/L ND 4.0 08/02/16 14:26 Methylene Chloride ug/L ND 5.0 08/02/16 14:26 n-Butylbenzene ug/L ND 5.0 08/02/16 14:26 n-Hexane ug/L ND 5.0 08/02/16 14:26 n-Propylbenzene ug/L ND 5.0 08/02/16 14:26 Naphthalene ug/L ND 5.0 08/02/16 14:26 p-Isopropyltoluene ug/L ND 5.0 08/02/16 14:26 sec-Butylbenzene ug/L ND 5.0 08/02/16 14:26 Styrene ug/L ND 5.0 08/02/16 14:26 tert-Butylbenzene ug/L ND 5.0 08/02/16 14:26 Tetrachloroethene ug/L ND 5.0 08/02/16 14:26 Toluene ug/L ND 5.0 08/02/16 14:26 trans-1,2-Dichloroethene ug/L ND 5.0 08/02/16 14:26 trans-1,3-Dichloropropene ug/L ND 5.0 08/02/16 14:26 trans-1,4-Dichloro-2-butene ug/L ND 100 08/02/16 14:26 Trichloroethene ug/L ND 5.0 08/02/16 14:26 Trichlorofluoromethane ug/L ND 5.0 08/02/16 14:26 Vinyl acetate ug/L ND 50.0 08/02/16 14:26 Vinyl chloride ug/L ND 2.0 08/02/16 14:26 Xylene (Total)ug/L ND 10.0 08/02/16 14:26 4-Bromofluorobenzene (S)%.95 79-116 08/02/16 14:26 Dibromofluoromethane (S)%.102 84-118 08/02/16 14:26 Toluene-d8 (S)%.96 86-110 08/02/16 14:26 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596532LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.550 101 74-130 1,1,1-Trichloroethane ug/L 57.350 115 72-123 1,1,2,2-Tetrachloroethane ug/L 49.750 99 72-124 1,1,2-Trichloroethane ug/L 51.750 103 75-125 1,1-Dichloroethane ug/L 53.950 108 70-120 1,1-Dichloroethene ug/L 56.750 113 69-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 37 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596532LABORATORY CONTROL SAMPLE: LCSSpike 1,1-Dichloropropene ug/L 51.550 103 81-129 1,2,3-Trichlorobenzene ug/L 46.550 93 71-130 1,2,3-Trichloropropane ug/L 52.550 105 77-127 1,2,4-Trichlorobenzene ug/L 47.150 94 66-126 1,2,4-Trimethylbenzene ug/L 54.750 109 73-125 1,2-Dibromoethane (EDB)ug/L 54.150 108 76-125 1,2-Dichlorobenzene ug/L 49.850 100 77-122 1,2-Dichloroethane ug/L 52.650 105 70-123 1,2-Dichloropropane ug/L 56.850 114 77-124 1,3,5-Trimethylbenzene ug/L 53.650 107 75-124 1,3-Dichlorobenzene ug/L 52.050 104 76-124 1,3-Dichloropropane ug/L 53.150 106 77-123 1,4-Dichlorobenzene ug/L 53.550 107 75-117 2,2-Dichloropropane ug/L 55.850 112 44-147 2-Butanone (MEK)ug/L 230250 92 60-135 2-Chlorotoluene ug/L 50.250 100 75-124 2-Hexanone ug/L 241250 96 65-139 4-Chlorotoluene ug/L 53.950 108 75-124 4-Methyl-2-pentanone (MIBK)ug/L 233250 93 66-134 Acetone ug/L 231250 93 47-144 Acrolein ug/L 11901000 119 31-200 Acrylonitrile ug/L 201200 100 64-133 Benzene ug/L 52.950 106 76-122 Bromobenzene ug/L 51.350 103 75-117 Bromochloromethane ug/L 57.450 115 74-134 Bromodichloromethane ug/L 54.050 108 71-124 Bromoform ug/L 43.250 86 60-125 Bromomethane ug/L 47.050 94 23-194 Carbon disulfide ug/L 52.050 104 63-130 Carbon tetrachloride ug/L 59.550 119 73-133 Chlorobenzene ug/L 52.550 105 76-118 Chloroethane ug/L 47.650 95 50-147 Chloroform ug/L 51.150 102 70-119 Chloromethane ug/L 41.750 83 52-136 cis-1,2-Dichloroethene ug/L 57.550 115 74-120 cis-1,3-Dichloropropene ug/L 53.850 108 71-134 Dibromochloromethane ug/L 49.850 100 73-127 Dibromomethane ug/L 51.250 102 75-124 Dichlorodifluoromethane ug/L 44.950 90 39-166 Ethyl methacrylate ug/L 212200 106 73-136 Ethylbenzene ug/L 55.750 111 75-123 Hexachloro-1,3-butadiene ug/L 49.750 99 70-125 Iodomethane ug/L 96.8100 97 56-142 Isopropylbenzene (Cumene)ug/L 54.350 109 84-134 Methyl-tert-butyl ether ug/L 53.850 108 65-131 Methylene Chloride ug/L 45.350 91 66-130 n-Butylbenzene ug/L 44.850 90 70-127 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 38 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596532LABORATORY CONTROL SAMPLE: LCSSpike n-Hexane ug/L 51.050 102 64-131 n-Propylbenzene ug/L 54.550 109 78-131 Naphthalene ug/L 50.950 102 65-134 p-Isopropyltoluene ug/L 54.250 108 75-124 sec-Butylbenzene ug/L 54.650 109 83-135 Styrene ug/L 51.350 103 78-128 tert-Butylbenzene ug/L 39.850 80 62-114 Tetrachloroethene ug/L 55.650 111 69-119 Toluene ug/L 48.250 96 74-122 trans-1,2-Dichloroethene ug/L 58.850 118 72-122 trans-1,3-Dichloropropene ug/L 53.450 107 66-135 trans-1,4-Dichloro-2-butene ug/L 170200 85 39-153 Trichloroethene ug/L 54.750 109 75-123 Trichlorofluoromethane ug/L 50.050 100 58-148 Vinyl acetate ug/L 211200 105 67-154 Vinyl chloride ug/L 46.250 92 61-147 Xylene (Total)ug/L 164150 109 75-127 4-Bromofluorobenzene (S)%.98 79-116 Dibromofluoromethane (S)%.98 84-118 Toluene-d8 (S)%.99 86-110 Parameter Units MS Result % Rec Limits Qual% RecConc. 1596533MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150369008 1596534 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1,1,1,2-Tetrachloroethane ug/L 50 92 44-14284 9 2050ND46.0 42.2 1,1,1-Trichloroethane ug/L 50 109 51-140101 8 2050ND54.6 50.3 1,1,2,2-Tetrachloroethane ug/L 50 88 49-13882 8 2050ND44.1 40.8 1,1,2-Trichloroethane ug/L 50 92 51-13884 9 2050ND46.1 42.0 1,1-Dichloroethane ug/L 50 101 48-13796 5 2050ND50.7 48.1 1,1-Dichloroethene ug/L 50 112 51-144105 6 2050ND55.9 52.6 1,1-Dichloropropene ug/L 50 99 54-15090 10 2050ND49.3 44.8 1,2,3-Trichlorobenzene ug/L 50 80 32-14076 4 2050ND39.9 38.1 1,2,3-Trichloropropane ug/L 50 94 51-13985 10 2050ND46.8 42.5 1,2,4-Trichlorobenzene ug/L 50 82 27-13476 8 2050ND40.8 37.8 1,2,4-Trimethylbenzene ug/L 50 97 32-14391 6 2050ND48.7 45.7 1,2-Dibromoethane (EDB)ug/L 50 102 52-13493 9 2050ND50.8 46.4 1,2-Dichlorobenzene ug/L 50 89 38-13884 6 2050ND44.3 41.8 1,2-Dichloroethane ug/L 50 99 44-14493 7 2050ND49.5 46.4 1,2-Dichloropropane ug/L 50 107 56-138101 7 2050ND53.7 50.3 1,3,5-Trimethylbenzene ug/L 50 95 28-14688 8 2050ND47.4 43.8 1,3-Dichlorobenzene ug/L 50 94 36-13988 6 2050ND46.9 44.0 1,3-Dichloropropane ug/L 50 97 54-13787 11 2050ND48.7 43.7 1,4-Dichlorobenzene ug/L 50 95 34-13491 4 2050ND47.3 45.4 2,2-Dichloropropane ug/L 50 91 20-14285 7 2050ND45.4 42.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 39 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596533MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150369008 1596534 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 2-Butanone (MEK)ug/L 250 83 44-14278 7 20250ND208194 2-Chlorotoluene ug/L 50 93 36-14387 7 2050ND46.5 43.3 2-Hexanone ug/L 250 87 43-15079 9 20250ND218199 4-Chlorotoluene ug/L 50 97 34-14391 7 2050ND48.7 45.5 4-Methyl-2-pentanone (MIBK) ug/L 250 84 46-14376 11 20250ND211190 Acetone ug/L 250 81 33-15078 4 20250ND203195 Acrolein ug/L 1000 102 32-20096 6 201000ND1020963 Acrylonitrile ug/L 200 92 47-14387 5 20200ND183174 Benzene ug/L 50 101 51-14094 7 2050ND50.5 47.0 Bromobenzene ug/L 50 95 41-13487 8 2050ND47.4 43.7 Bromochloromethane ug/L 50 106 53-148101 5 2050ND52.9 50.4 Bromodichloromethane ug/L 50 101 46-13792 9 2050ND50.5 45.9 Bromoform ug/L 50 78 36-12772 7 2050ND38.9 36.2 Bromomethane ug/L 50 85 10-188101 17 2050ND42.6 50.4 Carbon disulfide ug/L 50 104 35-14896 8 2050ND51.9 47.8 Carbon tetrachloride ug/L 50 115 45-151105 10 2050ND57.7 52.5 Chlorobenzene ug/L 50 99 45-13892 8 2050ND49.5 45.8 Chloroethane ug/L 50 92 33-16487 6 2050ND46.2 43.5 Chloroform ug/L 50 98 50-13591 7 2050ND48.8 45.5 Chloromethane ug/L 50 79 38-14676 4 2050ND39.5 37.9 cis-1,2-Dichloroethene ug/L 50 109 43-144102 6 2050ND54.4 51.1 cis-1,3-Dichloropropene ug/L 50 96 42-13689 8 2050ND48.2 44.5 Dibromochloromethane ug/L 50 91 45-13685 7 2050ND45.5 42.5 Dibromomethane ug/L 50 92 51-13987 5 2050ND46.1 43.7 Dichlorodifluoromethane ug/L 50 93 29-17485 10 2050ND46.7 42.4 Ethyl methacrylate ug/L 200 97 44-15089 9 20200ND194178 Ethylbenzene ug/L 50 107 36-14694 13 2050ND53.5 47.1 Hexachloro-1,3-butadiene ug/L 50 90 14-15084 6 2050ND44.8 42.1 Iodomethane ug/L 100 93 28-15391 2 20100ND92.9 91.1 Isopropylbenzene (Cumene)ug/L 50 103 43-15993 10 2050ND51.4 46.5 Methyl-tert-butyl ether ug/L 50 99 43-14694 6 2050ND49.7 47.0 Methylene Chloride ug/L 50 85 48-14079 7 2050ND42.5 39.6 n-Butylbenzene ug/L 50 79 16-15274 6 2050ND39.3 37.0 n-Hexane ug/L 50 95 40-14490 6 2050ND47.5 44.9 n-Propylbenzene ug/L 50 97 28-15790 8 2050ND48.6 45.0 Naphthalene ug/L 50 87 38-14183 5 2050ND43.4 41.5 p-Isopropyltoluene ug/L 50 97 21-15191 7 2050ND48.6 45.4 sec-Butylbenzene ug/L 50 98 27-16592 7 2050ND49.0 45.9 Styrene ug/L 50 93 31-14889 5 2050ND46.7 44.4 tert-Butylbenzene ug/L 50 74 24-13169 7 2050ND37.0 34.5 Tetrachloroethene ug/L 50 106 38-13997 9 2050ND52.9 48.4 Toluene ug/L 50 89 44-14082 8 2050ND44.9 41.6 trans-1,2-Dichloroethene ug/L 50 114 50-139108 6 2050ND57.1 54.0 trans-1,3-Dichloropropene ug/L 50 98 37-13888 10 2050ND48.8 44.0 trans-1,4-Dichloro-2-butene ug/L 200 75 10-15767 12 20200ND150133 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 40 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1596533MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150369008 1596534 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Trichloroethene ug/L 50 105 44-14699 6 2050ND52.5 49.5 Trichlorofluoromethane ug/L 50 106 41-16496 9 2050ND52.8 48.1 Vinyl acetate ug/L 200 81 15-14671 13 20200ND161141 Vinyl chloride ug/L 50 92 43-16687 5 2050ND46.2 43.7 Xylene (Total)ug/L 150 104 35-14693 11 20150ND156140 4-Bromofluorobenzene (S)%.101 79-11698 Dibromofluoromethane (S)%.100 84-118101 Toluene-d8 (S)%.98 86-110101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 41 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 344947 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50150369009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596713 Associated Lab Samples:50150369009 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/03/16 02:27 1,1,1-Trichloroethane ug/L ND 5.0 08/03/16 02:27 1,1,2,2-Tetrachloroethane ug/L ND 5.0 08/03/16 02:27 1,1,2-Trichloroethane ug/L ND 5.0 08/03/16 02:27 1,1-Dichloroethane ug/L ND 5.0 08/03/16 02:27 1,1-Dichloroethene ug/L ND 5.0 08/03/16 02:27 1,1-Dichloropropene ug/L ND 5.0 08/03/16 02:27 1,2,3-Trichlorobenzene ug/L ND 5.0 08/03/16 02:27 1,2,3-Trichloropropane ug/L ND 5.0 08/03/16 02:27 1,2,4-Trichlorobenzene ug/L ND 5.0 08/03/16 02:27 1,2,4-Trimethylbenzene ug/L ND 5.0 08/03/16 02:27 1,2-Dibromoethane (EDB)ug/L ND 5.0 08/03/16 02:27 1,2-Dichlorobenzene ug/L ND 5.0 08/03/16 02:27 1,2-Dichloroethane ug/L ND 5.0 08/03/16 02:27 1,2-Dichloropropane ug/L ND 5.0 08/03/16 02:27 1,3,5-Trimethylbenzene ug/L ND 5.0 08/03/16 02:27 1,3-Dichlorobenzene ug/L ND 5.0 08/03/16 02:27 1,3-Dichloropropane ug/L ND 5.0 08/03/16 02:27 1,4-Dichlorobenzene ug/L ND 5.0 08/03/16 02:27 2,2-Dichloropropane ug/L ND 5.0 08/03/16 02:27 2-Butanone (MEK)ug/L ND 25.0 08/03/16 02:27 2-Chlorotoluene ug/L ND 5.0 08/03/16 02:27 2-Hexanone ug/L ND 25.0 08/03/16 02:27 4-Chlorotoluene ug/L ND 5.0 08/03/16 02:27 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 08/03/16 02:27 Acetone ug/L ND 100 08/03/16 02:27 Acrolein ug/L ND 50.0 08/03/16 02:27 Acrylonitrile ug/L ND 100 08/03/16 02:27 Benzene ug/L ND 5.0 08/03/16 02:27 Bromobenzene ug/L ND 5.0 08/03/16 02:27 Bromochloromethane ug/L ND 5.0 08/03/16 02:27 Bromodichloromethane ug/L ND 5.0 08/03/16 02:27 Bromoform ug/L ND 5.0 08/03/16 02:27 Bromomethane ug/L ND 5.0 08/03/16 02:27 Carbon disulfide ug/L ND 10.0 08/03/16 02:27 Carbon tetrachloride ug/L ND 5.0 08/03/16 02:27 Chlorobenzene ug/L ND 5.0 08/03/16 02:27 Chloroethane ug/L ND 5.0 08/03/16 02:27 Chloroform ug/L ND 5.0 08/03/16 02:27 Chloromethane ug/L ND 5.0 08/03/16 02:27 cis-1,2-Dichloroethene ug/L ND 5.0 08/03/16 02:27 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 42 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1596713 Associated Lab Samples:50150369009 Matrix:Water Analyzed cis-1,3-Dichloropropene ug/L ND 5.0 08/03/16 02:27 Dibromochloromethane ug/L ND 5.0 08/03/16 02:27 Dibromomethane ug/L ND 5.0 08/03/16 02:27 Dichlorodifluoromethane ug/L ND 5.0 08/03/16 02:27 Ethyl methacrylate ug/L ND 100 08/03/16 02:27 Ethylbenzene ug/L ND 5.0 08/03/16 02:27 Hexachloro-1,3-butadiene ug/L ND 5.0 08/03/16 02:27 Iodomethane ug/L ND 10.0 08/03/16 02:27 Isopropylbenzene (Cumene)ug/L ND 5.0 08/03/16 02:27 Methyl-tert-butyl ether ug/L ND 4.0 08/03/16 02:27 Methylene Chloride ug/L ND 5.0 08/03/16 02:27 n-Butylbenzene ug/L ND 5.0 08/03/16 02:27 n-Hexane ug/L ND 5.0 08/03/16 02:27 n-Propylbenzene ug/L ND 5.0 08/03/16 02:27 Naphthalene ug/L ND 5.0 08/03/16 02:27 p-Isopropyltoluene ug/L ND 5.0 08/03/16 02:27 sec-Butylbenzene ug/L ND 5.0 08/03/16 02:27 Styrene ug/L ND 5.0 08/03/16 02:27 tert-Butylbenzene ug/L ND 5.0 08/03/16 02:27 Tetrachloroethene ug/L ND 5.0 08/03/16 02:27 Toluene ug/L ND 5.0 08/03/16 02:27 trans-1,2-Dichloroethene ug/L ND 5.0 08/03/16 02:27 trans-1,3-Dichloropropene ug/L ND 5.0 08/03/16 02:27 trans-1,4-Dichloro-2-butene ug/L ND 100 08/03/16 02:27 Trichloroethene ug/L ND 5.0 08/03/16 02:27 Trichlorofluoromethane ug/L ND 5.0 08/03/16 02:27 Vinyl acetate ug/L ND 50.0 08/03/16 02:27 Vinyl chloride ug/L ND 2.0 08/03/16 02:27 Xylene (Total)ug/L ND 10.0 08/03/16 02:27 4-Bromofluorobenzene (S)%.97 79-116 08/03/16 02:27 Dibromofluoromethane (S)%.100 84-118 08/03/16 02:27 Toluene-d8 (S)%.97 86-110 08/03/16 02:27 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596714LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 50.050 100 74-130 1,1,1-Trichloroethane ug/L 57.450 115 72-123 1,1,2,2-Tetrachloroethane ug/L 49.950 100 72-124 1,1,2-Trichloroethane ug/L 49.950 100 75-125 1,1-Dichloroethane ug/L 55.650 111 70-120 1,1-Dichloroethene ug/L 58.950 118 69-127 1,1-Dichloropropene ug/L 54.250 108 81-129 1,2,3-Trichlorobenzene ug/L 46.850 94 71-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 43 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596714LABORATORY CONTROL SAMPLE: LCSSpike 1,2,3-Trichloropropane ug/L 53.250 106 77-127 1,2,4-Trichlorobenzene ug/L 46.650 93 66-126 1,2,4-Trimethylbenzene ug/L 55.150 110 73-125 1,2-Dibromoethane (EDB)ug/L 54.750 109 76-125 1,2-Dichlorobenzene ug/L 50.250 100 77-122 1,2-Dichloroethane ug/L 53.650 107 70-123 1,2-Dichloropropane ug/L 59.850 120 77-124 1,3,5-Trimethylbenzene ug/L 52.950 106 75-124 1,3-Dichlorobenzene ug/L 53.050 106 76-124 1,3-Dichloropropane ug/L 51.550 103 77-123 1,4-Dichlorobenzene ug/L 52.850 106 75-117 2,2-Dichloropropane ug/L 43.950 88 44-147 2-Butanone (MEK)ug/L 230250 92 60-135 2-Chlorotoluene ug/L 50.650 101 75-124 2-Hexanone ug/L 238250 95 65-139 4-Chlorotoluene ug/L 53.450 107 75-124 4-Methyl-2-pentanone (MIBK)ug/L 234250 93 66-134 Acetone ug/L 235250 94 47-144 Acrolein ug/L 11501000 115 31-200 Acrylonitrile ug/L 209200 104 64-133 Benzene ug/L 54.450 109 76-122 Bromobenzene ug/L 51.250 102 75-117 Bromochloromethane ug/L 59.950 120 74-134 Bromodichloromethane ug/L 55.250 110 71-124 Bromoform ug/L 43.650 87 60-125 Bromomethane ug/L 60.050 120 23-194 Carbon disulfide ug/L 54.150 108 63-130 Carbon tetrachloride ug/L 60.850 122 73-133 Chlorobenzene ug/L 53.250 106 76-118 Chloroethane ug/L 50.150 100 50-147 Chloroform ug/L 52.250 104 70-119 Chloromethane ug/L 42.850 86 52-136 cis-1,2-Dichloroethene ug/L 59.150 118 74-120 cis-1,3-Dichloropropene ug/L 51.150 102 71-134 Dibromochloromethane ug/L 50.850 102 73-127 Dibromomethane ug/L 52.050 104 75-124 Dichlorodifluoromethane ug/L 47.250 94 39-166 Ethyl methacrylate ug/L 205200 102 73-136 Ethylbenzene ug/L 55.750 111 75-123 Hexachloro-1,3-butadiene ug/L 49.850 100 70-125 Iodomethane ug/L 107100 107 56-142 Isopropylbenzene (Cumene)ug/L 53.850 108 84-134 Methyl-tert-butyl ether ug/L 55.950 112 65-131 Methylene Chloride ug/L 47.350 95 66-130 n-Butylbenzene ug/L 43.850 88 70-127 n-Hexane ug/L 49.050 98 64-131 n-Propylbenzene ug/L 54.050 108 78-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 44 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1596714LABORATORY CONTROL SAMPLE: LCSSpike Naphthalene ug/L 50.250 100 65-134 p-Isopropyltoluene ug/L 54.850 110 75-124 sec-Butylbenzene ug/L 53.750 107 83-135 Styrene ug/L 51.750 103 78-128 tert-Butylbenzene ug/L 45.750 91 62-114 Tetrachloroethene ug/L 57.550 115 69-119 Toluene ug/L 48.650 97 74-122 trans-1,2-Dichloroethene ug/L 62.0 L05012472-122 trans-1,3-Dichloropropene ug/L 51.550 103 66-135 trans-1,4-Dichloro-2-butene ug/L 159200 79 39-153 Trichloroethene ug/L 56.550 113 75-123 Trichlorofluoromethane ug/L 54.950 110 58-148 Vinyl acetate ug/L 204200 102 67-154 Vinyl chloride ug/L 49.550 99 61-147 Xylene (Total)ug/L 163150 109 75-127 4-Bromofluorobenzene (S)%.96 79-116 Dibromofluoromethane (S)%.99 84-118 Toluene-d8 (S)%.101 86-110 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1596716MATRIX SPIKE SAMPLE: MSSpike Result 50150445004 1,1,1,2-Tetrachloroethane ug/L 48.050 96 44-142ND 1,1,1-Trichloroethane ug/L 53.050 106 51-140ND 1,1,2,2-Tetrachloroethane ug/L 48.650 97 49-138ND 1,1,2-Trichloroethane ug/L 50.050 100 51-138ND 1,1-Dichloroethane ug/L 54.950 110 48-137ND 1,1-Dichloroethene ug/L 52.150 104 51-144ND 1,1-Dichloropropene ug/L 44.050 88 54-150ND 1,2,3-Trichlorobenzene ug/L 41.450 83 32-140ND 1,2,3-Trichloropropane ug/L 50.850 102 51-139ND 1,2,4-Trichlorobenzene ug/L 40.350 81 27-134ND 1,2,4-Trimethylbenzene ug/L 11250 85 32-14369.3 1,2-Dibromoethane (EDB)ug/L 55.050 110 52-134ND 1,2-Dichlorobenzene ug/L 44.350 89 38-138ND 1,2-Dichloroethane ug/L 54.250 108 44-144ND 1,2-Dichloropropane ug/L 57.950 116 56-138ND 1,3,5-Trimethylbenzene ug/L 69.050 80 28-14628.9 1,3-Dichlorobenzene ug/L 44.650 89 36-139ND 1,3-Dichloropropane ug/L 53.050 106 54-137ND 1,4-Dichlorobenzene ug/L 46.150 92 34-134ND 2,2-Dichloropropane ug/L 35.850 72 20-142ND 2-Butanone (MEK)ug/L 243250 97 44-142ND 2-Chlorotoluene ug/L 45.250 90 36-143ND 2-Hexanone ug/L 242250 97 43-150ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 45 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1596716MATRIX SPIKE SAMPLE: MSSpike Result 50150445004 4-Chlorotoluene ug/L 43.650 87 34-143ND 4-Methyl-2-pentanone (MIBK)ug/L 235250 94 46-143ND Acetone ug/L 239250 96 33-150ND Acrolein ug/L 10501000 105 32-200ND Acrylonitrile ug/L 211200 106 47-143ND Benzene ug/L 52.250 104 51-140ND Bromobenzene ug/L 46.250 92 41-134ND Bromochloromethane ug/L 58.050 116 53-148ND Bromodichloromethane ug/L 55.050 110 46-137ND Bromoform ug/L 40.850 82 36-127ND Bromomethane ug/L 49.750 99 10-188ND Carbon disulfide ug/L 47.550 95 35-148ND Carbon tetrachloride ug/L 50.750 101 45-151ND Chlorobenzene ug/L 48.050 96 45-138ND Chloroethane ug/L 48.850 98 33-164ND Chloroform ug/L 51.950 104 50-135ND Chloromethane ug/L 42.850 86 38-146ND cis-1,2-Dichloroethene ug/L 59.550 119 43-144ND cis-1,3-Dichloropropene ug/L 47.850 96 42-136ND Dibromochloromethane ug/L 47.850 96 45-136ND Dibromomethane ug/L 51.650 103 51-139ND Dichlorodifluoromethane ug/L 33.350 67 29-174ND Ethyl methacrylate ug/L 210200 105 44-150ND Ethylbenzene ug/L 45.650 91 36-146ND Hexachloro-1,3-butadiene ug/L 32.750 65 14-150ND Iodomethane ug/L 104100 104 28-153ND Isopropylbenzene (Cumene)ug/L 43.250 86 43-159ND Methyl-tert-butyl ether ug/L 56.650 113 43-146ND Methylene Chloride ug/L 47.250 94 48-140ND n-Butylbenzene ug/L 37.350 59 16-1527.7 n-Hexane ug/L 33.050 66 40-144ND n-Propylbenzene ug/L 45.250 81 28-157ND Naphthalene ug/L 46.750 92 38-141ND p-Isopropyltoluene ug/L 43.350 82 21-151ND sec-Butylbenzene ug/L 40.550 77 27-165ND Styrene ug/L 46.550 93 31-148ND tert-Butylbenzene ug/L 30.450 61 24-131ND Tetrachloroethene ug/L 43.150 86 38-139ND Toluene ug/L 42.350 83 44-140ND trans-1,2-Dichloroethene ug/L 56.650 113 50-139ND trans-1,3-Dichloropropene ug/L 47.950 96 37-138ND trans-1,4-Dichloro-2-butene ug/L 147200 74 10-157ND Trichloroethene ug/L 50.050 100 44-146ND Trichlorofluoromethane ug/L 44.050 88 41-164ND Vinyl acetate ug/L 133200 67 15-146ND Vinyl chloride ug/L 45.450 91 43-166ND Xylene (Total)ug/L 138150 92 35-146ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 46 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1596716MATRIX SPIKE SAMPLE: MSSpike Result 50150445004 4-Bromofluorobenzene (S)%.96 79-116 Dibromofluoromethane (S)%.98 84-118 Toluene-d8 (S)%.99 86-110 Parameter Units Dup Result Max RPD QualifiersRPDResult 50150445003 1596715SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 20ND 1,1,1-Trichloroethane ug/L ND 20ND 1,1,2,2-Tetrachloroethane ug/L ND 20ND 1,1,2-Trichloroethane ug/L ND 20ND 1,1-Dichloroethane ug/L ND 20ND 1,1-Dichloroethene ug/L ND 20ND 1,1-Dichloropropene ug/L ND 20ND 1,2,3-Trichlorobenzene ug/L ND 20ND 1,2,3-Trichloropropane ug/L ND 20ND 1,2,4-Trichlorobenzene ug/L ND 20ND 1,2,4-Trimethylbenzene ug/L 12.6 4 2013.1 1,2-Dibromoethane (EDB)ug/L ND 20ND 1,2-Dichlorobenzene ug/L ND 20ND 1,2-Dichloroethane ug/L ND 20ND 1,2-Dichloropropane ug/L ND 20ND 1,3,5-Trimethylbenzene ug/L .6J 20ND 1,3-Dichlorobenzene ug/L ND 20ND 1,3-Dichloropropane ug/L ND 20ND 1,4-Dichlorobenzene ug/L ND 20ND 2,2-Dichloropropane ug/L ND 20ND 2-Butanone (MEK)ug/L ND 20ND 2-Chlorotoluene ug/L ND 20ND 2-Hexanone ug/L ND 20ND 4-Chlorotoluene ug/L ND 20ND 4-Methyl-2-pentanone (MIBK)ug/L ND 20ND Acetone ug/L ND 20ND Acrolein ug/L ND 20ND Acrylonitrile ug/L ND 20ND Benzene ug/L ND 20ND Bromobenzene ug/L ND 20ND Bromochloromethane ug/L ND 20ND Bromodichloromethane ug/L ND 20ND Bromoform ug/L ND 20ND Bromomethane ug/L ND 20ND Carbon disulfide ug/L ND 20ND Carbon tetrachloride ug/L ND 20ND Chlorobenzene ug/L ND 20ND Chloroethane ug/L ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 47 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 50150445003 1596715SAMPLE DUPLICATE: Chloroform ug/L ND 20ND Chloromethane ug/L ND 20ND cis-1,2-Dichloroethene ug/L ND 20ND cis-1,3-Dichloropropene ug/L ND 20ND Dibromochloromethane ug/L ND 20ND Dibromomethane ug/L ND 20ND Dichlorodifluoromethane ug/L ND 20ND Ethyl methacrylate ug/L ND 20ND Ethylbenzene ug/L ND 20ND Hexachloro-1,3-butadiene ug/L ND 20ND Iodomethane ug/L ND 20ND Isopropylbenzene (Cumene)ug/L ND 20ND Methyl-tert-butyl ether ug/L ND 20ND Methylene Chloride ug/L ND 20ND n-Butylbenzene ug/L 5.5 5 205.8 n-Hexane ug/L ND 20ND n-Propylbenzene ug/L 1.8J 20ND Naphthalene ug/L 3.8J 20ND p-Isopropyltoluene ug/L 2.1J 20ND sec-Butylbenzene ug/L 1.7J 20ND Styrene ug/L ND 20ND tert-Butylbenzene ug/L ND 20ND Tetrachloroethene ug/L ND 20ND Toluene ug/L .58J 20ND trans-1,2-Dichloroethene ug/L ND 20ND trans-1,3-Dichloropropene ug/L ND 20ND trans-1,4-Dichloro-2-butene ug/L ND 20ND Trichloroethene ug/L ND 20ND Trichlorofluoromethane ug/L ND 20ND Vinyl acetate ug/L ND 20ND Vinyl chloride ug/L ND 20ND Xylene (Total)ug/L ND 20ND 4-Bromofluorobenzene (S)%.97 399 Dibromofluoromethane (S)%.103 2102 Toluene-d8 (S)%.98 296 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 48 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 345154 EPA 8260 EPA 8260 8260 MSV Associated Lab Samples:50150369010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1597615 Associated Lab Samples:50150369010 Matrix:Water Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/03/16 14:15 1,1,1-Trichloroethane ug/L ND 5.0 08/03/16 14:15 1,1,2,2-Tetrachloroethane ug/L ND 5.0 08/03/16 14:15 1,1,2-Trichloroethane ug/L ND 5.0 08/03/16 14:15 1,1-Dichloroethane ug/L ND 5.0 08/03/16 14:15 1,1-Dichloroethene ug/L ND 5.0 08/03/16 14:15 1,1-Dichloropropene ug/L ND 5.0 08/03/16 14:15 1,2,3-Trichlorobenzene ug/L ND 5.0 08/03/16 14:15 1,2,3-Trichloropropane ug/L ND 5.0 08/03/16 14:15 1,2,4-Trichlorobenzene ug/L ND 5.0 08/03/16 14:15 1,2,4-Trimethylbenzene ug/L ND 5.0 08/03/16 14:15 1,2-Dibromoethane (EDB)ug/L ND 5.0 08/03/16 14:15 1,2-Dichlorobenzene ug/L ND 5.0 08/03/16 14:15 1,2-Dichloroethane ug/L ND 5.0 08/03/16 14:15 1,2-Dichloropropane ug/L ND 5.0 08/03/16 14:15 1,3,5-Trimethylbenzene ug/L ND 5.0 08/03/16 14:15 1,3-Dichlorobenzene ug/L ND 5.0 08/03/16 14:15 1,3-Dichloropropane ug/L ND 5.0 08/03/16 14:15 1,4-Dichlorobenzene ug/L ND 5.0 08/03/16 14:15 2,2-Dichloropropane ug/L ND 5.0 08/03/16 14:15 2-Butanone (MEK)ug/L ND 25.0 08/03/16 14:15 2-Chlorotoluene ug/L ND 5.0 08/03/16 14:15 2-Hexanone ug/L ND 25.0 08/03/16 14:15 4-Chlorotoluene ug/L ND 5.0 08/03/16 14:15 4-Methyl-2-pentanone (MIBK)ug/L ND 25.0 08/03/16 14:15 Acetone ug/L ND 100 08/03/16 14:15 Acrolein ug/L ND 50.0 08/03/16 14:15 Acrylonitrile ug/L ND 100 08/03/16 14:15 Benzene ug/L ND 5.0 08/03/16 14:15 Bromobenzene ug/L ND 5.0 08/03/16 14:15 Bromochloromethane ug/L ND 5.0 08/03/16 14:15 Bromodichloromethane ug/L ND 5.0 08/03/16 14:15 Bromoform ug/L ND 5.0 08/03/16 14:15 Bromomethane ug/L ND 5.0 08/03/16 14:15 Carbon disulfide ug/L ND 10.0 08/03/16 14:15 Carbon tetrachloride ug/L ND 5.0 08/03/16 14:15 Chlorobenzene ug/L ND 5.0 08/03/16 14:15 Chloroethane ug/L ND 5.0 08/03/16 14:15 Chloroform ug/L ND 5.0 08/03/16 14:15 Chloromethane ug/L ND 5.0 08/03/16 14:15 cis-1,2-Dichloroethene ug/L ND 5.0 08/03/16 14:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 49 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1597615 Associated Lab Samples:50150369010 Matrix:Water Analyzed cis-1,3-Dichloropropene ug/L ND 5.0 08/03/16 14:15 Dibromochloromethane ug/L ND 5.0 08/03/16 14:15 Dibromomethane ug/L ND 5.0 08/03/16 14:15 Dichlorodifluoromethane ug/L ND 5.0 08/03/16 14:15 Ethyl methacrylate ug/L ND 100 08/03/16 14:15 Ethylbenzene ug/L ND 5.0 08/03/16 14:15 Hexachloro-1,3-butadiene ug/L ND 5.0 08/03/16 14:15 Iodomethane ug/L ND 10.0 08/03/16 14:15 Isopropylbenzene (Cumene)ug/L ND 5.0 08/03/16 14:15 Methyl-tert-butyl ether ug/L ND 4.0 08/03/16 14:15 Methylene Chloride ug/L ND 5.0 08/03/16 14:15 n-Butylbenzene ug/L ND 5.0 08/03/16 14:15 n-Hexane ug/L ND 5.0 08/03/16 14:15 n-Propylbenzene ug/L ND 5.0 08/03/16 14:15 Naphthalene ug/L ND 5.0 08/03/16 14:15 p-Isopropyltoluene ug/L ND 5.0 08/03/16 14:15 sec-Butylbenzene ug/L ND 5.0 08/03/16 14:15 Styrene ug/L ND 5.0 08/03/16 14:15 tert-Butylbenzene ug/L ND 5.0 08/03/16 14:15 Tetrachloroethene ug/L ND 5.0 08/03/16 14:15 Toluene ug/L ND 5.0 08/03/16 14:15 trans-1,2-Dichloroethene ug/L ND 5.0 08/03/16 14:15 trans-1,3-Dichloropropene ug/L ND 5.0 08/03/16 14:15 trans-1,4-Dichloro-2-butene ug/L ND 100 08/03/16 14:15 Trichloroethene ug/L ND 5.0 08/03/16 14:15 Trichlorofluoromethane ug/L ND 5.0 08/03/16 14:15 Vinyl acetate ug/L ND 50.0 08/03/16 14:15 Vinyl chloride ug/L ND 2.0 08/03/16 14:15 Xylene (Total)ug/L ND 10.0 08/03/16 14:15 4-Bromofluorobenzene (S)%.97 79-116 08/03/16 14:15 Dibromofluoromethane (S)%.102 84-118 08/03/16 14:15 Toluene-d8 (S)%.99 86-110 08/03/16 14:15 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1597616LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 53.250 106 74-130 1,1,1-Trichloroethane ug/L 54.050 108 72-123 1,1,2,2-Tetrachloroethane ug/L 53.450 107 72-124 1,1,2-Trichloroethane ug/L 52.750 105 75-125 1,1-Dichloroethane ug/L 53.450 107 70-120 1,1-Dichloroethene ug/L 56.150 112 69-127 1,1-Dichloropropene ug/L 57.450 115 81-129 1,2,3-Trichlorobenzene ug/L 57.450 115 71-130 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 50 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1597616LABORATORY CONTROL SAMPLE: LCSSpike 1,2,3-Trichloropropane ug/L 54.550 109 77-127 1,2,4-Trichlorobenzene ug/L 57.550 115 66-126 1,2,4-Trimethylbenzene ug/L 53.450 107 73-125 1,2-Dibromoethane (EDB)ug/L 55.150 110 76-125 1,2-Dichlorobenzene ug/L 52.350 105 77-122 1,2-Dichloroethane ug/L 52.350 105 70-123 1,2-Dichloropropane ug/L 53.350 107 77-124 1,3,5-Trimethylbenzene ug/L 54.350 109 75-124 1,3-Dichlorobenzene ug/L 53.950 108 76-124 1,3-Dichloropropane ug/L 54.650 109 77-123 1,4-Dichlorobenzene ug/L 53.750 107 75-117 2,2-Dichloropropane ug/L 53.750 107 44-147 2-Butanone (MEK)ug/L 218250 87 60-135 2-Chlorotoluene ug/L 52.450 105 75-124 2-Hexanone ug/L 229250 91 65-139 4-Chlorotoluene ug/L 58.150 116 75-124 4-Methyl-2-pentanone (MIBK)ug/L 222250 89 66-134 Acetone ug/L 256250 102 47-144 Acrolein ug/L 12301000 123 31-200 Acrylonitrile ug/L 211200 106 64-133 Benzene ug/L 53.150 106 76-122 Bromobenzene ug/L 53.750 107 75-117 Bromochloromethane ug/L 55.250 110 74-134 Bromodichloromethane ug/L 51.350 103 71-124 Bromoform ug/L 48.850 98 60-125 Bromomethane ug/L 53.450 107 23-194 Carbon disulfide ug/L 46.050 92 63-130 Carbon tetrachloride ug/L 54.350 109 73-133 Chlorobenzene ug/L 51.550 103 76-118 Chloroethane ug/L 45.750 91 50-147 Chloroform ug/L 52.250 104 70-119 Chloromethane ug/L 39.450 79 52-136 cis-1,2-Dichloroethene ug/L 55.450 111 74-120 cis-1,3-Dichloropropene ug/L 53.250 106 71-134 Dibromochloromethane ug/L 54.150 108 73-127 Dibromomethane ug/L 55.250 110 75-124 Dichlorodifluoromethane ug/L 43.850 88 39-166 Ethyl methacrylate ug/L 207200 103 73-136 Ethylbenzene ug/L 54.750 109 75-123 Hexachloro-1,3-butadiene ug/L 57.850 116 70-125 Iodomethane ug/L 104100 104 56-142 Isopropylbenzene (Cumene)ug/L 53.050 106 84-134 Methyl-tert-butyl ether ug/L 53.850 108 65-131 Methylene Chloride ug/L 45.750 91 66-130 n-Butylbenzene ug/L 52.350 105 70-127 n-Hexane ug/L 53.850 108 64-131 n-Propylbenzene ug/L 55.850 112 78-131 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 51 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1597616LABORATORY CONTROL SAMPLE: LCSSpike Naphthalene ug/L 53.550 107 65-134 p-Isopropyltoluene ug/L 53.150 106 75-124 sec-Butylbenzene ug/L 54.650 109 83-135 Styrene ug/L 53.250 106 78-128 tert-Butylbenzene ug/L 45.650 91 62-114 Tetrachloroethene ug/L 55.850 112 69-119 Toluene ug/L 47.650 95 74-122 trans-1,2-Dichloroethene ug/L 54.850 110 72-122 trans-1,3-Dichloropropene ug/L 52.350 105 66-135 trans-1,4-Dichloro-2-butene ug/L 157200 79 39-153 Trichloroethene ug/L 54.650 109 75-123 Trichlorofluoromethane ug/L 48.650 97 58-148 Vinyl acetate ug/L 186200 93 67-154 Vinyl chloride ug/L 45.250 90 61-147 Xylene (Total)ug/L 160150 107 75-127 4-Bromofluorobenzene (S)%.100 79-116 Dibromofluoromethane (S)%.99 84-118 Toluene-d8 (S)%.98 86-110 Parameter Units Dup Result Max RPD QualifiersRPDResult 50150808001 1597617SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 20ND 1,1,1-Trichloroethane ug/L ND 20ND 1,1,2,2-Tetrachloroethane ug/L ND 20ND 1,1,2-Trichloroethane ug/L ND 20ND 1,1-Dichloroethane ug/L ND 20ND 1,1-Dichloroethene ug/L ND 20ND 1,1-Dichloropropene ug/L ND 20ND 1,2,3-Trichlorobenzene ug/L ND 20ND 1,2,3-Trichloropropane ug/L ND 20ND 1,2,4-Trichlorobenzene ug/L ND 20ND 1,2,4-Trimethylbenzene ug/L ND 20ND 1,2-Dibromoethane (EDB)ug/L ND 20ND 1,2-Dichlorobenzene ug/L ND 20ND 1,2-Dichloroethane ug/L ND 20ND 1,2-Dichloropropane ug/L ND 20ND 1,3,5-Trimethylbenzene ug/L ND 20ND 1,3-Dichlorobenzene ug/L ND 20ND 1,3-Dichloropropane ug/L ND 20ND 1,4-Dichlorobenzene ug/L ND 20ND 2,2-Dichloropropane ug/L ND 20ND 2-Butanone (MEK)ug/L ND 20ND 2-Chlorotoluene ug/L ND 20ND 2-Hexanone ug/L ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 52 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 50150808001 1597617SAMPLE DUPLICATE: 4-Chlorotoluene ug/L ND 20ND 4-Methyl-2-pentanone (MIBK)ug/L ND 20ND Acetone ug/L ND 20ND Acrolein ug/L ND 20ND Acrylonitrile ug/L ND 20ND Benzene ug/L ND 20ND Bromobenzene ug/L ND 20ND Bromochloromethane ug/L ND 20ND Bromodichloromethane ug/L ND 20ND Bromoform ug/L ND 20ND Bromomethane ug/L ND 20ND Carbon disulfide ug/L ND 20ND Carbon tetrachloride ug/L ND 20ND Chlorobenzene ug/L ND 20ND Chloroethane ug/L ND 20ND Chloroform ug/L ND 20ND Chloromethane ug/L ND 20ND cis-1,2-Dichloroethene ug/L ND 20ND cis-1,3-Dichloropropene ug/L ND 20ND Dibromochloromethane ug/L ND 20ND Dibromomethane ug/L ND 20ND Dichlorodifluoromethane ug/L ND 20ND Ethyl methacrylate ug/L ND 20ND Ethylbenzene ug/L ND 20ND Hexachloro-1,3-butadiene ug/L ND 20ND Iodomethane ug/L ND 20ND Isopropylbenzene (Cumene)ug/L ND 20ND Methyl-tert-butyl ether ug/L ND 20ND Methylene Chloride ug/L ND 20ND n-Butylbenzene ug/L ND 20ND n-Hexane ug/L ND 20ND n-Propylbenzene ug/L ND 20ND Naphthalene ug/L ND 20ND p-Isopropyltoluene ug/L ND 20ND sec-Butylbenzene ug/L ND 20ND Styrene ug/L ND 20ND tert-Butylbenzene ug/L ND 20ND Tetrachloroethene ug/L ND 20ND Toluene ug/L ND 20ND trans-1,2-Dichloroethene ug/L ND 20ND trans-1,3-Dichloropropene ug/L ND 20ND trans-1,4-Dichloro-2-butene ug/L ND 20ND Trichloroethene ug/L ND 20ND Trichlorofluoromethane ug/L ND 20ND Vinyl acetate ug/L ND 20ND Vinyl chloride ug/L ND 20ND Xylene (Total)ug/L ND 20ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 53 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 50150808001 1597617SAMPLE DUPLICATE: 4-Bromofluorobenzene (S)%.99 199 Dibromofluoromethane (S)%.101 0102 Toluene-d8 (S)%.98 2100 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 54 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343475 EPA 3510 EPA 8270 by SIM LVE 8270 Water PAH LV by SIM MSSV Associated Lab Samples:50150369001, 50150369002, 50150369003, 50150369004, 50150369005, 50150369006 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1591017 Associated Lab Samples:50150369001, 50150369002, 50150369003, 50150369004, 50150369005, 50150369006 Matrix:Water Analyzed 1-Methylnaphthalene ug/L ND 1.0 N207/25/16 20:12 2-Methylnaphthalene ug/L ND 1.0 07/25/16 20:12 Acenaphthene ug/L ND 1.0 07/25/16 20:12 Acenaphthylene ug/L ND 1.0 07/25/16 20:12 Anthracene ug/L ND 0.10 07/25/16 20:12 Benzo(a)anthracene ug/L ND 0.10 07/25/16 20:12 Benzo(a)pyrene ug/L ND 0.10 07/25/16 20:12 Benzo(b)fluoranthene ug/L ND 0.10 07/25/16 20:12 Benzo(g,h,i)perylene ug/L ND 0.10 07/25/16 20:12 Benzo(k)fluoranthene ug/L ND 0.10 07/25/16 20:12 Chrysene ug/L ND 0.50 07/25/16 20:12 Dibenz(a,h)anthracene ug/L ND 0.10 07/25/16 20:12 Fluoranthene ug/L ND 1.0 07/25/16 20:12 Fluorene ug/L ND 1.0 07/25/16 20:12 Indeno(1,2,3-cd)pyrene ug/L ND 0.10 07/25/16 20:12 Naphthalene ug/L ND 1.0 07/25/16 20:12 Phenanthrene ug/L ND 1.0 07/25/16 20:12 Pyrene ug/L ND 1.0 07/25/16 20:12 2-Fluorobiphenyl (S)%.52 18-117 07/25/16 20:12 p-Terphenyl-d14 (S)%.66 10-112 07/25/16 20:12 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591018LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene ug/L 4.0 N2104035-115 2-Methylnaphthalene ug/L 3.910 39 25-120 Acenaphthene ug/L 4.710 47 37-129 Acenaphthylene ug/L 5.310 53 36-139 Anthracene ug/L 7.010 70 43-147 Benzo(a)anthracene ug/L 6.910 69 49-149 Benzo(a)pyrene ug/L 6.310 63 28-150 Benzo(b)fluoranthene ug/L 5.410 54 35-147 Benzo(g,h,i)perylene ug/L 5.610 56 15-133 Benzo(k)fluoranthene ug/L 6.610 66 24-149 Chrysene ug/L 6.810 68 45-139 Dibenz(a,h)anthracene ug/L 5.410 54 14-139 Fluoranthene ug/L 6.710 67 46-166 Fluorene ug/L 5.310 53 38-138 Indeno(1,2,3-cd)pyrene ug/L 5.610 56 17-139 Naphthalene ug/L 4.810 48 29-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 55 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591018LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene ug/L 6.410 64 48-145 Pyrene ug/L 7.010 70 48-152 2-Fluorobiphenyl (S)%.50 18-117 p-Terphenyl-d14 (S)%.62 10-112 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591019MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50149955027 1591020 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2,R1102416-12129 21 2010ND2.4 2.9 2-Methylnaphthalene ug/L 10 23 11-12227 15 2010ND2.3 2.7 Acenaphthene ug/L R1103114-13738 21 2010ND3.1 3.8 Acenaphthylene ug/L 10 39 17-14145 15 2010ND3.9 4.5 Anthracene ug/L R1105522-14569 23 2010ND5.5 6.9 Benzo(a)anthracene ug/L 10 59 16-12869 16 2010ND5.9 6.9 Benzo(a)pyrene ug/L R1105410-9767 22 2010ND5.4 6.7 Benzo(b)fluoranthene ug/L R1104810-10363 27 2010ND4.8 6.3 Benzo(g,h,i)perylene ug/L R1104710-7058 22 2010ND4.7 5.8 Benzo(k)fluoranthene ug/L 10 56 10-9568 19 2010ND5.6 6.8 Chrysene ug/L 10 61 15-11874 20 2010ND6.1 7.4 Dibenz(a,h)anthracene ug/L R1104510-7357 23 2010ND4.5 5.7 Fluoranthene ug/L 10 59 24-15970 17 2010ND5.9 7.0 Fluorene ug/L 10 40 19-14047 17 2010ND4.0 4.7 Indeno(1,2,3-cd)pyrene ug/L R1104710-7458 22 2010ND4.7 5.8 Naphthalene ug/L 10 30 10-13236 20 2010ND3.1 3.7 Phenanthrene ug/L 10 54 31-14163 14 2010ND5.4 6.3 Pyrene ug/L 10 61 29-14472 17 2010ND6.1 7.2 2-Fluorobiphenyl (S)%.39 18-11745 p-Terphenyl-d14 (S)%.50 10-11262 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 56 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 343476 EPA 3510 EPA 8270 by SIM LVE 8270 Water PAH LV by SIM MSSV Associated Lab Samples:50150369007, 50150369008, 50150369009, 50150369010 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1591021 Associated Lab Samples:50150369007, 50150369008, 50150369009, 50150369010 Matrix:Water Analyzed 1-Methylnaphthalene ug/L ND 1.0 N207/26/16 08:12 2-Methylnaphthalene ug/L ND 1.0 07/26/16 08:12 Acenaphthene ug/L ND 1.0 07/26/16 08:12 Acenaphthylene ug/L ND 1.0 07/26/16 08:12 Anthracene ug/L ND 0.10 07/26/16 08:12 Benzo(a)anthracene ug/L ND 0.10 07/26/16 08:12 Benzo(a)pyrene ug/L ND 0.10 07/26/16 08:12 Benzo(b)fluoranthene ug/L ND 0.10 07/26/16 08:12 Benzo(g,h,i)perylene ug/L ND 0.10 07/26/16 08:12 Benzo(k)fluoranthene ug/L ND 0.10 07/26/16 08:12 Chrysene ug/L ND 0.50 07/26/16 08:12 Dibenz(a,h)anthracene ug/L ND 0.10 07/26/16 08:12 Fluoranthene ug/L ND 1.0 07/26/16 08:12 Fluorene ug/L ND 1.0 07/26/16 08:12 Indeno(1,2,3-cd)pyrene ug/L ND 0.10 07/26/16 08:12 Naphthalene ug/L ND 1.0 07/26/16 08:12 Phenanthrene ug/L ND 1.0 07/26/16 08:12 Pyrene ug/L ND 1.0 07/26/16 08:12 2-Fluorobiphenyl (S)%.49 18-117 07/26/16 08:12 p-Terphenyl-d14 (S)%.57 10-112 07/26/16 08:12 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591022LABORATORY CONTROL SAMPLE: LCSSpike 1-Methylnaphthalene ug/L 4.5 N2104535-115 2-Methylnaphthalene ug/L 4.210 42 25-120 Acenaphthene ug/L 5.410 54 37-129 Acenaphthylene ug/L 6.010 60 36-139 Anthracene ug/L 6.910 69 43-147 Benzo(a)anthracene ug/L 7.410 74 49-149 Benzo(a)pyrene ug/L 6.910 69 28-150 Benzo(b)fluoranthene ug/L 6.310 63 35-147 Benzo(g,h,i)perylene ug/L 5.910 59 15-133 Benzo(k)fluoranthene ug/L 6.810 68 24-149 Chrysene ug/L 7.510 75 45-139 Dibenz(a,h)anthracene ug/L 5.810 58 14-139 Fluoranthene ug/L 7.210 72 46-166 Fluorene ug/L 6.210 62 38-138 Indeno(1,2,3-cd)pyrene ug/L 5.910 59 17-139 Naphthalene ug/L 4.910 49 29-120 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 57 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1591022LABORATORY CONTROL SAMPLE: LCSSpike Phenanthrene ug/L 7.210 72 48-145 Pyrene ug/L 7.610 76 48-152 2-Fluorobiphenyl (S)%.54 18-117 p-Terphenyl-d14 (S)%.66 10-112 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591023MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150268006 1591024 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2102116-12123 7 2010ND2.1 2.3 2-Methylnaphthalene ug/L 10 21 11-12222 4 2010ND2.1 2.2 Acenaphthene ug/L 10 29 14-13731 8 2010ND2.9 3.1 Acenaphthylene ug/L 10 34 17-14137 7 2010ND3.4 3.7 Anthracene ug/L 10 47 22-14554 14 2010ND4.7 5.4 Benzo(a)anthracene ug/L 10 54 16-12858 9 2010ND5.4 5.8 Benzo(a)pyrene ug/L 10 50 10-9755 10 2010ND5.0 5.5 Benzo(b)fluoranthene ug/L 10 46 10-10356 19 2010ND4.6 5.6 Benzo(g,h,i)perylene ug/L 10 40 10-7045 13 2010ND4.0 4.5 Benzo(k)fluoranthene ug/L 10 48 10-9551 5 2010ND4.8 5.1 Chrysene ug/L 10 54 15-11858 7 2010ND5.4 5.8 Dibenz(a,h)anthracene ug/L 10 41 10-7345 8 2010ND4.1 4.5 Fluoranthene ug/L 10 50 24-15960 17 2010ND5.0 6.0 Fluorene ug/L 10 36 19-14041 11 2010ND3.6 4.1 Indeno(1,2,3-cd)pyrene ug/L 10 42 10-7447 10 2010ND4.2 4.7 Naphthalene ug/L 10 26 10-13228 9 2010ND2.6 2.8 Phenanthrene ug/L 10 47 31-14155 15 2010ND4.7 5.5 Pyrene ug/L 10 51 29-14456 10 2010ND5.1 5.6 2-Fluorobiphenyl (S)%.34 18-11740 p-Terphenyl-d14 (S)%.43 10-11248 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591025MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150340002 1591026 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2102416-12128 15 2010<0.057 2.4 2.8 2-Methylnaphthalene ug/L 10 23 11-12227 16 2010<0.065 2.3 2.7 Acenaphthene ug/L 10 33 14-13738 14 2010<0.072 3.3 3.8 Acenaphthylene ug/L 10 38 17-14144 16 2010<0.069 3.8 4.4 Anthracene ug/L 10 49 22-14560 20 2010<0.057 4.9 6.0 Benzo(a)anthracene ug/L 10 57 16-12866 15 2010<0.056 5.7 6.6 Benzo(a)pyrene ug/L 10 53 10-9761 14 2010<0.038 5.3 6.1 Benzo(b)fluoranthene ug/L 10 49 10-10352 6 2010<0.061 4.9 5.2 Benzo(g,h,i)perylene ug/L 10 44 10-7052 18 2010<0.036 4.4 5.2 Benzo(k)fluoranthene ug/L R1105210-9567 25 2010<0.031 5.2 6.7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 58 of 64 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1591025MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150340002 1591026 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Chrysene ug/L 10 58 15-11866 13 2010<0.061 5.8 6.6 Dibenz(a,h)anthracene ug/L 10 45 10-7351 14 2010<0.040 4.5 5.1 Fluoranthene ug/L 10 55 24-15964 14 2010<0.076 5.5 6.4 Fluorene ug/L 10 40 19-14046 14 2010<0.067 4.0 4.6 Indeno(1,2,3-cd)pyrene ug/L 10 45 10-7453 17 2010<0.035 4.5 5.3 Naphthalene ug/L 10 29 10-13234 16 2010<0.078 2.9 3.4 Phenanthrene ug/L 10 51 31-14160 16 2010<0.11 5.1 6.0 Pyrene ug/L 10 55 29-14465 16 2010<0.069 5.5 6.5 2-Fluorobiphenyl (S)%.38 18-11744 p-Terphenyl-d14 (S)%.50 10-11255 Parameter Units MS Result % Rec Limits Qual% RecConc. 1591027MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 50150369008 1591028 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. 1-Methylnaphthalene ug/L N2102216-12125 12 2010ND2.2 2.5 2-Methylnaphthalene ug/L 10 21 11-12224 15 2010ND2.1 2.4 Acenaphthene ug/L 10 30 14-13733 10 2010ND3.0 3.3 Acenaphthylene ug/L 10 35 17-14139 10 2010ND3.5 3.9 Anthracene ug/L 10 54 22-14559 8 2010ND5.4 5.9 Benzo(a)anthracene ug/L 10 60 16-12866 9 2010ND6.0 6.6 Benzo(a)pyrene ug/L 10 58 10-9762 7 2010ND5.8 6.2 Benzo(b)fluoranthene ug/L 10 49 10-10359 19 2010ND4.9 5.9 Benzo(g,h,i)perylene ug/L 10 49 10-7054 11 2010ND4.9 5.4 Benzo(k)fluoranthene ug/L 10 62 10-9560 3 2010ND6.2 6.0 Chrysene ug/L 10 62 15-11868 10 2010ND6.2 6.8 Dibenz(a,h)anthracene ug/L 10 46 10-7353 13 2010ND4.6 5.3 Fluoranthene ug/L 10 62 24-15965 4 2010ND6.2 6.5 Fluorene ug/L 10 39 19-14042 9 2010ND3.9 4.2 Indeno(1,2,3-cd)pyrene ug/L 10 48 10-7454 11 2010ND4.8 5.4 Naphthalene ug/L 10 28 10-13231 10 2010ND2.8 3.1 Phenanthrene ug/L 10 54 31-14158 7 2010ND5.4 5.8 Pyrene ug/L 10 60 29-14466 10 2010ND6.0 6.6 2-Fluorobiphenyl (S)%.38 18-11741 p-Terphenyl-d14 (S)%.53 10-11254 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 59 of 64 #=QL# QUALIFIERS Pace Project No.: Project: 50150369 4850 W Western Ave South Bend DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - IndianapolisPASI-I ANALYTE QUALIFIERS Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0 Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in associated samples. Results unaffected by high bias.L3 The lab does not hold TNI accreditation for this parameter.N2 RPD value was outside control limits.R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. Not NELAP Accredited 4860 Blazer Parkway Dublin, OH 43017 (614)486-5421 Page 60 of 64 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 50150369 4850 W Western Ave South Bend Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 50150369001 343795 344297KM-GW-SB-1 EPA 3010 EPA 6010 50150369002 343795 344297KM-GW-SB-2 EPA 3010 EPA 6010 50150369003 343795 344297KM-GW-SB-3 EPA 3010 EPA 6010 50150369004 343795 344297KM-GW-SB-4 EPA 3010 EPA 6010 50150369005 343795 344297KM-GW-SB-5 EPA 3010 EPA 6010 50150369006 343795 344297KM-GW-SB-6 EPA 3010 EPA 6010 50150369007 343795 344297KM-GW-SB-7 EPA 3010 EPA 6010 50150369008 343795 344297KM-GW-FD-1 EPA 3010 EPA 6010 50150369009 343795 344297KM-GW-ERB EPA 3010 EPA 6010 50150369010 343795 344297KM-GW-TB EPA 3010 EPA 6010 50150369001 343475 343575KM-GW-SB-1 EPA 3510 EPA 8270 by SIM LVE 50150369002 343475 343575KM-GW-SB-2 EPA 3510 EPA 8270 by SIM LVE 50150369003 343475 343575KM-GW-SB-3 EPA 3510 EPA 8270 by SIM LVE 50150369004 343475 343575KM-GW-SB-4 EPA 3510 EPA 8270 by SIM LVE 50150369005 343475 343575KM-GW-SB-5 EPA 3510 EPA 8270 by SIM LVE 50150369006 343475 343575KM-GW-SB-6 EPA 3510 EPA 8270 by SIM LVE 50150369007 343476 343582KM-GW-SB-7 EPA 3510 EPA 8270 by SIM LVE 50150369008 343476 343582KM-GW-FD-1 EPA 3510 EPA 8270 by SIM LVE 50150369009 343476 343582KM-GW-ERB EPA 3510 EPA 8270 by SIM LVE 50150369010 343476 343582KM-GW-TB EPA 3510 EPA 8270 by SIM LVE 50150369001 344899KM-GW-SB-1 EPA 8260 50150369002 344899KM-GW-SB-2 EPA 8260 50150369003 344899KM-GW-SB-3 EPA 8260 50150369004 344899KM-GW-SB-4 EPA 8260 50150369005 344899KM-GW-SB-5 EPA 8260 50150369006 344899KM-GW-SB-6 EPA 8260 50150369007 344899KM-GW-SB-7 EPA 8260 50150369008 344899KM-GW-FD-1 EPA 8260 50150369009 344947KM-GW-ERB EPA 8260 50150369010 345154KM-GW-TB EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, Inc..Date: 08/05/2016 11:27 AM Pace Analytical Services, Inc. 7726 Moller Road Indianapolis, IN 46268 (317)228-3100 Pace Analytical Services, Inc. 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